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Search results for: SHELTERIN COMPLEX
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Novel structure and design of enhanced-bandwidth hybrid quadrature patch coupler
PublicationA novel structure and design optimization procedure of an enhanced-bandwidth hybrid quadrature patch coupler is proposed. Improved performance of the circuit has been obtained by parameterizing the coupler sections using splines, which introduces additional degrees of freedom. Due to computational complexity of the parameter adjustment problem, a sequential design procedure is applied. In each iteration, a selected number of spline...
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Mobile Gas Chromatographs Coupled with Mass and Ion Mobility Spectrometers and their Applications
PublicationThe articles describes the developments un combining of mass and ion mobility spectrometers (MS, IMS0 with miniature gas chromatographs (GC). The examples of applications of miniaturised GC-MS and GC-IMS devices are presented.
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First Copper(I) and Silver(I) Complexes Containing Phosphanylphosphido Ligands
PublicationThree new complexes with phosphanylphosphido ligands, [Cu4{μ2-P(SiMe3)-PtBu}4](1), [Ag4{μ2-P(SiMe3)-PtBu2}4](2) and [Cu{η1-P(SiMe3)-PiPr2}2]–[Li(Diglyme)2] (3) were synthesized and structurally characterized by X-ray diffraction, NMR spectroscopy, and elemental analysis. Complexes 1 and 2 were obtained in the reactionsof lithium derivative of diphosphane tBu2P-P(SiMe3)Li·2.7THF withCuCl and [iBu3PAgCl]4, respectively....
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Surpassing the Line: Urban-Oriented Strategies in the Development of Business Complexes in Poland
PublicationDevelopment trends regarding the business-related urban complexes seem to evolve from the “big-box” towards the more “multi-use” types of structures. Within it, the special role is reserved for places, which—due to economic, political, and geographical reasons—have not been previously considered as major business hubs. Only recently, places like cities in Central and Eastern Europe have become attractive locations for business...
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Scheduling with Complete Multipartite Incompatibility Graph on Parallel Machines: Complexity and Algorithms
PublicationIn this paper, the problem of scheduling on parallel machines with a presence of incompatibilities between jobs is considered. The incompatibility relation can be modeled as a complete multipartite graph in which each edge denotes a pair of jobs that cannot be scheduled on the same machine. The paper provides several results concerning schedules, optimal or approximate with respect to the two most popular criteria of optimality:...
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Study of the anticancer potential of Cd complexes of selenazoyl-hydrazones and their sulfur isosters
PublicationThe biological activity of Cd compounds has been investigated scarce since Cd has been recognized as a human carcinogen. However, the toxicity of cadmium is comparable to the toxicity of noble metals such as Pt and Pd. The paradigm of metal toxicity has been challenged suggesting that metal toxicity is not a constant property, yet it depends on many factors like the presence of appropriate ligands. Studies on anticancer activity...
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Computational methods for calculation of binding free energy for ligand-receptor complexes
PublicationAccurate description of the molecular complexes energetic influence is required for understanding of many biological functions carried out by proteins. Therefore, estimation of binding free energy for ligand-receptor complexes is of highest importance for structure-based ligand design and drug discovery approaches.Experimental methods of determination of difference in Gibbs'es free energy have many limitations. Thus, computational...
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Study of nonreciprocal devices using three-strip ferrite coupled line
PublicationW pracy przedstawiono badania układów niewzajemnych wykorzystujących nowe złącze ferrytowych linii sprzężonych, zaprojektowane w oparciu o linię koplanarną, w której półpłaszczyzny masy zredukowane zostały do postaci pasków. Badane złącze złożone jest z sekcji ferrytowej umieszczonej pomiędzy dwoma sekcjami dielektrycznymi. W sekcji ferrytowej podłużnie magnesowana płytka ferrytowa umieszczona jest pod lub nad paskami przewodzącymi...
