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Volatile organic compound separation from gas phase using ionic liquids
PublikacjaZanieczyszczenie powietrza lotnymi związkami organicznymi staje się światowym problemem ochrony środowiska w związku z ich toksycznymi właściwościami. W związku z tym poszukuje się nowych, efektywnych technologii oczyszczania strumieni gazowych. Powszechnie stosowaną metodą jest utlenianie termiczne. Wiąże się ono jednak z Wysokiem zużyciem energii i efektami ubocznymi w postaci emisji dwutlenku węgla i tlenków azotu. Alternatywą...
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Investigation of the distribution of imidazolium ionic liquids in the environment - aggregation in water and sorption on minerals
PublikacjaWpływ cieczy jonowych na środowisko, a w szczególności: migracja do wód powierzchniowych i gruntowych, jak również transport/retencja w gruntach jest determinowany przede wszystkim przez właściwości fizykochemiczne cieczy jonowej jak i właściwości matrycy środowiskowej. Znajomość zjawisk zachodzących w wyniku kontaktu cieczy jonowych z wodą oraz glebą jest jednym z podstawowych warunków oceny ryzyka chemicznego. W pracy wykazano,...
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Determination of ionic conductivity in the Bi-Si-O and Pb-Si-O glasses
PublikacjaImpedance spectroscopy measurements in various gas atmospheres were carried out in order to explain the doubts about the type of carriers and the mechanism of electrical conductivity in Bi-Si-O and Pb-Si-O glasses. In bismuth silicate glass, a typical ionic conductivity with oxygen ions as charge carriers was observed. The level of electrical conductivity of the glass at 400 °C was 5 × 10−8 S·cm−1 , with the activation energy of...
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The domination of ionic conductivity in tetragonal phase of the organometal halide perovskite CH3NH3PbI3-xClx
PublikacjaOrganometal trihalide perovskites have recently gained extreme attention due to their high solar energy conversion in photovoltaic cells. Here, we investigate the contribution of iodide ions to a total conductivity of the mixed lead halide perovskite CH3NH3PbI3−xClx with a use of the modified DC Hebb–Wagner polarization method. It has been identified that an ionic conductivity dominates in tetragonal phase which is associated with room...
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Chromatographic behaviour of ionic liquid cations in view of quantitative structure-retention relationship
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Ionic liquids for nano- and microstructures preparation. Part 1: Properties and multifunctional role
PublikacjaIonic liquids (ILs) are a broad group of organic salts of varying structure and properties, used in energy conversion and storage, chemical analysis, separation processes, as well as in the preparation of particles in nano- and microscale. In material engineering, ionic liquids are applied to synthesize mainly metal nanoparticles and 3D semiconductor microparticles. They could generally serve as a structuring agent or as a reaction...
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Selected issues related to the toxicity of ionic liquids and deep eutectic solvents—a review
PublikacjaGreen Chemistry plays a more and more important role in implementing rules of sustainable development to prevent environmental pollution caused by technological processes, while simultaneously increasing the production yield. Ionic liquids (ILs) and deep eutectic solvents (DESs) constitute a very broad group of substances. Apart from many imperfections, ILs and DESs have been the most promising discoveries in the world of Green...
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Comparison of different advanced oxidation processes for the degradation of room temperature ionic liquids
PublikacjaZbadano możliwość zastosowania wybranych zaawansowanych technologii utleniania (UV, UV/H2O2, UV/TiO2) do degradacji cieczy jonowych. Do degradacji wytypowano pięć związków: HHiM, BMiM, MiM, OMiM oraz EEiM.
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Mixed electronic-ionic conductivity in vanadate oxide glasses containing alkaline ions
PublikacjaZbadano mieszane przewodnictwo polaronowo-jonowe w szkłach wanadanowych zawierających jony metali alkalicznych.
