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Search results for: LITHIUM-ION DIFFUSION COEFFICIENT
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Determination of the Diffusion Coefficient of Lithium Ions in Graphite Coated with Polymer-Derived SiCN Ceramic
PublicationPraca dotyczy wyznaczenia wsółczynnik adyfuzji jonów litu w materiale elektrodowym składającym się z grafitu pokrytego materiałem ceramicznym krzemo-azotkiem węgla (SiCN). Wartość współczynnika dyfuzji zmierzono elektrochemicznie technikami: woltamperometrii cyklicznej (CV), elektrochemicznej spektrodkopii impedancyjnej (EIS) oraz miareczkowania galwanostatycznego (GITT). Materiał otrzymano na drodze pirolizy mieszaniny grafit:polimer...
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Determination of Chemical Diffusion Coefficient of Lithium Ions in Ceramics Derived from Pyrolysed Poly(1,2-dimethylsilazane) and Starch
PublicationThe apparent chemical diffusion coefficient Li+ (DappLI+) in pyrolysed poly(1,2-dimethylsilazane)/starch (PSN/S) (weight ratio: 30/70) ceramic anode composite is determined by galvanostatic intermittent titration technique (GITT). The electrode material composition is C6.00N0.14H0.47O0.12Si0.13. The calculated values of DappLI+, depend on the applied potential, vary from 10-14 to 10-9 [cm2/s]. The diffusion coefficient of lithium...
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Poly(hydroxybutyrate-co-hydroxyvalerate) as a biodegradable binder in a negative electrode material for lithium-ion batteries
PublicationIn this work, graphite-based negative electrode for lithium-ion battery consisting a novel and biodegradable binder poly(hydroxybutyrate-co-hydroxyvalerate) (PHBV) is compared with standard graphite electrode with polyvinylidene fluoride (PVDF) as a binder. The rate and cycling performance of lithium ion insertion/extraction of electrodes with PHBV in a half-cell configuration are evaluated. Moreover, on the basis of the electrochemical...
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A facile strategy for reclaiming discarded graphite and harnessing the rate capabilities of graphite anodes
PublicationGraphite negative electrodes are unbeaten hitherto in lithium-ion batteries (LiBs) due to their unique chemical and physical properties. Thus, the increasing scarcity of graphite resources makes smart recycling or repurposing of discarded graphite particularly imperative. However, the current recycling techniques still need to be improved upon with urgency. Herein a facile and efficient hydrometallurgical process is reported to...
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Advanced Lithium-Ion Battery Model for Power System Performance Analysis
PublicationThe paper describes a novel approach in battery storage system modelling. Different types of lithium-ion batteries exhibit differences in performance due to the battery anode and cathode materials being the determining factors in the storage system performance. Because of this, the influence of model parameters on the model accuracy can be different for different battery types. These models are used in battery management system...
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Tin Oxide Encapsulated into Pyrolyzed Chitosan as a Negative Electrode for Lithium Ion Batteries
PublicationTin oxide is one of the most promising electrode materials as a negative electrode for lithium-ion batteries due to its higher theoretical specific capacity than graphite. However, it suffers lack of stability due to volume changes and low electrical conductivity while cycling. To overcome these issues, a new composite consisting of SnO2 and carbonaceous matrix was fabricated. Naturally abundant and renewable chitosan was chosen...
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Theoretical calculation of the physico-chemical properties of 1-butyl-4-methylpyridinium based ionic liquids
PublicationACCEPTED MAIonic liquids (ILs) have attracted much attention for their unique physicochemical properties, which can be designed as needed by altering the ion combinations. Besides experimental work, numerous computational studies have been concerned with prediction of physical properties of ILs. The results of molecular dynamics simulations of ILs depend strongly on the proper force field parameterization. Classical force fields...
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Porous carbon derived from rice husks as sustainable bioresources: insights into the role of micro-/mesoporous hierarchy in hosting active species for lithium–sulphur batteries
PublicationThe exploration of natural resources as sustainable precursors affords a family of green materials. Exploring highly abundant and available biowaste precursors remaining from food processing throughout a scalable and cost-effective material synthesis path is highly important especially for new materials discovery in emerging energy storage technologies such as lithium–sulphur (Li–S) batteries. Herein, we have produced a series...
