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Search results for: ZRO2
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Effect of ZrO2 on corrosion behaviour of chromium coatings
PublicationW celu zbadania wpływu cząstek ZrO2 na zachowania korozyjne powłok chromowych pokryto stal chromem z elektrolitów Cr(VI) z dodatkiem i bez ZrO2. Właściwości korozyjne osadzonych warstw zbadano w elektrolicie 0,01 mol L(-1) kwasu siarkowego plus 0,5 mol L(-1) siarczanu sodu za pomocą metody spektroskopii impedancyjnej i woltamperometrii cyklicznej. Zaproponowano elektryczny obwód zastępczy dla procesu korozji i wyznaczono pęd korozji....
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Luminescent properties of ZrO2:Tb nanoparticles for applications in neuroscience
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Polyurethane/Silane-Functionalized ZrO2 Nanocomposite Powder Coatings: Thermal Degradation Kinetics
PublicationA polyurethane (PU)-based powder coating reinforced with vinyltrimethoxysilane (VTMS)-functionalized ZrO2 nanoparticles (V-ZrO2) for thermal stability was developed. Chemical structure, microstructure and thermal degradation kinetics of the prepared coatings were investigated. The peak of aliphatic C–H vibrating bond in the Fourier transform infrared (FTIR) spectrum of V-ZrO2 was a signature of VTMS attachment. Scanning electron...
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Change of the Phase Composition and Strength of Al2O3–ZrO2-Ceramic After Hydrothermal Aging
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Thermal and physical properties of ZrO2–AlO(OH) nanopowders synthesised by microwave hydrothermal method
PublicationIndustrially relevant nanopowder was synthesised by microwave hydrothermal synthesis to obtain well-controlled composition (ZrO2–AlO(OH) system) which was found to determine a number of physical and thermal characteristics. This study reports variation of particle size, density, specific surface area (SSABET), as well as thermal behaviour of nanopowder mixtures of ZrO2–AlO(OH) in the whole range of compositions. It was found that...
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Mechanism of Reduced Sintering Temperature of Al2O3–ZrO2 Nanocomposites Obtained by Microwave Hydrothermal Synthesis
PublicationA novel method to obtain Al2O3–ZrO2 nanocomposites is presented. It consists of the co-precipitation step of boehmite (AlO(OH)) and ZrO2, followed by microwave hydrothermal treatment at 270 ◦ C and 60 MPa, and by calcination at 600 ◦ C. Using this method, we obtained two nanocomposites: Al2O3–20 wt % ZrO2 and Al2O3–40 wt % ZrO2. Nanocomposites were characterized by Fourier transformed infrared spectroscopy, Raman spectroscopy,...
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Carbon Paste Electrode Modified with ZrO2 Nanoparticles and Ionic Liquid for Sensing of Dopamine in the Presence of Uric Acid
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Catalytic Activity of Nickel and Ruthenium–Nickel Catalysts Supported on SiO2, ZrO2, Al2O3, and MgAl2O4 in a Dry Reforming Process
PublicationDry reforming of methane (DRM) is an eco-friendly method of syngas production due to the utilization of two main greenhouse gases—methane and carbon dioxide. An industrial application of methane dry reforming requires the use of a catalyst with high activity, stability over a long time, and the ability to catalyze a reaction, leading to the needed a hydrogen/carbon monoxide ratio. Thus, the aim of the study was to investigate the...
