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Search results for: photoconversion of CO2
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Cavitation erosion of steels processed by CO2 laser beams of various parameters.
PublicationPrzedstawiono wpływ parametrów przetapiania stali za pomocą wiązki lasera CO2 na jej własności kawitacyjne. Do badań użyto stali 45, 2H13 i OH18N9. Wyniki badań wskazują na znaczny wpływ parametrów przetapiania na poziom odporności kawitacyjnej stali.
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Prediction of CO2 emissions of a car using the discrete map of the operating conditions
PublicationW pracy przedstawiono propozycję opisu warunków eksploatacji pojazdów w wybranej aglomeracji miejskiej z użyciem dyskretnej mapy warunków eksploatacji. Mapa taka umożliwia prognozowanie wybranych parametrów eksploatacyjnych pojazdów dla przyjętych dróg przejazdu oraz różnych jednostek napędowych. Głównymi parametrami wyznaczanymi z użyciem dyskretnej mapy warunków eksploatacji są: całkowita energia przeznaczana do napędu wybranego...
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Numerical analysis of CO2-water separation in a horizontal double T-junction
PublicationCarbon dioxide is considered one of the main factors leading to global warming. Considering the significant impacts of CO2 on climate change, various technologies have been developed in recent decades to control carbon emission, such as for example CO2 capture and storage. The developed cycle of a negative CO2 emission power plant includes some devices, out of which, separator plays an indispensable role. To this end, T-junction...
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Core-shell cobalt particles Co@CoO loaded on nitrogen-doped graphene for photocatalytic water-splitting
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Luminescent, Scintillation, and Photoconversion Properties of Micro‐Pulling‐Down‐Grown Single Crystals of Ce 3+ ‐Doped Gd 3− x Lu x Al 5− y Ga y O 12 Garnets
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Corrigendum to “The influence of α,ω-diols and SiO2 particles on CO2 absorption and NH3 escaping during carbon dioxide capture in ammonia solutions” [J. CO2 Util. 80 (2024) 102698]
Publicationnie dotyczy
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Simultaneous voltammetric determination of Cd2+, Pb2+, and Cu2+ ions captured by Fe3O4@SiO2 core-shell nanostructures of various outer amino chain length
PublicationIn the present study, we examined a novel functionalised magnetic nanoparticles Fe3O4@SiO2-Nn as a nano adsorbent for binding of Cd2+, Pb2+, Cu2+ ions in an aqueous solution. First, we obtained the nanoparticles functionalised with various carbon chains containing different number of amino groups: (3-amino)propyltriethoxysilane (Fe3O4@SiO2-N1), N-(2-aminoethyl)-3-aminopropyltrimethoxysilane (Fe3O4@SiO2-N2) and N1-(3-trimethoxysilylpropyl)diethylenetriamine...
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Ru/Al2O3 on Polymer-Derived SiC Foams as Structured Catalysts for CO2 Methanation
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Conventional and Alternative Sources of Thermal Energy in the Production of Cement—An Impact on CO2 Emission
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A novel concept of negative CO2 emission power plant for utilization of sewage sludge
PublicationCarbon Capture and Storage (CSS) technology is considered an important “bridge technology”, allowing effective abatement of CO2 emissions for power units using fossil fuels. However, if biomass is used in a power plant, equipped with CCS system, negative CO2 emissions can be achieved. In practice, wide development of such technologies would enable not only reduction of CO2 emissions, but also reversal of the harm done so far. In...
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Influence of Selected Saccharides on the Precipitation of Calcium-Vaterite Mixtures by the CO2 Bubbling Method
PublicationCalcium carbonate is a compound existing in living organisms and produced for many biomedical applications. In this work, calcium carbonate was synthesized by a CO2 bubbling method using ammonia as a CO2 absorption promotor. Glucose, fructose, sucrose, and trehalose were added into the reaction mixture to modify characteristics of precipitated calcium carbonate particles. To determine the polymorphic form of produced calcium carbonate...