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Evaluation of Temperature Influence on Electrochemical Processes Occurring in a Lithium-Ion Supercapacitor with the Use of Dynamic Electrochemical Impedance Spectroscopy
PublicationIn order to obtain the full impedance characteristics of a lithium-ion capacitor as a function of temperature, the authors proposed the use of dynamic electrochemical impedance spectroscopy. Impedance tests were carried out under wide range of dynamic temperature changes for lithium-ion supercapacitors. Significant differences in electrochemical processes were observed as a result of working temperature. Moreover, the quality of...
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SILICA AEROGEL TOWARDS ANODES FOR LITHIUM-ION BATTERIES
PublicationAn increasing demand for electrochemical energy storage and conversion devices stimulates progress in research on electrode and electrolyte materials. In the field of electrodes materials, silicon is the one of the most promising anode materials for Li-ion batteries. However silicon has the drastic volume variation (around 3 times lower on extraction) during insertion and extraction of lithium ions. As an alternative, nanocomposites...
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Impact of diffusion coefficient averaging on solution accuracy of the 2D nonlinear diffusive wave equation for floodplain inundation
PublicationIn the study, the averaging technique of diffusion coefficients in the two-dimensional nonlinear diffusive wave equation applied to the floodplain inundation is presented. As a method of solution, the splitting technique and the modified finite element method with linear shape functions are used. On the stage of spatial integration, it is often assumed that diffusion coefficient is constant over element and equal to its average...
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Silicon Oxycarbide (SiOC) Ceramic Materials as Anodes for Lithium Ion Batteries
PublicationPolymer derived ceramics (PDCs) have attracted attention as alternative anode material for Li-ion batteries. It has been found that ternary SiOC and SiCN ceramics obtained through pyrolysis of various preceramic polymers display high reversible capacities of 500 – 650 mAh/g. In this work we try to correlate the electrochemical performance of polymer derived silicon oxycarbide with its chemical composition and microstructural features....
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Silicon oxycarbide ceramics as anodes for lithium ion batteries: influence of carbon content on lithium storage capacity
PublicationWe report here on the synthesis and characterization of silicon oxycarbide (SiOC) in view of its application as a potential anode material for Li-ion batteries. SiOC ceramics are obtained by pyrolysis of various polysiloxanes synthesized by sol–gel methods. The polysiloxanes contain different organic groups attached to silicon, which influence the chemical composition and the microstructure of the final ceramic product. The structure...
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Diatoms Biomass as a Joint Source of Biosilica and Carbon for Lithium-Ion Battery Anodes
PublicationThe biomass of one type cultivated diatoms (Pseudostaurosira trainorii), being a source of 3D-stuctured biosilica and organic matter—the source of carbon, was thermally processed to become an electroactive material in a potential range adequate to become an anode in lithium ion batteries. Carbonized material was characterized by means of selected solid-state physics techniques (XRD, Raman, TGA). It was shown that the pyrolysis...
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Lignin-based carbon fibers for renewable and multifunctional lithium-ion battery electrodes
PublicationLignin-based carbon fibers (LCFs) from the renewable resource softwood kraft lignin were synthesized via oxidative thermostabilization of pure melt-spun lignin and carbonization at different temperatures from 1000°C to 1700°C. The resulting LCFs were characterized by tensile testing, scanning electron microscopy (SEM), X-ray diffraction (XRD) and confocal Raman spectroscopy. The microstructure is mainly amorphous carbon with some...
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Composites of tin oxide and different carbonaceous materials as negative electrodes in lithium-ion batteries
PublicationAbstract Tin and tin oxide have been considered as suitable materials with high theoretical capacity for lithium ion batteries. Their low cost, high safety and other technical benefits placed them as promising replacements for graphite negative electrodes. The problem to overcome with tin oxide, as well as with other metallic materials, is high volume changes during alloying/dealloying, subsequent pulverization, delamination from...
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Application of fiber optic sensors using Machine Learning algorithms for temperature measurement of lithium-ion batteries
PublicationOptical fiber sensorsusing low-coherence interferometry require processing ofthe output spectrum or interferogramto quickly and accurately determine the instantaneous value of the measured quantity, such as temperature.Methods based on machine learning are a good candidate for this application. The application of four such methods in an optical fiber temperature sensoris demonstrated.Using aZnO-coated...
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The influence of nanostructures size on V2O5 electrochemical properties as cathode materials for lithium ion battery
PublicationIn this paper, V2O5 nanostructures with a size depending on the annealing temperature are successfully synthesized by a sol-gel method. The crystal structure and morphology of samples are characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), selected area electron diffraction (SEAD) and scanning electron microscopy (SEM), respectively. Electrochemical testing such...
