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Search results for: MEMBRANE POLYMER.
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Construction and investigation of SO2 amperometric sensor with a solid polymer electrolyte membrane
Publicationn this paper a sensor for detection of the sulphur dioxide based on three electrode cell configuration with a liquid electrolyte, a mercury sulphate reference electrode and a solid polymer electrolyte working electrode is presented. Working elec- trode was obtained by using Takenaka-Torikai chemical deposi- tion method by precipitation of Au particles into the pores of the Nafion membrane. Sensors characteristics measurements were...
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Investigation of Taste Substances by five Channel Lipid-Polymer Membrane Sensor.
PublicationBadano substancje o różnych stężeniach należące do czterech klas smaku za pomocą pięcio-kanałowego sensora opartego o elektrody jonoselektywne z różnymi membranami polimerowo-lipidowymi. Stwierdzono, że sensor jest czuły na zmiany stężeń chlorowodorku chininy, kawsu cytrynowego i chlorku sodu, przeciwnie jak w przypadku sacharozy. Na podstawie tych wyników można przypuszczać, że sensor może być zastosowany do roztworów składających...
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On the possibility of using liquid or lipid - polymer membrane systems as taste sensors
PublicationMembrany ciekłe z anionowym surfaktanetem mogą być użyte do rozpoznawania molekularnego substancji smakowych ale nie mogą stanowić podstawy sensora smaku głównie z powodu chaotycznych zachowań. Przeciwnie membrany polimerowo-lipidowe mogą być zastosowane w sensorze smaku do badania jakości pewnych napojów handlowych.
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Transport of lead across polymer inclusion membrane with p-tert-butylkalix[4]arene derivative
PublicationOpisane zostały ułatwienia w transporcie jonów ołowiu (II) przez polimerową membranę inkluzyjną (PIMs),która składała się z trój octanu celulozy jako polimerowego suportu, eteru o-nitrofenylooktylu jako plastyfikatora i 25,26,27,28, tetra-(N-hydroksy-N-metylokarbonylo metoksy)-p-tert-butylokaliks[4]arenu jako nośnika jonów. Polimerowa membrana inkluzyjna została scharakteryzowana przy pomocy mikroskopu sił atomowych (AFM). Otrzymane...
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Selective transport of Pb(II) across polymer inclusion membrane using imidazole azocrown ethers as carriers.
PublicationZbadano selektywność transportu jonów ołowiu(II) z równomolowych roztworów jonów Zn(II), Cd(II) i Pb(II) przez polimerowe membrany inkluzyjne (PIM) zawierające imidazolowe etery azokoronowe.Wykazano, że polimerowe membrany inkluzyjne z imidazolowymi azokoronami wykazują dużą stabilność, zależną w dużym stopniu od rodzaju jonoforu.
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Evolution of the nanostructure of Pt and Pt–Co polymer electrolyte membrane fuel cell electrocatalysts at successive degradation stages probed by X-ray photoemission
PublicationWe present a set of XPS (X-ray photoemission spectroscopy) measurements and detailed data-analysis of electrodes for polymer electrolyte membrane fuel cell (PEMFC) based on carbon supported catalysts (Pt and Pt–Co) subjected to a step-like potential cycling (accelerated degradation test). The results of the measurements complete and corroborate parallel TEM (transmission electron microscopy), XRD (X-ray diffraction) and XAS (X-ray...
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Studies on removal of Zn(II), Cd(II) and Pb(II) ions in polymer inclusion membrane transport with calix[4]-crown-6 derivatives
PublicationZbadano selektywność procesu wydzielania jonów cynku(II), kadmu(II) i ołowiu(II) z wodnych roztworów azotanowych zawierających równomolową mieszaninę tych trzech metali (cMe= 0,01 M) w procesie transportu przez polimerowe membrany inkluzyjne (PIM) przy użyciu w roli przenośników jonów pochodnych kaliks[4]-korony-6. Membrany typu PIM syntezowano z trójoctanu celulozy (nośnik), eteru o?nitrofenylopentylowego (pastyfikator) i pochodnych...
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The comparison of the removal of copper(II) and zinc(II) ions from aqueous solution using 2,6-diaminopyridine in a polymer inclusion membrane and in a classic solvent extraction
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Recent advances in the recovery of precious metals (Au, Ag, Pd) from acidic and WEEE solutions by solvent extraction and polymer inclusion membrane processes – a mini-review
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The Application of 2,6-Bis(4-Methoxybenzoyl)-Diaminopyridine in Solvent Extraction and Polymer Membrane Separation for the Recovery of Au(III), Ag(I), Pd(II) and Pt(II) Ions from Aqueous Solutions
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Deep eutectic solvents – A new platform in membrane fabrication and membrane-assisted technologies
PublicationDeep eutectic solvents (DESs) are a new class of solvents that can offset some of the primary drawbacks of typical solvents and ionic liquids (ILs). Since DESs fall into the guidelines of “Twelve Principles of Green Chemistry”, their implementation in several types of applications has exponentially increased over the last years. The usage of DESs has been directed to the designing, manufacture and purification of new materials...
