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Search results for: ORGANIC PHOTOVOLTAIC DEVICES
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Highly efficient organic electrophosphorescent light-emitting diodes with a reduced quantum efficiency roll off at large current densities.
PublicationW pracy opisano diody elektrofosforescencyjne zbudowane na bazie organicznych komplesów platyny PtOEP oraz Pt(thpy)2. Pokazano, ze mechanizmem ograniczjącym wydajność świecenia tych diod w zakresiedużych prądów elektycznych jest elektrycznopolowa dysocjacja ekscytonutrypletowego z transferem dziury na molekułę TPD.
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Bioactive hybrid metal-organic framework (MOF)-based nanosensors for optical detection of recombinant SARS-CoV-2 spike antigen
PublicationFast, efficient, and accurate detection of SARS-CoV-2 spike antigen is pivotal to control the spread and reduce themortality of COVID-19. Nevertheless, the sensitivity of available nanobiosensors to detect recombinant SARS-CoV-2 spike antigen seems insufficient. As a proof-of-concept, MOF-5/CoNi2S4 is developed as a low-cost, safe, and bioactive hybrid nanostructure via the one-pot high-gravity protocol. Then, the porphyrin, H2TMP,...
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Biocomposites from recycled resources as candidates for laboratory reference material to validate analytical tools used in organic compounds emissions investigation
PublicationA suitably chosen reference material should meet specific criteria like representing one of the compound classes most commonly occurring in indoor materials as well as having optimal long-term stability during storage and transport to its destination point and having a compact size. The described interdisciplinary pilot research was aimed to develop and characterize a polymer-based candidate for the laboratory reference material...
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New heterometallic Co/Zn, Ag/Co, and Ag/Zn imidazolates: structural characterization and catalytic activity in the oxidation of organic compounds
PublicationNanocrystalline powders of monometallic and bimetallic imidazolates of Co, Zn, and Ag were produced by a reaction carried out in water. The powders were characterized by powder X-ray diffraction and the crystal structures of new compounds Ag2ZnIm4 and Ag2CoIm4 (Im = imidazolate) were solved. Heterometallic Co/Zn imidazolates showed the standard ZIF-8 crystal structure while Ag/Zn and Ag/Co systems were isostructural with the copper...
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Fabrication and photoactivity of ionic liquid–TiO2 structures for efficient visible-light-induced photocatalytic decomposition of organic pollutants in aqueous phase
PublicationTo investigate the effect of the ionic liquid (IL) chain length on the surface properties and photoactivity of TiO2, a series of TiO2 microspheres have been synthesized via a solvothermal method assisted by 1-methyl-3-octadecylimidazolium chloride ([ODMIM][Cl]) and 1-methyl-3-tetradecylimidazolium chloride ([TDMIM][Cl]). All as-prepared samples were characterized by X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy...
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Synergistic catalysis of Fe3O4/CuO bimetallic catalyst derived from Prussian blue analogues for the efficient decomposition of various organic pollutants
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Development of headspace-gas chromatography-flame ionization detection procedure to determine volatile fatty acids in zoo organic waste leachate
PublicationNadrzędnym celem pracy było opracowanie metodyki oznaczania lotnych kwasów tłuszczowych z fazy nadpowierzchniowej opartej na chromatografii gazowej z detektorem płomieniowo-jonizacyjnym oraz sprawdzenie jej przydatności w analizie próbek odcieku ze składowiska odpadów ogrodu zoologicznego. Na podstawie przeprowadzonych badań określono warunki, w jakich przebiegać powinna izolacja lotnych kwasów tłuszczowych, a także określono najlepsze...
