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Search results for: UMOCNIENIE METALU
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A first-principles study of electronic and magnetic properties of 4d transition metals doped in Wurtzite GaN for spintronics applications
PublicationWe studied the electronic and magnetic properties of wurtzite GaN (w-GaN) doped with different concentrations of the 4d transition metal ions Nb, Mo, and Ru. We incorporated spin-polarized plane-wave density functional theory within an ultrasoft pseudopotential formalism. The 4d transition metals were doped at different geometrical sites to determine the geometry with the lowest total energy and the one that induced the largest...
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Noble metal-modified octahedral anatase titania particles with enhanced activity for decomposition of chemical and microbiological pollutants
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The role of aluminium in metal–organic frameworks derived carbon doped with cobalt in electrocatalytic oxygen evolution reaction
PublicationWater electrolysis is one of the most crucial processes in the development of new energy sources, where ultra-clean fuel is produced - hydrogen. Oxygen evolution reaction (OER) is the sluggish process of overall water splitting. Therefore, this study presents the design, characterization and electrochemical study of cobalt-based electrocatalysts embedded into porous carbons derived from an Al-metal–organic...
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A facile preparation method and proof of cycle-stability of carbon-coated metal oxide and disulfide battery materials
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Fabrication and characterizations of hybrid materials based on polyaniline, metal oxide, and graphene nano-platelets for supercapacitor electrodes
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Tribological Anti-Wear and Extreme-Pressure Performance of Multifunctional Metal and Nonmetal Doped C-based Nanodots
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Elimination of metal catalyst and carbon-like impurities from single-wall carbon nanotube raw material
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A concerted evolution of supramolecular interactions in a {cation; metal complex; π-acid; solvent} anion-π system
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Effect of Different Radiation Sources and Noble Metal Doped onto TiO2 for Contaminants of Emerging Concern Removal
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Hierarchical porous carbon materials from nanosized metal-organic complex for high-performance symmetrical supercapacitor
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Heavy metal accumulation and distribution in Phragmites australis seedlings tissues originating from natural and urban catchment
PublicationThe retention of heavy metal (HM) was studied in root and rhizomes (BLG), stems (ST), and leaves (LF) of Phragmites australis (common reed) seedlings collected from different locations, differing in the scale of anthropogenic interference. The analysis includes the reference samples of sediments in uncontaminated lake Garczonki and contaminated roadside ditch in Cieplewo. The concentrations of Zn, Cu, Pb, Cd, Ni, and Cr were analyzed...
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Metal-Organic Frameworks-Based Sensors for the Detection of Toxins in Food: A Critical Mini-Review on the Applications and Mechanisms
PublicationUsing scientific technologies to detect toxins in food is significant to prevent food safety problems and protect people’s health. Recently, the rise of sensors has made rapid, efficient, and safe detection of food toxins possible. One of the key factors impacting the sensor’s performance is the nanomaterials employed. Metal-organic frameworks (MOFs), with high specific surface area, tunable composition, porous structure, and flexible...
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Effect of metal ions from Ginkgo biloba extracts on the oxidative stability of rapeseed oil and its triacylglycerols
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A Systematic and Comparative Study of Binary Metal Catalysts for Carbon Nanotube Fabrication Using CVD and Laser Evaporation
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Effect of time on the metal-support (Fe-MgO) interaction in CVD synthesis of single-walled carbon nanotubes
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Visible light activity of rare earth metal doped (Er3+, Yb3+ or Er3+/Yb3+) titania photocatalysts
PublicationA series of Er3+-TiO2, Yb3+-TiO2 and Er3+/Yb3+-TiO2 photocatalysts were obtained via sol-gel method, using rare earth metal (RE) precursor ranging from 0.25 to 10 mol%. The experiments demonstrated that phenol in aqueous solutions was successfully degraded under visible light (> 450 nm) using RE3+-TiO2. The as-prepared samples were characterized by X-ray diffraction (XRD), X-ray photoelectron emission spectroscopy (XPS), UV-Vis...
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Biological responses to environmental contamination. How can metal pollution impact signal honesty in avian species?
PublicationEnvironmental pollution, for example with metals, can significantly affect the ecosystem balance leading to severe changes. Biologically active pigments are relevant for the appearance and condition of birds. Melanin and carotenoid particles are the most frequently deposited pigments in avian integument. They are responsible for the majority of colors of bird plumage. The phenotypic expression can be affected by metal contamination....
