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Search results for: ION%20EXCLUSION%20CHROMATOGRAPHY
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Cell Membrane Transport Mechanisms: Ion Channels and Electrical Properties of Cell Membranes
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Poly(3-octylthiophene) as solid contact for ion-selective electrodes: contradictions and possibilities
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Solid-phase microextraction and ion chromatographic analysis of anions based on polypyrrole electrode
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Hollow carbon sphere/metal oxide nanocomposites anodes for lithium-ion batteries
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Binder-induced surface structure evolution effects on Li-ion battery performance
PublicationA comparative investigation on binder induced chemical and morphological evolution of Li4Ti5O12 electrodes was performed via X-ray photoemission spectroscopy, scanning electron microscopy, and electrochemical measurements. Composite electrodes were obtained using three different binders (PAA, PVdF, and CMC) with 80:10:10 ratio of active material:carbon:binder. The electrochemical performances of the electrodes, were found to be...
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Tailoring of SiOC composition as a way to better performing anodes for Li-ion batteries
PublicationPolymer derived silicon oxycarbide (SiOC) ceramics are investigated as potential anodes for lithiumion batteries. Different SiOC ceramics are prepared by pyrolysis (1000 °C and 1400 °C under controlled argon atmosphere) of polysiloxanes ceramic precursors. Preceramic polymers are synthesized using the sol–gel method. Phenyltriethoxysilane (PhTES) and methyltriethoxysilane (MTES) have been used as starting precursors and mixed with...
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Investigation of poly(3,4-ethylenedioxythiophene) deposition method influence on properties of ion-selective electrodes based on bis(benzo-15-crown-5) derivatives
PublicationGlassy carbon electrodes modified by conductive polymers and membrane with derivatives of bis(benzo-15-crown-5) were tested as solid contact ion selective electrodes for K+ ions concentration determination. PEDOT with PSS, Cl- and ClO4- counter ions was electrochemically deposited onto glassy carbon substrates using four different electrochemical approaches (potentiostatic, galvanostatic, potentiodynamic and potentiostatic pulses)....
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Lithium ion insertion into poly(3,4-ethylenedioxythiophene) films from propylene carbonate electrolytes.
PublicationPolimerowa matryca złożona z poli(3,4-etylenodioksytiofenu z poli(styrenosulfonianem) otrzymana została na drodze syntezy elektrochemicznej. Transport jonowy w matrycy polimerowej w kontakcie z węglanem propylenu zawierającym LiClO4 został scharakteryzowany za pomocą metody impedancji ac oraz chronowoltoamperometrii. Wyznaczono przewodność jonową matrycy oraz efektywne współczynniki dyfuzji dla kationu Li+. Wielkości te...
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Determination of Formaldehyde and Cyanide Ion in Human Nasal Discharge by Using Simple Spectrophotometric Methods
PublicationEnvironmental tobacco smoke (ETS) contains many toxic compounds which include substances classified as aldehydes (e.g. formaldehyde) and inorganic substances such as cyanide ions. The information on the determination of these compounds in water is available, but the monitoring data on the level of these substances in human body fluids are still lacking. In this work the procedure for determining cyanide ions and formaldehyde in...
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Well-Designed Porous Graphene Flakes for Lithium-Ion Batteries with Outstanding Rate Performance
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Selective Synthesis of Magnetite Nanospheres with Controllable Morphologies on CNTs and Application to Lithium‐Ion Batteries
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Could graphene construct an effective conducting network in a high-power lithium ion battery?
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Ion-selective electrodes based on p-tert-butyl-homooxacalixarene di(ethyl) amides
PublicationPochodne dietyloamidowe p-tert-butylodihomooksakaliks[4]arenu (1), p-tert-butyloheksahomotrioksakaliks[3]arenu (2) oraz p-tert-butylokaliks[4]arenu (3) były wykorzystane jako materiał aktywny w membranach elektrod jonoselektywnych w celu sprawdzenia detekcji kationów różnych rodzajów (Na+, K+, Cs+, Mg2+, Ca2+, Mn2+, Cu2+, Zn2+, Cd2+, Pb2+ oraz kation tetrametyloammoniowy). Wyznaczono charakterystyki elektrod oraz współczynniki...
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Comparison of Ion Chromatography and Isotachophoresis for the Determination of selected Anions in Atmospheric Wet Deposition Samples
PublicationW pracy przedstawiono porównanie wyników oznaczenia zawartości wybranych anionów w próbkach opadów atmoferycznych z zastosowaniem technik izotachoforezy i chromatografii jonowej. Na podstawie otrzymanych wyników można stwierdzić, że technika chromatografii jonowej charakteryzuje się niższymi wartościami granic wykrywalności i oznaczalności, szerokim zakresem pomiarowym i możliwością oznaczania analitów w próbkach o róznym składzie...