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Converting real-world mixed waste plastics into porous carbon nanosheets with excellent performance in the adsorption of an organic dye from wastewater
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Direct QSPR: the most efficient way of predicting organic carbon/water partition coefficient (log K OC) for polyhalogenated POPs
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Selective Photocatalytic Oxidation of 4-Methoxybenzyl Alcohol to p-Anisaldehyde in Organic-Free Water in a Continuous Annular Fixed Bed Reactor
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Electronic nose as a tool for differentiation of volatile organic compounds = Elektroniczny nos jako instrument do rozróżniania lotnych związków organicznych
PublicationW pracy porównano dwie metody analizy zapachów lotnych związków organicznych: klasyczną analizę opartą na percepcji ludzkiego węchu i technikę elektronicznego nosa. W przeprowadzonych badaniach za pomocą klasycznej analizy brało udział 8 ochotników w okresie 2 tygodni. Do instrumentalnej metody analizy zapachu wykorzystano zaprojektowany przez autorów prototypowy 6-cio czujnikowy elektroniczny nos. Przeprowadzone badania z wykorzystaniem...
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Efficient synthesis of PMMA@Co0.5Ni0.5Fe2O4 organic-inorganic hybrids containing hyamine 1622 – Physicochemical properties, cytotoxic assessment and antimicrobial activity
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Synthesis of Micro-Spikes and Herringbones Structures by Femtosecond Laser Pulses on a Titanium Plate—A New Material for Water Organic Pollutants Degradation
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Thermally induced formation of zinc oxide nanostructures with tailoring morphology during metal organic framework (MOF-5) carbonization process
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Volatile organic pollutants in the Odra river - sources. Lotne związki organiczne obecne w wodach rzeki Odry - próba identyfikacji.
PublicationPrzedstawiono wyniki oznaczania i identyfikacji lotnych związków organicznych obecnych w wodach Odry. Próbki do analiz pobierano w ramach Międzynarodowego Programu Odra. W badaniach wykorzystano zestaw do jednoczesnego wymywania i wychwytywania analitów na stałym sorbencie (Purge and Trap)Oznaczenia końcowe wykonano z wykorzystaniem techniki chromatografii gazowej połączonej ze spektrometrem mas. W wodach zidentyfikowano szeroką...
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Differentiation of the concentration of heavy metals and persistent organic pollutants in lake sediments depending on the catchment management (Lake Gopło case study)
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Recent Developments in the Synthesis of Unsymmetrical Disulfanes (Disulfides). A Review
PublicationThe synthesis of unsymmetrical disulfanes is an important transformation in organic synthesis and medicinal chemistry. The current review is intended to summarize achievements in the synthesis of unsymmetrical disulfanes over the last decade (2004–2014).
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Effect of Laminar Pulsatile Fluid Flow on Separation of Volatile Organic Compounds from Aqueous Solution by a Hollow Fiber Membrane-Based Process
PublicationIn this study, a laminar pulsatile fluid flow was used for the separation of benzene, toluene, ethylbenzene, and xylene isomers (BTEX) from aqueous solutions. Polyether sulfone hollow fiber membrane has been applied to this process. The effects of BTEX concentration, and feed and extraction flow rates were examined. It was found that the application of the pulsatile fluid flow with...
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Solubility Characteristics of Acetaminophen and Phenacetin in Binary Mixtures of Aqueous Organic Solvents: Experimental and Deep Machine Learning Screening of Green Dissolution Media
PublicationThe solubility of active pharmaceutical ingredients is a mandatory physicochemical characteristic in pharmaceutical practice. However, the number of potential solvents and their mixtures prevents direct measurements of all possible combinations for finding environmentally friendly, operational and cost-effective solubilizers. That is why support from theoretical screening seems to be valuable. Here, a collection of acetaminophen...
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High-Speed Videoendoscopy Enhances the Objective Assessment of Glottic Organic Lesions: A Case-Control Study with Multivariable Data-Mining Model Development
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A new pH/organic modifier gradient RP HPLC method for convenient determination of lipophilicity and acidity of drugs as applied to established imidazoline agents
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Determination of nicotine in saliva, urine and wastewater samples using tantalum metal organic framework pipette tip micro-solid phase extraction
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Titania nanotubes infiltrated with conducting polymer PEDOT modified by Prussian Blue – a novel type of organic-inorganic heterojunction characterised with enhanced photoactivity.
PublicationA highly ordered p–n heterojunction was formed based on titania nanotubes containing a conducting polymer with Prussian blue matrix. The study demonstrates, for the first time, cases when a composite based on titania array scaffolding and Prussian blue embedded in PEDOT exhibits reversible FeII/FeIII redox activity. Highly enhanced photoactivity and capacitance of the obtained material are depicted in comparison to pristine titania....
