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Thermoelectric properties of bismuth-antimony-telluride alloys obtained by reduction of oxide reagents
PublikacjaThe BieSbeTe alloys with different Bi/Sb/Te ratio were fabricated by an innovative method. For that purpose the oxide reagents were melted at high temperature, then quenched to form pellets, milled to a powder and finally reduced in hydrogen at various temperatures. Complex structures consisting of connected thin layers forming a continuous path between nano- and micrometer size grains have been obtained. The electrical conductivity,...
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Polyurethane Nanocomposites Containing Reduced Graphene Oxide, FTIR, Raman, and XRD Studies
PublikacjaRecently, graphene and other graphene-based materials have become an essential part of composite science and technology. Their unique properties are not only restricted to graphene but also shared with derivative compounds like graphene oxide, reduced graphene oxide, functionalized graphene, and so forth. One of the most structurally important materials, graphene oxide (GO), is prepared by the oxidation of graphite. Though removal...
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Shape Memory Polyurethane Materials Containing Ferromagnetic Iron Oxide and Graphene Nanoplatelets
PublikacjaIntelligent materials, such as memory shape polymers, have attracted considerable attention due to wide range of possible applications. Currently, intensive research is underway, in matters of obtaining memory shape materials that can be actuated via inductive methods, for example with help of magnetic field. In this work, an attempt was made to develop a new polymer composite—polyurethane modified with graphene nanoplates and...
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Phage-Directed Synthesis of Photoluminescent Zinc Oxide Nanoparticles under Benign Conditions
PublikacjaBiological systems, especially bacteriophages and peptides, are an attractive green alternative to other known methods of nanoparticle synthesis. In this work, for the first time, bacteriophages were employed to synthesize a specific peptide, capable of producing nanoparticles (NPs). Derivatives of M13 bacteriophage exposing a ZnO-binding peptide (TMGA-LGLKWPV) on either pIII or pVIII phage coat protein were constructed and used...
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Spray pyrolysis of doped-ceria barrier layers for solid oxide fuel cells
PublikacjaGadolinium doped ceria (Ce0.8Gd0.2O2 − x-CGO) layer fabricated by spray pyrolysis is investigated as the diffusion barrier for solid oxide fuel cell. It is deposited between the La0.6Sr0.4FeO3 − δ cathode and the yttria stabilized zirconia electrolyte to mitigate harmful interdiffusion of elements. The parameters of the fabrication process are linked to the measured area specific resistances of the symmetrical cells and the efficiency...
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Experimental review of the performances of protective coatings for interconnects in solid oxide fuel cells
PublikacjaFerritic stainless steel interconnects are used in solid oxide fuel cells; however, coatings are required to improve their performance. Although several types of coatings have been proposed, they have been scarcely investigated under similar conditions. This study compares the characteristics of uncoated Crofer 22 APU and eight different coatings on Crofer 22 APU for up to 3000 h at 800 ◦C. The coatings were deposited at various...
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X-ray diffraction (XRD) of silica-coated bismuth oxide (Bi2O3) and gadolinium oxide (Gd2O3) structures
Dane BadawczeData contain results from X-ray diffraction (XRD) measurements of pristine Bi2O3 and Gd2O3 structures using Aeris diffractometer (Malvern Panalytical, Malvern, UK) with Cu-Kα radiation (λ = 1.544 Å)
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Particle size distribution (laser granulometry) of pristine bismuth oxide (Bi2O3) and gadolinium oxide (Gd2O3) structures
Dane BadawczeData contain raw results of particle size distribution (by volume) of Bi2O3 and Gd2O3 particles determined using a laser diffraction method (Malvern Mastersizer 2000, Worcestershire, UK).