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Investigations of cylindrical ferrite coupled line junction using hybrid technique
PublicationW pracy zaproponowano nowe cylindryczne złącze magnesowanych wzdłużnie ferrytowych linii sprzężonych. W porównaniu do znanych w literaturze planarnych konfiguracji złączy ferrytowych, zaproponowana struktura charakteryzuje się znacznie wyższym współczynnikiem sprzężenia żyrotropowego. Pozwala to na uzyskanie wymaganej w układach niewzajemnych rotacji Faraday'a o kąt 45 stopni przy znacznie krótszej długości sekcji linii ferrytowych...
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Assestment of the anti-cancer activity of the copper complexes with imidazole and pivalato ligands
PublicationDespite the development of science and technology progress so far there have not been found effective drugs for cancer. Many coordination compounds were investigated due to their antitumor potential. The most known cis-diamminedichloroplatinum(II) is used as anti-cancer therapeutic agent. The copper complexes are the coordination compounds possessing anti-tumour properties. Their capability to kill cancer cells is mainly linked...
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Reliable Document-Centric Processing in Loosely Coupled Email-Based Systems
PublicationEmail is a simple way to exchange digital documents of any kind. The Mobile INteractive Document architecture (MIND) enables self-coordination and self-steering of document agent systems based on commonly available email services. In this paper, a mechanism for providing integrity and reliability of such an email based agent system is proposed to cope with message soft or hard bounces, user interrupts, and other unexpected events....
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A compact microstrip rat-race coupler constituted by nonuniform transmission lines
PublicationIn this work, a step-by-step development of a compact microstrip rat-race coupler (RRC) has been presented and discussed. A high degree of miniaturization has been obtained by substituting six quarter-wavelength uniform atomic building blocks of a RRC by their nonuniform counterparts. The miniaturization procedure has been realized in three progressive steps: (i) the first layout solution of a miniaturized RRC has been acquired...
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Dissociative multi-photon ionization of isolated uracil and uracil-adenine complexes
PublicationRecent multi-photon ionization (MPI) experiments on uracil revealed a fragment ion at m/z 84 that was proposed as a potential marker for ring opening in the electronically excited neutral molecule. The present MPI measurements on deuterated uracil identify the fragment as C3H4N2O+ (uracil+ less CO), a plausible dissociative ionization product from the theoretically predicted open-ring isomer. Equivalent measurements on thymine...
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Histaminol and Its Complexes with Copper(II) - Studies in Solid State and Solution
PublicationHistaminol [4(5)-(B-hydroxyethyl)imidazole, 4-(1H-imidazol-2-yl)ethanol, L] is an analogue of histamine and its minor metabolite. So far its properties have not been studied in detail due to the synthetic difficulties. Here, the structure and acid-base properties of histaminol, as well as the results of studies on its copper(II) complexes in solid state and aqueous solution are reported. Stability constants of the histaminol–CuII...
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Two-Dimensional Gas Chromatography Coupled With Mass Spectrometry in Food Analysis
PublicationThe development of instrumental analytical techniques provided the opportunity for in-depth characterization of many food matrices. In particular, the use of gas chromatography coupled with mass spectrometry gives impressive results in terms of quality and authenticity testing, conducting food freshness evaluations and contamination assessments. A new variant of gas chromatography, namely two-dimensional gas chromatography (GC...
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A New Coupler Concept for Contactless High-Speed Data Transmission Monitoring
PublicationThis paper presents a new concept of a couplerthat can be applied to high-speed data transmission contactlessmeasurements. The proposed approach is dedicated for differentialsignal transmission monitoring in microstrip coupled lineson printed circuit boards (PCBs). The coupler, produced on aseparate PCB, is overlayed on the transmission line with thedifferential signal and delivers decoupled differential signal tothe main measurement...
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Aggregation properties of some zirconium phosphate loaded with dirhenium(III) complexes
PublicationOne of the important areas of modern science is the selection of the right forms of drug delivery. Layered inorganic nanoparticles, such as zirconium phosphate, have proven themselves well in this area. The study of the properties of these systems and methods of their preparation makes it possible to determine a rational technology of their manufacture, storage conditions as well as suggest a possible mechanism of therapeutic action....