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Evaluation, Pitfalls and Recommendations for the “Water Layer Test” for Solid Contact Ion‐selective Electrodes
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Ion-selective electrodes based on p-tert-butyl-homooxacalixarene di(ethyl)amides
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Porphyrazines Peripherally Functionalized with Hybrid Ligands as Molecular Scaffolds for Bimetallic Metal-Ion Coordination
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Nonlinear Impedance as Possible Result of Ion-Polaron Interaction in Cu2O-Al2O3-SiO2 Glass
PublicationNonlinear a.c. impedance measurements were performed in Cu2O-Al2O3-SiO2 glass in wide frequency range. The obtained results shows that a large nonlinearity in the impedance signal is observed at moderate electric fields of an order 1V/mm. The contents of the third harmonics reaches about 10% and strongly depends on temperature and frequency. The investigated glass exhibits mixed electronic-ionic conductivity. Electronic conduction...
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Fabrication of 3D graphene/MoS2 spherical heterostructure as anode material in Li-ion battery
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Carbon nanotubes decorated by mesoporous cobalt oxide as electrode material for lithium-ion batteries
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Ion conduction in beryllium-alumino-silicate glasses doped with sodium or sodium and lithium ions
PublicationElectrical properties of beryllium-alumino-silicate glasses containing sodium ions or sodium and lithium ions were studied with impedance spectroscopy technique over a frequency range from 10 mHz to 1 MHz and at temperature range from 213 to 473 K. The frequency- and temperature-dependent conductivity spectra of individual single alkali glasses were superimposed by means of the Summerfield scaling. Mixed-alkali glasses do not overlap...
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Rapid ion-exchange matrix removal for a decrease of detection limits in the analysis of salt-rich reservoir waters for fluorobenzoic acids by liquid chromatography coupled with tandem mass spectrometry
PublicationA matrix removal procedure with ion-exchange resin prior to analysis for 18 fluorinated benzoic acids (FBAs) tracers in saline (>25% salt) reservoir water was optimized. The elimination of >98% of salt and the simultaneous matrix sample cleanup allowed the direct analysis using the supernatant by liquid chromatography coupled with tandem mass spectrometry (LC-MS/MS). This resulted in a gain in detection limits for most of the tracers...
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Selectivity of lithium electrodes: correlation with ion-ionophore complexstability constants and with interfacial exchange current densities
PublicationMembranowe elektrody selektywne na jony litu oparte na dwóch różnych dicyk-lohesyloamidowych jonoforach poddane zostały systematycznym badaniom. Potencjometrycznie wyznaczono wartości współczynników selektywności. Wartości stałych trwałości kompleksów z jonami litu, sodu i potasu wyznaczono metodą membran "sandwichowych". Transfer ładunków przez membranę oraz przez granicę faz membrana/roztwór badano metodą spektroskopii impedancyjnej....
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Analysis of the enthalpies of transfer of Co(II) ion in mixed solvents by means of the theory of preferential solvation.
PublicationZa pomocą teorii solwatacji preferencyjnej zanalizowano entalpie przeniesienia jonu Co(II) w kilku mieszaninach wodno-organicznych i organicznych, wyznaczając parametry, które w sposób ilościowy opisują solwatację preferencyjną jonu i jego wpływ na oddziaływania między cząsteczkami rozpuszczalnika. Przeprowadzono porównanie właściwości solwatacyjnych mieszanin. Wyznaczono także średni skład sfery solwatacyjnej jonu w zależności...
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Comparison of Fluoride Ion-Selective Electrode Based Potentiometric Methods of Fluoride Determination in Human Urine
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Influence of mechanochemical and microwave modification on ion-exchange properties of tin dioxide with respect to uranyl ions
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Ion Exchange And Related Phenomena In Glass Periodical GRIN Matrices During The Mosaic-Assembling Technology
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Influence of the preparation method and aluminum ion substitution on the structure and electrical properties of lithium–iron ferrites
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Chromium Ion Pair Luminescence: A Strategy in Broadband Near-Infrared Light-Emitting Diode Design
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SOLVENT EXTRACTION AND ION EXCHANGE
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Determination of the amount of wash amines and ammonium ion in desulfurization products of process gases and results of related studies
PublicationPrzedstawiono metodę oznaczania tzw. amin myjących i ich produktów degradacji, włączając jon amonowy w wodach procesowych i ściekach wytwarzanych podczas odsiarczania gazów. W procesach rafinacji ropy naftowej zastosowano jonowymienną chromatografię cieczową z detektorem refraktometrycznym oraz tanią kationowymienną kolumnę HPLC. Otrzymane wyniki oznaczeń porównano z wynikami uzyskanymi przez miareczkowanie potencjometryczne....
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Recycling of Plastic Wastes for the Mass Production of Yolk–Shell-Nanostructured Co3O4@C for Lithium-Ion Batteries
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Hollow carbon spheres loaded with uniform dispersion of copper oxide nanoparticles for anode in lithium- ion batteries
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Improved performance in lithium ion battery of CNT-Fe3O4@graphene induced by three-dimensional structured construction
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<title>Correction of fiber optic ion sensor readings using a fiber optic temperature sensor</title>
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Citropin 1.1 Trifluoroacetate to Chloride Counter-Ion Exchange in HCl-Saturated Organic Solutions: An Alternative Approach
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Pyrrole azocrown ethers. Synthesis, complexation, selective lead transport and ion-selective membrane electrode studies
PublicationOtrzymano nowe, 21-członowe, lipofilowe etery koronowe z jednostką pirolową i dwoma grupami azowymi jako składowymi makrocyklu. Właściwości kompleksujące tych nowych oraz dwóch wcześniej otrzymanych makrocykli zbadano w acetonitrylu. Ligandy te zostały użyte jako jonofory w badaniach konkurencyjnego transportu równomolowej mieszaniny jonów metali: Co2+, Ni2+, Cu2+, Zn2+, Cd2+, Ag2+, Pb2+ w układzie woda(pH 4.9)/chloroform/woda(pH...
