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Search results for: ASYMMETRIC SCHIFF BASES
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Modularized Knowledge Bases Using Contexts, Conglomerates and a Query Language
PublicationArtykuł prezentuje nowatorskie podejście do projektowania i budowy baz wiedzy, zorientowane na wyróżnianie kontekstów i ich implementację za pomocą semantycznych modułów wiedzy zwanych konglomeratami.
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Experimental bases for the rail track surface damage detection system
PublicationA diagnosis of rail surface is generally based on the classical method of direct assessment and track geometry measurements. Identification and qualification of inequality and damage on the surface rails is depend on the skills and experience person who conducting inspection. In times of increasing exploitation of railways, infrastructure managers decide to use systems supporting the assessment of technical condition of the railways....
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The immunological, biochemical and molecular bases of canine senescence and carcinogenesis: a review
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Geometry Parametric Model Order Reduction with Randomly Generated Projection Bases
PublicationIn this work, a reduced-order model for geometry parameters and fast frequency sweep is proposed. The Finite Element Method is used to solve time-harmonic Maxwell’s equations. Taking into account the electromagnetic field does not arbitrarily vary as a function of frequency and geometry parameters, a low dimension system manifold is identified. Thus, the original Finite Element problem can be approximated by a model of reduced...
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Cross section calculations for electron scattering from DNA and RNA bases.
PublicationPoliczono różniczkowy i scałkowany przekrój czynny na rozproszenie sprężyste elektronów (w przybliżeniu atomów niezależnych) na uracylu, cytozynie, guaninie, adeninie i tyminie w zakresie energii od 50-4000 eV. W przybliżeniu modelu BEB policzono również przekroje czynne na jonizację tych molekuł.
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Spectral criterion of infinite fatigue life of beams under asymmetric random loads
PublicationRozpatrywana jest trwałość zmęczeniowa belek poddanych stałym i zmiennym obciążeniom osiowym, giętnym i skrętnym o znanych gęstościach widmowych mocy. Założono, że materiał posiada granicę zmęczenia i jest zgodny z modelem Kelvina-Voigta, oraz że składowe naprężenia są stacjonarne, stacjonarnie skorelowane i różniczkowalne w sensie średniokwadratowym. Zdefiniowano naprężenie równoważne i sformułowano kryterium nieograniczonej trwałości...
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Mechanical and Physicochemical Properties of Newly Formed ZnO-PMMA Nanocomposites for Denture Bases
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Preparation and Characterisation of Poly(methyl metacrylate)-Titanium Dioxide Nanocomposites for Denture Bases
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S-Modules - An Approach to Capture Semantics fo Modularized DL Knowledge Bases
PublicationModularity of ontologies has been recently recognized as a key requirement for collaborative ontology engineering and distributed ontology reuse. Partitioning of an ontology into modules naturally gives rise to development of module processing methods. In this paper we describe an algebra of ontology modules developed during our work on a Knowledge Base Management System called RKaSeA. The idea differs from other algebras in the...
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Changes in Muscle Pattern Activity during the Asymmetric Flat Bench Press (Offset Training)
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Associations between heart rate asymmetry expression and asymmetric detrended fluctuation analysis results
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Dipole-bound and dispersion-bound anions supported by the asymmetric tautomers of aminophosphine: H3NPH and HNPH3
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Examination of selected failure criteria with asymmetric shear stresses in the collapse analysis of laminated shells
PublicationThe paper is concerned with failure analysis of composite shells performed with the usage of the nonlinear 6‐parameter shell theory with drilling rotation degree of freedom. This special theory embodies naturally unlim-ited translations and rotations and is suitable for analysis of irregular shells for instance with various, partic-ularly orthogonal, intersections. The presence of the drilling rotation is inherently accompanied...
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Proton transfer reactions from NH acid to various N-bases in acetonitrile
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Preparation of Internal Standards for 2D-UPLC-MS/MS Quantification of Noncanonical DNA Bases
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Compressed Projection Bases for Model-Order Reduction of Multiport Microwave Components Using FEM
PublicationThis paper presents a projection basis compression technique for generating compact reduced-order models (ROM) in the FE analysis of microwave devices. In this approach redundancy is removed from the projection basis by means of the proper orthogonal decomposition technique applied to the projected system of linear equations. Compression allows for keeping the size of a reduced-order model as small as possible without compromising...