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Thermodynamic analysis of the double Brayton cycle with the use of oxy combustion and capture of CO2
PublicationIn this paper, thermodynamic analysis of a proposed innovative double Brayton cycle with the use of oxy combustion and capture of CO2, is presented. For that purpose, the computation flow mechanics (CFM) approach has been developed. The double Brayton cycle (DBC) consists of primary Brayton and secondary inverse Brayton cycle. Inversion means that the role of the compressor and the gas turbine is changed and firstly we have expansion...
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Separation of CO2 from flue gas in air-sparged hydrocyclone (ash) reactor
PublicationPrzedmiotem badań była absorpcja dwutlenku węgla w wodnym roztworze wodorotlenku sodu, z fazy gazowej w skali laboratoryjnej i technologicznej z wykorzystaniem reaktora typu ash. Natężenie przepływu powietrza wynosiło 900 dm3/min a wodnego roztworu NaOH 15 dm3/min w skali technologicznej. Zbadano stężenie CO2, pH w fazie ciekłej, wpływ natężenia przepływu fazy gazowej i fazy ciekłej na efektywność absorpcji
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Con l’introduzione
PublicationNata nel 1953 con l’obiettivo di portare l’Italia tra le nazioni avanzate anche in campo energetico, Eni rappresenta una delle principali imprese ad aver influenzato l’innovazione economica del Paese. La sua storia, legata a doppio filo alla figura di Enrico Mattei, consente di seguirne le traiettorie di sviluppo e le strategie di internazionalizzazione, nel quadro di un contesto in continua evoluzione. Questo volume ripercorre...
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Use of broad-spectrum antibiotics in children diagnosed with multisystem inflammatory syndrome temporarily associated with SARS-CoV-2 infection in Poland: the MOIS-CoR study
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Ocena warunków procesu precypitacji węglanu wapnia w reaktorze gaz(CO2)-lift
PublicationOtrzymywano węglan wapnia w reakcji wodorotlenku wapnia z dwutlenkiem węgla. Zbadano wpływ stężenia Ca(OH)2 oraz prędkości przepływu dwutlenku węgla na czas reakcji i wykorzystanie CO2. Określono strukturę otrzymanych cząstek CaCO3 za pomocą XRD.
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Direct conversion of biomass to nanoporous activated biocarbons for high CO2 adsorption and supercapacitor applications
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CO2 Separation Using Supported Deep Eutectic Liquid Membranes Based on 1,2-propanediol
PublicationIn this work, deep eutectic solvents (DESs) composed of choline chloride, acetylcholine chloride or tetrabutylammonium chloride, and 1,2-propanediol were used as a liquid phase for polypropylene-based supported liquid membranes (SLMs) and evaluated for the separation of carbon dioxide from CO2/N2 mixtures. Fourier transform infrared spectra were obtained to confirm DES formation, and the thermal stability of solvents was investigated...
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Development of a spray-ejector condenser for the use in a negative CO2 emission gas power plant
PublicationOne promising solution for developing low-emission power technologies is using gaseous fuel combustion in pure oxygen when the exhaust gas mixture is composed of H2O and CO2, and where CO2 is separated after steam condensation. The paper presents the results of computational analyses providing to the Spray-Ejector Condenser (SEC) development, which is one of the crucial components of the negative CO2 gas power plant (nCO2PP) cycle...
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Effects of CO2 and Nd:YAG Laser Remelting of the Ti6Al4V Alloy on the Surface Quality and Residual Stresses
PublicationThe titanium alloys are materials susceptible to tribological wear and the laser treatment can be applied in surface treatment processes to obtain for example higher hardness level. From the other side, it is important to take into consideration, that hardness increase that can be connected with cracks . The aim of this research was to investigate the effects of different lasers and the process parameters on the form and level...
