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Search results for: METALE CIĘŻKIE
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Bacterial ACC Deaminase Activity in Promoting Plant Growth on Areas Contaminated with Heavy Metals
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The K x-ray line structures of the 3d-transition metals in warm dense plasma
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Calix[4]Arenes Appended with Thioamide Moieties as Powerful Tool for Heavy Metals Recognition
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Simultaneous Removal of Heavy Metals from Wastewater Using Modified Sodium Montmorillonite Nanoclay
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Impact of chitosan/noble metals-based coatings on the plasmochemically activated surface of NiTi alloy
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Current and future emissions of selected heavy metals to the atmosphere from anthropogenic cources in Europe
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Bioaccumulation of selected metals in bivalves (Unionidae) and Phragmites australis inhabiting a municipal water reservoir
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STUDYING THE PROCESS OF OBTAINING PHOSPHATES OF METALS BASED ON THE PHASE EQUILIBRIA OF FOUR COMPONENT SYSTEMS
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Synthesis of carbon nanotubes via chemical vapor deposition by using rareearth metals as catalysts
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Spectral criterion for high-cycle fatigue of metals under multiaxial static and stochastic loading.
PublicationPraca dotyczy oceny zmęczenia metali ciągliwych w złożonych stanach wieloosiowych obciążeń statycznych i dynamicznych, przy założeniu, że składowe naprężenia są stacjonarnymi procesami stochastycznymi, które są stacjonarnie skorelowane i różniczkowalne w sensie średniokwadratowym. Przyjmując, że wartości średnie i gęstości widmowe mocy tych procesów są znane, sformułowano kryterium ograniczonej trwałości zmęczeniowej w dziedzinie...
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Spectral criterion for high-cycle fatigue of anisotropic metals under multiaxial random loads
PublicationPraca dotyczy oceny ograniczonej trwałości zmęczeniowej metali ciągliwych, poddanych wieloosiowym obciążeniom statycznym i dynamicznym. Zakłada się, że kartezjańskie składowe tensora naprężenia są sumą losowych wartości średnich o znanych drugich momentach statystycznych i stacjonarnych procesów stochastycznych o znanych gęstościach widmowych mocy. Przyjmując, że procesy te są stacjonarnie skorelowane, różniczkowalne w sensie średnio-kwadratowym...
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High-cycle fatique criterion for anisotropic metals under multiaxial constant and periodic loads
PublicationPrzedmiotem rozważań jest okresowe naprężenie, którego kartezjańskie składowe są dane w postaci szeregów Fouriera. Dla uwzględnienia wpływu składowych stałych zastosowano zmodyfikowaną formułę Soderberga. Zdefiniowano naprężenie równoważne o synchronicznych składowych i sformułowano kryterium ograniczonej trwałości zmęczeniowej. Kryterium to obejmuje warunki wytrzymałości statycznej i bezpieczeństwa zmęczeniowego z zakresie wysokocyklowym...
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Calix[4]arenes appended with thioamide moieties as powerful tool for heavy metals recognition
PublicationSelectivity of new thioamide derivatives was assessed using those ligands as sensor materials in ion-selective membrane electrodes and tested towards Pb2+ - selectivity. The influence of the nature of the thioamide function (linear, branched or cyclic substituents) on their ionophoric properties was investigated. Electrodes based on cyclic thioamide moieties are promising analytical tools for monitoring Pb2+ concentration in natural...
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Land development and forms of heavy metals occurrence (zn, cd, pb) in polish rivers
PublicationEkosystemy rzeczne podlegają intensywnej antropopresji. Metale ciężkie występujące w glebie i osadach dennych w różnych formach specjacyjnych mają istotny wpływ na wtórne zanieczyszczenie wody ze względu na takie procesy jak migracja, akumulacja i biowzbogacanie.Przedmiotem badań były próbki gleby, osadów dennych oraz wody pobrane z różnych rzek z południowej części województwa świętokrzyskiego. W trakcie badań próbek wykorzystano...