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The performance of multicomponent oxide systems based on TiO2, ZrO2 and SiO2 in the photocatalytic degradation of Rhodamine B: Mechanism and kinetic studies
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Third order nonlinear optical effects of ZnO–ZrO2–B2O3 glass ceramics embedded with ZnZrO3 perovskite crystal phases
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BET adsorption-desorption isotherm of nano-ZrO2
Open Research DataThe dataset includes the isotherms of adortion and desorption of N2 at LN2 temperature. The sorption isotherms were obtained using Quatachrome NovaTouch LX1 equippment. The ceramic measured powder was composed of nanometric ZrO2 (CA-assisted method of synthesis)
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Cathodic activation of synthesized highly defective monoclinic hydroxyl‐functionalized ZrO2 nanoparticles for efficient electrochemical production of hydrogen in alkaline media
PublicationThe high electrochemical stability of Zirconia (ZrO2) at high potentials strongly suggested it as an alternative to carbon supports, which experience reduced efficiency due to some corrosion problems particularly during prolonged electrocatalysis activity. However, the use of ZrO2 was limited by its low electrical conductivity and surface area. In this work, we developed a methodology for synthesizing monoclinic ZrO2 NPs with increased...
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The Effect of Zirconium Dioxide (ZrO2) Nanoparticles Addition on the Mechanical Parameters of Polymethyl Methacrylate (PMMA): A Systematic Review and Meta-Analysis of Experimental Studies
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The XPS spectra of ZrO2/5%Cu prepared using wet impregnation method
Open Research DataThe dataset includes XPS spectra of ZrO2/5%Cu catalyst sintered under air atmosphere. Samples were produced using aqueous soft chemistry methods and incipient wettness impregnation using nitrate solution. The XPS spectra were collected for all species.
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Growth and characterization of PrBa2Cu3O7-δ single crystals
PublicationWe report on the growth of PrBa2Cu3O7-δ single crystals in the Al2O3 and ZrO2 crucibles by flux method. The high influence of the reaction between crucible and liquid on the initial melt composition has been established. We found that the precipitation of the chemically stable compound BaZrO3 and BaAl2O4 occurs by direct chemical reaction between BaCuO2 and ZrO2 or Al2O3 crucibles materials. Free separated crystals with maximum...
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Results of abrasive slurry dosage in lapping process
PublicationPrzedstawiono wyniki badań dawkowania zawiesiny ściernej w docieraniu powierzchni płaskich elementów ceramicznych. Analizowano wpływ dawkowania na podstawowe parametry chropowatości powierzchni ceramiki Al2O3 i Al2O3-ZrO2.
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The XRD diffraction pattern of interdiffusion test in the CLO-NiO-YSZ system (30wt.%YSZ)
Open Research DataThe dataset includes the XRD pure diffraction pattern of the interdiffusion system consisting of CLO (Ce0.8La0.2O2), NiO and 8YSZ (8mol.% Y2O3 stabilized ZrO2). The mixture contains equal amounts of CLO and NiO as well as 30wt.% 8YSZ. Samples were sintered at 1400 oC. The reaction between CLO and YSZ is visible.
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The XRD diffraction pattern of interdiffusion test in the CLO-NiO-YSZ system (10wt.%YSZ)
Open Research DataThe dataset includes the XRD pure diffraction pattern of the interdiffusion system consisting of CLO (Ce0.8La0.2O2), NiO and 8YSZ (8mol.% Y2O3 stabilized ZrO2). The mixture contains equal amounts of CLO and NiO as well as 10wt.% 8YSZ. Samples were sintered at 1400 oC. The reaction between CLO and YSZ is visible.
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The XRD diffraction pattern of interdiffusion test in the CLO-NiO-YSZ system (20wt.%YSZ)
Open Research DataThe dataset includes the XRD pure diffraction pattern of the interdiffusion system consisting of CLO (Ce0.8La0.2O2), NiO and 8YSZ (8mol.% Y2O3 stabilized ZrO2). The mixture contains equal amounts of CLO and NiO as well as 20wt.% 8YSZ. Samples were sintered at 1400 oC. The reaction between CLO and YSZ is visible.
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Study of abrasive slurry dosage in flat surfaces lapping process
PublicationPrzedstawiono wyniki badań dozowania pasty i zawiesiny ściernej w procesach docierania powierzchni płaskich. Badano wpływ wielkości dawki ścierniwa na podstawowe parametry chropowatości powierzchni elementów miedzianych i ceramicznych. Docierano miedź betlenową MOOB oraz ceramikę Al2O3 i Al2O3-ZrO2 mikroziarnami węglika krzemu i węglika boru.
