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Search results for: metal softening
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Microplastics removal from aqueous environment by metal organic frameworks
PublicationThis paper provides an overview of recent research performed on the applications of metal–organic frameworks (MOFs) for microplastics (MPs) removal from aqueous environments. MPs pollution has become a major environmental concern due to its negative impacts on aquatic ecosystems and human health. Therefore, developing effective and sustainable methods for removing them from aqueous environments is crucial. In recent years, MOFs...
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Mitigating metal-organic framework (MOF) toxicity for biomedical applications
PublicationMetal-organic frameworks (MOFs) are a novel class of crystalline porous materials, consisting of metal ions and organic linkers. These hybrid materials are highly porous and have a large specific surface area, making them of great interest for applications in gas separation, energy storage, biomedical imaging, and drug delivery. As MOFs are being explored for biomedical applications, it is essential to comprehensively assess their...
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A Critical Reanalysis of Uncontrollable Washboarding Phenomenon in Metal Band Sawing
PublicationThe article analyzes the cutting process of hard bars. Investigations conducted in industrial conditions demonstrated the presence of surface errors in the machined workpieces in the form of washboard patterns. The purpose of this study was to analyze the results of cutting on band sawing machines with different band saw blades. The cutting processes were conducted on three different horizontal band sawing machine types. Analyzed...
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Buckling analyses of cylindrical metal silos containing bulk solids
PublicationThe paper presents quasi-static 3D buckling analysis results of thin-walled cylindrical metal silos with and without bulk solids. The behaviour of the bulk solid was described with a hypoplastic constitutive model. Non-linear analyses with geometric and material non-linearity were performed with a perfect and an imperfect silo shell. Different initial geometric imperfections were considered. The influence of internally stored bulk...
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A constitutive model for concrete based on continuum theory with non-local softening coupled with eXtended Finite Element Method. Computational Modelling of Concrete Structures,
PublicationArtykuł omawia model połączony ciągły-nieciągły do modelowania stref lokalizacji i rys w betonie niezbrojonym. Obliczenia wykonano stosując rozszerzoną metodę elementów skończonych. Wyniki numeryczne porównano z doświadczeniami.
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Wwpływ temperatury suszenia osadów ściekowych na specjację metali ciężkich (Zn, Cu, Cd, Pb) = Influence of thermal drying temperature on heavy metal (Zn, Cu, Cd, Pb) speciation in sewage sludge
PublicationPrzedstawiono wpływ temperatury suszenia osadów ściekowych na zmiany specjacji metali ciężkich oraz określono stopień mobilności metali ciężkich w aspekcie ich późniejszego zagospodarowania. Ekstrakcja sekwencyjna metali ciężkich została wykonana wg schematu Tessier'a.
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Reasons for shortening snow cover duration in the Western Sudetes in light of global climate change
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Hybrid metal and non-metal activation of Oxone by magnetite nanostructures co-immobilized with nano-carbon black to degrade tetracycline: Fenton and electrochemical enhancement with bio-assay
PublicationElectrochemically synthesized magnetite nanostructures (ESMNPs) as a metal activator and nano-carbon black (NCB) as a non-metal activator were co-immobilized by alginate natural polymer to activate Oxone for the degradation of tetracycline (TC) antibiotic. The formation of sulfate radical was indirectly confirmed during the Oxone/ESMNPs/NCB/alginate process via the addition of scavenging compounds. This study revealed the high...
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Medal dla Andrzeja Januszajtisa
PublicationArtykuł poświęcony doc. dr Andrzejowi Januszajtisowi - pierwszemu laureatowi Medalu im Ignacego Adamczewskiego, najwyższego wyróżnienia za popularyzację fizyki przyznawanego przez Oddział Gdańskiego Towarzystwa Fizycznego
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Medal dla Kazimierza Badziąga
PublicationArtykuł poświęcony doc. dr K. Badziagowi - laureatowi najwyższego wyróżnienia za popularyzację fizyki przyznawanego przez Oddział Gdańskiego Towarzystwa Fizycznego
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Wyznaczanie własności plastycznych metali.
PublicationWiększość metali i ich stopów posiada zdolność do odkształceń plastycznych.Zdolność ta jest wykorzystywana do realizacji określonych zmian kształtu materiału, mających na celu uzyskanie rożnego rodzaju wyrobów.Przebieg procesu plastycznego kształtowania zależy w istotny sposób od rodzaju i właściwości materiału poddanego obróbce plastycznej. Celem pracy jest analiza podstawowych metod badania własności metali oraz określenie krzywych...