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Distribution and removal efficiency of heavy metals in two constructed wetlands treating landfill leachate
PublicationThe results of heavy metals (Fe, Mn, Zn, Ni, Cu, Cr, Pb, Cd) removal and partitioning between aqueous and solid phases at two wetlands (TWs) treating municipal landfill leachates are presented. One of the TWs is a surface flow facility consisting of 10 ponds. The other TW is a newly constructed pilot-scale facility consisting of three beds with alternately vertical and horizontal sub-surface flow. The metals concentrations were...
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Krytyczny przegląd założeń metody badań nieniszczących opartej na ''Magnetycznej Pamięci Metalu''
PublicationPraca konfrontuje założenia metodyki MMM, powszechnie stosowanej w polskich instalacjach energetycznych, z aktualną wiedzą na temat zjawisk magnetosprężystych. Analiza bibliograficzna i rozważania sprzężeń zjawisk mechanicznych i magnetycznych prowadzą do wniosku, że potencjał metody jest przez jej promotorów przeszacowany.
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Structural and catalytic properties of ceria layers doped with transition metals for SOFCs fueled by biogas
PublicationThe aim of this paper was to investigate an influence of the nanocrystalline Ce0.8A0.2O2-δ (A = Mn, Fe, Co, Ni, Cu) materials on the direct internal reforming of biogas in SOFC. Structural analysis of fabricated compounds has been done. An in-situ analysis of a composition of outlet gases from operating SOFC was performed using FTIR spectroscopy with simultaneous electrical tests. It was found out, that type of dopant strongly...
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Waste management in the mining industry of metals ores, coal, oil and natural gas - A review
PublicationWaste generated due to mining activity poses a serious issue due to the large amounts generated, even up to 65 billion tons per year, and is often associated with the risk posed by its storage and environmental management. This work aims to review waste management in the mining industry of metals ores, coal, oil and natural gas. It includes an analysis and discussion on the possibilities for reuse of certain types of wastes generated...
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The role of noble metals in TiO2 nanotubes for the abatement of parabens by photocatalysis, catalytic and photocatalytic ozonation
PublicationThe role of modified TiO2 nanotubes (TNTs) with noble metals was studied for photocatalysis, catalytic and photocatalytic ozonation of a paraben’s mixture. The TNTs were obtained by anodization and were modified by photodeposition with 0.25 mol% of Au, Pt or Pd. Results showed that solar photocatalysis led to higher degradation than UVA radiation, and under UVA radiation, the use of 3 Pt-TNTs (3 TNTs plates modified with Pt) and...
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Ongoing progress on novel nanocomposite membranes for the separation of heavy metals from contaminated water
PublicationMembranes, as the primary separation element of membrane-based processes, have greatly attracted the attention of researchers in several water treatment applications, including wastewater treatment, water purification, water disinfection, toxic and non-toxic chemical molecules, heavy metals, among others. Today, the removal of heavy metals from water has become challenging, in which chemical engineers are approaching new materials...
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Anthropogenic trace metals in Setiu Wetland: Spatial and seasonal distribution and implications for environmental health
PublicationThe growing urban wastewater volume poses a major global environmental challenge, especially in developing nations where inadequate treatment and discharge impact clean water availability. This study focused on Setiu Wetland, aiming to analyze seasonal and spatial variations of trace metals in particulate form from anthropogenic and pathogenic sources. Surface water samples were collected from multiple stations, measuring physical...
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Review of cigars and cigar-type products as potential sources of consumer exposure to heavy metals
PublicationThe popularity of cigars, growing since 1993, has not gone hand in hand with the increased interest of researchers in these products. Although the literature widely describes the harmfulness of tobacco and the content of toxic substances in tobacco products, the topic is often treated selectively as relating primarily to cigarettes and rarely extends to other products of the broadly defined tobacco industry. However, there is no...