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Application of surface active amino acid ionic liquids as phase-transfer catalyst
PublikacjaFive structurally related morpholinium derived ionic liquids containing N-acetyl-glycinate anion were synthesized and their thermal stability, surface properties and activity as phase transfer catalysts investigated. The thermal properties were studied by differential scanning calorimetry, while the adsorption at the air/water interface and micellization behavior was analyzed by surface tension measurements, conductometry and isothermal...
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Use of pyridinium and pyrrolidinium ionic liquids for removal of toluene from gas streams
PublikacjaSeparation of toluene from a toluene/N2 gas mixture using supported liquid membranes based on a series of pyridinium (1-butylpyridinium- bis(trifluoromethylsulfonyl)imide - [C4Py][Tf2N], 1-hexylpyridinium trifluoromethanesulfone [C6Py][Tf2N]) and pyrrolidinium (1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide - [C4Pyrr][Tf2N], 1-hexyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide - [C6Pyrr][Tf2N], 1-butyl-1-methylpyrrolidinium...
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Deodorization of model biogas by means of novel non-ionic deep eutectic solvent
PublikacjaThe paper presents new non-ionic deep eutectic solvent (DES) composed of natural and non-toxic components i.e. guaiacol, camphor and levulinic acid in 1:1:3 molar ratio as a promising absorbent for removal of selected volatile organic compounds (VOCs) including dichloromethane, toluene, hexamethyldisiloxane and propionaldehyde from model biogas. The affi nity of DES for VOCs was determined as vapour-liquid coeffi cients and the...
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A new duty cycles calculation method in pulse width modulation for direct matrix converters based on the shape function concept
PublikacjaPaper presents a new approach to duty cycle calculation in pulse width modulation for direct matrix converters. The essence of the proposed method is the use of elementary shape function of finite element. The algorithm for calculating the duty cycles was reduced to simple operations on the coordinates of input and output voltage vectors without trigonometric functions.
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Current harmonic controller in multiple reference frames for series active power filter integrated with 18-pulse diode rectifier
PublikacjaThe paper presents the control system and selected results of experimental tests of the AC/DC power converter consisting of an 18-pulse diode rectifier based on coupled reactors and a serial active power filter. Proportional integral controllers with decoupling components are implemented in multiple reference frames for selective line current harmonic suppression. The regulator is provided with a backtracking anti-windup mechanism...
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Effect of pulse laser treatment at different process variables on mechanical behavior of carbon nanotubes electrophoretically deposited on titanium alloy
PublikacjaPurpose: Titanium and its alloys are widely used as biomaterials for long-term implants, but they are usually surface-modified due to their weak bioactivity and wear resistance. Laser processing was used to modify the surface layer, and elemental carbon was a component of the deposited coatings. This research aims to use a combination of both methods based on preliminary electrophoretic deposition of multi-wall carbon nanotubes...
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Robert Bogdanowicz dr hab. inż.
OsobyRobert Bogdanowicz received his Ph.D. degree with honours in Electronics from the Gdansk University of Technology. He worked as a post-doc researcher in Ernst-Moritz-Arndt-Universität Greifswald Institut für Physik. He has initiated optical emission imaging of muti-magnetron pulsed plasma and contributed to the development of antibacterial implant coatings deposited by high-power impulse magnetron sputtering. He moved back to...
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Jacek Stefański prof. dr hab. inż.
OsobyJacek Stefański ukończył studia na Wydziale Elektroniki Politechniki Gdańskiej (PG) w 1993 r. W 2000 r. uzyskał stopień doktora nauk technicznych w dyscyplinie telekomunikacja, w 2012 r. stopień doktora habilitowanego, natomiast w 2020 r. tytuł profesora nauk inżynieryjno-technicznych. Obecnie pracuje na stanowisku profesora w Katedrze Systemów i Sieci Radiokomunikacyjnych (KSiSR) PG. W latach 2005-2009 był zatrudniony w Instytucie...