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Asymmetric Properties of the Heart Rate Microstructure in Healthy Adults during 48 h ECG Recordings
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Effect of asymmetric fluid flow distribution on flow boiling in a microchannel heat sink – An experimental investigation
PublicationFlow boiling in microchannels is emerging as an exclusive cooling solution for miniaturized high-power electronic devices alongside having other high heat flux applications. Size miniaturization at microscale strangely increases heat transfer performance as well as flow boiling instabilities. Many flow boiling instabilities are interrelated and result from imperfect hydrodynamic conditions. One of such problems is flow maldistribution among...
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Colorimetric study of zinc oxide poly(methyl methacrylate) nanocomposite – new biomaterial for denture bases
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Evaluation of Glass Powder-Based Geopolymer Stabilized Road Bases Containing Recycled Waste Glass Aggregate
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Proton transfer reaction from some C–H acids to N-bases in polar aprotic solvents
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Pitting corrosion characterization by electrochemical noise measurements on asymmetric electrodes. [DOI 10.1007/s10008-008-0643-y]
PublicationObecność korozji wżerowej może być wykryta na podstawie występowania charakterystycznych przebiegów prądu płynącego między dwiema elektrodami, których wyprowadzenia są zwarte. Autorzy proponują nową metodę, która zachowuje informacje o stałej czasowej tych charakterystycznych dla procesów wżerowania przebiegów. Metoda została zastosowana do analizy szumów występujących podczas korozji stali 0H18N9 pod wpływem 1M roztworu FeCl3...
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A dual-control strategy based on electrode material and electrolyte optimization to construct an asymmetric supercapacitor with high energy density
PublicationMetal-organic frames (MOFs) are regarded as excellent candidates for supercapacitors that have attracted much attention because of their diversity, adjustability and porosity. However, both poor structural stability in aqueous alkaline electrolytes and the low electrical conductivity of MOF materials constrain their practical implementation in supercapacitors. In this study, bimetallic CoNi-MOF were synthesized to enhance the electrical...
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Zinc Oxide Nanoparticles Cytotoxicity and Release from Newly Formed PMMA–ZnO Nanocomposites Designed for Denture Bases
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FTIR, NMR and kinetic studies of proton transfer reactions from nitro-substituted diarylmethanes to N-bases with guanidine character
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Are 8-oxoguanine (8-oxoGua) and 5-hydroxymethyluracil (5-hmUra) oxidatively damaged DNA bases or transcription (epigenetic) marks?
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Nickel(II) tri-tert-butoxysilanethiolates with N-heterocyclic bases as additional ligands: Synthesis, molecular structure and spectral studies
PublicationW publikacji przedstawiono metodę syntezy trzech kompleksów silanotiolanowych z takimi N-heterocyklicznymi zasadami jak: pirydyna, 2-metylopirydyna i 3,5-dimetylopirydyna. Dla tych kompleksów przeprowadzono badania X-Ray, analizy elementarnej. Przy pomocy rentgenowskiej analizy strukturalnej wykazano różną koordynację atomu centralnego - niklu.
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Kinetic and equilibrium studies of the proton and deuteron transfer reaction between bis(2,4-dinitrophenyl)methane and strong nitrogen bases in acetonitrile
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Icosahedral Carborane Superacids and their Conjugate Bases Comprising H, F, Cl, and CN Substituents: A Theoretical Investigation of Monomeric and Dimeric Cages
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TspGWI, a thermophilic class-IIS restriction endonuclease from Thermus sp.,recognizes novel asymmetric sequence 5´-ACGGA(N11/9)-3
PublicationA novel prototype class-IIS restriction endonuclease, TspGWI, was isolated from the thermophilic bacterium Thermus sp. GW. The recognition sequence and cleavage positions have been established: TspGWI recognizes the non-palindromic 5-bp sequence 5′-ACGGA-3′ and cleaves the DNA 11 and 9 nt downstream in the top and bottom strand, respectively. In addition, an accompanying endonuclease, TspGWII, an isoschizomer of Pst I, was found...
