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Wyniki wyszukiwania dla: FT-IR SPECTRA
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Efficient Extraction of Fermentation Inhibitors by Means of Green Hydrophobic Deep Eutectic Solvents
PublikacjaThe methods for hydrogen yield efficiency improvements, the gaseous stream purification in gaseous biofuels generation, and the biomass pretreatment are considered as the main trends in research devoted to gaseous biofuel production. The environmental aspect related to the liquid stream purification arises. Moreover, the management of post-fermentation broth with the application of various biorefining techniques gains importance....
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Evaluating the impact of ZnO doping on electrical and thermal properties of calcium-aluminosilicate oxynitride glass-ceramics
PublikacjaThis study aimed to investigate the impact of ZnO content on the structure, thermal, and electrical properties of oxynitride glass-ceramic(s) within the Ca–Al–Si–O–N (CASON) system. The base glass had the composition of Ca7Al14Si17O52N7, with ZnO additions ranging from 3 to 15 % by weight. A pristine Ca7Al14Si17O52N7 glass was successfully prepared by melt-quenching technique followed by converted into glass-ceramic by incorporating various...
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Interactions in aqueous solutions of K-peptide and DMSO – spectroscopic and calorimetric studies
PublikacjaIntroduction K-peptide (GILQINSRW) – short 9 amino acid fragment of the hen egg white lysozyme has the ability to form amyloid structures. Dimethyl sulfoxide (DMSO) is an osmolyte which can alter this ability. Our goal was to get an insight into the mechanism of Kpeptide-DMSO interactions in aqueous solutions. Such a knowledge can be helpful to understand processes leading to various neurodegenerative diseases. Methods ATR-FTIR...
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PHOTONICS SPECTRA
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Comparison of Cadmium Cd2+ and Lead Pb2+ Binding by Fe2O3@SiO2‐EDTA Nanoparticles – Binding Stability and Kinetic Studies
PublikacjaThis study describes the synthesis and characterization of ethylenediaminetetraacetic acid (EDTA) functionalized magnetic nanoparticles of 20 nm in size – Fe3O4@SiO2‐EDTA – which were used as a novel magnetic adsorbent for Cd(II) and Pb(II) binding in aqueous medium. These nanoparticles were obtained in two‐stage synthesis: covering by tetraethyl orthosilicate and functionalization with EDTA derivatives. Nanoparticles were characterized...
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Polynomial analysis as a new way of describing dynamic impedance spectra – Differential and relative impedance spectra
PublikacjaModel measurements of an equivalent electrical system were carried out using the technique of Dynamic Electrochemical Impedance Spectroscopy. The measurement took the form of potentiodynamic changes imposed on the tested system. Using the possibility of continuous impedance measurements, an attempt was made to develop an original and innovative method of analyzing impedance spectrograms, which is termed polynomial analysis. As...
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IR-THERMAL IMAGING IN CARDIOSURGERY
PublikacjaA method for monitoring the state of the myocardium during cardiosurgical interventions based on thermal IR imaging is presented. These methods called Static Thermography and Active Dynamic Thermography (ADT) uses information about distribution of temperature on the surface and an external excitation source to induce thermal transient processes in a tested object. Recording time series of thermograms allows to calculate parametric...
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Development of biocompatible iron oxide-silicon oxide core-shell nanoparticles as subcellular delivery platform for glucosamine-6-phosphate synthase inhibitors
PublikacjaIn order to develop the preparation of iron oxide-silica coreshell nanoparticles (CSNPs), thesis deeply explores the cetyltrimethylammonium (CTA+) directed silica coating methods of the oleic-acid capped iron oxide nanoparticles (OA-IONPs) initialized under near-neutral pH conditions. It is demonstrated that the initial alkaline hydrolysis of ethyl acetate in the presence of CTA+ and OA-IONPs induces an unusual ligand exchange...
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Similarities and differences in d6 low-spin ruthenium, rhodium and iridium half-sandwich complexes: synthesis, structure, cytotoxicity and interaction with biological targets
PublikacjaIn this paper, we discussed the similarities and diferences in d6 low-spin half-sandwich ruthenium, rhodium and iridium complexes containing 2,2′-biimidazole (H2biim). Three new complexes, {[RuCl(H2biim)(η6 -p-cymene)]PF6}2·H2O (1), [(η5 - Cp)RhCl(H2biim)]PF6 (2), and [(η5 -Cp)IrCl(H2biim)]PF6 (3), were fully characterized by CHN, X-ray difraction analysis, UV–Vis, FTIR, and 1 H, 13C and 15N NMR spectroscopies. The complexes exhibit...
