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Search results for: STABLE PHOSPHANYLPHOSPHAALKENES
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Two complementary approaches for the synthesis and isolation of stable phosphanylphosphaalkenes
PublicationPhospha-Wittig (phosphanylphosphinidene titanium(IV) complex) and phospha-Peterson (lithiated diphosphane) reactions were used to obtain phosphanylphosphaalkenes with the general formula XYC=P-PtBu2 (X = alkyl, aryl group or H; Y = alkyl or aryl group). Therefore, two series of reactions with different ketones and aldehydes were performed. An examination revealed that the two methods are complementary. For smaller carbonyl compounds,...
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Group 11 complexes with a phosphanylphosphaalkene ligand: preparation and stability study
PublicationThe reactivities of two selected phosphanylphosphaalkenes, Ph2C=P-PtBu2 (1a) and (p-MeO-Ph)2C=P-PtBu2 (1b), toward CuCl, AgCl and (tht)AuCl (tht = tetrahydrothiophene) were investigated. As a result, new phosphanylphosphaalkene dimeric and monomeric complexes were formed (Cu and Ag dimeric and Au monomeric). All obtained products were air and moisture stable and light insensitive.
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From phosphanylphosphaalkenes to coordination copper and silver polymers containing P–P bonds
PublicationThis study was focused on the activation of the C[double bond, length as m-dash]P bond via reactions of Ph2C[double bond, length as m-dash]P-PtBu2 (1) with 1,6-hexanediol and selected dithiols (1,4-butanedithiol, 1,4-benzenedithiol and 1,4-benzenedimethanethiol). These reactions proceed according to a 1,2-addition mechanism, providing new compounds with formulas {(Ph)2(H)C-P-PtBu2}{μ2-(O-(CH2)6-O)}{tBu2P-P-C(H)(Ph)2} (2), {(Ph)2(H)C-P-PtBu2}{μ2-(S-(CH2)4-S)}{tBu2P-P-C(H)(Ph)2}...
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Stable and unstable bifurcation in the von Karman problem for a circular plate
PublicationW niniejszej pracy badamy równania von Karmana dla cienkiej, sprężystej, kołowej płyty, która znajduje się na sprężystym podłożu, pod działaniem sił ściskających wzdłuż swojego brzegu.Stosując metody analizy nieliniowej, dowodzimy istnienia stabilnychi niestabilnych punktów bifurkacji w zbiorze rozwiązań badanych równań.
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Activation of the C=P bond in phosphanylphosphaalkenes C=P–P bond system) in the reaction with nucleophilic reagents: MeLi, nBuLi and tBuLi
PublicationThree reactions of phosphanylphosphaalkene (1) with nucleophiles were performed to activate the diphosphorus monomer. We observed similar results in the reactions with MeLi and nBuLi, in which the P–P bond is cleavaged and triphosphorus systems [P(Me)2–CH(biph)–CH(biph)–P–(PtBu 2)]- (1a'') and [P(nBu)2–CH(biph)–CH(biph)–P–(PtBu 2)]- (1b''), respectively, are formed depending on the nucleophilic reagent (biph ¼ biphenyl). In the...
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The Only Stable State of O2- Is the X 2Πg Ground State and It (Still!) Has an Adiabatic Electron Detachment Energy of 0.45 eV
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EFEKTY NAGNIATANIA GŁADKOŚCIOWEGO STALI W STANIE UTWARDZONYM
PublicationPrzedstawiono wyniki z badań eksperymentalnych dotyczących procesu nagniatania narzędziem z dociskiem hydrostatycznym. Badania dotyczyły obróbki materiału w stanie utwardzonym po hartowaniu. Skoncentrowano się na ocenie wpływu posuwu i prędkości nagniatania oraz wstępnych wartości parametrów chropowatości powierzchni na stan geometryczny powierzchni opisanej parametrami chropowatości.
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Polyurethane glycolysate from industrial waste recycling to develop low dielectric constant, thermally stable materials suitable for the electronics
PublicationWe are utilizing a new method to improve the dielectric properties of a conventional polymer using a recycled polymer product. The polyurethane foams are recycled by glycolysis process and the derived material was applied to improve the dielectric properties of the brittle DGEBA epoxy resin. Two main parameters that determine the applicability of the material as a dielectric (the dielectric constant and dielectric loss), were studied...
