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Search results for: HYDRAZONE BOND
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Activation of N2O and SO2 by the P–B Bond System. Reversible Binding of SO2 by the P–O–B Geminal Frustrated Lewis Pair
PublicationHerein, we present the first transformation of borylphosphine into borylphosphinite using nitrous oxide. Borylphosphine reacts with N2O via insertion of a single oxygen atom into the P−B bond and formation of a P−O−B bond system. Borylphosphine and borylphosphinite capture SO2 and activate it in an irreversible and reversible manner, respectively.
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BONE MARROW TRANSPLANTATION
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Molecular Structures of the Phospha-Wittig Reaction Intermediate: Initial Step in the Synthesis of Compounds with a C═P–P Bond as Products in the Phospha-Wittig Reaction
PublicationThe phospha-Wittig reactivity ofβ-diketiminate titanium(III) complexes with phosphanylphosphido ligands was investigated. The reactions of [MeNacNacTi(Cl){η2-P(SiMe3)-PtBu2}] and [MeNacNacTi(Cl){η2-P(SiMe3)-P(Ph)tBu}] with acetone conducted in toluene solution under mild conditions led to the phospha-Wittig intermediates [{(ArN=C(Me)CHC(Me)=NAr)(C(Me)2O}Ti(Cl){PtBu2-P(SiMe3)C(Me)2O}] (1) and [{(ArN=C(Me)CHC(Me)=NAr) (C-(Me)2O}Ti(Cl){P(Ph)tBu-P(SiMe3)C(Me)2O}]...
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Dirichlet-to-Neumann and Neumann-to-Dirichlet embedding methods for bound states of the Dirac equation
PublicationZaprezentowano uogólnienie formalizmu operatorów Dirichleta-Neumanna (DtN) i Neumanna-Dirichleta (NtD) na przypadek równania Diraca. Przedstawiono zastosowanie tego formalizmu do znajdowania poziomów energetycznych cząstki Diraca związanej w potencjale.
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Temperature effect on the emission spectra of narrow band Mn4+phosphors for application in LEDs
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Hydrogen-Containing Na3HTi1–xMnxF8 Narrow-Band Phosphor for Light-Emitting Diodes
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Quantitative Ultrasound Bone Measurements in Pre-Pubertal Children with Type 1 Diabetes
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A bound on the number of middle-stage crossbars in f-cast rearrangeable Clos networks
PublicationIn 2006 Chen and Hwang gave a necessary and sufficient condition under which a three-stage Clos network is rearrangeable for broadcast connections. Assuming that only crossbars of the first stage have no fan-out property, we give similar conditions for f-cast Clos networks, where f is an arbitrary but fixed invariant of the network. Such assumptions are valid for some practical switching systems, e.g. high-speed crossconnects....
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Algorytm branch-and-bound dla pewnego problemu szeregowania zadań uwarunkowanych czasowo
PublicationW artykule został przedstawiony algorytm branch-and-bound dla problemu szeregowania zadań uwarunkowanych czasowo 1 | pi = 1 + aisi | sum Ci. Przedstawiono także wyniki eksperymentów komputerowych prezentujących wydajność algorytmu. Zastosowanie przedstawionego algorytmu umożliwia powiększenie "obliczalnych" rozmiarów instancji o 6-10 zadań w stosunku do algorytmu pełnego przeszukiwania.
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Effective one-band Hamiltonian for the copper-oxygen plane in the superconducting copper oxides
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In vivo and in vitro study of a novel nanohydroxyapatite sonocoated scaffolds for enhanced bone regeneration
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Interfacial behavior of polar, weakly polar, and nonpolar compounds bound to activated carbons
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Dipolowe anteny planarne do zastosowań w standardzie Ultra-Wide band
PublicationW pracy dokonano przeglądu dipolowych anten planarnych projektowanych dla standardu UWB. Przedstawiono przykładowe promienniki oraz symetryzatory szerokopasmowe, które składają sie na antenę dipolową. porównano dopasowania anten dla wybranych kształtów promienników.
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Electronic and optical properties of theMg2−xFexSiO4spinel: From band insulator to Mott insulator
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Simplifying biochemical tumorous bone remodeling models through variable order derivatives
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Polyphenol-Enriched Composite Bone Regeneration Materials: A Systematic Review of In Vitro Studies
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A strongly bound OF3- anion and its unstable parent neutral OF3 species
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Inverse surrogate models for fast geometry scaling of miniaturized dual-band couplers
PublicationRe-design of microwave structures for various sets of performance specifications is a challenging task, particularly for compact components where considerable electromagnetic (EM) cross-couplings make the relationships between geometry parameters and the structure responses complex. Here, we address geometry scaling of miniaturized dual-band couplers by means of inverse surrogate modeling. Our approach allows for fast estimation...