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Materiały wewnętrzne jako źródło lotnych związków organicznych w powietrzu wewnętrznym = Indoor building materials as source of volatile organic compound
PublicationW pracy przedstawiono źródła lotnych związków organicznych w powietrzu wewnętrznym, ze szczególnym uwzględnieniem materiałów budowlanych i materiałów wykorzystywanych jako elementy wyposażenia pomieszczeń. Omówiono sposób prowadzenia badań przesiewowych oraz badań z zastosowaniem komory testowej, które pozwoliły na ocenę natężenia strumienia emisji lotnych związków organicznych z materiałów wewnętrznych.
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Photoconduction and magnetic field effect on photoconduction in hole-transporting star-burst amine (m-MTDATA) films
PublicationPhotoconduction and magnetic field effect on photoconduction have been investigated as a function of electric field strength, excitation light intensity and wavelength in vacuum evaporated films of m-MTDATA (4,4′,4″-tris(N-(3-methylphenyl)-N-phenylylamino) triphenylamine), the starburst amine commonly used as hole-transporting material in organic light-emitting diodes. The photocurrent is found to be generated by the singlet exciton...
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Highly linear CMOS triode transconductor for VHF applications
PublicationA high-speed, fully balanced complementary-symmetry metal-oxide-semiconductor (CMOS) triode transconductor is presented. The proposed approach exploits a pseudo-differential-pair triode configuration with a simple adaptive circuit stabilising the drain-to-source voltages of metal-oxide-semiconductor (MOS) transistors. Since no additional active circuits (apart from the resistors made of the cut-off MOS devices) and no feedback...
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Emergence of Aggregation Induced Emission (AIE), Room-Temperature Phosphorescence (RTP), and Multistimuli Response from a Single Organic Luminogen by Directed Structural Modification
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Średnio - i trudnolotne związki organiczne w powietrzu wewnętrznym. Analityka i monitoring = Semivolatile organic compounds in indoor air. Analytics and monitoring
PublicationZwiązki organiczne występujące w powietrzu wewnętrznym na różnych poziomach stężeń mogą stanowić poważną przyczynę problemów zdrowotnych mieszkańców i użytkowników pomieszczeń. Bardzo ważnym staje się zagadnienie monitoringu obecności związków organicznych, należących do grupy trwałych zanieczyszczeń organicznych (POP).
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Correction: Titania nanotubes infiltrated with the conducting polymer PEDOT modified by Prussian blue – a novel type of organic–inorganic heterojunction characterised with enhanced photoactivity
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The conversion of multinuclear μ-oxo titanium(IV) species in the reaction of Ti(OiBu)4 with branched organic acids; results of structural and spectroscopic studies
PublicationW reakcji tetraizobutoksylanu tytanu z rozgałęzionymi kwasami karboksylowymi otrzymano szereg wielordzeniowych związków kompleksowych tytanu(IV). Otrzymane produkty scharakteryzowano wykorzystując techniki spektroskopowe: FTIR, 1H i 13C NMR oraz rentgenowską analizę strukturalną. Zaproponowano ścieżki reakcji prowadzące do konwersji poszczególnych związków w coraz stabilniejsze formy.
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Multifunctional nitrogen-doped nanoporous carbons derived from metal–organic frameworks for efficient CO2 storage and high-performance lithium-ion batteries
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Ethylcellulose in Organic Solution or Aqueous Dispersion Form in Designing Taste-Masked Microparticles by the Spray Drying Technique with a Model Bitter Drug: Rupatadine Fumarate
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Synthesis of UiO-66-OH zirconium metal-organic framework and its application for selective extraction and trace determination of thorium in water samples by spectrophotometry
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Specjacja fizyczna analitów z grupy wielopierścieniowych węglowodorów aromatycznych w środowisku wodnym = Physical speciation of polycyclic organic hydrocarbons in water environment
PublicationW oparciu o literaturę opisano zagadnienia związane ze specjacją fizyczną wielopierścieniowych węglowodorów aromatycznych w środowisku wodnym. Przedstawiono podstawowe zagadnienia związane z losami środowiskowymi tych związków oraz z ich fizyczną analityką specjacyjną.