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Numerical analysis of size effect in RC beams scaled along height or length using elasto-plastic-damage model enhanced by non-local softening.
PublicationArtykuł omawia wyniki numeryczne dotyczące efektu skali w belkach żelbetowych uzyskane stosując metodę elementów skończonych. Dwuwymiarowe obliczenia wykonano dla belek żelbetowych podczas 4-punktowego zginania. Belki były skalowane wzdłuż wysokości lub długości. Beton został opisany prawem sprężysto-plastycznym z degradacją sztywności, rozszerzonym o nielokalność w osłabieniu. Wyniki numeryczne zostały porównane z wynikami doświadczalnymi....
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Neon-Bearing Ammonium Metal Formates: Formation and Behaviour under Pressure
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Metal complexes with mixed s-donor ligands - a route via silanethiolates
PublicationW ramach prezentowanej pracy przedstawiono pierwsze próby syntezy mieszanych układów zawierających jednocześnie przykoordynowane reszty ditiokarbaminianową oraz silanotiolanowych. W badaniach posłużono się - jako substratami tri-tert-butoksysilanotiolanami kompleksami Cd, Zn, Cu, Pb, Hg, Ag i Co, a także solami kwasów: dietyloditiokarbaminowego oraz pirolidynoditiokarbaminowego. W przypadku związku Ag nie udało się wyizolować stałych...
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Metal Oxides and Low Temperature SWCNT Synthesis via Laser Evaporation
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Interaction of selected divalent metal ions with human ataxin-3 Q36
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Recovery of hydrochloric acid from metal pickling solutions by membrane distillation
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Direct cloning of heavy metal resistance genes from metagenomic DNA
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Noble metal-modified titania with visible-light activity for the decomposition of microorganisms
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Remediation techniques for elimination of heavy metal pollutants from soil: A review
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Airborne peptidoglycans as a supporting indicator of bacterial contamination in a metal processing plant
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Studies of complexation of metal cations by tris(3,6-dioxaheptyl)amine in solution
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Stimulation of Heavy Metal Adsorption Process by Using a Strong Magnetic Field
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Application of Carbonized Metal–Organic Framework as Efficient Adsorbent of Cationic Dye
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Calix[4]arene-Thioamides as Ionophores for Transition and Heavy Metal Cations.
PublicationPochodne kaliks[4]arenów odgrywają ważną rolę jako materiał aktywny w membranowych elektrodach jonoselektywnych. Obecnie duży nacisk kładzie się na kontrolę stężeń kationów metali ciężkich, takich jak Pb, Cd, Hg, Cu w wodach naturalnych. Naszym zadaniem było zaprojektować i zsyntezować ligandy, które wykazują zdolność do wiązania kationów metali ciężkich i przejściowych. Synteza, struktury krystaliczne, ekstrakcja i właściwości...
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Calix[4]arene-Thioamides as Ionophores for Transition and Heavy Metal cations
PublicationCalix[4]arene derivatives play an important role as sensing materials in Ion Selective Electrodes(ISEs). Nowadays a high impact is put to control in natural waters the level of toxic heavy metals, like Pb ,Cd, Hg or Cu which may cause the great risk to human health. Our goal was to design and to synthesize ligands possessing ability to bind transition and heavy metal cations. The synthesis, crystal structures,extractive and ionophoric...
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Speciation of heavy metal compounds in samples of biota from marine ecosystems
PublicationIt has become increasingly evident that the toxicity, mobility, bioavailability and bioaccumulation of metals are dependent on the particular physico-chemical form in which the element occurs in the environment. Special attention is paid to metals, which are essential for the proper functioning of organisms if present in appropriate amounts but are toxic if in excess (i.e. Se, Cr, Zn), and also to non-essential elements (i.e. Hg,...
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Azomacrocyclic derivatives of imidazole: synthesis, structure, and metal ion complexation properties
PublicationNew azocrown ethers comprising imidazoles in the macrocycle have been synthesized. Imidazole, 2-methyl-, 4-methyl-, and 4-phenylimidazole were incorporated to form macrocyclic units by coupling with the appropriate bis-diazonium salts. The syntheseswere performed under high dilution conditions. The X-ray structure of a water adduct of the 21-membered crown ether derivative of 4-methylimidazole 8 has been solved. Metal...