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Modeling the debonding process of osseointegrated implants due to coupled adhesion and friction
PublicationCementless implants have become widely used for total hip replacement surgery. The long-term stability of these implants is achieved by bone growing around and into the rough surface of the implant, a process called osseointegration. However, debonding of the bone–implant interface can still occur due to aseptic implant loosening and insufficient osseointegration, which may have dramatic consequences. The aim of this work is to...
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Silver(I) complexes with nitrile ligands: New materials with versatile applications
PublicationIn the present study, the structure, thermal stability, conductive properties, and antimicrobial activity of silver(I) complexes with nitrile ligands were investigated. For the construction of the materials, 2-cyanopyridine (2-cpy), 4-cyanopyridine (4-cpy), 1,2-dicyanobenzene (1,2-dcb), and 1,3-dicyanobenzene (1,3-dcb) were used in addition to the silver nitrite and nitrate. Four new compounds were isolated and structurally characterized:...
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Efficient modeling of the time-domain crosstalk phenomena in coupled microstrip lines
PublicationW pracy przedstawiono efektywną technikę analizy zjawiska przesłuchu w sprzężonych liniach mikropaskowych. Analiza uwzględnia hybrydową naturę prowadzonych fal i prowadzi do określenia postaci czasowych sygnałów na zaciskach struktury w zależności od parametrów układu linii sprzężonych oraz własności obciążeń. Wyniki analizy zweryfikowano poprzez porównanie z wynikami badań eksperymentalnych, uzyskując bardzo dobrą zgodność.
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FE-modelling of strain localization in concrete with coupled elasto-plasticity and damage
PublicationW artykule przedstawiono wyniki numerycznej dla zginania belki betonowej przy zastosowaniu modelu sprężysto-plastycznego, modelu z degradacja sztywności i modelu połączonego sprężysto-plastycznego z degradacją sztywności. Wszystkie modele rozszerzono o długość charakterystyczną mikrostruktury za pomocą teorii nielokalnej.
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Interactions of telomeric proteins with nucleic acids: sequence recognition on intact and oxidatively damaged telomeres
PublicationTelomeres are complex nucleoprotein assemblies that play a vital role in the maintenance of functional ends of linear chromosomes. Telomeric DNA, composed of tandem repeats of the 5'-TTAGGG-3' motif, solves the so-called end replication problem: as chromosomes shorten with each cell division, no information is lost, and the telomere can be re-extended. In the cell, many protein factors regulate telomere length, nuclear positioning...
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Structure, physicochemical and biological properties of new complex salt of aqua-(nitrilotriacetato-N,O,O′,O″)-oxidovanadium(IV) anion with 1,10-phenanthrolinium cation
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Discovery of small-molecule regenerative drugs using a model of complex tissue injury in mice. Transcriptomic responses of neurodevelopmental genes during pharmacologically induced regeneration
PublicationDespite significant development in regenerative medicine, there is a deficit of effective therapies for wound healing and tissue regeneration. Research performed using animal wound models allows for a better understanding of this complex process, searching for compounds with pro-regenerative properties, and assessing their efficacy and safety. Unfortunately, the lack of adequate preclinical models proves to be an issue as no animal...
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Complexes of manganese(II) tri-tert-butoxysilanethiolate with chelating N-donor ligands.
PublicationTri-tert-butoksysilanotiolan manganu(II) jest związkiem wrażliwym i rozkładającym się w warunkach atmosferycznych. Z tego względu synteza jego pochodnych z chelatującymi zasadami heterocyklicznymi takimi jak 1,10-fenantrolinaza czy 2,2'-bipirydyl wydawał się dogodną metodą otrzymania bardziej stabilnych układów. Otrzymane w ten sposób krystaliczne proszki wykazują znacznie wyższą stabilność temperaturową, możliwe jest więc przechowywanie...