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X-ray diffraction (XRD) of silica-coated bismuth oxide/gadolinium oxide (Bi2O3+Gd2O3) structures
Dane BadawczeData contain results from X-ray diffraction (XRD) measurements of pristine Bi2O3 and Gd2O3 structures using Aeris diffractometer (Malvern Panalytical, Malvern, UK) with Cu-Kα radiation (λ = 1.544 Å)
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Enhancing the Fresh and Early Age Performances of Portland Cement Pastes via Sol-Gel Silica Coating of Metal Oxides (Bi2O3 and Gd2O3)
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Graphene oxide thin films deposited on a PCB board - chemical analysis
Dane BadawczeGraphene oxides based films were measured by X-ray photoemission spectroscopy (XPS) method. TheXPS measurements were carried out with the Omicron NanoTechnology UHV equipment. The hemispherical spectrophotometer was equipped with a 128-channel collector. The XPS measurements were performed at room temperature at a pressure below 1.1 × 10−8 mBar. The...
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Chemical composition of tellurium oxides thin films deposited by magnetron sputtering method
Dane BadawczeThin films were prepared by radio frequency reactive magnetron sputtering technique. Metallic Te target was sputtered for about 45 min in argon-oxygen atmosphere what resulted in 300 nm film thickness deposition. The pressure in the chamber was below 0.2 Pa and substrate was heated at 200 °C. The distance between sputtered target and the Corning 1737...
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X-Ray Computer Tomography Study of Degradation of the Zircaloy-2 Tubes Oxidized at High Temperatures
PublikacjaThe investigations of high-temperature oxidation of zirconium alloys, applied for fuel pellets in nuclear power plants, are usually limited to oxidation kinetics, phase transformations and microstructural characterization. The purpose of this research was to characterize the degradation phenomena occurring within oxide layer and at the interface oxide/metal, on internal and external Zircaloy-2 tube...
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Applications of spin coating of polymer precursor and slurrysuspensions for Solid Oxide Fuel Cell fabrication
PublikacjaW pracy przedstawiono możliwości zastosowania w tlenkowych ogniwach paliwowych metody nanoszenia wirowego prekursorów polimerowych i zawiesin. Przedstawiono przykłady zastosowania tej metody do wytworzenia elektrolitu oraz warstw ochronnych dla stali nierdzewnych.
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Local anaesthetics upregulate nitric oxide generation in cord blood and adult human neutrophils
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Fabrication of solid oxide fuel cell supported on speciallyperformed ferrite-based perovskite cathode
PublikacjaW pracy przedstawiono warunki technologiczne niezbedne do wytworzenia tlenkowego ogniwa paliwowego na elencie nośnym z materiału perowskitowego LSF. Jako elektrolit stosowana była ceramika z tlenku ceru. Między innymi badany były właściwości elektryczne zarówno materiału katodowego jak i ogniwa.
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Cuprous Oxide Thin Films Implanted with Chromium Ions - Optical and Physical Properties Studies
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Spinel of Nickel-Cobalt Oxide with Rod-Like Architecture as Electrocatalyst for Oxygen Evolution Reaction
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The effect of boiling in a thermosyphon on surface tension and contact angle of silica and graphene oxide nanofluids
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Carbon nanotubes decorated by mesoporous cobalt oxide as electrode material for lithium-ion batteries
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The covalent and non-covalent conjugation of graphene oxide with hydroxycamptothecin in hyperthermia for its anticancer activity
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Cation-ordered perovskite-type anode and cathode materials for solid oxide fuel cells
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High-Entropy Perovskites as Multifunctional Metal Oxide Semiconductors: Synthesis and Characterization of (Gd0.2Nd0.2La0.2Sm0.2Y0.2)CoO3
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Lyotropic liquid crystal based on zinc oxide nanoparticles obtained by microwave solvothermal synthesis
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Dielectric properties of modified graphene oxide filled polyurethane nanocomposites and its correlation with rheology
PublikacjaThis study aims at investigating the dynamic mechanical, dielectric and rheological properties of reinforced polyurethane (PU) nanocomposites containing hydrophilic graphene oxide (GO) and/or hydrophobic modified graphene oxide (mGO) sheets. The organic modification of GO was performed with 4,4′-methylenebis (phenyl isocyanate) (MDI) and the samples were prepared by solvent mixing. We found that addition of mGO provides a more...