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Carbon Nanomaterials From Metal-Organic Frameworks: A New Material Horizon for CO2 Reduction
PublicationThe rise of CO2 in the atmosphere, which results in severe climate change and temperature increase, is known as the major reason for greenhouse effect. Reducing CO2 to value-added products is an attractive solution to this severe problem, along with addressing the energy crisis, to which the catalysts being employed are of vital importance. Due to their high porosity and tunable compositions, Metal-Organic Frameworks (MOFs) show...
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Copper oxide thin films as components for heterojunction formation with TiO2 for photocatalytic CO2 reduction
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Cold Plasma Synthesis and Testing of NiOX-Based Thin-Film Catalysts for CO2 Methanation
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The Impact of Energy Development of the European Union Euro Area Countries on CO2 Emissions Level
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Wpływ prędkości przesuwu wiązki lasera CO2 na odporność kawitacyjną stali 2H13
PublicationPrzedstawiono badania odporności kawitacyjnej stali 2H13 po przetapianiu jej powierzchni wiązką lasera CO2, przy różnych prędkościach obróbki laserowej. Stwierdzono wzrost odporności kawitacyjnej przy wzroście prędkości obróbki.
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Zastosowanie unieruchomionych ciekłych membran z cieczami jonowymi w procesach separacji CO2
PublicationPrzedmiotem pracy jest efektywność przenikania CO2 i CH4 przez ciekłe membrany z cieczami jonowymi osadzonymi na nośnika polimerowych. Jako fazę membranową zastosowano imidazoliowe ciecz jonowe będące kombinacją kationu o różnej długości podstawnika alkilowego oraz różnych anionów [Tf2N][, [TfO],[BF4] i [PF6]. Porównano szybkość permeacji obu gazów w układzie laboratoryjnym, gdzie powierzchnia membrany wynosiła 13cm2.
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Strącanie węglanu wapnia w kolumnowym reaktorze barbotażowym z CO2 jako reagentem
PublicationBadano przebieg procesu precypitacji węglanu wapnia z roztworu wodorotlenku wapnia za pomocą dwutlenku węgla w reaktorze typu airlift. Zbadano wpływ czasu nagazowania, prędkości przepływu dwultenku węgla i przepływu mieszaniny dwutlenku węgla i powietrza na wielkość otrzymywanych cząstek. W czasie procesu mierzono pH mieszaniny reakcyjnej oraz stopień zatrzymania gazu.
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Relationship among Economic Growth, Energy Consumption, CO2 Emission, and Urbanization: An Econometric Perspective Analysis
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Potassium citrate-derived porous carbon with high CO2 capture and Congo red adsorption performance
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Ag modified ZnO microsphere synthesis for efficient sonophotocatalytic degradation of organic pollutants and CO2 conversion
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CO2 EMISSION TO THE ATMOSPHERE FROM CARBONATE WATERS: THE STUDY CASE OF THE LUBLIN UPLAND AND ROZTOCZE REGIONS
PublicationThe concentration of carbon dioxide dissolved in water (CO2(aq)) was measured in consecutive phases of the hydrological cycle. Its potentially possible degassing from groundwaters to the atmosphere was also assessed. The research was conducted in the area of occurrence of carbonate rocks of the Lublin Upland and Roztocze (SE Poland). The results of the measurements of CO2(aq) concentration varied as follows (min-max/mean): precipitation...
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Yields and Time-of-Flight Spectra of Neutral High-Rydberg Fragments at the K Edges of the CO2 Molecule
PublicationWe have studied the production of neutral fragments in high-Rydberg (HR) states at the C 1s and O 1s edges of the CO2 molecule by performing two kinds of experiments. First, the yields of neutral HR fragments were measured indirectly by ionizing such fragments in a static electric field and by collecting resulting singly charged positive ions as a function of the photon energy. Such measurements reveal not only excitations below...