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Solid Phase Micro-Extraction, a Versatile and Handy Tool in Environmental Trace Organic Analysis, Gets a New Class of Coatings, Polymeric Ionic Liquids
PublicationSolid phase microextraction (SPME) fundamentals, characteristics and application are described. The special stress is put on characteristics of sorbents used as SPME fiber coatings. Description of commercially available fibers and the present-day trends in development of new sorbents for SPME are given. Discussion is focused on possibility of application of ionic liquids (IL) and polymeric ionic liquids (PIL) as SPME fiber coatings....
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Chapter 8 – Active Sampling of Air
PublicationThis chapter reviews the literature information on analytical techniques and laboratory equipment used for active sampling of air (atmospheric and indoor) in regular monitoring research. It describes popular analytical devices applied for sample collection using various types of polymeric bags, e.g. Tedlar bags, Teflon or Nafion bags, and/or stainless steel vacuum containers. It reviews literature data about the application of...
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The Ellenbogen's "Matter as Software" Concept for Quantum Computer Implementation: II Bonding Between the C60 and X@C60 Molecules as Available Molecular Building Blocks (MBBs) for Tip-Based Nanofabrication (TBN) of Quantum Computing Devices
PublicationThe binding energy, BE of the X@C60-X@C60 homodimer and the X@C60-Y@C60 heterodimer resulting from the bond formation between the occupied X@C60 MBB and the C60 molecule was studied by means of semiempirical PM7 calculations, where X and Y denote atoms from H to Bi, excluding Tc and lanthanides. All possible combinations of N = 68 guest atoms were considered, which resulted in K = 2346 of different calculated dimers of (X@C60-Y@C60)...
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Botanical and geographical origin characterization of polish honeys by headspace SPME-GCxGC-TOFMS
PublicationVolatile organic compounds (VOCs) composition of Polish honeys obtained from various geographical regions was studied. Headspace solid phase microextraction (HS-SPME) using Divinylbenzene/Carboxen/Polydimethylsiloxane-coated fibers was used in combination with comprehensive two-dimensional gas chromatography-time-of-flight mass spectrometry (GC× GC-TOFMS) because of the complexity of the samples. Acacia, linden, rapeseed, buckwheat...
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Spin-Resolved Band Structure of Hoffman Clathrate [Fe(pz)2Pt(CN)4] as an Essential Tool to Predict Optical Spectra of Metal–Organic Frameworks
PublicationParamount spin-crossover properties of the 3D-Hoffman metalorganic framework (MOF) [Fe(pz)2Pt(CN)4] are generally described on the basis of the ligand field theory, which provides adequate insight into theoretical and simulation analysis of spintronic complexes. However, the ligand field approximation does not take into account the 3D periodicity of the actual complex lattice and surface effects and therefore cannot predict a full-scale...
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Skład moczu jako źródło informacji o narażeniu zawodowym na związki organiczne = Urine as a source of information on accupational exposure to organic compounds - A review
PublicationW publikacja przedstawiono przegląd informacji na temat wykorzystania próbek moczu ludzkiego do badań analitycznych, prowadzonych w celu uzyskania informacji o ekspozycji zawodowej na związki organiczne. Toksyczne działanie większości z tych związków stwarza nadal duże zagrożenie wystąpienia chorób zawodowych. Stąd też bardzo ważne jest wykorzystanie monitoringu biologicznego do ocena ryzyka zawodowego. W pracy przedstawiono również...