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Badania jakości docierania elementów z ceramiki technicznej i węglików spiekanych na docierarce jednotarczowej.
PublicationPrzedstawiono wyniki badań docierania elementów płaskich na docierarce jednotarczowej zawiesiną z węglika krzemu. Docierano elementy z tlenkowej ceramiki technicznej Al2O3 i Al2O3-ZrO2 oraz węgliki spiekane SM25, H15X i H20S. Badano wydajność obróbki oraz chropowatość powierzchni po docieraniu. Czynnikami zmiennymi badań była prędkość docierania, nacisk jednostkowy i czas docierania.
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SEM images of 8YSZ sintered using flash sintering programme
Open Research DataThe dataset contains the SEM images of 8YSZ (8mol% Y2O3-ZrO2) sintered using the flash technique in the muffle furnace. The programme was as follows: 3oC/min to 1000C - 1h hold- 3oC/min 1100C - 1h hold- 3oC/min 1200C - 2h hold- 3oC/min 1400- 30 min hold- 5oC/min 1200C - 15h hold- 4oC/min RT
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Nagniatanie ślizgowe elementem ceramicznym z dociskiem sztywnym na tokarce CNC
PublicationW rozdziale przedstawiono możliwość korekcji kształtu na tokarce CNC z wykorzystaniem nagniatania ślizgowego elementem ceramicznym z dociskiem sztywnym. Do nagniatania wykorzystano kulkę ceramiczną ZrO2. Redukcja średnicy i kształtu zrealizowana została na powierzchni stożkowej stali 40H po hartowaniu o twardości 53 HRC. Powierzchnia charakteryzowała się zmieniającą chropowatością (w zakresie Ra = 0,21-0,51µm) i falistością oraz...
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Ocena stanu powierzchni kulek ceramicznych po nagniataniu tocznym stali hartowanej Cf53
PublicationW artykule przedstawiono wyniki z badań eksperymentalnych dotyczących przydatności kulek wykonanych z ceramiki technicznej, do nagniatania tocznego, narzędziami z dociskiem hydrostatycznym. W badaniach wykorzystano narzędzie umożliwiające wymianę kulek nagniatających. Badania wykonano poprzez nagniatanie wałków wykonanych ze stali Cf53 w stanie utwardzonym (zahartowanym). Wyniki badań obejmują charakterystyki stanu powierzchni...
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ZUŻYCIE POWIERZCHNI KULEK CERAMICZNYCH W PROCESIE NAGNIATANIA TOCZNEGO STALI HARTOWANEJ
PublicationPrzedstawiono wyniki z badań eksperymentalnych dotyczących przydatności kulek wykonanych z ceramiki technicznej, do nagniatania tocznego, narzędziami z dociskiem hydrostatycznym. W przeprowadzonych badaniach zastosowano narzędzie umożliwiające wymianę kulek ceramicznych zastosowanych jako elementów nagniatające. Badania wykonano poprzez nagniatanie próbek - wałków wykonanych ze stali Cf53 w stanie utwardzonym (zahartowanym). Wyniki...
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Evaluation of adhesive forces and the specific surface energy of zirconia stabilized by yttria with alumina additions ceramic by AFM method
PublicationThe adhesive forces and the specific surface energy of ceramic material surfaces are very important for further tribological and biomedical applications of ceramics. Partially stabilized zirconia (zirconium oxide) is popular for manufacturing various medical products. ZrO2 stabilized by Y2O3 with additions of 5 wt% alumina was produced by slip casting method with a subsequent sintering. Structure and chemical composition of ceramic...