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Mixed conductivity in tungstenite-phosphate glasses containing alkali metal ions
PublicationThe conductivity of glasses in the 50WO3-(50-x)P2O5-xA2O (A = Na, K, Cs) system has been investigated as a function of composition. It is shown that in tungstenite-phosphate glasses containing different alkali metal ions the conductivity decreases with an increase in the alkali metal ion content. A decrease in conductivity is larger for heavier ions and reaches more than seven orders of magnitude in the case of glass containing...
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FEM approach to estimate the behaviour of biocomposite metal-surface coating system
PublicationA three dimensional (3D) model of biocomposite metal-surface coating system, which is influenced byknown external forces, is proposed. This model consists of the metallic substrate (Ti6Al4V) and thehydroxyapatite (HA) coating. Using FEM (finite element method), strain-stress maps of model weregenerated for investigating relations between the extreme stress of HA coating and the magnitude ofexternal force and the thickness of the...
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Noble metal–TiO2 supported catalysts for the catalytic ozonation of parabens mixtures
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Application of Coordination Compounds with Transition Metal Ions in the Chemical Industry—A Review
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Lightweight glass and metal roof structures in the 19th century. Architecture and construction.
PublicationThe 19th century brought new construction possibilities. The usage of metal elements in mesh structures, filled in with glass, resulted in creating entirely new types of objects. They have distinguished themselves in architecture and technical solutions. The envelope structures giving spatial interiors were arising very quickly. They have been enabling large light penetration, triggering them extremely bright. Thus these building...
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The 15th Workshop on Progress in Trace Metal Speciation for Environmental Analytical Chemistry
PublicationArtykuł jest sprawozdaniem z konferencji TRACESPEC - the 15th Workshop on progress in trace Metal Speciation for Environmental Analytical Chemistry, ktora odbyla sie we wrzesniu 2016 na Politechnice Gdańskiej. W artykule przedstawiono głowne cele i załozenia konferencji oraz opisano program naukowy.
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Metal enhanced fluorescence of flavin mononucleotide using new plasmonic platform
PublicationNew plasmonic platform was successfully obtained to investigate the increase of fluorescence intensity of a fluorophore in the presence of silver nanoparticles. A flavin mononucleotide, was selected by us as a fluorophore for this study as a very important biological compound playing a key role in many biochemical process. Plasmonic platforms were characterized by means of luminescence spectroscopy. Flavin mononucleotide deposited...
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Assessment of hydrogenation of deposited metal of P 62 MR covered electrodes
PublicationThe determination of diffusible hydrogen content in deposited metal of P 62 MR covered electrodes for manual metal arc welding by mercury method was carried out. The test results indicate that covered electrodes 62 P MR grade generate a mean of 4.02 ml/100g of diffusible hydrogen in deposited metal, which is consistent with H5 class.
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Azomacrocyclic derivatives of imidazole: synthesis, structure, and metal ion complexation properties
PublicationOtrzymano nowe azokorony zawierające resztę imidazolu w makropierścieniu. Na drodze sprzęgania z solami diazoniowymiotrzymano pochodne imidazolu 2-metylo, 4-metylo oraz 4-fenyloimidazolu. Synteza była prowadzona w warunkach wysokiego ciśnienia. Dla 21-członowej pochodnej 4-metyloimidazolu określono strukturę jej adduktu z wodą przy pomocy metod rentgenograficznych.Zdolność kompleksowania jonów metali badano spektrofotometrycznie...
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Metal heksacyanoferrate network synthesized inside polymer matrix for electrochemical capacitors
PublicationPrzedmiotem publikacji jest charakterystyka elektrochemiczna polimeru przewodzącego (poli(3,4-etylenodioksytiofenu)) modyfikowanego błękitem pruskim oraz jego pochodnymi, pochodną kobaltową oraz pochodną niklową. Materiały są stabilne elektrochemicznie, a uzyskane wartości pojemności elektrycznej pozwalają na wykorzystanie ich przy konstrukcji kondensatorów elektrochemicznych.
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Characterization and photocatalytic activity of rare earth metal-doped titanium dioxide
PublicationW publikacji została przedstawiona metoda otrzymywania fotokatalizatorów na bazie TiO2 modyfikowanego erbem i iterbem. Otrzymane nanocząstki zostały scharakteryzowane za pomocą powierzchni właściwej BET, objętości porów. Zostały przedstawione widma absorpcyjne UV-Vis oraz właściwości fluorescencyjne otrzymanych nanoproszków. Dokonano również przedstawienia wyników pomiaru aktywności fotokatalitycznej pod wpływem promieniowania...