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CO2 capture through direct-contact condensation in a spray ejector condenser and T- junction separator
PublicationThe design principle underlying the steam condensation and CO2 purification in a gas power plant with a focus on reducing CO2 emissions encompasses the deployment of a spray ejector condenser (SEC) and separator. This innovative system facilitates direct-contact condensation of steam with non-condensable gas (CO2) by inter acting with a spray of subcooled water, seamlessly integrated with a T-junction separator mechanism aimed...
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Thermodynamic interpretation and prediction of CO2 solubility in imidazolium ionic liquids based on regular solution theory
PublicationRegular solution theory (RST) is the most popular model for the interpretation of the interaction between CO2 and ionic liquids. In the present work, the parameters of this model were determined for the CO2 absorption in eleven imidazolium ionic liquids. The y-intercept (A) of the RST model for the investigated imidazolium liquids increases with increasing temperature whereas the slope (B) remains constant. The values of RST parameters...
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CO2 capture enhancement by metal oxides impregnated coal fly ash: a breakthrough adsorption study
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Mathematical modelling of gasification process of sewage sludge in reactor of negative CO2 emission power plant
PublicationSewage sludge is a residue of wastewater processing that is biologically active and consists of water,organic matter, including dead and alive pathogens, as well as organic and inorganic contaminants suchas polycyclic aromatic hydrocarbons (PAHs) and heavy metals. Due to the nature of sewage sludge and itspossible influence on human health and wellbeing, it is a subject of various regulations. Currently,sewage sludge is considered...
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Ag modified ZnO microsphere synthesis for efficient sonophotocatalytic degradation of organic pollutants and CO2 conversion
PublicationThe synthesis and design of non-precious and efficient sonophotocatalyts by an environment friendly technique are requisites for solar energy conversion and environmental remediation. This work reports the preparation of Ag/ZnO microspheres with different Ag contents through deposition–precipitation method for pollutant degradation and CO2 conversion. Detail structural investigation reveals that ZnO microspheres and Ag-ZnO microspheres...
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Computational Fluid Dynamics Simulation of Gas–Liquid Multiphase Flow in T-junction for CO2 Separation
PublicationThe article presents the results of a computational fluid dynamics (CFD) analysis of gas-liquid multiphase flow. The simulation was conducted using CFD code and the Euler–Euler approach. The presented study relates to the non–reactive, steady-state, turbulent flow of water and carbon dioxide mixture in a 3D pipe. Separation phenomenon between phases is observed. The solution was obtained using a mixture model. Different values...
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Evaluation of the reference fuel consumption and CO2 emission of vehicle with using of the map of operating conditions for selected agglomeration
PublicationZaproponowana w pracy metoda tworzenia mapy warunków eksploatacji dla wybranej aglomeracji może zostać przeprowadzona przy wykorzystaniu tanich i prostych w obsłudze urządzeń. Podstawowym urządzeniem badawczym jest pojazd samochodowy wyposażony w system pomiaru położenia GPS z układem korekty wskazań wysokości i rejestracji parametrów jazdy. Zamieszczony w pracy przykład wykorzystania mapy warunków eksploatacji pokazuje możliwości...
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The effect of 1,4-butanediol on the efficiency of CO2 absorption and inhibition of NH3 escape during the mineral carbonation of gypsum
PublicationThis study explored the optimal concentration of 1,4-butanediol for maximizing CO2 absorption and minimizing ammonia desorption. Mineral carbonation of gypsum slurry was carried out in a bubble reactor with a magnetic stirrer maintaining constant speed for 1 hour. The gas introduced to the reactor was a mixture of CO2 and air. The gas flow was controlled by the mass controllers. Gas sensors were used to determine the concentration...