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Safety Analysis for the Operation Process of Electronic Systems Used Within the Mobile Critical Infrastructure in the Case of Strong Electromagnetic Pulse Impact
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Konfrontowanie reprezentatywnych struktur spektralnych odpowiedzi impulsowej kanału głosowego [Confronting representative spectral structures of vocal tract pulse responses]
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Virtual Space Vector Pulse Width Modulation Algorithm for Three-Level NPC Converters Based on the Final Element Shape Functions
PublikacjaThe paper puts forth a novel idea for the computation of Nearest Three Virtual Space Vector Pulse Width Modulation for the three level NPC converters. The computations are based on the concept of final element shape function widely used in the domain of finite element analysis. The proposed approach significantly frees the computations from the use of trigonometric functions, which simplifies the computations and permits easier...
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Issue of Assessment of the Strong Electromagnetic Pulses Impact on the Functioning of Selected Electronic Devices
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Determination of Safety Levels of Electronic Devices Exposed to Impact of Strong Electromagnetic Pulses
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The Reliability and Operational Analysis of ICT Equipment Exposed to the Impact of Strong Electromagnetic Pulses
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Engineering Au nanoparticle arrays on SiO2 glass by pulsed UV laser irradiation
PublikacjaWe study semi-regular arrays of Au nanoparticles (NP) obtained via UV laser irradiation of thin Au films on glass substrate. The NP structures are prepared from films of a thickness up to 60 nm produced by discharge sputtering or pulsed laser deposition, and annealed by nanosecond laser pulses at 266 or 308 nm, respectively, at fluencies in the range of 60-410 mJ/cm2. For the rare- and close-packed NP structures, consistent description...
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Preparation of porous TiO2 films by means of pulsed laser deposition for photocatalytic applications
PublikacjaIn this work the preparation and structure properties of porous thin films of TiO2 were investigated. The films were produced by means of the pulsed laser deposition technique using laser pulses at 266nm (10Hz) and at fluencies of 1-3.5J/cm2. The process was performed in vacuum using O2 buffer gas and films were deposited on the SiO2 glass or Si substrate. X-ray diffraction (XRD) and Raman analysis of the structure and chemical...
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Determination of cyanide in urine and saliva samples by ion chromatography with pulsed amperometric detection
PublikacjaCommonly known as a highly toxic chemical, cyanide is also an essential reagent for many industrial processes. It naturally occurs in plant seeds as a cyanogenic glycosides. Another relatively common mode of cyanide exposure is inhalation of environmental tobacco smoke. This study concerns importance to determine cyanide ion in human biological samples. Urine and saliva samples were collected healthy volunteers exposed to tobacco...
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Supercapacitors in stand-alone pv systems with instantaneus high output energy pulses
PublikacjaSuperkondensatory (ang. supercapacitors, ultracapacitors, double-layer capacitors, gold capacitors and power capacitors) stanowią stosunkową nowość w energetyce prądu stałego, zwłaszcza w dziedzinie magazynowania i oddawania energii. Podjęto próby zastosowania superkondensatorów jako jedynego lub wspierającego źródła, służącego do gromadzenia energii PV w autonomicznych instalacjach. Opracowany we własnym zakresie, wykonany i opisany...
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Colorimetric study of the post-processing effect due to pulsed laser cleaning of paper.
PublikacjaW artykule przedstawiono wyniki badań procesu oczyszczania papieru implulsami laserowymi o różnej długości fali. Oceny dokonywano na podstawie pomierzonych wartości parametrów kolorymetrycznych. Badania obejmowały próbki papieru o różnym wieku.
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The interaction of the pulsed laser irradiation with titania nanotubes - Theoretical studies on the thermal effect
PublikacjaThis paper reports temperature dispersion simulations of titania nanotubes irradiated by the 355 nm, pulsed, nanosecond laser. The modelling with the use of Finite Elements Method concerns titania nanotubes of the length and the wall thickness in the range of 0.5–2 μm and 5–20 nm, respectively. The uniqueness of the morphology was preserved by ensuring the wall thickness variation along the height of the tube, which was determined...