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Tin oxide nanoparticles from laser ablation encapsulated in a carbonaceous matrix – a negative electrode in lithium-ion battery applications
PublicationThis report concerns carbonaceous electrodes doped with tin(II) oxide nanoparticles. Tin nanoparticles are obtained by pulsed laser ablation in water. Crystalline nanoparticles have been encapsulated in a carbonaceous matrix formed after pyrolysis of a mixture consisting of tin/tin(IV) oxide nanoparticles and gelatine. The obtained material is characterized by means of X-ray diffraction, selected area diffraction, scanning electron...
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Nano Tin/Tin Oxide Attached onto Graphene Oxide Skeleton as a Fluorine Free Anode Material for Lithium-Ion Batteries
PublicationHerein, we show a composite formation method of tin/tin oxide nanoparticles with graphene oxide and CMC based on laser ablation technique as an electrode material for energy storage devices. The material exhibited a three-dimensional conducting graphene oxide network decorated with tin or tin oxide nanoparticles. The structure, homogeneous distribution of nanoparticles, and direct contact between inorganic and organic parts were...
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Composite Materials Based on Polymer-Derived SiCN Ceramic and Disordered Hard Carbons as Anodes for Lithium-Ion Batteries
PublicationNew composite materials based on polymer-derived SiCN ceramics and hard carbons were studied in view of its application as anodes for lithium-ion batteries. Two kinds of composites were prepared by pyrolysis of the preceramic polysilazane (HTT1800, Clariant) at 1000 °C in Ar atmosphere mixed with hard carbons derived from potato starch (HC_PS) or with a hard carbon precursor, namely potato starch (PS), denoted as HTT/HC_PS and...
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Filled Carbon Nanotubes as Anode Materials for Lithium-Ion Batteries
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MiMSeg - an algorithm for automated detection of tumor tissue on NMR apparent diffusion coefficient maps.
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Creation of mesopores in carbon nanotubes with improved capacities for lithium ion batteries
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Aquatic biomass containing porous silica as an anode for lithium ion batteries
PublicationA composite electrode was manufactured by pyrolysis of Red Algae (Polysiphonia fucoides) covered by diatoms (Diatomophyceae). Electrodes were tested as a half cell with capacity of 500 mA h g−1 after 80 cycles. XPS analysis shows formation of lithium silicate under reduction of silica in an aprotic electrolyte containing LiPF6 salt.
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Composite Materials Based on Silicon Oxycarbide as Anodes for Lithium-Ion Batteries
PublicationIn this work, the properties of binary SiOC/graphite and SiOC/tin, as well as ternary SiOC/graphite/tin obtained from various preceramic precursors are described. During the first step, the materials were synthesized using various techniques such as sol-gel and hydrosilylation. To prevent sedimentation and agglomeration of graphite particles during the gelation stage without using surfactants and thickeners, a new gelation technique...
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N-doped graphene quantum dot-decorated MOF-derived yolk-shell ZnO/NiO hybrids to boost lithium and sodium ion battery performance
PublicationSurface engineering at the nanoscale to obtain robust interface between metal oxides and quantum dots is essential for improving the performance and stability of battery materials. Herein, we designed and prepared novel N-doped graphene quantum dot-modified ZnO/NiO anode materials with a well-defined yolk-shell structure for lithium and sodium-ion batteries. NG QDs were assembled on the ZnO/NiO microspheres using three different...
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A review on the critical challenges and progress of SiOx-based anodes for lithium-ion batteries
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Hollow carbon sphere/metal oxide nanocomposites anodes for lithium-ion batteries
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Well-Designed Porous Graphene Flakes for Lithium-Ion Batteries with Outstanding Rate Performance
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Selective Synthesis of Magnetite Nanospheres with Controllable Morphologies on CNTs and Application to Lithium‐Ion Batteries
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Could graphene construct an effective conducting network in a high-power lithium ion battery?
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Carbon nanotubes decorated by mesoporous cobalt oxide as electrode material for lithium-ion batteries
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Lithium ion insertion into poly(3,4-ethylenedioxythiophene) films from propylene carbonate electrolytes.
PublicationPolimerowa matryca złożona z poli(3,4-etylenodioksytiofenu z poli(styrenosulfonianem) otrzymana została na drodze syntezy elektrochemicznej. Transport jonowy w matrycy polimerowej w kontakcie z węglanem propylenu zawierającym LiClO4 został scharakteryzowany za pomocą metody impedancji ac oraz chronowoltoamperometrii. Wyznaczono przewodność jonową matrycy oraz efektywne współczynniki dyfuzji dla kationu Li+. Wielkości te...