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Investigation of catalytic layers on anode for solid oxide fuel cells operating with synthetic biogas
PublikacjaIn this paper solid oxide fuel cells operating with dry synthetic biogas have been examined. In order to increase their stability the layers of CuO-CeO2, Cu1.3Mn1.7O4 and Y0.08Sr0.92Ti0.8Fe0.2O3 -δ have been deposited on the Ni-YSZ anode site. These layers should catalyze the internal biogas reforming and prevent the carbon deposition on the anode site. It has been found that CuO-CeO2 and Cu1.3Mn1.7O4 catalysts led to an increase...
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Linear and nonlinear impedance in iron oxide glasses containing alkaline ions and alkali free
PublikacjaThe linear and nonlinear impedance spectra of oxide glasses were measured in the frequency range of 1 mHz to 1 MHz and in the temperature range of 153K to 483K. Two groups of iron oxide glass samples were prepared, the first one containing alkaline ions and the second one without alkali. In the first group, compositions of glasses were as follows: (in %mol) 50% SiO2 , 25% PbO, 15% Fe2O3 and 15% one of alkaline oxides: Na2O, K2O,...
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Stainless steel/yttria stabilized zirconia composite supported solid oxide fuel cell
PublikacjaW tym artykule opisano wytworzenie i przebadanie kompozytowych elementów nośnych tlenkowych ogniw paliwowych. Podłoża nośne zostały wytworzone ze stali nierdzewnej i tlenkiem itru stabilizowanego tlenku cyrkonu (YSZ), których proszki zmieszano w różnych proporcjach objętościowych. Zachowanie podłoży podczas spiekania (skurcz liniowy, porowatość) oraz wysokotemperaturowe właściwości (odporność na utlenianie, przewodność elektryczna)...
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Fabrication methods of porous perovskite type ceramics for Solid Oxide Fuel Cells (SOFCs)
PublikacjaPublikacja opisuje metody wytwarzania porowatych materiałów ceramicznych o strukturze perowskitu.
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Preparation of Ag/Cu-doped titanium (IV) oxide nanoparticles in W/O microemulsion
PublikacjaNanocząstki Cu-TiO2 oraz Ag/Cu-TiO2 otrzymano w mikroemulsji W/O. Właściwości fotokatalityczne zbadano w procesie degradacji fenolu (0,21mM) w zakresie światła widzialnego. Właściwości biobójcze zbadano poprzez wyznaczenie minimalnego stężenia zahamowania wzrostu (MIC) na szczepach bakterii E. coli, St. aureus oraz grzybów S. Cerevisiae i z rodziny Candida. Dla otrzymanych fotokatalizatorów określono wpływ stężenia domieszki metali...
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Anode supported single chamber solid oxide fuel cell in CH4-Air Mixture.
PublikacjaW tej pracy przedstawiono wyniki prac ogniw paliwowych na bazie elektrolitu z tlenku cyrkonu stabilizowanego itrem o grubości 1-2um wytworzonego na podłożu cermetu z tlenku niklu i tlenku cyrkonu stabilizowanego itrem. LSCF był wykorzystany jako katoda. Ogniwo paliwowe było testowane w konfiguracji jednokomorowej w mieszaninie powietrza i metanu. Uzyskano napięcie o wartości 0.8V, zaś moc wynosiła 0.12W/cm2. Zbdadano wpływ przepływu...
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Femtosecond laser ablated trench array for improving performance of commercial solid oxide cell
PublikacjaThe performance of electrode-supported solid oxide cells (SOCs) is limited adversely by gas diffusion impedance in thick and porous support. This work focuses on the improvement of gas transport properties of commercial Ni-YSZ anode-supported SOFC by femtosecond laser-based micromachining where micro-holes of identical depth but different hole separations pitches with minimal heated affected zones were imposed. The polarization...