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Analysis of coupled coplanar waveguide with ideal bonding wires between ground conductors
PublicationPrzedstawiono zmodyfikowaną analizę sprzężonych linii koplanarnych prowadzącą do uproszczenia procesu modelowania struktur wieloprzewodowych zawierających poprzecznie ułożone względem kierunku propagacji fali mostki dla wyrównania potencjałów na odseparowanych przestrzennie przewodach. Wyniki analizy teoretycznej zweryfikowano doświadczalnie uzyskując potwierdzenie poprawności zastosowanego podejścia.
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Slow-wave resonant structures in branch-line coupler miniaturization: a case study
PublicationA case study of novel slow-wave resonant structures dedicated to efficient microstrip branch-line coupler size reduction has been presented. A compact 3-dB branch-line coupler has been designed to mimic the performance of its conventional counterpart, simultaneously demonstrating a substantial 88% surface area reduction. The vital usefulness of the approach in the process of microstrip line abbreviation has been experimentally...
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Investigations of four-port circulator utilizing cylindrical ferrite coupled line junction
PublicationW pracy przedstawiono wykorzystanie pojedynczej cylindrycznej sekcji ferrytowych linii sprzężonych do realizacji układu cyrkulatora czterowrotowego. Opisany został proces projektowy sekcji FCL oraz planarnych układów zasilające. Otrzymane z symulacji wyniki zostały zweryfikowane eksperymentalnie.
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On the Mechanism of Coupled Transport of Cu(II) Ions Through Bulk Liquid Membranes.
PublicationTransport jonów Cu(II) przez ciekłe membrany za pomocą 5 - nonylosalicyloaldoksimu jako przenośnika wymaga obecności kompleksu o stosunku metalu do przenośnika 1:2. Zbadano dwie możliwości mechanizmu jego tworzenia. Roztrzygnięcie, który mechanizm jest prawidłowy nie jest możliwe w oparciu jedynie o kinteykę chemiczną.
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Design of quarter-wave compact impedance transformers using coupled transmission lines
PublicationPrzedstawiono porównanie wyników symulacji jedno i wielosekcyjnych transformatorów impedancji budowanych w postaci struktur wykorzystujących idealnenie sprzężone linie transmisyjne, idealne sprzężone symetryczne linie transmisyjne oraz rzeczywiste sprzężone linie mikropaskowe. Pokazano, że możliwa jest konstrukcja transformatorów impedancji o bardzo dobrych parametrach technicznych wykorzystująca sprzężone linie mikropaskowe, pomimo...
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Scattering in a section of ferrite coupled microstrip lines: theory and application in nonreciprocal devices
PublicationPrzeprowadzono analizę pełnofalową sekcji sprzężonych ferrytowych linii mikropaskowych wykorzystującą w rozwinięciu pola em fale prowadzone w izotropowych złączach wejściowych sekcji oraz jej fajl ferrytowych. W wyniku określono macierz S sekcji. Przeprowadzono modelowanie własności rozproszenia układu oraz symulację parametrów transmisyjnych układów niewzajemnych projektowanych z wykorzystaniem proponowanego układu ferrytowego.
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Determination of stability constants of complexes of selected amide ionophores with alkali metal cations
PublicationPodano właściwości kompleksujące jony litowców czterech jonoforów typu amidów. Wyznaczono wartości stałych kompleksów z jonów Li+, Na+, K+ metodą potencjometryczną z zastosowaniem elektrod jonoselektywnych stosując dwie różne procedury: 1) stosując jako kation referencyjny TMA+, 2) stosując chromofor kompleksujący H+.
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Ruthenium(II) and Iridium(III) Complexes as Tested Materials for New Anticancer Agents
PublicationThe oncological use of cisplatin is hindered by its severe side eects and a very important resistance problem. To overcome these problems, scientists have attempted to design new generation transition-metal anticancer complexes. In this study, we present new complexes, ruthenium(II) [(6-p-cymene)RuCl(py2CO)]PF6 (1), iridium(III) [(5-Cp)IrCl(py2CO)]PF6 (2), and NH4[IrCl4(py2CO)]H2O (3), based on di-2-pyridylketone (py2CO). The prepared...