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Performance evaluation of phosphonium based deep eutectic solvents coated cerium oxide nanoparticles for CO2 capture
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Thermodynamic, ecological, and economic analysis of negative CO2 emission power plant using gasified sewage sludge
PublicationCurrently, sewage sludge is considered as a biomass, according to the Polish act on renewable energy sources from 20th of February 2015 and its novel version from 19th of July 2019. Possibility to utilize sewage sludge in gasification process is an additional advantage of the negative CO2 emissions power plant (nCO2PP). The work presents results of thermodynamic, ecological, and economical analysis using a zero-dimensional mathematical...
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A Novel Method of Endotoxins Removal from Chitosan Hydrogel as a Potential Bioink Component Obtained by CO2 Saturation
PublicationThe article presents a new approach in the purification of chitosan (CS) hydrogel in order to remove a significant amount of endotoxins without changing its molecular weight and viscosity. Two variants of the method used to purify CS hydrogels from endotoxins were investigated using the PyroGene rFC Enzymatic Cascade assay kit. The effect of the CS purification method was assessed in terms of changes in the dynamic viscosity of...
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Improvement of CO2 absorption and inhibition of NH3 escape during CaCO3 precipitation in the presence of selected alcohols and polyols
PublicationThis research aims to investigate the effect of selected organic substances containing hydroxyl groups on the reduction of NH3 escape and the improvement of CO2 capture during the precipitation of calcium carbonate by carbonation method using post-distillation liquid from the Solvay process and gas stream containing CO2 in the amount corresponding to the exhausted gases produced by the combustion of fossil fuels. Glycerol, ethylene...
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New nanoadsorbent based on magnetic iron oxide containing 1,4,7,10-tetraazacyclododecane in outer chain (Fe3O4@SiO2-cyclen) for adsorption and removal of selected heavy metal ions Cd2+, Pb2+, Cu2+
PublicationMagnetic Fe3O4@SiO2-cyclen nanoparticles were prepared and used as adsorbent for Cd2+, Pb2+ and Cu2+ from aqueous solution removal process controlled with differential pulse anodic stripping voltammetry (DPASV) and hanging mercury drop electrode (HDME). Nanomaterial was synthesised in three-step process co-precipitation of Fe3O4 core, coating with silane and N-(3-(triethoxysilyl)propyl)-1,4,7,10-tetraazacyclododecane-1-carboxamide...
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Use of hop cone extract obtained under supercritical CO2 conditions for producing antibacterial all-purpose cleaners
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Selective preparation of biomass-derived porous carbon with controllable pore sizes toward highly efficient CO2 capture
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Combined operation of 900MW power plant with the ORC through the bleed steam extraction point and CO2 recovery system
PublicationThe work presented here is aimed at utylisation of waste heat in the reference supercritical power plant in the manner to produce electricity in ORC installation. The waste heat is available in the form of a stream of hot water at 90 C, recovered from the exhaust gases in the amount of 200MW. Such low enthalpy heat source is rather insufficient to produce a good quality vapour to feed the ORC turbine. Therefore an original approach...
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Preparation and characterization of genipin cross-linked porous chitosan–collagen–gelatin scaffolds using chitosan–CO2 solution
PublicationNovel porous scaffolds composed of chitosan, collagen and gelatin were prepared by the multistep procedure involving final freeze-drying and characterized. To eliminate the need for residual acid removal from the material after drying, carbon dioxide saturation process was used for chitosan blend formulation. The use of CO2 for chitosan dissolution made the scaffold preparation process more reproducible and economically sustainable....
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Zr‐Based Metal‐Organic Framework UiO‐66/Ultem® 1000 Membranes for Effective CO2/H2 Separation
PublicationMixed-matrix membranes (MMMs) using UiO-66 nanofillers as dispersing inorganic phase and polyetherimide (PEI) as continuous polymeric matrix were synthesized. Different UiO-66 loadings of 10, 20, and 30 wt % were applied. The morphology and UiO-66 dispersion over the prepared MMMs were examined. Gas separation measurements were performed for H2/CO2 gas mixture to evaluate the influence of UiO-66 on the separation yield of resulting...