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Dirichlet-to-Neumann and Neumann-to-Dirichlet embedding methods for bound states of the Schrodinger equation.
PublicationPrzeformułowano metodę Inglesfielda, stosowaną do obliczania własności stanów związanych równania Schrodingera, stosując formalizm operatorów całkowych Dirichleta-do-Neumanna(DtN) i Neumanna-do-Dirichleta (NtD). Wykorzystano zasady wariacyjne dla energii dopuszczające użycie funkcji próbnych nieciągłych wraz z pochodnymi. Podano metodę konstrukcji jąder operatorów DtN i NtD za pomocą rozwiązań zagadnienia własnego typu Steklova....
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The Righi-Leduc effect: on evidence of two-band electronic structure in Nd1.86Ce0.14CuO4-y.
PublicationPrzedstawiono badania temperaturowe zależności oporu elektrycznego, efektu Halla (RH), przewodnictwa cieplnego (k) i współczynnika Righi-Leduc(SRL). Badania wykazały, że współczynnik RL> 0 w szerokim zakresie temperatur RH zmienia znak dwukrotnie w T=50 i 250K. Niezgodność znaków SRL i RH jednoznacznie wskazuje obecność w materiale nośników obu znaków tzn. n- i p- typu. W pracy pokazano, że transport ciepła zdominowany jest przez...
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From phosphanylphosphaalkenes to coordination copper and silver polymers containing P–P bonds
PublicationThis study was focused on the activation of the C[double bond, length as m-dash]P bond via reactions of Ph2C[double bond, length as m-dash]P-PtBu2 (1) with 1,6-hexanediol and selected dithiols (1,4-butanedithiol, 1,4-benzenedithiol and 1,4-benzenedimethanethiol). These reactions proceed according to a 1,2-addition mechanism, providing new compounds with formulas {(Ph)2(H)C-P-PtBu2}{μ2-(O-(CH2)6-O)}{tBu2P-P-C(H)(Ph)2} (2), {(Ph)2(H)C-P-PtBu2}{μ2-(S-(CH2)4-S)}{tBu2P-P-C(H)(Ph)2}...
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Green engineered biomaterials for bone repair and regeneration: Printing technologies and fracture analysis
PublicationDespite the exceptional self-regeneration properties of bone, severe injuries often require additional surgical intervention such as using artificial bone constructs. These structures need to meet a number of criteria regarding their structure, performance, alongside the rate and the mechanism of erosion and fracture when implanted, for stimulating the regeneration of defected bone and, more critically providing support in the...
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BIOLOGICAL AGE ASSESSMENT ALGORITHMS BASED ON X-RAY IMAGES OF BONE TISSUE
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Capacity of Surface Production of Band Sawing in Manufacture of Oak Floor Upper Layers
PublicationThin lamellae, corresponding to the layer components of structural glued members, i.e., 2-ply or 3-ply glued flooring, can be manufactured in re-sawing operations of kiln-dried wood blocks or in wet technologies, which currently seem to be more common because of the shorter drying time. The re-sawing process in wet technology is conducted on dedicated thin-cutting band sawing machines with stellite-tipped band saws. The goal of...
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Design of compact self-quintuplexing antenna with high-isolation for penta-band applications
PublicationThis article presents a novel compact self-quintuplexing antenna architecture based on a substrate-integrated rectangular cavity (SIRC) for pentaband applications. The proposed self-quintuplexing antenna is constructed by employing an SIRC, one Pi-shaped slot (PSS), one T-shaped slot (TSS), and five 50Ω microstrip feedlines. The PSS and TSS are engraved on the top of the SIRC to create five radiating patches, which are excited...
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Rapid dimension scaling of triple-band antennas by means of inverse surrogate modeling
PublicationGeometry scaling of antennas, i.e., finding optimum dimensions of the structure for given operating conditions and material parameters is an important yet challenging problem. In this paper, we discuss fast dimension scaling of triple-band antennas with respect to operating frequencies. We adopt the inverse surrogate modeling approach where the surrogate model is a function of the three operating frequencies of the antenna and...
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Biomechanical testing of bioactive bone cements – a comparison of the impact of modifiers: antibiotics and nanometals
PublicationApart from its bone filler and fracture stabilizing function, bone cement can be used as a carrier of bioactive substances, and such modified bone cement can protect the implant against microorganisms, treat local infections and combat bacteria introduced during the surgical procedure. In this paper, the effects of modifying antibiotics and nanosilver on the biomechanical properties of bone cement were examined. The following tests...
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Comprehensive dimension scaling of multi-band antennas for operating frequencies and substrate parameters
PublicationIn this paper, low-cost and comprehensive redesign of multi-band antennas with respect to the operating frequencies and material parameters of the substrate is presented. Our approach exploits an inverse surrogate model identified based on a set of reference designs optimized at the level of coarse-discretization EM simulations of the antenna at hand. An iterative correction procedure is also implemented to account for the initial...