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Reviewing the recent developments of using graphene-based nanosized materials in membrane separations
PublicationAccording to the potentialities of graphene-based materials and their unique physicochemical properties. Such 2D nanomaterials are likely to be the most implemented within the improvement of the selective separations of polymer membranes, together with enhanced physicochemical properties (such as hydrophilicity/hydrophobicity, transport of molecules, mechanical and thermal features, among others). Hence, this review compiles and...
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Investigation of solid polymer electrolyte gas sensor with different electrochemical techniques
PublicationIn this work solid polymer electrolyte (SPE) amperometric sulphur dioxide sensor is investigated. Nafion was used as a membrane electrode and 1M sulphuric acid as an internal electrolyte. Sensor response to sulphur dioxide was measured. Besides traditional constant voltage amperometry also different electrochemical techniques were used. Results obtained by these methods are compared.
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Preparation and characterisation of solution-cast Nafion membrane
PublicationNafion is a commercial name for a perfluorosulfonic polymer, which has been developed in 1962 by Dupont de Nemours. This polymer consists of a polytetrafluoroethylene backbone and regular spaced long perfluorovinyl ether pendant side chains terminated by a sulfonate ionic group. These sulfonate groups are responsible for cation-exchange properties of Nafion. Thanks to the ion-exchange properties, water permeability, good chemical,...
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Application of g-C3N4/ZnO nanocomposites for fabrication of anti-fouling polymer membranes with dye and protein rejection superiority
PublicationPolysulfone (PSf) membranes are privileged for water and wastewater treatment, but because of their hydrophobic nature, they suffer from fouling, which lowers their performance and lifetime. In this work, g-C3N4 and g-C3N4/ZnO nanomaterials were synthesized via a hydrothermal method to modify the PSf membrane for effective dye separation and reduction of organic fouling. Since g-C3N4/ZnO possesses –OH and –NH reactive groups, g-C3N4/ZnO/PSf...
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Highly antifouling polymer-nanoparticle-nanoparticle/polymer hybrid membranes
PublicationWe introduce highly antifouling Polymer-Nanoparticle-Nanoparticle/Polymer (PNNP) hybrid membranes as multi-functional materials for versatile purification of wastewater. Nitrogen-rich polyethylenimine (PEI)-functionalized halloysite nanotube (HNT-SiO2-PEI) nanoparticles were developed and embedded in polyvinyl chloride (PVC) membranes for protein and dye filtration. Bulk and surface characteristics of the resulting HNT-SiO2-PEI...
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INVESTIGATION OF ACIDIC SOLUTIONS BY POTENTIOMETRIC TASTE SENSOR WITH ALL SOLID STATE ELECTRODES
PublicationPotentiometric taste sensors with electrodes containing lipophilic compound / polymer membranes were already used to distinguish commercial liquid products. In this paper a new potentiometric taste sensor consisting of six All Solid State Electrodes (ASSEs) has been presented. Each of the membrane contains a selected lipophilic compound. The set-up consists of a reference electrode and six ASSEs. The inner layer made of a conducting...
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Fabrication of the cross-linked PVA/TiO2/C nanocomposite membrane for alkaline direct methanol fuel cells
PublicationA crosslinked Poly(vinyl alcohol) based composite membrane was developed through a phase inversion process for use in alkaline direct methanol fuel cells (ADMFCs). The titanium dioxide (TiO2) and carbon nanoparticles (NPs) have been incorporated into the PVA polymer matrix to improve the mechanical and thermal properties. The membrane samples were further modified with maleic acid, a carboxylic acid acting as the cross-linker,...
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Comparative Study of Taste Substance Sensing by Liquid Membrane Oscillator and Electrochemical Systems With All-Solid-State Electrodes
PublicationIn food industry, different types of sensors are used for characterizing and quantifying taste substances. Therefore, it is important to establish the principal advantages and disadvantages of these sensors for optimal application. In this paper, two possible systems are compared for sensing the four fundamental tastes: sour (citric acid), salty (sodium chloride), sweet (sucrose), and bitter (caffeine or quinine hydrochloride). One...
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Investigation of poly(3,4-ethylenedioxythiophene) deposition method influence on properties of ion-selective electrodes based on bis(benzo-15-crown-5) derivatives
PublicationGlassy carbon electrodes modified by conductive polymers and membrane with derivatives of bis(benzo-15-crown-5) were tested as solid contact ion selective electrodes for K+ ions concentration determination. PEDOT with PSS, Cl- and ClO4- counter ions was electrochemically deposited onto glassy carbon substrates using four different electrochemical approaches (potentiostatic, galvanostatic, potentiodynamic and potentiostatic pulses)....