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Ion Chromatography with Pulsed Amperometric Detection for Determining Cyanide in Urine and Meconium Samples
PublikacjaThe parents’ addictions and eating habits have a significant influence on the child’s growth. The first stool of a newborn baby provides a large amount of information about xenobiotics transmitted by the mother’s body. The analytical technique used in the study is ion chromatography with pulsed amperometric detection (IC-PAD). The biological samples, which were obtained from women staying in a maternity ward and their partners,...
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Characterization of Aliphatic Polyesters Synthesized via Enzymatic Ring-Opening Polymerization in Ionic Liquids
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Efficient method for Knoevenagel condensation in aqueous solution of amino acid ionic liquids (AAILs)
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Rapana thomasiana hemocyanin modified with ionic liquids with enhanced anti breast cancer activity
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Aqueous Biphasic Systems Using Chiral Ionic Liquids for the Enantioseparation of Mandelic Acid Enantiomers
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A miniaturized solid-contact potentiometric multisensor platform for determination of ionic profiles in human saliva
PublikacjaThis paper describes a miniaturized multisensor platform (MP-ISES) consisting of electrodes: a reference one (RE) and ion-selective electrodes (ISEs) for monitoring Na+, K+, Ca2+, Mg2+, Cl−, and SCN− ions and pH in human saliva. Gold electrode surface was modified by deposition of two layers: electrosynthesized PEDOT:PSS forming an intermediate layer, and ion-selective membrane. The developed ISEs were characterized by a wide linear...
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Separation of toluene from gas phase using supported imidazolium ionic liquid membrane
PublikacjaInvestigation on utilization of supported ionic liquids membranes for hydrocarbon separation from the gas phase was performed. Properties of membrane phase, wettability of supports, swelling effects and solubility of toluene were taken into account. Toluene permeation rates were significantly higher than those of pure nitrogen, the selectivity in a range of 17–341 was satisfying for separation. Despite the increase of viscosity...
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The ILs-assisted electrochemical synthesis of TiO2 nanotubes: The effect of ionic liquids on morphology and photoactivity
PublikacjaFacile and environmentally benign one-step titanium anodization method for TiO2 nanotubes (NTs) formation in a presence of ionic liquids (ILs) was proposed. Influence of the IL structure and its content in ethylene glycol electrolyte on morphology, surface properties and photoactivity of the TiO2 NTs was investigated. Possible interactions between IL and TiO2 NTs as well as the mechanism of NTs formation during anodic oxidation...
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Micellar Route of the Synthesis of Alkyl Xylosides: An Unexpected Effect of Amphiphilic Imidazolium Ionic Liquids
PublikacjaThis manuscript presents results from the investigation on the synthesis of alkyl xylosides by the novel, very efficient and promising protocol of the Fischer synthesis from unprotected xylose and aliphatic alcohol. The use of 1-alkyl-3-methylimidazolium hydrogen sulfate ionic liquids as the catalysts with dual functionality (surfactant + acid catalyst) and micellar reaction system are the main novelty of described method. It has...
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Quantitative structure–retention relationships of ionic liquid cations in characterization of stationary phases for HPLC
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Suppression of deleterious effects of free silanols in liquid chromatography by imidazolium tetrafluoroborate ionic liquids
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Transport properties of aqueous ionic liquid microemulsions: influence of the anion type and presence of the cosurfactant
PublikacjaTransport properties, viz. specific conductivity, dynamic viscosity and apparent diffusion coefficients, were measured as a function of water content in aqueous ionic liquid microemulsions containing 1-butyl-3- methylimidazolium hexafluorophosphate, [BMIM][PF6] and bis(trifluoromethanesulphonyl)imide, [BMIM][Tf2N], stabilized by the nonionic surfactant TX-100, or its mixture with a cosurfactant, i.e. butanol. The investigation covered...