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Graphene hydrogels with embedded metal nanopatricles as efficient catalysts in 4-nitrophenol reduction and methylene blue decolorization
PublicationSynthesis and characterization of the graphene hydrogels with three different metallic nanoparticles, that is Au, Ag and Cu, respectively is presented. Synthesized in a one-pot approach graphene hydrogels with embedded metallic nanoparticles were tested as heterogeneous catalysts in a model reaction of 4-nitrophenol reduction. The highest activity was obtained for graphene hydrogel with Cu NPs and additional reaction of methylene...
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Cobalt(II) tri-tert-butoxysilanethiolates: in search of models for catalytic metal site of liver alcohol dehydrogenase
PublicationPrzeprowadzono syntezę trzech kompleksów: [Co{SSi(OBut)3}2(NH3)(L-pic)],[Co{SSi(OBut)3}2(NH3)2]xMeCN i [Co{SSi(OBut)3}3(H2O)][NHEt3]. Kompleksy są monomeryczne, dla nich wyznaczono strukturę krystalograficzną. Kompleks [Co{SSi(OBut)3(NH3)(L-pic)] o rdzeniu CoN2OS2 posiada dwa różne ligandy azotowe, zaś [Co{SSi(OBut)3(L-pic)] stanowi substrat do syntezy związku modelującego centrum katalityczne LADH.
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Advanced nanomaterials and metal-organic frameworks for catalytic bio-diesel production from microalgal lipids – A review
PublicationIncreasing energy demands require exploring renewable, eco-friendly (green), and cost-effective energy resources. Among various sources of biodiesel, microalgal lipids are an excellent resource, owing to their high abundance in microalgal biomass. Transesterification catalyzed by advanced materials, especially nanomaterials and metal-organic frameworks (MOFs), is a revolutionary process for overcoming the energy crisis. This review...
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Design of novel highly sensitive sensors for crack detection in metal surfaces: theoretical foundation and experimental validation
PublicationThe application of different types of microwave resonators for sensing cracks in metallic structures has been subject of many studies. While most studies have been focused on improving the sensitivity of planar crack sensors, the theoretical foundation of the topic has not been treated in much detail. The major objective of this study is to perform an exhaustive study of the principles and theoretical foundations for crack sensing...
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Solvation and partial molar volumes of some transition metal cations in N,N-dimethylacetamide, triethylphosphate and acetonitrile.
PublicationW oparciu o precyzyjne pomiary gęstości roztworów nadchloranów metali przejściowych szeregu Mn(II)-Zn(II) w DMA, TEP i AN wyznaczono pozorne molowe oraz graniczne wartości cząstkowych molowych objętości sole w temperaturach 293, 298 i 303,15 K. Wyznaczone wartości rozdzielono na udziały jonowe. Przeanalizowano czynniki decydujące o wielkości cząstkowych molowych objętości solwatowanych kationów.
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Investigations of local/global buckling of cylindrical metal silos with corrugated sheets and open-sectional column profiles
PublicationArtykuł zajmuje się problemem lokalnego/globalnego wyboczenia w cylindrycznych metalowych silosach z blachy falistej z otwartymi cienkościennymi profilami słupowymi. Obliczenia wykonano w ramach liniowej teorii bifurkacji stosując metodę elementów skończonych w programie ABAQUS. Zbadano obszernie wpływ różnych parametrów (średnica i wysokość silosów, grubość blachy falistej, wielkość fali blachy, rozstaw słupów, przekrój słupów)...
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Internalized stigma and its correlates among patients with severe mental illness
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Exploring the influence of personal factors on physiological responses to mental imagery in sport
PublicationImagery is a well-known technique in mental training which improves performance efficiency and influences physiological arousal. One of the biomarkers indicating the amount of physiological arousal is skin conductance level (SCL). The aim of our study is to understand how individual differences in personality (e.g. neuroticism), general imagery and situational sport anxiety are linked to arousal measuring with SCL in situational...