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Application of Structural Control Systems for the Cables of Cable-Stayed Bridges: State-of-the-Art and State-of-the-Practice
PublicationStay cables are one of the key elements of cable-stayed bridges and are characterized by lightweight, low inherent damping, and high flexibility. They are continuously subjected to small-to large-amplitude vibrations due to various types of dynamic loads that may, in the long term, cause fatigue and fracture problems for the cable system, and may eventually compromise the safety of cable-stayed bridges. Thus, several countermeasures...
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Are HBO−and BOH−electronically stable?
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Wave Method for Structural Health Monitoring: Testing Using Full-Scale Shake Table Experiment Data
PublicationAn algorithm of the wave method for structural health monitoring (SHM) is tested and calibrated using shake table experiment data of a full-scale, seven-story, reinforced-concrete building slice. The method is based on monitoring changes in the velocity of waves propagating vertically through the structure, identified by least-squares (LSQ) fit of beam models. The experiment was conducted by a team from the University of California,...
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PROBLEMATYKA POMIARU SIŁ W PROCESIE NAGNIATANIA STALI CF53 W STANIE UTWARDZONYM
PublicationPrzedstawiono wyniki z badań eksperymentalnych dotyczących analizy sił nagniatania tocznego i ślizgowego kulkami ceramicznymi wałków ze stali Cf53 w stanie utwardzonym. W przypadku nagniatania tocznego zastosowano docisk hydrostatyczny, natomiast podczas nagniatania ślizgowego docisk sprężysty elementu roboczego. W obu przypadkach siły pomierzono stosując pojemnościowy czujnik siły firmy Kistler. W badaniach analizowano zmiany...
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Wpływ parametrów szlifowania na chropowatość powierzchni stali 10562 w stanie zmiękczonym
PublicationW artykule przedstawiono wyniki badań procesu szlifo-wania elementów konstrukcyjnych wykonanych ze stali stopowej 1.0562 w stanie zmiękczonym. W badaniach analizowano wpływ głębokości szlifowania ae i prędkości posuwu wzdłużnego przedmiotu vft na chropowatość po-wierzchni. Przedstawiono wartości parametrów chropowatości Ra, Rz i Rt możliwe do uzyskania dla zastosowanych warunków badań.
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Wpływ parametrów szlifowania na chropowatość powierzchni stali 1.0562 w stanie zmiękczonym
PublicationPrzedstawiono wyniki badań procesu szlifowania elementów konstrukcyjnych ze stali stopowej 1.0562 w stanie zmiękczonym. Przeanalizowano wpływ głębokości szlifowania ae i prędkości posuwu wzdłużnego przedmiotu vft na chropowatość powierzchni. Zaprezentowano wartości parametrów chropowatości Ra, Rz i Rt możliwe do uzyskania w przyjętych warunkach badań.
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Thermally Stable and Deep Red Luminescence of Sr1–xBax[Mg2Al2N4]:Eu2+ (x = 0–1) Phosphors for Solid State and Agricultural Lighting Applications
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Assessment of the histrionic self-presentation style: initial validation of the Polish version of the As-If-Scale
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Weakly connected domination stable trees [online]
PublicationPraca dotyczy pełnej charakteryzacji drzew stabilnych ze względu na liczbę dominowania słabo spójnego.
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Study on stable dispersion of functionalized Fe-MWCNTs
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Wpływ posuwu nagniatania na chropowatość powierzchni przedmiotów ze stali w stanie utwardzonym
PublicationPrzedstawiono wyniki badań eksperymentalnych procesu nagniatania stali twardej (62 HRC) narzędziem ceramicznym (kulką) z dociskiem hydrostatycznym. Analizowano wpływ posuwu nagniatania oraz parametrów poprzedzającej obróbki toczeniem na twardo na stan powierzchni opisanej wybranymi parametrami chropowatości.
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Vessel Energy Requirement Prediction from Acceleration Stage Towing Tests on Scale Models
PublicationOne of the most crucial tasks for naval architects is computing the energy required to meet the ship’s operational needs. When predicting a ship’s energy requirements, a series of hull resistance tests on a scale model vessel is carried out in constant speed stages, while the acceleration stage measurements are ignored. Another important factor in seakeeping analysis is the ship’s hydrodynamic added mass. The second law of dynamics...
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Synthesis of Thermally Stable Energetic 1,2,3-Triazole Derivatives
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Badania eksperymentalne modelu zbiornika stalowego na stole sejsmicznym = Experimental study on steel tank model using shaking table
PublicationCylindrical steel tanks are very popular structures used for storage of products of chemical and petroleum industries. Their safety and reliability is really crucial because any failure may have serious consequences. Earthquakes are the most dangerous and also the most unpredictable dynamic loads acting on such structures. On the other hand, rockburst-induced ground motions are usually considered to be less severe due to lower...