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Superconductivity in PrBa 2Cu 3O 7− δ single crystals after high-temperature thermal treatment
PublicationThe influence of post-growth treatment, consisting of high-temperature reduction, quench and oxidation, on the structural, electrical and magnetic properties of PrBa2Cu3O7−δ single crystals, obtained in Al2O3 and ZrO2 crucibles by the self-flux method, was examined. We report on the observation of inhomogeneous superconductivity in several Al-doped crystals from the ac magnetic susceptibility and resistivity measurements. Superconducting...
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Zirconia ceramics with additions of Alumina for advanced tribological and biomedical applications
PublicationThe results of an investigation on slip cast and sintered Y2O3 (3 wt%)- stabilized ZrO2 with additions of 5, 10, 15 wt% Al2O3 are reported. The surface roughness, porosity and density of the samples were measured. The hardness HRc and Hv, fracture toughness K1C, and friction coefficients were also measured using standard methods. The structural properties of the samples were observed by Scanning Electron Microscopy (SEM). The surface...
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Cu supported on various oxides as a candidate catalyst for dry methane reforming in DIR-SOFCs systems
PublicationA series of Cu-support systems were tested as potential candidates for DIR-SOFC (Direct Internal Reforming SOFC) catalysts towards a dry reforming of methane (DRM). The various supports (-Al2O3, CeO2, ZrO2, SrTiO3) with comparable specific surface area (SSA), and additionally -Al2O3 with SSA an order of magnitude larger than that of the other supports has been applied. The obtained Cu-support systems were characterized in terms...
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X-ray diffraction patterns of BaCe0.6Zr0.2Y0.1M0.1O3-δ (M = Fe, Pr, Tb)
Open Research DataThe dataset consists of three raw X-ray diffraction (XRD) files collected using a Phillips X’Pert Pro diffractometer (CuKα radiation (𝜆 = 1.541 Å), under 40 kV and 30 mA). The diffraction patterns of BaCe0.6Zr0.2Y0.1Fe0.1O3-δ (BCZYFe), BaCe0.6Zr0.2Y0.1Pr0.1O3-δ (BCZYPr), and BaCe0.6Zr0.2Y0.1Tb0.1O3-δ (BCZYTb) were collected at room temperature. Collected...
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Growth and Electric Transport of Ca-doped PrBa2Cu3O7-δSingle Crystals
PublicationCrystal growth of Ca-doped PrBa2Cu3O (Pr-123) single crystals by slow cooling of Pr3O11-CaCO3-BaCO3-CuO melts (self-flux technique) in ambient air atmosphere was studied. As the first approach the growth of Ca-free crystals in Al2O3 and ZrO2 crucibles was investigated. The best quality crystals with the average size of 5 x 5 x 0.2mm3 were obtained from Al2O3 crucibles for Ba/Cu = 0.41 and 15 wt.% (2.41 mol.%) of stoichiometric...
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Status report on high temperature fuel cells in Poland – Recent advances and achievements
PublicationThe paper presents recent advances in Poland in the field of high temperature fuel cells. The achievements in the materials development, manufacturing of advanced cells, new fabrication techniques, modified electrodes and electrolytes and applications are presented. The work of the Polish teams active in the field of solid oxide fuel cells (SOFC) and molten carbonate fuel cell (MCFC) is presented and discussed. The review is oriented...
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Development of conductive porous media as packing materials for biotrickling filter – microbial fuel cell system (BTF-MFC system)
Open Research DataDataset presents values of electrical resistance measured for three developed conductive packimg materials for the application in a BTF-MFC system.
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Spectroscopic properties of Rhodamine B entrapped in hybrid porous nanolayers at high dye concentration
PublicationThe preparation procedure and characterization of Rhodamine B entrapped in zirconia, silica and mixed silica–zirconia nanolayers is described. The nanolayers were produced by the sol–gel spin-coating technique. The pronounced effect of the dye concentration on the absorption and fluorescence spectra as well as on time-resolved fluorescence spectra was found. The results show that the aggregation of Rhodamine B is stronger in silica...