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Transition-Metal-Promoted Oxidative Cyclization To Give 1,2,4-Trisubstituted Carbazole Scaffolds
PublicationHerein, we describe the synthesis of a 1,2,4-trisubstituted carbazole core from 5-(1H-indol-3-yl)-3-oxopentanoic acid esters or amides. For oxidative cyclization, we tested two different approaches. First, we used manganese triacetate as a conventional moderate oxidizer to ensure the radical course of the reaction. Second, we examined the use of a more complex oxidizing agent I2/Me(OTf)3. In both cases, formation of a fused-ring...
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Optical and photocatalytic properties of rare earth metal-modified ZnO quantum dots
PublicationA series of novel ZnO quantum dots modified with rare earth metals was successfully prepared by a simple sol-gel approach. The effects of types (Eu, Er, Tb, Yb, Ho, La) and amounts (from 0.09 to 0.45 mmol) of lanthanides on the optical properties, structural characterization and photocatalytic activity of ZnO/RE QDs were systematically investigated. The X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Fourier transform...
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Apparent molar volumes and compressibilities of alkaline earth metal ions in methanol and dimethylsulfoxide
PublicationTemperature dependencies of density of magnesium (II), calcium (II), strontium (II), barium (II) perchlorates as well as beryllium (II), and sodium trifluoromethanesulfonates in methanol and dimethylsulfoxide have been determined over the composition range studied. From density data the apparent molar volumes and partial molar volumes of the salts at infinite dilution as well as the expansibilities have been evaluated. The apparent...
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Optical and photocatalytic properties of rare earth metal-modified ZnO quantum dots
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Cadmium tri-tert-butoxysilanethiolates. Structural and spectroscopic models of metal sites in proteins.
PublicationW publikacji opisano syntezy i struktury dla dwóch heteroleptycznych kompleksów kadmu z rdzeniem CdS2NO2 i CdS2N2. Bis(tri-tert-butoksysilanotiolato)(1-metyloimidazol)kadmu(II) oraz bis(tri-tert-butoksysilanotiolato)bis(1-metyloimidazol)kadmu(II) współistnieją w roztworze chloroformu przy różnych stężeniach Bis(tri-tert-butoksysilanotiolanu) kadmu(II) i 1 metyloimidazolu. Rotzwór ten został scharakteryzowany za pomocą analizy spektralnej...
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Elastic-plastic properties of metal matrix composites: Validation of mean-field approaches
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Heavy-metal tolerance of photobiont in pioneer lichens inhabiting heavily polluted sites
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Hybrid electrodes composed of electroactive polymer and metal hexacyanoferrates in non-aqueous electrolytes
PublicationMateriały hybrydowe złożone z polimeru elektroaktywnego poli(3,4-etylenodioksytiofenu) (pEDOT) i heksacyjanożelazianów wybranych metali Mehcf (Me = Fe, Co, Ni) zostały poddane testom w elektrolitach niewodnych składających się z mieszaniny rozpuszczalników węglan etylenu (EC) : węglan propylenu (PC) w stosunku objętościowym 1:1 oraz wybranych soli: KPF6 i LiPF6. Właściwości elektrochemiczne materiałów badane były metodami woltamperometrii...
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Identification of multisite behavior in a broadly emitting transition-metal system using pressure
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Recent Advances in Graphene Oxide-Based Membranes for Heavy Metal Ions Separation
PublicationGraphene oxide (GO)-based membranes have been widely investigated for separation of dyes, salt ions, heavy metal ions, and biomolecules due to their high mechanical strength, single-layered structure, large surface area, and high affinity. However, due to irregular pore structure, nanochannels, interlayer distance, easy functionalization, swelling effect, and chemical stability under aqueous environment limited their separation...