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Contribution of non-carbonate inorganic and organic alkalinity to total measured alkalinity in pore waters in marine sediments (Gulf of Gdansk, S-E Baltic Sea)
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Textural Characteristics of Resorcinol—Formaldehyde Resin and Temperature Behavior of Bound Water Affected by Co-Adsorbed Trifluoroacetic Acid or Pyridine in Weakly Polar Organic Media
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Fast determination of bisphenol A in spiked juice and drinking water samples by pipette tip solid phase extraction using cobalt metal organic framework as sorbent
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Application of the Heavy-Atom Effect for (Sub)microsecond Thermally Activated Delayed Fluorescence and an All-Organic Light-Emitting Device with Low-Efficiency Roll-off
PublicationThefeatureof abundantandenvironmentallyfriendlyheavyatoms(HAs)like bromineto acceleratespin-forbiddentransitionsin organicmoleculeshas beenknownforyears.In combinationwiththe easinessof incorporation,brominederivativesof organicemittersshowingthermallyactivateddelayedfluorescence(TADF)emergeas a cheapand efficientsolutionforthe slowreverseintersystemcrossing(rISC)problemin suchemittersand strongefficiencyroll-offof all-organiclight-emittingdiodes(OLEDs).Here,we...
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Izolacja lotnych związków organicznych z próbek wody. Metody i aparatura. Analysis of volatile organic compounds (VOCs) in water samples. Methods and apparatus.
PublicationOmówiono techniki wykorzystywane do przygotowania próbek wody do oznaczeń analitów z grupy lotnych związków organicznych (VOCs) za pomocą chromatografii gazowej. Opisano wady i zalety takich technik jak: bezpośrednie dozowanie próbki wody do kolumny chromatograficznej, ekstrakcja rozpuszczalnikiem, ekstrakcja do fazy stałej lub stacjonarnej, ekstrakcja membranowa oraz analiza fazy nadpowierzchniowej. Omówiono także nowe rozwiązania...
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Studies on intercorrelation between selected persistent organic pollutants (POPs) and ions in sea water from the coastal zone of the Baltic Sea, Gdańsk Bay Region
PublicationMorze Bałtyckie jest zbiornikiem słonej wody a szacunkowy czas wymiany z innymi akwenami wynosi 25 lat. Woda morska jest zanieczyszczona wieloma nieorganicznymi oraz organicznymi substancjami. Opracowanie przedstawia wyniki badań monitoringowych oraz ocenę stanu zanieczyszczenia środowiska morskiego w południowej części Morza Bałtyckiego, w rejonie Zatoki Gdańskiej. W próbkach wody morskiej oznaczano: wielopierścieniowe węglowodory...
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Modelling of migration and fate of selected persistent organic pollutans in the Gulf of Gdańsk and the Vistula catchment (Poland): selected results from the EU ELOISE EuroCat project
PublicationW publikacji przedstawiono wyniki pomiarów poziomu stężeń wybranych trwałych zanieczyszczeń organicznych w próbkach wody pobranych z Zatoki Gdańskiej i Wisły. Zamieszczono także opis modelu migracji zanieczyszczeń Co Z Mo - POP. Pokazano także migrację wybranych heksachlorobenzenów i polichlorowanych bifenyli w ekosystemie Zatoki Gdańskiej i Wisły.
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Electromodulation of monomer and excimer phosphorescence in vacuum-evaporated films of platinum (II) complexes of 1,3-di(2-pyridyl)benzenes
PublicationElectric field-modulated photoluminescence (EML) measurements are presented for vacuum-evaporated films of cyclometallated Pt (II) complexes of 1,3-di(2-pyridyl) benzenes used as triplet emitters in organic light-emitting diodes (OLEDs). The excimer phosphorescence is quenched by the external electric field of 2.5 MV/cm up to 25% but the same effect on monomer phosphorescence is one order of magnitude smaller. The higher quenching...
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Solvothermal growth of {0 0 1} exposed anatase nanosheets and their ability to mineralize organic pollutants. The effect of alcohol type and content on the nucleation and growth of TiO2 nanostructures
PublicationHerein, the series of {0 0 1} exposed anatase nanosheets from HF-assisted solvothermal growth synthesis were obtained. The two-dimensional TiO2 were characterized, including both bulk (XRD, DR-UV–Vis, Mott-Schottky) and surface characteristics (N2 sorption, XPS, SEM) with experimental results compiled with Density Functional Theory (DFT) calculations. The effect of alcohol amount and type was studied, demonstrating the crucial...
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Comparative effects of biochar-nanosheets and conventional organic-amendments on health risks abatement of potentially toxic elements via consumption of wheat grown on industrially contaminated-soil
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