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Effect of aeration of antibiotic-loaded bone cement on its properties and bactericidal effectiveness
PublicationBACKGROUND: Antibiotic-loaded bone cements are now widely used in medicine. They are able to locally deliver antibiotic particles and they allow treat or protect against infection. It is assumed that the bactericidal effectiveness of bioactive bone cements depend on the parameters of its production. Hence, the aim of this study was to check the effect of aeration of bone cement before mixing the components on its properties as...
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Influence of Different Nanometals Implemented in PMMA Bone Cement on Biological and Mechanical Properties
PublicationCemented arthroplasty is a common process to fix prostheses when a patient becomes older and his/her bone quality deteriorates. The applied cements are biocompatible, can transfer loads, and dampen vibrations, but do not provide antibacterial protection. The present work is aimed at the development of cement with antibacterial effectivity achieved with the implementation of nanoparticles of different metals. The powders of Ag,...
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VALUATION OF EMBEDDED OPTIONS IN NON-MARKETABLE CALLABLE BONDS: A NEW NUMERICAL APPROACH
PublicationThe issue of how to price options embedded in callable bonds has attracted a lot of interest over the years. The usual bond valuation methods rely on yield curves, risk premium, and other parameters to estimate interest rates used in discounted cash flow calculations. The option to retire the bond is, however, neglected in the standard pricing models, causing a systematic overvaluation of callable bonds. In the event of a decline...
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Person Tracking in a Ferry Environment Using Ultra-Wide Band Radio Interface
PublicationThis article presents research and analysis of effectiveness of tracking moving people in an environment of passenger ferry, using measurements of propagation time of ultra-wide band radio signal (UWB - Ultra-Wide Band). Constructed measurement stand and results of measurements carried out in a real propagation conditions were shortly discussed.
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JOURNAL OF BONE AND JOINT SURGERY-AMERICAN VOLUME
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JOURNAL OF BONE AND JOINT SURGERY-BRITISH VOLUME
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Cost-Effective and Sufficiently Precise Integration Method Adapted to the FEM Calculations of Bone Tissue
PublicationThe technique of Young’s modulus variation in the finite element is not spread in biomechanics. Our future goal is to adapt this technique to bone tissue strength calculations. The aim of this paper is to present the necessary studies of the element’s integration method that takes into account changes in material properties. For research purposes, a virtual sample with the size and distribution of mechanical properties similar...
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Use of Materials Based on Polymeric Silica as Bone-Targeted Drug Delivery Systems for Metronidazole
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In-situ and ex-situ resistance measurements of polypyrrole film using double-band electrode
PublicationMany in-situ techniques are performed in order to determine the resistance of conducting polymer film. However, the resistance measured in solution can be the combination of polymer resistance and that of other components, such as resistance of supporting electrolyte. Therefore, in this work, the influence of the solution on the resistance of polypyrrole (PPy) film has been studied. PPy film was electrchemically synthesized onto...
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Postmortem analysis of human bone marrow aspirate - Quantitative determination of SSRI and SNRI drugs
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Charakterystyka sond dynamicznych i metod interpretacji wyników sondowań stosowanych w Polsce.
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Dynamic Formation and Breaking of Disulfide Bonds in Molecular Dynamics Simulations with the UNRES Force Field
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Prognostic value of stage IV neuroblastoma metastatic immunophenotype in the bone marrow: preliminary report
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Opportunistic tri-band carrier aggregation in licensed spectrum for multi-operator 5G hetnet
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Investigation ofcis/trans ratios of peptide bonds in AVP analogues containingN-methylphenylalanine enantiomers
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Influence of hydrophobic nanosilica and hydrophobic medium on water bound in hydrophilic components of complex systems
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Optimization of Polycrystalline CVD Diamond Seeding with the Use of sp³/sp² Raman Band Ratio
PublicationThe influence of various nanodiamond colloids used for seeding nondiamond substrates in microwave plasma enhanced chemical vapour deposition diamond process was investigated. Colloids based on deionized water, isopropanol alcohol and dimethyl sulfoxide (DMSO) were used with different grain size dispersion: 150, 400 and 35 nm, respectively. The influence of growth time was also taken into consideration and bias enhanced nucleation....
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Crystal structure, hydrogen bonds, and lattice dynamics in kanemite from first-principles calculations
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Dielectric response of electric-field distortions of the twist-bend nematic phase for LC dimers
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(MgO)n−(n=1–5)Clusters: Multipole-Bound Anions and Photodetachment Spectroscopy
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Anab initiostudy of the betaine anion–dipole-bound anionic state of a model zwitterion system
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The influence of the place of residence, smoking and alcohol consumption on bone mineral content in the facial skeleton
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