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IR and Raman study of oxy-nitride glasses
PublikacjaVarious silicate and phosphate glasses with and without nitride addition were structurally characterized by IR and Raman spectroscopy. The studied glass systems include Na-Ca-P-O-N (1), AE-Si-O-N (with AE=Mg, Ca, Sr, Ba)(2), La-Si-O-N (3) as well as the Na-(Li)-Be-O-(N) (4,5) system. The samples were prepared by different techniques such as remelting of pre-prepared glass samples of the oxide systems with Mg and/or Si3N4 powders...
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Algorithms of chemicals detection using raman spectra
PublikacjaRaman spectrometers are devices which enable fast and non-contact identification of examined chemicals. These devices utilize the Raman phenomenon to identify unknown and often illicit chemicals (e.g. drugs, explosives)without the necessity of their preparation. Now, Raman devices can be portable and therefore can be more widely used to improve security at public places. Unfortunately, Raman spectra measurements is a challenge...
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Organizacijos etyika ir kultura: buti ar atrodyti
PublikacjaW artykule podjęta próba wyjaśnienia wpływu instytucjonalizacji etyki na in-tegrację kultury organizacyjnej oraz jakośc wykonawstwa.
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Phosphorescence response to excitonic interactions in Ir organic complex-based electrophosporescent emitters
PublikacjaSpadek kwantowej wydajności fosforescencji ze wzrostem natężenia światła wzbudzajacego w Ir(ppy)3 tworzącym 100% warstwę naparowaną próżniowo oraz w Ir(ppy)3 umieszczonym w matrycy polimerowej PC:TPD, jest wywołany odziaływaniami między ekscytonami trypletowymi. Stała oddziaływania tryplet-tryplet wynosi (1-3)x 10-12 cm3/s i tylko nieznacznie zależy od stężenia Ir(ppy)3 w warstwie.
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Surface Science Spectra
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Strong-coupling superconductivity of SrIr2 and SrRh2 : Phonon engineering of metallic Ir and Rh
PublikacjaExperimental and theoretical studies on superconductivity in SrIr2 and SrRh2 Laves phases are presented. The measured resistivity, heat capacity, and magnetic susceptibility confirm the superconductivity of these compounds with Tc = 6.07 and 5.41 K, respectively. Electronic structure calculations show that the Fermi surface is mostly contributed by 5d (4d) electrons of Ir (Rh), with Sr atoms playing the role of electron donors....
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Indole-Acrylonitrile Derivatives as Potential Antitumor and Antimicrobial Agents—Synthesis, In Vitro and In Silico Studies
PublikacjaA series of 2-(1H-indol-2-yl)-3-acrylonitrile derivatives, 2a–x, 3, 4a–b, 5a–d, 6a–b, and 7, were synthesized as potential antitumor and antimicrobial agents. The structures of the prepared compounds were evaluated based on elemental analysis, IR, 1H- and 13NMR, as well as MS spectra. X-ray crystal analysis of the representative 2-(1H-indol-2-yl)-3-acrylonitrile 2l showed that the acrylonitrile double bond was Z-configured. All...
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Determination of Hydroxy Groups in the Modified Epoxy Oligomers Using IR-Spectroscopy
PublikacjaThe use of IR-spectroscopy has been proposed to determine the content of hydroxy groups in the modified functional oligomers based on bisphenol A diglycidyl ether. Apart from hydroxy groups the investigated oligomers contain epoxy or peroxy, carboxy or acrylic groups.
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Quantitative Active Dynamic Thermal IR-Imaging and Thermal Tomography in Medical Diagnostic
PublikacjaPrinciples of Active dynamic thermal (ADT) IR-imaging and Thermal Tomography are described in details. Basic medical applications of this new modality are also discussed.
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Ekonomika ir Vadyba: Aktualijos ir Perspektyvos
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LCT, PIV and IR Imaging Detection in Selected Technical and Biomedical Applications
PublikacjaPaper presents the brief summary of the history of Thermochromic liquid crystals (TLC), Particle Image Velocimetry (PIV) and Infrared Imaging Themography (IR). Principal methods and tools are described and some examples are presented. With this objective, a new experimental technique have been developed and applied to the study of heat and mass transfer and for biomedical diagnosis. Selected results of experiments using these methods...
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Porównanie spektroskopii IR oraz NIR w analizie tożsamościowej surowców kosmetycznych i farmaceutycznych
PublikacjaTechniki wykorzystujące spektroskopię podczerwieni (IR) i bliskiej podczerwieni (NIR) znalazły szerokie zastosowanie w wielu gałęziach przemysłu takich jak: przemysł spożywczy, farmaceutyczny, petrochemiczny, kosmetyczny, rolniczy. Spektroskopia podczerwieni wykorzystywana jest zarówno w analizie jakościowej jak i ilościowej surowców, produktów końcowych czy też podczas monitorowania procesów produkcyjnych. Dzięki połączeniu spektroskopii...