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[Rozdział] 2. Prognoza emisji metali ciężkich do atmosfery z obszaru Europy w perspektywie roku 2020
PublicationWiedza na temat przyszłych, spodziewanych lub wymaganych, poziomów emisji zanieczyszczeń powietrza w Europie jest jedną z podstawowych informacji wykorzystywanych przy sporządzaniu różnego rodzaju długoterminowych strategii wspomagających politykę środowiskową Unii Europejskiej, programów zajmujących się zarządzaniem jakością powietrza atmosferycznego, czy też ocen narażenia zdrowotnego ludności. Przedstawiona prognoza emisji,...
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Silicon occurrence, uptake, transport and mechanisms of heavy metals, minerals and salinity enhanced tolerance in plants with future prospects: A review
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Heavy metals in lake surface sediments in protected areas in Poland: concentration, pollution, ecological risk, sources and spatial distribution
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Specjacja metali ciężkich w ściekach i wodach odciekowych podczas oczyszczania ścieków w reaktorach systemu MUCT
PublicationCelem prowadzonych badań była analiza występowania i dostępności wybranych metali ciężkich po kolejnych stopniach oczyszczania w wysokoefektywnej oczyszczalni z biologicznym usuwaniem azotu i fosforu. Przeprowadzono analizę rozmieszczenia fazowego wybranych metali pomiędzy fazą rozpuszczoną i zawiesinową dla ścieków oraz wód odciekowych. Zastosowanie ekstrakcji sekwencyjnej pozwoliło na określenie stężeń wybranych metali ciężkich:...
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Specjacja metali ciężkich w osadach ściekowych powstających w trakcie oczyszczania ścieków w reaktorach systemu MUCT
PublicationCelem prowadzonych badań była analiza zawartości metali ciężkich w poszczególnych frakcjach po kolejnych stopniach obróbki osadów powstających reaktorach wielofazowych MUCT. Przeprowadzone badania pozwoliły na ocenę wpływu stosowanej technologii przeróbki osadów na specjację metali oraz ich biodostępność w aspekcie przyrodniczego ich zagospodarowania.
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Możliwości sterowania kinetyką wydzielania z roztworu pojedynczych jonów w procesie jednoczesnej flotacji kilku jonów metali
PublicationZbadano wpływ pH surówki flotacyjnej, stężenia kolektora i prędkości przepływu powietrza na przebieg flotacji jonowej i precypitacyjnej mieszaniny Al(III), Cu(II) i Zn(II). Najwyższe wartości stałych szybkości flotacji badanych metali uzyskano dla procesów prowadzonych dla pH około 8, tj. w warunkach flotacji precypitacyjnej. Wykazano, że stałe szybkości flotacji badanych metali są proporcjonalne do prędkości przepływu powietrza flotującego...
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Assessment of Trace Metals Leaching During Rainfall Events from Building Rooftops with Different Types of Coverage – Case Study
PublicationRunoff water is an important medium transporting various types of pollution originating from the atmosphere and washed out from roofing materials. The study presents a quality assessment of runoff from different roofs in the context of trace metal concentrations. The analysed rooftops were covered with copper, tar paper and ceramic tile. The quality of the rain water collected at the same time satisfies the demands of the first...
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Protective Effect of Aronia Melanocarpa Polyphenols on Cadmium Accumulation in the Body: A Study in a Rat Model of Human Exposure to this Metal
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Correlational nutritional relationships and interactions between expansive holoparasite Orobanche laxissima and woody hosts on metal-rich soils
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Study of the selection mechanism of heavy metal (Pb 2+, Cu 2+, Ni 2+ and Cd2+) adsorption on clinoptilite
PublicationBadano proces adsorpcji jonów metali ciężkich (w warunkach statycznych) z wodnych roztworów jednoskładnikowych i wieloskładnikowych na klinoptylolicie zarówno surowym jak i po wstępnej obróbce. Proces sorpcji ma charakter procesu jonowymiennego i składa sie z trzech etapów:- adsorpcji na powierzchni mikokryształów,- inwersji,- adsorpcji wewnątrz mikrokryształów.Proces sorpcji może być dobrze opisany zarówno za pomocą modelu Frendlicha...