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Synthesis of 2-Propanoyl-5-Norbornene in Pyridinium Ionic Liquids Catalyzed by Yttrium Salts
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Determination of the ionic conductivity of Sr-doped lanthanum manganite by modified Hebb–Wagner technique
PublikacjaThe Hebb–Wagne rpolarization method with the electron blocking electrode has been discussed in this paper in aim to determine a partial ionic conductivity of Sr-doped lanthanum manganite.The “limiting current” in the proposed system was measured using the two-point DC technique with additional Pt electrode between LSM and blocking electrode.The electrochemical model based on bulk diffusion processes and Boltzmann statistics has...
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Effect of the ionic liquids on extraction of aromatic and sulfur compounds from the model petrochemical stream
PublikacjaSuitability of a imidazolium ionic liquids (ILs) as solvents in dearomatization and desulfurization in the ternary systems and in a model multicomponent systems has been analyzed. With this aim, ternary liquid-liquid phase equilibrium data (LLE) have been obtained for ternary mixtures of {IL + benzene, or toluene, or thiophene, or 2-butanethiol + hexane}, or {IL + benzene + 2-methylpentane} at T = 298.15 K and ambient pressure,...
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Epoxy/Ionic Liquid-Modified Mica Nanocomposites: Network Formation–Network Degradation Correlation
PublikacjaWe synthesized pristine mica (Mica) and N-octadecyl-N’-octadecyl imidazolium iodide (IM) modified mica (Mica-IM), characterized it, and applied it at 0.1–5.0 wt.% loading to prepare epoxy nanocomposites. Dynamic differential scanning calorimetry (DSC) was carried out for the analysis of the cure potential and kinetics of epoxy/Mica and epoxy/Mica-IM curing reaction with amine curing agents at low loading of 0.1 wt.% to avoid particle...
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The effects of the IM1-12Br ionic liquid and the oxytetracycline mixture on selected marine and brackish microorganisms
PublikacjaThe number of applications and commercialized processes utilizing ionic liquids has been increasing, and it is anticipated that this trend will persist and even intensify in the future. Ionic liquids possess desirable characteristics, such as low vapor pressure, good water solubility, amphiphilicity, and stability. Nevertheless, these properties can influence their environmental behavior, resulting in resistance to biotic and abiotic...
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Tailoring of Magnetic Properties of NiO/Ni Composite Particles Fabricated by Pulsed Laser Irradiation
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Analiza dokładności pomiarów pulsu na podstawie zarejestrowanej sekwencji wideo obszaru twarzy
PublikacjaZa pomocą prostej kamery internetowej zarejestrowano sekwencje wideo obszaru twarzy, równolegle wykonując pomiar EKG. Sekwencje wideo poszczególnych składowych (R,G,B) uśredniono w następujących obszarach: całej twarzy, czoła oraz policzków uzyskując w ten sposób dla każdego z kanałów RGB serie czasowe odpowiadające wybranym obszarom twarzy. Aby usunąć zakłócenia związane m.in. z oddechem i ruchem zastosowano filtr pasmowy (FIR)....
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Novel Functionalization of Boron-Doped Diamond by Microwave Pulsed-Plasma Polymerized Allylamine Film
PublikacjaWe report the novel modification of a hydrogen-terminated polycrystalline boron-doped electrode with a microwave pulsed-plasma polymerized allylamine. Boron-doped diamond (BDD) was coated with a very thin layer of adherent cross-linked, pinhole- and additive-free allylamine plasma polymer (PPAAm) resistant to hydrolysis and delamination and characterized by a high density of positively charged amino groups. The pulsed microwave...
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On the Formation of Single-Walled Carbon Nanotubes in Pulsed-Laser-Assisted Chemical Vapor Deposition
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