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Dosimetry study of Re-188 liquid balloon for intravascular brachytherapy using polymer gel dosimeters and laser-beam optical CT scanner
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Tri-tert-butoxysilanethiolate complexes of manganese(II) with chelating heterocyclic bases - Structure of compounds with a MnN2O2S2 or MnN2OS2 kernel and MeOH within the coordination sphere
PublicationNieliczna, do tej pory, grupa tiolanowych kompleksów manganu (II) wzbogaciła się o układy wywodzące się z tri-tert-butoksysilanotiolu jako źródła liganda. Połączenia te można ustabilizować wprowadzając N-donorowe ligandy chelatujące takie jak 2,2'-bipirydyl (bipy), 1,10-fenantrolina (phen) czy też 2,9-dimetylo-1,10-fenantrolina (neo).Skład związków[(tBuO)3SiS]2Mn(bipy) (2), [(tBuO)3SiS]2Mn(phen)(MeOH)] (3), [(tBuO)3SiS]2Mn(phen)]...
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Risk factors for chronic kidney disease do not influence the serum levels of asymmetric dimethylarginine in HIV-1-infected patients without significant renal disease
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Chiral [Mn II Mn III 3 M′] (M′=Na I , Ca II , Mn II ) and [Mn II Mn III 6 Na I 2 ] Clusters Built from an Enantiomerically Pure Schiff Base: Synthetic, Chiroptical, and Magnetic Properties
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Concept of the agent system for the information technology evaluation
PublicationIn this paper the concept of the agent system for the information technology evaluation has been presented. This article includes the concept description and shows abilities of using software tools which can be applicable to implementation and verification of proposed solution. The article is the part of common researches over creation solutions for information technology evaluation which range over using expert's evaluation and...
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Styrene Oxidation by Copper(II) Complexes Salen-Type Encapsulated into Nay Zeolite
PublicationThe copper(II) complex with a Schiff-base salen-type ligand has been encapsulated in the nanopores of a NaY zeolite by using two different methodologies, the flexible ligand and in situ complex preparation methods. The encapsulated and non-encapsulated copper(II) complexes were screened as catalysts for styrene oxidation by using TBHP as the oxygen source in acetonitrile solvent. Under the optimized conditions, the catalysts exhibited...
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DBpedia As a Formal Knowledge Base – An Evaluation
PublicationDBpedia is widely used by researchers as a mean of accessing Wikipedia in a standardized way. In this paper it is characterized from the point of view of questions answering system. Simple implementation of such system is also presented. The paper also characterizes alternatives to DBpedia in form of OpenCyc and YAGO knowledge bases. A comparison between DBpedia and those knowledge bases is presented.
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Nonlinear FEM analysis of irregular shells composed of fiber metal laminates
PublicationThe paper deals with the analysis of failure initiation in shells made of Fiber Metal Laminates (FML). The elas-tic material law for orthotropic lamina is stated accounting for asymmetric in-plane stress and strain measures. The asymmetry results from the employed general nonlinear 6-field shell theory where the generalized dis-placements involve the translation and the proper rotation field. The novelty of the presented results...
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DBpedia and YAGO as Knowledge Base for Natural Language Based Question Answering—The Evaluation
PublicationThe idea of automatic question answering system has a very long history. Despite constant improvement of the systems asking questions in the natural language requires very complex solutions. In this paper the DBpedia and YAGO are evaluated as a knowledge bases for simple class 1 and 2 question answering system. For this purpose a question answering system was designed and implemented. The proposed solution and the knowledge bases...
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State and control system variables sensitivity to rotor asymmetry in the induction motor drive
PublicationThe aim of this paper is to undertake analysis and comparison of the closed-loop and sensorless control systems sensitivity to the broken rotor for diagnostic purposes. For the same vector control system induction motor drive analysis concerning operation with the asymmetric motor, broken rotor fault handling and operation were investigated. Reliability, range of stable operation, fault symptoms and application of diagnosis methods...
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The Reactivity of the Imine Bond within Polynuclear Nickel(II) Complexes
PublicationThree novel Ni complexes with the Schiff base ligand 2-methoxy-6-(E-2-pyridyliminomethyl)-phenol (L1) are described. In comparison with the similar 2-(pyridine-2-ylimino-methyl)phenol (pymp), the mode of coordination of L1 is altered due to the presence of methoxy substituent introducing the sterical hindrance. During the synthesis of the complexes, partial hydrolysis of the ligand was observed. Since such immediate hydrolysis...
