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Catalog Publications

Year 2014
  • 237Np Mössbauer effect study on NpFeAsO
    Publication
    • P. Gaczyński
    • T. Klimczuk
    • H. Walker
    • R. Springell
    • E. Colineau
    • R. Eloirdi
    • J. Griveau
    • R. Caciuffo

    - JOURNAL OF PHYSICS-CONDENSED MATTER - Year 2014

    We report 237Np Mössbauer measurements on NpFeAsO. The Np atoms were found to occupy only one crystallographic site. The value of the isomer shift (δ ∼ 9.1 mm s−1 versus NpAl2) indicates a 5f4 electronic configuration (Np3+ ions). The magnetic ordering of the Np sublattice below 60 K is established and the saturated ordered magnetic moment is determined to be 1.73μB at 3.6 K. The unique set of hyperfine parameters exclude a modulated...

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Year 2015
  • 3D porous graphene-based structures- synthesis and applications
    Publication

    Porous carbon-based materials are of the great industrial and academic interest due to their high surface area, low density, good electrical conductivity, chemical inertness and low cost of fabrication. Up to now, the main approach to obtain porous carbon structures has involved the pyrolysis of carbonaceous natural or synthetic precursors. After the isolation of graphene, the interest in 3D porous graphene-based structures (called...

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  • A large family of filled skutterudites stabilized by electron count
    Publication
    • H. Luo
    • J. Krizan
    • L. Muechler
    • N. Haldolaarachchige
    • T. Klimczuk
    • W. Xie
    • M. Fuccillo
    • C. Felser
    • R. J. Cava

    - Nature Communications - Year 2015

    The Zintl concept is important in solid-state chemistry to explain how some compounds that combine electropositive and main group elements can be stable at formulas that at their simplest level do not make any sense. The electronegative elements in such compounds form a polyatomic electron-accepting molecule inside the solid, a ‘polyanion’, that fills its available energy states with electrons from the electropositive elements...

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Year 2009
  • A XAS study of a highly diluted Pt electrocatalyst operating in PEM fuel cells
    Publication

    - PHYSICAL CHEMISTRY CHEMICAL PHYSICS - Year 2009

    We present an X-ray absorption spectroscopy (XAS) study of a low Pt content catalyst layer(Pt loading 0.1 mg c2) operating at the cathode of a proton exchange membrane fuel cell(PEMFC). This catalyst is based on the use of a mesoporous inorganic matrix as a support forthe catalyst Pt nanoparticles. Due to the high Pt dilution, in situ measurements of itsstructural properties by XAS are challenging and suitable experimental strategies...

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  • Ab initio Structure Determination of Mg10Ir19B16
    Publication
    • Q. Xu
    • T. Klimczuk
    • T. Gortenmulder
    • J. Jansen
    • M. Mcguire
    • R. J. Cava
    • H. W. Zandbergen

    - CHEMISTRY OF MATERIALS - Year 2009

    Określono strukturę krystalograficzną nowego, nie-centrosymetrycznego nadprzewodzącego związku chemicznego, mg10ir19b16. Została zastosowana cała gama technik eksperymentalnych: dyfrakcja elektronowa, proszkowa dyfrakcja promieniowania rentgenowskiego, mikroskopia elektronowa wysokiej rozdzielczości, itd. Określenie struktury krystalograficznej było skrajnie trudne ponieważ jest to nowy, nieznany dotąd typ struktury krystalicznej,...

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