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Estimation, optimization and analysis based investigation of the energy consumption in machinability of ceramic-based metal matrix composite materials
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Broad-Range Spectral Analysis for Chiral Metal Coordination Compounds: (Chiro)optical Superspectrum of Cobalt(II) Complexes
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Volumes of N,N-dimethylacetamide solvated metal cations. Variation within the manganese(II) to zinc(II) series
PublicationDensities and apparent molar volumes for Mn(ClO4)2,Co(ClO4)2 , Ni(ClO4)2,Cu(ClO4)2 , and Zn(ClO4)2 in N, N -dimethylacetamide (DMA) solutions at T = 298.15 K are reported. Densities and apparent molar volumes of tetrabutylammonium tetraphenylborate...
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Application of 3D digital image correlation for development and validation of FEM model of self-supporting metal plates structures
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Correlation between destruction of the metal surface caused by pitting corrosion and intensity of the observed electrochemical noise (Invited Paper)
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O-substituted tetrahydroxamate derivatives of p-tert-butylcalix[4]arene as receptors for transition and heavy metal cations
PublicationTetrasubstituted O-hydroxamate derivatives of p-tert-butylcalix[4]arene were applied as active materials in ion-selective membrane electrodes and were tested towards Pb-selectivity. The electrodes gave near-Nernstian characteristics for Pb2+ cations. The selectivity coefficients were determined. The influence of plasticizer on the electrode behaviour was studied. The dependence of the chemical structure on selectivity coefficients...
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Influence of vacuum sublimation deposited metal layer thickness on metrological parameters of the amperometric gas sensor with Nafion membrane
PublicationThe paper presents the results of investigation on an influence of vacuum sublimation deposited platinum layer thickness on the signal, sensitivity and response time of a prototype of sulphur dioxide sensor with Nafion membrane. The working electrode was made by vacuum sublimation deposition of platinum on a surface of Nafion membrane. Pt layers deposited changed an initial structure of Nafion membrane and that phenomenon was utilized...
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Nitrogen‐Doped Porous Graphene‐Based Aerogels toward Efficient Heavy Metal Ion Adsorption and Supercapacitor Applications
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The importance of evaluating metal exposure and predicting human health risks in urban–periurban environments influenced by emerging industry
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Metal (Mo, W, Ti) Carbide Catalysts: Synthesis and Application as Alternative Catalysts for Dry Reforming of Hydrocarbons—A Review
PublicationDry reforming of hydrocarbons (DRH) is a pro-environmental method for syngas production. It owes its pro-environmental character to the use of carbon dioxide, which is one of the main greenhouse gases. Currently used nickel catalysts on oxide supports suffer from rapid deactivation due to sintering of active metal particles or the deposition of carbon deposits blocking the flow of gases through the reaction tube. In this view,...
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A pilot study to assess an in-process inspection method for small diameter holes produced by Direct Metal Laser Sintering
PublicationPurpose The purpose of this research is to evaluate the geometric quality of small diameter holes in parts printed by DMLS technology. An in-process optical inspection method is proposed and assessed during a pilot study. The influence of the theoretical hole diameter assumed in a CAD system and the sample thickness (hole length) on the hole clearance was analysed. Design/methodology/approach The samples made of two different...
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Silicon polypodands: powerful metal cation complexing agents and solid–liquid phase-transfer catalysts of new generation
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Study on the effect of the metal–support (Fe-MgO and Pt-MgO) interaction in alcohol-CVD synthesis of carbon nanotubes
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Noble metal modified TiO2 microspheres: Surface properties and photocatalytic activity under UV-vis and visible light
PublicationComposite photocatalysts that consist of TiO2and noble metal nanostructures have been considered tobe the promising and pivotal material for accessible enhancement of the efficiency in the photocatalyticprocess carried out in the aqueous and gas phases. In this work we fabricated porous TiO2microspheresthrough a hydrothermal process followed by photochemical reduction of noble metal nanoparticles atthe TiO2surface. The morphology...
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Solvation of alkaline earth metal ions in N,N-dimethylformamide and N,N-dimethylacetamide – A volumetric and acoustic study
PublicationDensities and sound velocities at temperatures (298.15, 303.15, 308.15, 313.15 and 318.15) K of magnesium(II), calcium(II) and strontium(II) rifluoromethanesulfonates (triflates), as well as barium(II) perchloratein N,N-dimethylformamide (dmf) and N,N-dimethylacetamide (dma) have been measured over the composition range studied. From these results, apparent molar volumes and apparent molar isentropic compressibilities at infinite...