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Adsorption-assisted transport of water vapour in super-hydrophobic membranes filled with multilayer graphene platelets
PublicationThe effects of confinement of multilayer graphene platelets in hydrophobic microporous polymeric membranes are here examined. Intermolecular interactions between water vapour molecules and nanocomposite membranes are envisaged to originate assisted transport of water vapour in membrane distillation processes when a suitable filler-polymer ratio is reached. Mass transport coefficients are estimated under different working conditions,...
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A critical review on electrospun membranes containing 2D materials for seawater desalination
PublicationElectrospun nanofibers are a cutting-edge class of membranes which have been applied in several molecular separations. These membranes can be well designed and tailored due to the versatility of the electrospinning process. Eminently, electrospun membranes, once implemented in membrane processes, are an alternative in removing salts and some other minerals from water, so-called desalination, for producing drinking water. Such membranes...
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All solid state electrodes taste sensor with modified polymer membranes for discrimination of mineral water with different CO2 content
PublicationA potentiometric taste sensor with All Solid State Electrodes containing five all solid state electrodes with appropriate lipophilic compounds (benzyldimethyltetradecylammonium chloride, dodecyltrimethylammonium bromide, palmitic acid, stearic acid, and phytol) embedded in a polymer membrane was applied for discrimination of mineral water samples differed in CO2 content. Samples of still, slightly sparkling, and sparkling Naleczowianka...
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Chitosan-Based Membranes as Gentamicin Carriers for Biomedical Applications — Influence of Chitosan Molecular Weight
PublicationOver the past decade, much attention has been paid to chitosan as a potential drug carrier because of its non-toxicity, biocompatibility, biodegradability and antibacterial properties. The effect of various chitosan characteristics on its ability to carry different antibiotics is discussed in the literature. In this work, we evaluated the influence of the different molecular weights of this polymer on its potential as an antibacterial...
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Usuwanie lotnych związków organicznych z fazy gazowej z zastosowaniem cieczy jonowych
PublicationUżycie cieczy jonowej do usuwania LZO jest limitowane przez rozpuszczalność usuwanych związków. Dane literaturowe sugerują, że ciecze jonowe jako faza membranowa mogą być z powodzeniem stosowane do selektywnej separacji węglowodorów aromatycznych z mieszanin węglowodorów aromatycznych i alifatycznych. Przedmiotem pracy było kompleksowe opisanie procesu separacji LZO z fazy gazowej z uwzględnieniem czynników wpływających na efektywność...
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Challenges and Possibilities of Deep Eutectic Solvent-Based Membranes
PublicationDeep eutectic solvents (DES) are a category of a new class of solvents that can overcome some of the main drawbacks of typical solvents and ionic liquids (ILs). DES have been widely investigated and applied by the research community in several applications since their invention. Over the past years, the use of DES has been directed to the production of new materials and items for new products and processes. This is the case for...
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Towards azeotropic MeOH-MTBE separation using pervaporation chitosan-based deep eutectic solvent membranes
PublicationDeep eutectic solvents (DESs) are a new class of solvents that can offset some of the major drawbacks of common solvents and ionic liquids. When dealing with the preparation of dense membranes, the use of DESs is still challenging due to their low compatibility with the polymer phase. In this research, a novel L-proline:sulfolane (molar ratio 1:2) DES was synthesized and used for the preparation of more sustainable bio-based membranes...
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Pervaporation Zeolite-Based Composite Membranes for Solvent Separations
PublicationThanks to their well-defined molecular sieving and stability, zeolites have been proposed in selective membrane separations, such as gas separation and pervaporation. For instance, the incorporation of zeolites into polymer phases to generate composite (or mixed matrix) membranes revealed important advances in pervaporation. Therefore, the goal of this review is to compile and elucidate the latest advances (over the last 2-3 years)...
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The possibility of the application of a potentiometric sensor with all-solid-state electrodes for the quality control of different natural waters
PublicationThe quality of various natural waters was examined by a new potentiometric sensor with six all solid state electrodes containing an appropriate lipophilic compound in a polymer membrane. Physicochemical parameters such as conductivity and acidity of tested waters were also tested. All waters were neutral or slightly alkaline and contained different ions (e.g., Cl–) due to the place of their sampling (a coastal zone and a moraine...
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Badania bioaktywności z wykorzystaniem komórek kościotwórczych na tytanie pokrytym chitozanem = Bioactivity studies using osteogenic cells on titanium coated with chitosan
PublicationChitosan is a natural polymer from the group of polysaccharides, which has found wide application in biomedical applications to induce bioactivity of implant. The studies described were carried out test imposition of chitosan membranes with varying degrees of deacetylation on the surface of titanium, and then check the bioactivity of the material in vitro, using osteogenic cells MC3T3-E1. Titanium surface before imposition of...