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Resource productivity and environmental degradation in EU-27 countries: context of material footprint
PublicationThis study explores the relationship between the resource productivity and environmental degradation in European Union-27 countries. This study tests this relationship in context of high, moderate, and low material footprint sub-samples; these samples are formed utilizing the expectation–maximization machine learning algorithm. Using the panel data set of EU-27 countries from 2000 to 2020, linear and non-linear autoregressive distributed...
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Terminological and Assertional Queries in KQL Knowledge Access Language
PublicationOne of the directions of development of information systems in recent years in the evolution of data-based systems into the knowledge-based systems. As a part of this process there is ongoing work on a whole range of languages for accessing knowledge bases. They can be used in a variety of applications, however their main drawback is the lack of clearly defined algebra representing a theoretical basis for them. For instance, such...
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Contextualizing a Knowledge Base by Approximation – A Case Study
PublicationModular knowledge bases give their users opportunity to store and access knowledge at different levels of generality. In this paper we present how to organize a modular knowledge bases organized into contexts in which a user can express their knowledge in much simplified way, yet without losing its precision. The work is centered around the notion of approximation - i.e. reducing the arity of predicates used. The presentation is...
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Synthetic Principles Determining Local Organization of Copolyesters Prepared from Lactones and Macrolactones
PublicationA highly effective and facile technique for catalytic ring-opening copolymerization (cROP) of lactones viz. ε- caprolactone and ε-decalactone with ω-pentadecalactone is being described. The reactions were mediated by Zn- and Cabased tridentate Schiff base complexes and benzyl alcohol as initiator. The catalysts were successfully employed for the preparation of numerous block and random copolymers. To unravel the composition of...
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Unassisted formation of hemiaminal ether from 4-aminopyridine and o-vanillin - experimental and theoretical study
PublicationThe reactions between o-vanillin and three isomeric aminopyridines lead to imines of diverse spatial conformation and reactivity. The direct products of these simple reactions carried out in methanol are either imine compounds formed in the reactions of 2- amino- and 3-aminopyridine with o-vanillin or the α-aminoether formed in the reaction of o-vanillin with 4-aminopyridine. The Schiff-type derivative of 4-aminopyridine and o-vanillin,...
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Continuum wave functions for estimating the electric dipole moment: Calculation based on a multiconfiguration Dirac-Hartree-Fock approximation
PublicationThe multiconfiguration Dirac-Hartree-Fock method is employed to calculate the continuum electron wave functions, which are then used to estimate their contribution to the atomic electric dipole moment (EDM) of 129Xe. The EDM arises from (P,T)-odd electron-nucleon tensor-pseudotensor and pseudoscalar-scalar interactions, the nuclear Schiff moment, the interaction of the electron electric dipole moment with nuclear magnetic moments,...
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Variable-temperature X-ray diffraction study of structural parameters of NH---S hydrogen bonds in triethylammonium and pyridinium silanethiolates
PublicationHydrogen bonds in triethylammonium and pyridinium silanethiolate salts have been characterized by X-ray, FT–IR and NMR spectroscopies. DFT calculations reveal strongly asymmetric double-well minima at the potential energy curves of the studied compounds
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The migration policy of Armenia
PublicationAbstract: The aim of this study is to describe the legal bases of the migration policy of Armenia and its practical implementation in 1995–2013. The author examined the international and national documents that provide the legal bases of Armenia’s migration policy, as well as the balance between departures and arrivals in the period 1995–2013, Armenian citizens’ reasons for emigrating and the occupations of emigrants. The study...
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Effect of osmolytes of different type on DNA behavior in aqueous solution. Experimental and theoretical studies
PublicationOsmolytes, the small organic molecules accumulated in cells under environmental stress, can modulate the stability of biopolymers such as proteins and DNA. In spite of many years of research, there is no established molecular mechanism of the influence of osmolytes on DNA structure. Here, we used two model osmolytes that denature (urea) or stabilize (trimethylglycine, TMG) proteins to study their effect on DNA in aqueous solutions...