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Multilayer coatings based on cerium oxide and manganese cobaltite spinel for Crofer22APU SOC interconnects
PublikacjaThe current state of the art steel interconnect coating materials are based on critical raw material - Co-oxide spinels. Replacing Co-oxide spinels with alternative, abundant materials can reduce the dependence on the critical raw materials. Cobalt-free coatings with the general formula Mn2-xCuFexO4, where x = 0, 0.1, 0.3, were electrophoretically deposited on a ferritic stainless-steel support and evaluated. Prior to deposition,...
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Effect of cathode materials on the performance of single chamber solid oxide fuel cell and module
PublikacjaW pracy przedstawiono wyniki badań nad jednokomorowym ogniwem paliwowym. Badane były ogniwa przygotowane z różnymi rodzajami materiałow katodowych oraz określana była wydajność ogniwa. Zbudowano i zbadano moduł ogniwa paliwowego jednokomorowego.
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Facilitated water transport in composite reduced graphene oxide pervaporation membranes for ethanol upgrading
PublikacjaHigh purity ethanol is one of the most sought-after renewable energy sources. However, standard production methods yield ethanol of insufficient quality. Membrane processes such as pervaporation are recognized as a viable method for upgrading ethanol. Their performance and selectivity depend solely on membrane employed. Hydrophilic polyvinyl alcohol (PVA) membranes are used industrially for this purpose, but there is a trade-off...
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Development of iron doped strontium titanates as oxygen electrode for solid oxide fuel cells
PublikacjaProducing efficient solid oxide fuel cells (SOFC) without the use of harmful elements is one of the current challenges. Increasing the safety of people and reducing production costs is possible, among others, thanks to the use of iron doped strontium titanates as porous oxygen electrodes. In this thesis, the results of research on iron doped strontium titanates as potential oxygen electrodes for SOFC are presented. The research...
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Functional fluorine-doped tin oxide coating for opto-electrochemical label-free biosensors
PublikacjaSensors operating in multiple domains, such as optical and electrochemical, offer properties making biosensing more effective than those working in a single domain. To combine such domains in one sensing device, materials offering a certain set of properties are required. Fluorine-doped tin oxide (FTO) thin film is discussed in this work as functional optically for guiding lossy modes and simultaneously electrochemically, i.e....
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Investigation of functional layers of solid oxide fuel cell anodes for synthetic biogas reforming
PublikacjaSolid oxide fuel cells (SOFCs) are one of the most promising energy conversion devices due to their high efficiency, low pollution and fuel flexibility. Unfortunately, when hydrocarbons are used as a fuel, for example in the form of a biogas, solid carbon can deposit on the anode surface. This process leads to the degradation of the fuel cell performance. A possible solution to this problem is to apply an additional catalytic material,...
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Sustainable energy system combined biogas-feedSolid Oxide Fuel Cell and Microalgae technology
PublikacjaIn the new frontier of energy and environmental safety, new efficient and clean safe energy conversion systems are required. In this sense, the present work is framed within the context of Circular Economy and proposes a multidisciplinary study for the development of more efficient, economically viable and non-polluting energy conversion systems, based on the synergetic combination of different technologies: fuel cells, biofuels,...
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Functionalization of graphene oxide coatings with phosphorus atoms and their corrosion resistance in sodium chloride environment
PublikacjaIn this work, we compared corrosion resistance of graphene oxide, and phosphorus functionalized reduced graphene oxide coatings obtained as a result of electrophoretic deposition on the copper substrate. Doping graphene oxide with phosphorus atoms was performed by a hydrothermal method in the presence of different amounts of phosphoric acid. Structural studies confirmed the insertion of phosphorus atoms into the graphene oxide...