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Experimental Study on Steel Tank Model Using Shaking Table/ Badania Eksperymentalne Modelu Zbiornika Stalowego Na Stole Sejsmicznym
PublicationStalowe zbiorniki walcowe są bardzo popularnymi konstrukcjami używanymi do magazynowania produktów przemysłu chemicznego i naftowego. Ich bezpieczeństwo i niezawodność są kluczowe, ponieważ każde uszkodzenie może nieść za sobą bardzo poważne konsekwencje. Trzęsienia ziemi są najbardziej niebezpiecznymi, a zarazem najbardziej nieprzewidywalnymi obciążeniami dynamicznymi, które mogą oddziaływać na tego typu konstrukcje. Z drugiej...
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Extraction of stable foreground image regions for unattended luggage detection
PublicationA novel approach to detection of stationary objects in the video stream is presented. Stationary objects are these separated from the static background, but remaining motionless for a prolonged time. Extraction of stationary objects from images is useful in automatic detection of unattended luggage. The proposed algorithm is based on detection of image regions containing foreground image pixels having stable values in time and...
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Analytical design of stable delta-domain generalized predictive control
PublicationPraca dotyczy analitycznej metody projektowania układów sterowania skalarnymi (SISO) obiektami czasu ciągłego według strategii uogólnionego sterowania predykcyjnego (GPC) w oparciu o dyskretnoczasowe modele takich obiektów. Założono wykorzystanie numeryczne odpornych modeli opartych o tak zwany operator delta. Przyjmując kwadratowy funkcjonał kosztów, w którym prognozowany przebieg przyszłego wyjścia sterowanego obiektu porównywany...
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Moderately Reactive Molecules Forming Stable Ionic Compounds with Superhalogens
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N-doped carbon materials as electrodes for highly stable supercapacitors
PublicationThis article reports a strategy to use nitrogen-doped carbon materials as electrodes for supercapacitors. Depending on the carbon precursor, the porous structure is changed with specific surface area reached up to 2270 m2 g−1. The capacitance of carbon materials used as electrodes is related strictly to pore size. The microstructure and nitrogen functionalities enable a high capacitance (327 F g−1) and cycle durability. The nanoporous...
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Synthesis of compounds with C-P-P and C=P-P bond systems based on the phospha-Wittig reaction
PublicationA reactivity study of a β-diketiminate titanium(III) phosphanylphosphido complex [MeNacNacTi(Cl){η2-P(SiMe3)-PtBu2}] (1) towards ketones such as benzophenone, 9-fluorenone, acetophenone, cyclopentanone, cyclohexanone and cycloheptanone is reported. The reactions of 1 with aromatic ketones (without α-protons) directly lead to the Ti(III) complex [MeNacNacTi(μ2-Cl)(OSiMe3)] (5) as well as Ti(IV) complexes with the pinacol condensation...
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Stale austenityczne - szlachetny materiał.
PublicationPrzedstawiono skład chemiczny, struktury i właściwości stali odpornych na korozję klasy austenitycznej oraz zagrożenia uszkodzeniem i zniszczeniem tych stali.
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Stable isotopes unveil one millennium of domestic cat paleoecology in Europe
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Design of dimensionally stable composites using efficient global optimization method
PublicationDimensionally stable material design is an important issue for space structures such as space laser communication systems, telescopes, and satellites. Suitably designed composite materials for this purpose can meet the functional and structural requirements. In this paper, it is aimed to design the dimensionally stable laminated composites by using efficient global optimization method. For this purpose, the composite plate optimization...
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An efficient approach to optimization of semi‐stable routing in multicommodity flow networks
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Design of dimensionally stable composites using efficient global optimization method
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Analysis of electrical patterns activity in artificial multi-stable neural networks
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In Vitro Toxicological Screening of Stable and Senescing Cultures of Aphanizomenon, Planktothrix, and Raphidiopsis
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Heavy stable charged particles search by novel pattern comparator processor
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Repulsive Coulomb Barriers in Compact Stable and Metastable Multiply Charged Anions
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Why Are SiX5– and GeX5– (X = F, Cl) Stable but Not CF5– and CCl5–?