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Ion conduction in beryllium-alumino-silicate glasses doped with sodium or sodium and lithium ions
PublicationElectrical properties of beryllium-alumino-silicate glasses containing sodium ions or sodium and lithium ions were studied with impedance spectroscopy technique over a frequency range from 10 mHz to 1 MHz and at temperature range from 213 to 473 K. The frequency- and temperature-dependent conductivity spectra of individual single alkali glasses were superimposed by means of the Summerfield scaling. Mixed-alkali glasses do not overlap...
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Influence of the preparation method and aluminum ion substitution on the structure and electrical properties of lithium–iron ferrites
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Selectivity of lithium electrodes: correlation with ion-ionophore complexstability constants and with interfacial exchange current densities
PublicationMembranowe elektrody selektywne na jony litu oparte na dwóch różnych dicyk-lohesyloamidowych jonoforach poddane zostały systematycznym badaniom. Potencjometrycznie wyznaczono wartości współczynników selektywności. Wartości stałych trwałości kompleksów z jonami litu, sodu i potasu wyznaczono metodą membran "sandwichowych". Transfer ładunków przez membranę oraz przez granicę faz membrana/roztwór badano metodą spektroskopii impedancyjnej....
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Recycling of Plastic Wastes for the Mass Production of Yolk–Shell-Nanostructured Co3O4@C for Lithium-Ion Batteries
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Hollow carbon spheres loaded with uniform dispersion of copper oxide nanoparticles for anode in lithium- ion batteries
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Improved performance in lithium ion battery of CNT-Fe3O4@graphene induced by three-dimensional structured construction
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Recycling of Plastic Wastes for the Mass Production of Yolk–Shell-Nanostructured Co3O4@C for Lithium-Ion Batteries
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Mn3O4 encapsulated in hollow carbon spheres coated by graphene layer for enhanced magnetization and lithium-ion batteries performance
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New easy way preparation of core/shell structured SnO2@carbon spheres and application for lithium-ion batteries
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The electrochemical impedance spectroscopy studies of the anode material based on polymer and starch derived ceramic for lithium ion batteries
PublicationThe anode materials derived of preceramic polymer poly(1,2-dimethylsilazane) (PSN) and starch was study. Commercially available polysilazane (poly(1,2-dimethylsilazane (PSN 2M01 Gelest) was mixed with commercially available starch (POCH Gliwice). The ratio polymer/starch (PSN/starch) was 1/1 or 3/7. The polysialazane/starch blend was cross-linked at 230 ºC for 2 h followed by heating to the final temperature (500 ºC, 700 ºC and...
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Anna Lisowska-Oleksiak prof. dr hab.
PeopleAnna Lisowska-Oleksiak, born in 1952, has been working at GUT since 1977. Currently is employed at the Faculty of Chemistry as a full professor. She was employed as a research assistant at the University of St Andrews in the group of C. A. Vincent and P.G. Bruce (1991-1994). She completed a two-month research internship in CEA Grenoble (2011). Anna Lisowska-Oleksiak obtained her MSc in chemistry at Nicolaus Copernicus University...
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A general approach towards carbonization of plastic waste into a well-designed 3D porous carbon framework for super lithium-ion batteries
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Beaded structured CNTs-Fe3O4@C with low Fe3O4 content as anode materials with extra enhanced performances in lithium ion batteries
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Multifunctional nitrogen-doped nanoporous carbons derived from metal–organic frameworks for efficient CO2 storage and high-performance lithium-ion batteries
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Monika Wilamowska-Zawłocka dr hab. inż.
PeopleDr Monika WILAMOWSKA-ZAWŁOCKA obtained her PhD in Chemistry in 2011 at Faculty of Chemistry, Gdańsk University of Technology. She then was a post-doctoral fellow at Technische Universität Darmstadt, Germany. Since 2013 she has worked at Gdańsk University of Technology, since 2019 as an Associate Professor. Her research interests include composite materials for energy storage devices, especially for lithium-ion and sodium-ion batteries,...
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Controllable Synthesis of 3D Hollow-Carbon-Spheres/Graphene-Flake Hybrid Nanostructures from Polymer Nanocomposite by Self-Assembly and Feasibility for Lithium-Ion Batteries
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