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Influence of Two-Stage Anodization on Properties of the Oxide Coatings on the Ti–13Nb–13Zr Alloy
PublikacjaThe increasing demand for titanium and its alloys used for implants results in need of such innovative surface treatment that may jointly increase corrosion resistance and biocompatibility, and demonstrate antibacterial protection at no cytotoxicity. The purpose of this research was to characterize the effect of two-stage anodization, performed for 30 min in phosphoric acid, at the presence of hydrofluoric acid in the second stage....
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Trimethylamine N-oxide and the reverse cholesterol transport in cardiovascular disease: a cross-sectional study
PublikacjaThe early atherosclerotic lesions develop by the accumulation of arterial foam cells derived mainly from cholesterol-loaded macrophages. Therefore, cholesterol and cholesteryl ester transfer protein (CETP) have been considered as causative in atherosclerosis. Moreover, recent studies indicate the role of trimethylamine N-oxide (TMAO) in development of cardiovascular disease (CVD). The current study aimed to investigate the association...
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Edgewise Compressive Behavior of Composite Structural Insulated Panels with Magnesium Oxide Board Facings
PublikacjaEdgewise compression response of a composite structural insulated panel (CSIP) with magnesium oxide board facings was investigated. The discussed CSIP is a novel multifunctional sandwich panel introduced to the housing industry as a part of the wall, floor, and roof assemblies. The study aims to propose a computational tool for reliable prediction of failure modes of CSIPs subjected to concentric and eccentric axial loads. An advanced...
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Morphology and the physical and thermal properties of thermoplastic polyurethane reinforced with thermally reduced graphene oxide
PublikacjaIn this study, thermally reduced graphene oxide (TRG)-containing polyurethane nanocomposites were obtained by the extrusion method. The content of TRG incorporated into polyurethane elastomer systems equaled 0.5, 1.0, 2.0 and 3.0 wt%. The morphology, static and dynamic mechanical properties, and thermal stability of the modified materials were investigated. The application of TRG resulted in a visible increase in material stiffness...
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Composites of tin oxide and different carbonaceous materials as negative electrodes in lithium-ion batteries
PublikacjaAbstract Tin and tin oxide have been considered as suitable materials with high theoretical capacity for lithium ion batteries. Their low cost, high safety and other technical benefits placed them as promising replacements for graphite negative electrodes. The problem to overcome with tin oxide, as well as with other metallic materials, is high volume changes during alloying/dealloying, subsequent pulverization, delamination from...
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The Effect of Titanium Oxyfluoride Morphology on Photocatalytic Activity of Fluorine-Doped Titanium(IV) Oxide
PublikacjaTitanium oxyfluoride (TiOF2) is a metastable product that can be obtained in a fluorine-rich environment. This material can also be a valuable precursor in the synthesis of titanium(IV) oxide (TiO2). However, the effect of TiOF2 morphology on the physicochemical properties of TiO2 has not been studied so far. In this work, single-phase TiOF2 was prepared by a solvothermal method. The as-synthesized samples exhibited a variety of...
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Atmospheric emission of nitric oxide and processes involved in its biogeochemical transformation in terrestrial environment
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BET specific surface area measurements of silica-coated bismuth oxide(Bi2O3) and gadolinium oxide (Gd2O3) structures
Dane BadawczeThe BET specific surface area was measured using an N2 adsorption/desorption isotherm (Micromeritics ASAP 2460, Norcross, GA, USA).
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Intense and stable room-temperature photoluminescence from nanoporous vanadium oxide formed by in-ambient degradation of VI3 crystals
PublikacjaVanadium oxides have attracted research interest because their optoelectronic properties make them optically active with room-temperature photoluminescence (PL) emission, which, however, is not sufficiently intense for real applications. For this reason, many nanostructured vanadium oxides are currently fabricated through several precursors and different treatments to improve the PL efficiency and enhance the PL intensity. Herein,...
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Salivary Xanthine Oxidase as a Potential Biomarker in Stroke Diagnostics
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