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Characterization of PVDF/Graphene Nanocomposite Membranes for Water Desalination with Enhanced Antifungal Activity
PublicationSeawater desalination is a worldwide concern for the sustainable production of drinking water. In this regard, membrane distillation (MD) has shown the potential for effective brine treatment. However, the lack of appropriate MD membranes limits its industrial expansion since they experience fouling and wetting issues. Therefore, hydrophobic membranes are promising candidates to successfully deal with such phenomena that are typical...
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The selected roof covering technologies in the aspect of their life cycle costs
PublicationIn the article is presented an analysis of the life cycle costs calculation for selected roof coverings. The scope of research includes costs of construction, maintenance and demolition of the roof covering structure for two alternative technologies – the traditional and new generation. On the presented example of an industrial building with a roof area of 1000 m², the above costs are taken to consideration for the roof covering...
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Fault Diagnostics in PEMFC Stacks by Evaluation of Local Performance and Cell Impedance Analysis
PublicationStarvation, flooding, and dry‐out phenomena occur in polymer electrolyte membrane fuel cells (PEMFCs), due to heterogeneous local conditions, material inhomogeneity, and uneven flow distribution across the single cell active area and in between the individual cells. The impact of the load level and air feed conditions on the performance was identified for individual single cells within a 10‐cell stack. Analysis of the current density...
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Zeolitic imidazolate framework (ZIF-8) modified cellulose acetate NF membranes for potential water treatment application
PublicationIn this study, cellulose acetate (CA)-based nanofiltration membranes, modified with zeolitic imidazole framework-8 (ZIF-8) particles, were prepared with various ZIF-8 contents (0, 0.1, 0.25, 0.5, 1 and 2 wt%), to obtain membranes with improved flux and filtration performance by combining advantages of CA polymer and ZIF-8 metal-organic frameworks. Removal efficiency studies were carried out with bovine serum albumin and two different...
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Koncepcja i modelowanie wysokoobrotowego napędu elektrycznego turbosprężarki. Zastosowanie w ogniwach paliwowych pojazdów samochodowych
PublicationAbstract: Electrical vehicles powered by hydrogen fuel cells become a potential alternative to conventional vehicles. The polymer electrolyte membrane (PEM) are typical fuel cells used in fuel cell vehicle (FCV). The global efficiency of a PEM fuel cell stack is greatly impacted by the use of a motorized compressor for the air supply system. The motor-compressor set-up may consume up to 19 % of the energy supplied by the PEM fuel...
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Investigation of sweet substances of different molecular structure by potentiometric taste sensor with all solid state electrodes
PublicationA five channel potentiometric taste sensor consisting of an array of All Solid State Electrodes (ASSESs) with different lipid-polymer membranes has been developed. The electrodes are constructed of glassy carbon discs with electrochemically deposited poly(3,4-ethylenedioxythiophene) (PEDOT) acting as ion to electron transducer. The outer layer of the electrode is lipid-polymer membrane. Lipid substances immobilized in PVC membranes...
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Simple synthesis route for fabrication of protective photo‐crosslinked poly(zwitterionic) membranes for application in non‐enzymatic glucose sensing
PublicationThis work focuses on the fabrication of non-enzymatic glucose sensing materials based on laser-formed Au nanoparticles embedded in Ti-textured substrates. Those materials possess good catalytic activity toward glucose oxidation in 0.1 × phosphate buffered saline as well as resistance to some interferants, such as ascorbic acid, urea, and glycine. The electrodes are further coated with three different polymers, that is, Nafion,...
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Development of stabilized protonconducting membrane based on poly(ethylene-co-vinyl alcohol)
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Selectivity of Pb(II) transport across polymer inclusion membranes doped with imidazole azothiacrown ethers
PublicationMembrany wykonane z trioctanu celulozy zawierające jako jonofor 18 i 21-członowe azotiakorony z resztą imidazolu w makropierścieniu przebadano pod kątem transportu jonów Zn(II), Cd(II) i Pb(II) z wodnego roztworu soli (pH ~5.5, cMe = 0,001 M). W wyniku badań ustalono, że jon Pb(II) może być efektywnie wydzielony z roztworu mieszaniny jonów Pb(II), Zn(II), Co(II), Ni(II), Cu(II) i Cd(II).Sekwencja selektywności transportu dla 18-członowej...
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Sulfonated poly(benzoyl paraphenylene) as a membrane for PEMFC: Ex situ and in situ experiments of thermal and chemical stability
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Application of g-C3N4/ZnO nanocomposites for fabrication of anti-fouling polymer membranes with dye and protein rejection superiority
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