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Tribological performance of PTFE-metal binary coatings in rolling/sliding contact
PublicationTribological performance of surface coatings with embedded PTFE reservoirs in rolling/sliding contact is reported. Using two different coating materials and two shapes and patterns of PTFE reservoirs test samples in the form of discs were prepared and tested in a four-ball contact configuration under loads corresponding to nominal contact pressure of 0.5 and 1.0 GPa. It was found that one coating, namely aluminium-bronze with embedded...
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Indoor atmospheric degradation of historical metal objects studied by spectroscopic techniques
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Metal status in human endometrium: Relation to cigarette smoking and histological lesions
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Investigation of behaviour of metal structures with polymer dampers under dynamic loads
PublicationA large number of accidents concerning structures subjected to dynamic loads have been recently observed. One of the examples of such a structure is a temporary steel grandstand erected using scaffolding system. Dynamic load that is generated by crowd movement has a significant influence on the behaviour of the structure and may lead to excessive structural vibrations. The aim of the study is to consider the idea of using polymer...
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Metal-organic frameworks (MOF) based heat transfer: A comprehensive review
PublicationHigher than a standard level, the humidity provides a suitable environment for the pathogenic microorganisms to grow and increases energy consumption for cooling, increasing greenhouse gas emissions. Desiccant air-conditioning (DAC) is an effective method to reduce humidity and energy simultaneously. Conventional desiccants are not suitable for use as a desiccant in building air conditioners, mainly because of high regeneration...
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Nonlinear FEM analysis of irregular shells composed of fiber metal laminates
PublicationThe paper deals with the analysis of failure initiation in shells made of Fiber Metal Laminates (FML). The elas-tic material law for orthotropic lamina is stated accounting for asymmetric in-plane stress and strain measures. The asymmetry results from the employed general nonlinear 6-field shell theory where the generalized dis-placements involve the translation and the proper rotation field. The novelty of the presented results...
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The effect of laser on metal surfaces for multidisciplinary usage in material and thermal engineering
PublicationThe subject of heat transfer and cooling systems is still a matter of contention in many different fields of science and industry. Infrigidation is much more difficult than warming, and so, much more needed in more and more different devices, starting from massive industrial machinery and air conditioning in commercial buildings, up to micro and nano-surgery tools. In fact, the size of many cooling systems is still a problem. It...
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Signature of Oxide-Ion Conduction in Alkaline-Earth-Metal-Doped Y3GaO6
PublicationWe have studied alkaline-earth-metal-doped Y3GaO6 as a new family of oxide-ion conductor. Solid solutions of Y3GaO6 and 2% −Ca2+-, −Sr2+-, and −Ba2+-doped Y3GaO6, i.e., Y(3−0.06)M0.06GaO6−δ (M = Ca2+, Sr2+, and Ba2+), were prepared via a conventional solid-state reaction route. X-ray Rietveld refined diffractograms of all the compositions showed the formation of an orthorhombic structure having the Cmc21 space group. Scanning electron...
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Application of non-metal doped titania for inverted polymer solar cells
PublicationDomieszkowany jodem oraz domieszkowany jodem ditlenek tytanu uzyto jako warstwę buforową w ogniwie ITO/X-TiO2?P3HT-PCMB /MnO2/ Ag.Warswty X-TiO2 nalożono metodą spin-coatingu z zawiesiny nanocząstek w DMSO. Jednorodne struktury scharakteryzowane pod względem morfologii mikroskopowo metodą AFM. Charakterystyka prądowo-napięciowa urzdzeń wskazuje iż domieszkowany jodem TiO2 pozwala osiągnąć lepsze parametry PCE (1,67%) i prąd zwarcia...
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Aspects of the biomonitoring studies using mosses and lichens as indicatorsof metal pollution.
PublicationWykazano, wbrew wszelkim ograniczeniom, że mchy i porosty są dobrymi narzędziami służącymi do monitorowania zanieczyszczenia powietrza. Najlepsze rezultaty przynoszą badania w których stosuje się zarówno mchy jak i porosty łącznie, ponieważ rośliny te różnią się retencją i przyswajalnością metali.W pracy przedstawiono pasywną oraz aktywną formę monitoringu z wykorzystaniem biowskaźników i omówiono zalety oraz ograniczenia...
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Emulsion cleaning of metal surfaces contaminated with fresh and oxidized printing ink.
PublicationWykonano badania usuwania farby drukarskiej, stosowanej do druku offsetowego za pomocą emulsji terpentyny i hexanu w wodzie.