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Modyfikacja sposobu wytłumiania wybranej częstotliwości w widmie sygnału UWB-IR
PublikacjaW artykule przeanalizowano wybraną metodę kształtowania widma impulsowego sygnału UWB przez odpowiedni dobór stosowanych ciągów pseudoprzypadkowych. Opisano opracowaną modyfikację tej metody polegającą na zastosowaniu dodatkowej modulacji amplitudy generowanych impulsów, co w rezultacie poprawia jakość wytłumiania niepożądanej częstotliwości w widmie sygnału UWB-IR. Przedstawiono wyniki porównawcze wykonanych w tym zakresie badań...
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Raman Spectra Measurements for Chemical Identifications - Aspect of Uncertainty Sources and Reduction of Their Effects
PublikacjaRaman spectrometers enable fast and non-contact identification of examined chemicals. These devices measure Raman spectra and compare with the spectra database to identify unknown and often illicit chemicals (e.g. drugs, explosives) usually without any sample preparation. Raman spectra measurements are a challenge due to noise and interferences present outside the laboratories (field applications). The design of a portable Raman...
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Vapor correction of FTIR spectra – A simple automatic least squares approach
PublikacjaFTIR spectroscopy is one of the best techniques to study intermolecular interactions. However, such an application requires high quality spectra with as little noise as possible, which are often difficult to obtain. One of the main sources of unwanted interference is water vapor. Here a robust method is proposed for automatic, fast and reliable vapor correction of FTIR spectra. The presented least squares approach of vapor subtraction...
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LCT, PIV and IR Imaging Detection in Selected Technical and Biomedical Applications
PublikacjaThermochromic liquid crystals (TLC), Particle Image Velocimetry (PIV) and Infrared Imaging Themography (IR) have been successfully used in non-intrusive technical, industrial and biomedical studies and applications. These four tools (based on the desktop computers) have come together during the past two decades to produce a powerful advanced experimental technique as a judgment of quality of information that cannot be obtained...
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Liquid Crystals, PIV and IR-Photography in Selected Technical and Biomedical Applications
PublikacjaThermochromic liquid crystals (TLC), Particle Image Velocimetry (PIV), Infrared Imaging Themography (IR) and True-Colour Digital Image Processing (TDIP) have been successfully used in non-intrusive technical, industrial and biomedical studies and applications. These four tools (based on the desktop computers) have come together during the past two decades to produce a powerful advanced...
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Temperature influence on tyre/road noise frequency spectra
PublikacjaThe correction for temperature effect on measured tyre/road noise is very important as it may be one of the main sources of errors in measurement results due to substantial influence of this parameter on obtained values. The latest version of the Technical Specification ISO/CD TS 13471-1 about Temperature Corrections contains a proposal of correction procedure for normalizing measured noise levels to a reference air temperature...
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Modyfikacja β-cyklodekstryny w celu uzyskania pH czułego nośnika leków antracyklinowych
PublikacjaW 2012 roku 68% zgonów było spowodowanych przez choroby niezakaźne takie, jak nowotwory, choroby układu krążenia, przewlekłe choroby układu oddechowego [1]. Zgodnie z danymi Światowej Organizacji Zdrowia (ang. World Health Organization, WHO) w 2012 roku 32,6 miliona osób cierpiało z powodu chorób nowotworowych, a 8,2 miliona zmarło z ich powodu [2]. Szacowane jest, że z roku na rok odsetek osób chorujących na choroby nowotworowe...
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Hydration of amino acids: FTIR spectra and molecular dynamics studies
PublikacjaThe hydration of selected amino acids, alanine, glycine, proline, valine, isoleucine and phenylalanine, has been studied in aqueous solutions by means of FTIR spectra of HDO isotopically diluted in H2O. The difference spectra procedure and the chemometric method have been applied to remove the contribution of bulk water and thus to separate the spectra of solute-affected HDO. To support interpretation of obtained spectral results,...
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Veterinarija ir Zootechnika
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Darbai ir Dienos
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Advances of IR-Thermal Diagnostics in Medicine
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A new diagnostic IR-thermal imaging method for evaluation of cardiosurgery procedures
PublikacjaTwo methods for monitoring the state of the myocardium during cardiosurgical interventions based on thermal IR imaging are presented below. These methods, called static thermography and active dynamic thermography (ADT), use information about the distribution of temperature on the surface, and an external excitation source to induce thermal transient processes in a tested object. Recording the time series of thermograms allows...
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Consideration of dynamic loads in the determination of axle load spectra for pavement design
PublikacjaAxle load spectra constitute a crucial part of the data for pavement design and pavement distress analysis. Typically, axle load spectra represent static load from vehicles and do not include dynamic loads generated by vehicles in motion. While dynamic loads can significantly contribute to faster pavement distress, this fact is mostly omitted in pavement design methods. The paper presents a methodology for consideration of dynamic...