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Stable anions formed by organic molecules substituted with superhalogen functional groups
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Dihydroxyanthraquinones as stable and cost-effective TiO2 photosensitizers for environmental and biomedical applications
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Achieving Efficient and Stable Deammonification at Low Temperatures—Experimental and Modeling Studies
PublicationThe short-term effects of temperature on deammonification sludge were evaluated in a laboratory-scale sequencing batch reactor (SBR). Mathematical modeling was used for further evaluations of different intermittent aeration strategies for achieving high and stable deammonification performance at decreasing temperatures. As for the biomass cultivated at high temperatures (e.g., 30 C), a higher temperature dependency (the adjusted...
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Estimation of wastewater treatment plant state for model predictive control of N-P remowal at medium time scale.
PublicationPrzy ograniczonych możliwościach pomiarowych estymaty stanu są potrzebne w sterowaniu optymalizującym, opartym na sterowaniu predykcyjnym, sterującym usuwaniem azotu i fosforu, w biologicznej oczyszczalni ścieków. Optymalizator MPC do implementacji sprzężenia zwrotnego z obiektu potrzebuje tych estymat. Dodatkowo aktualizowane muszą być parametry modelu Gray-Box wykorzystywanego w module MPC. Wtedy estymaty stanu są używane przez...
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Stable and degradable microgels linked with cystine for storing and environmentally triggered release of drugs
PublicationEnvironmentally sensitive, degradable microgels based on poly(N-isopropylacrylamide) (pNIPA) crosslinked with the diacryloyl derivative of cystine (BISS) were synthesized by applying surfactant-free emulsion polymerization. pNIPA contributed the sensitivity to temperature to the microgels and the cross-linker made them degradable and sensitive to pH. The morphology of the microgels was investigated by using scanning and transmission...
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Effect of phosphorylation of the maize starch on thermal generation of stable and short-living radicals
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Is it possible to create a unified urban greenery management system (UGMS) on a national scale? The concept for EU Member State of Poland
PublicationMotives: Currently developed urban greenery management systems (UGMS) are limited in scope and profiled towards solving particular issues. Moreover, due to the lack of common standards and solutions, UGMS implementation requires considerable financial effort, which is only feasible for wealthy urban centres. There is a need for universal, cost-effective technological solutions which could constitute a common urban green infrastructure...
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Influence of H2S on degradation of 9Cr-1Mo steel in advanced stage of metal dusting process
PublicationPrzedstawiono wyniki badań stali 9Cr-1Mo w zaawansowanym stadium procesu pylenia metalu po 10 latach eksploatacji w piecu rafineryjnej instalacji platformingu CCR, przeprowadzonych w celu podjęcia decyzji o dozowaniu związków siarki do wsadu instalacji. Na podstawie długotrwałej ekspozycji próbek stali w 600C w mieszaninie wodoru i siarkowodoru wykazano, że siarka może być powodem procesów wpływających niekorzystnie na stan materiału...
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Simple stable discrete-time generalised predictive control with anticipated filtration of control error
PublicationPraca dotyczy uogólnionego sterowania predykcyjnego w czasie dyskretnym z antypacyjną filtracją błędu sterowania. Pokazano, iż przy spełnieniu pewnych warunków rozwiązanie problemu syntezy optymlanego regulatora predykcyjnego zawsze istnieje oraz prowadzi do stabilnego zamkniętego układu sterowania o określonych własnościach dynamicznych. W pracy rozważano także problem syntezy regulatora predykcyjnego dla modeli sterowania obiektów...
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Stable indirect adaptive control based on discrete-time T-S fuzzy model
PublicationThis paper presents an indirect adaptive fuzzy control scheme for uncertain nonlinear asymptotically stable plants.A discrete-time T-S fuzzy input-output model is employed to approximate the unknown plant dynamics. The T-S fuzzy model is fed with its own states, which are indeed its past outputs, rather than the measurements from the plants. Entirely based on this model, a feedback linearization control law is designed by using...
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Stable indirect adaptive control based on discrete-time T-S fuzzy model
PublicationThis paper presents an indirect adaptive fuzzy control scheme for uncertain nonlinear asymptotically stable plants.A discrete-time T-S fuzzy input-output model is employed to approximate the unknown plant dynamics. The T-S fuzzy model is fed with its own states, which are indeed its past outputs, rather than the measurements from the plants. Entirely based on this model, a feedback linearization control law is designed by using...
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Novel non-covalent stable supramolecular ternary system comprising of cyclodextrin and branched polyethylenimine
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