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Probing the Magnetic Anisotropy of Co(II) Complexes Featuring Redox-Active Ligands
PublicationCoordination complexes that possess large magnetic anisotropy (otherwise known as zero-field splitting, ZFS) have possible applications in the field of magnetic materials, including single molecule magnets (SMMs). Previous studies have explored the role of coordination number and geometry in controlling the magnetic anisotropy and SMM behavior of high-spin (S = 3/2) Co(II) complexes. Building upon these efforts, the present work...
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High-Efficacy Global Optimization of Antenna Structures by Means of Simplex-Based Predictors
PublicationDesign of modern antenna systems has become highly dependent on computational tools, especially full-wave electromagnetic (EM) simulation models. EM analysis is capable of yielding accurate representation of antenna characteristics at the expense of considerable evaluation time. Consequently, execution of simulation-driven design procedures (optimization, statistical analysis, multi-criterial design) is severely hindered by the...
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The spectral finite element model for analysis of flexural–shear coupled wave propagation
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Interfacial Charge Transfer Complexes in TiO2-Enediol Hybrids Synthesized by Sol–Gel
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New Dinuclear Macrocyclic Copper(II) Complexes as Potentially Fluorescent and Magnetic Materials
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Symmetry-Dependent Vibrational Circular Dichroism Enhancement in Co(II) Salicylaldiminato Complexes
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Conservative surgical repair in cervical atresia associated with partial or complete absence of the vagina
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Molecular Dynamics of Complexes of Atosiban with Neurohypophyseal Receptors in the Fully Hydrated Phospholipid Bilayer
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Odontogenic orbital cellulitis in a young man with complete vision loss – a case report
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A compact seven-section rat-race hybrid coupler incorporating pbg cells
PublicationA conventional rat-race coupler has been doubly miniaturized: (i) characteristic impedances and electrical lengths of microstrip sections have been adequately modified as the first step of size reduction and (ii) T-shaped PBG cells have been implemented to diminish strip section length as the second step of circuit rat-race couplerminiaturization. The experimental results show good agreement with theoretical characteristics. Furthermore,...
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Investigations of the circulation effects in the structure using ferrite coupled slot-line section
PublicationW artykule przedstawiono badania cyrkulatora zrealizowanego w oparciu o magnesowaną wzdłużnie sekcję ferrytowych szczelinowych linii sprzężonych. Zaproponowane rozwiązanie pozwala na minimalizację rozmiarów układu cyrkulatora oraz na uzyskanie parametrów porównywalnych z dotychczas publikowanymi. W treści artykułu opisano kolejne etapy projektu. Wyniki numeryczne zweryfikowano eksperymentalnie. Pomierzony układ charakteryzował...
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Self-assembly of zinc and cobalt complexes mimicking active site of alcohol dehydrogenase
PublicationPo raz pierwszy zsyntetyzowano obojętne kompleksy cynku i kobaltu naśladujące strukturę centrum aktywnego dehydrogenazy alkoholowej z wodą jako dodatkowym ligandem. Jakość otrzymanych kryształów pozwoliła na szczegółową analizę wewnątrzcząsteczkowych wiązań wodorowych w kryształach tych związków. Wnioski potwierdzono za pomocą spektroskopii FT-IR w ciele stałym.
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Determination of Urinary Pterins by Capillary Electrophoresis Coupled with LED-Induced Fluorescence Detector
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Thermal properties of lanthanide(III) complexes with 5-amino-1,3-benzenedicarboxylic acid
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New dioxomolybdenum(VI) complexes of tetradentate Schiff base as catalysts for epoxidation of olefins
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Tribological and nanoscale research on model friction couples intended for hip joint prostheses
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B-podand complexes with sodium ions: the reaction heats and PM5 semiempirical calculation
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