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EARTHQUAKE SPECTRA
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Computer Support of Analysis of Optical Spectra Measurements
PublikacjaThe verification of measurement errors has a big impact on the assessment of the accuracy of conducted measurements and obtained results. In many cases, computer simulation results are compared with measurement results in order to evaluate measurement errors. The purpose of our research was to check the accuracy of measurements made with a Fabry–Perot interferometer working in the transmission mode. In the measurement setup, a...
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Sea spectra revisited
PublikacjaPokazano, że widma falowania ITTC, wywodzące się z widma Bretschneidera, zależnego od dwóch parametrów, można zredukować do wspólnego widma bezwymiarowego, co oznacza, że są one geometrycznie powinowate. To samo dotyczy widma JONSWAP, które dodatkowo charakteryzuje trzeci paprametr, związany z kształtem piku. Umożliwia to aproksymację tych widm za pomocą rozkładu log-normalnego, co zapewnia realistyczny parametr szerokości widma,...
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FT-Raman spectroscopy as a tool in evaluation the response of plants to drought stress
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Comparison of modelling and measurement results of spectra emitted by a programmable lamp
PublikacjaNowadays artificial light with an optimized spectrum is used in many different applications. For instance, it is widely used in museums and exhibitions to illuminate the art. Moreover, such light stimulates the growth of plants, or can be applied in industry and healthcare. To achieve the best results for each application, the adjusting of a dedicated spectrum is required, which is a complicated task. The ongoing research is focused...
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Komisja Programowa FT
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WEiE - FT 2024
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Electromodulation of photoluminescence in vacuum-evaporated films of fac-tris(2-phenylpyridine)iridium(III)
PublikacjaZaobserwowano silne wygaszenie fosforescencji w komórkach sandwiczowych Al/Ir(ppy)3/Al/kwarc, które w polu elektrycznym o natężeniu 3 MV/cm dochodzi do 30%. Mechanizm wygaszania jest związany z dysocjacją ekscytonów trypletowych pod działaniem zewnętrznego pola elektrycznego w obszarach zdefektowanych sieci krystalicznej.
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FT-Raman Spectroscopy as a Tool to Study the Secondary Structures of Wheat Gliadin Proteins
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Chemometric Method of Spectra Analysis Leading to Isolation of Lysozyme and CtDNA Spectra Affected by Osmolytes
PublikacjaW niniejszej pracy zaprezentowana została chemometryczna metoda analizy danych widmowych, prowadząca do wyizolowania widm FTIR biomakrocząsteczek (lizozymu z białka jaja kurzego i ctDNA) zaburzonych przez wybrane osmolity (TMAO, betainę) w roztworach wodnych. Została ona oparta na metodzie widm różnicowych, wykorzystywanej pierwotnie do określania struktury rozpuszczalnika wokół cząsteczek substancji rozpuszczonej. Cykliczne wykorzystanie...
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Calculation of Vibrational Resonance Raman Spectra of Molecules Using Quantum Chemistry Methods
PublikacjaThe understanding and interpretation of experimental resonance Raman (RR) spectra can strongly benefit from theoretical simulations. These can be achieved by combining quantum chemistry (QC) methods to calculate the electronic and vibrational molecular properties, together with appropriate models and approximations to compute the Raman intensities. This chapter presents the main and most commonly employed approaches to calculate...
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The amplitude analysis of impedance spectra
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A study of the photoelectron spectra of α-tetrahydrofurfuryl alcohol over the outer valence energy region (9–25 eV)
PublikacjaPhotoelectron spectra of α-tetrahydrofurfuryl alcohol (THFA) molecules, the threshold spectrum and spectra for constant photoelectron energies, have been measured over the photon energy range 9–25 eV. Analysis of the photoelectron spectra has allowed overlapping photoionization bands to be separated, tentatively assigned and their vertical photoionization energies to be determined. These energies are compared with existing theoretical...
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Frequency response spectra applied to assess efficiency of the training techniques
PublikacjaThe purpose of the research is to assess the increase of the muscle strength and power. Movement of the human body when the moving one impacts a stationary or moving body is taken under consideration. The waveform produced by an impact is transformed into frequency domain. The acceleration record is transformed as a complex spectrum, by the use of a Discrete Fourier Transformation. In this paper the applications of the discrete...
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Study on the accuracy of axle load spectra used for pavement design
PublikacjaWeigh-in-Motion (WIM) systems are used in order to reduce the number of overloaded vehicles. Data collected from WIM provide characteristics of vehicle axle loads that are crucial for pavement design as well as for the development of pavement distress prediction models. The inaccuracy of WIM data lead to erroneous estimation of traffic loads and in consequence inaccurate prediction of pavement distress process. The objective of...
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Local chirality measures in QSPR : IR and VCD spectroscopy
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