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Novel Photocatalytic Nanocomposite Made of Polymeric Carbon Nitride and Metal Oxide Nanoparticles
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Free-ranging domestic cats are characterized by increased metal content in reproductive tissues
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Structure Analysis of the Modified Cast Metal Matrix Composites by Use of the Rve Theory
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Removal of metal particles from carbon nanotubes using conventional and microwave methods
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The Influence of Hybridization of Epoxy–Glass Laminates Modified with Metal Oxides and Graphite Particles
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Material Balance for Stepwise Extraction of Freshwater Algae Biomass with Heavy Metal Sequestration
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Use of clinoptilolite for the immobilization of heavy metal ions and preparation of autoclaved building composites
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Bottom up approach of metal assisted electrochemical exfoliation of boron towards borophene
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Tuning Carbon Nanotubes Through Poor Metal Addition to Iron Catalysts in CVD
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Hollow carbon sphere/metal oxide nanocomposites anodes for lithium-ion batteries
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Detailed investigation on FAME capped metal nanocomposite synthesis as potential antifungal agent
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Cadmium tri-tert-butoxysilanethiolates: Structural and spectroscopic models of metal sites in proteins
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Electroabsorption study of metal-to-ligand charge transfer in an organic complex of iridium (III).
PublicationW pracy zmierzono i zinterpretowano widmo elektroabsorpcji (EA) próżniowo naparowanych warstw organicznego kompleksu Ir(ppy)3, powszechnie stosowanego jako emiter fosforescencyjny w organicznych diodach elektroluminescencyjnych. Analiza widma EA potwierdziła fakt,że niskoenergetyczne stany elektronowe tego kompleksu związane są z przeniesieniem ładunku metal-ligand.
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Apparent molar volumes of divalent transition metal bromides in dimethyl sulfoxide solutions
PublicationWyznaczono pozorne i cząstkowe molowe objętości bromków dwuwartościowych metali przejściowych szeregu Mn(II)-Zn(II)w roztworach w dimetylosulfotlenku. Przedyskutowano korelacje między objętościami molowymi a stanami koordynacyjnymi i sposobem jonizacji soli.
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Determination of stability constants of complexes of selected amide ionophores with alkali metal cations
PublicationPodano właściwości kompleksujące jony litowców czterech jonoforów typu amidów. Wyznaczono wartości stałych kompleksów z jonów Li+, Na+, K+ metodą potencjometryczną z zastosowaniem elektrod jonoselektywnych stosując dwie różne procedury: 1) stosując jako kation referencyjny TMA+, 2) stosując chromofor kompleksujący H+.
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Numerical Modeling and Simulation of Vehicular Crashes into Three-Bar Metal Bridge Rail
PublicationAdvanced finite element (FE) modeling and simulations were performed on vehicular crashes into a three-bar metal bridge rail (TMBR). The FE models of a sedan, a pickup truck, and a TMBR section were adopted in the crash simulations subject to Manual for Assessing Safety Hardware (MASH) Test Level 2 (TL-2) and Test Level 3 (TL-3) requirements. The test vehicle models were first validated using full-scale physical crash tests conducted...
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Designate CTOD of Weld Metal of butt weld, No WOiO/II/108/2013
PublicationTypical (normative) testing of materials and/or welded joints do not answer on all questions about material or welded joint properties. In ship building and off-shore sectors, many strucures requires materials and joint with higher than typical fatigue resistance. Imact tests, which are carried out during welding technology qualification, gives answer about ductility, CTOD tests results about material or welded joint ability...
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DETERMINATION OF DIFFUSIBLE HYDROGEN CONTENT IN DEPOSITED METAL OF RUTILE ELECTRODES BY GLYCERIN METHOD
PublicationThe presence of diffusible hydrogen in welded joints is one of the causes of formation the welding imperfections. Improvement of weldability can be achieved by reducing the hydrogen amount in welded joints. This requires, among others, the finding of sources of hydrogen. For high hydrogen processes the commonly used method of determining the diffusible hydrogen amount is the glycerin method. This paper concerns issues related to...