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The application of isotopically labeled analogues for the determination of small organic compounds by GC/MS with selected ion monitoring
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Medical Plant Extract Purification from Cadmium(II) Using Modified Thermoplastic Starch and Ion Exchangers
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Disiloxanes and Functionalized Silica Gels: One Route, Two Complementary Outcomes—Guanidinium and Pyridinium Ion-Exchangers
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Core/shell structured Ti/Si/C composite for high-performance zinc-ion hybrid capacitor
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Recycling of Plastic Wastes for the Mass Production of Yolk–Shell-Nanostructured Co3O4@C for Lithium-Ion Batteries
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Crystal structure and isothermal titration calorimetry studies of new cobalt(II) complex with 2-methylnitrilotriacetate ion
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Cyclic voltammetry curves of the V2O5 nanorods (Na-ion batteries)
Open Research DataThe DataSet contains the next thirty cycles voltammetry curves for the V2O5 nanorods obtained by the sol-gel method. The cyclic voltammetry was measured using the AUTOLAB 302N potentiostat-galvanostat. The measurements were carried out in a voltage range of 2 V to 4 V vs. Na/Na+ at a scan rate of 1 mV/s. As an electrolyte 1M NaPF6 was applied.
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Cyclic voltammetry curves of the V2O5 nanorods (Li-ion batteries)
Open Research DataThe DataSet contains the next thirty cycles voltammetry curves for the V2O5 nanocrystals obtained by the sol-gel method. The cyclic voltammetry was measured using the AUTOLAB 302N potentiostat-galvanostat. The measurements were carried out in a voltage range of 2 V to 4 V vs. Li/Li+ at a scan rate of 1 mV/s. The results show that in the subsequent cycles,...
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Cyclic voltammetry curves of the V2O5 nanocrystals (Na-ion batteries)
Open Research DataThe DataSet contains the next thirty cycles voltammetry curves for the V2O5 nanocrystals obtained by the sol-gel method. The cyclic voltammetry was measured using the AUTOLAB 302N potentiostat-galvanostat. The measurements were carried out in a voltage range of 2 V to 4 V vs. Na/Na+ at a scan rate of 1 mV/s. As an electrolyte 1M NaPF6 was applied.
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Cyclic voltammetry curves of the V2O5 nanocrystals (Li-ion batteries)
Open Research DataThe DataSet contains the next thirty cycles voltammetry curves for the V2O5 nanocrystals obtained by the sol-gel method. The cyclic voltammetry was measured using the AUTOLAB 302N potentiostat-galvanostat. The measurements were carried out in a voltage range of 2 V to 4 V vs. Li/Li+ at a scan rate of 1 mV/s. The results show that in the subsequent cycles,...
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Magnetic anisotropy and structural flexibility in the f ield-induced single ion magnets [Co{(OPPh2) (EPPh2)N}2], E = S, Se, explored by experimental and computational methods
PublicationDuring the last few years, a large number of mononuclear Co(II) complexes of various coordination geometries have been explored as potential single ion magnets (SIMs). In the work presented herein, the Co(II) S = 3/2 tetrahedral [Co{(OPPh2)(EPPh2)N}2], E = S, Se, complexes (abbreviated as CoO2E2), bearing chalcogenated mixed donor-atom imidodiphosphinato ligands, were studied by both experimental and computational techniques. Specifically,...
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Monika Wilamowska-Zawłocka dr hab. inż.
PeopleDr Monika WILAMOWSKA-ZAWŁOCKA obtained her PhD in Chemistry in 2011 at Faculty of Chemistry, Gdańsk University of Technology. She then was a post-doctoral fellow at Technische Universität Darmstadt, Germany. Since 2013 she has worked at Gdańsk University of Technology, since 2019 as an Associate Professor. Her research interests include composite materials for energy storage devices, especially for lithium-ion and sodium-ion batteries,...
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The electrochemical impedance spectroscopy studies of the anode material based on polymer and starch derived ceramic for lithium ion batteries
PublicationThe anode materials derived of preceramic polymer poly(1,2-dimethylsilazane) (PSN) and starch was study. Commercially available polysilazane (poly(1,2-dimethylsilazane (PSN 2M01 Gelest) was mixed with commercially available starch (POCH Gliwice). The ratio polymer/starch (PSN/starch) was 1/1 or 3/7. The polysialazane/starch blend was cross-linked at 230 ºC for 2 h followed by heating to the final temperature (500 ºC, 700 ºC and...