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Search results for: Cr3+
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Simultaneous functionalization and magnetization of biochar via NH3 ambiance pyrolysis for efficient removal of Cr (VI)
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The accumulation of metal (Co, Cr, Cu, Mn and Zn) in freshwater Ulva (Chlorophyta) and its habitat
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Durability evaluation of Ni‐Cr‐Mo super alloys in a simulated scrubbed flue gas environment
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Microscopic impact of creep damage incipience and development on the magnetic properties of ferromagnetic Cr-Mo steel
PublicationPokazano wyniki badań emisji magneto-akustycznej (EMA0 oraz magnetostrykcji dla stali P22 w stanie dostawy i po ekploatacji. Wyniki te pokazują, że maksimum EMA jest skorelowane z maksimum pochodnej magnetostrykcji. Badania morfologii wydzieleń w granicach ziarn i w ich wnętrzu potwierdzają tezę, iż te pierwsze są główną przyczyną zmniejszania natężenia EMA. Zaproponowano prosty model tłumaczący ilościowo funkcję zmian natężenia...
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Wpływ długotrwałej eksploatacji na strukturę i własności mechaniczne stali Cr-Mo-V,
PublicationW artykule omówiono zagadnienie oceny stopnia degradacji stali Cr-Mo-V pracujących w warunkach pełzania. Przedstawiono wyniki badań diagnostycznych rury 273x32,0 mm głównego rurociągu parowego po eksploatacji w temperaturze 540C przez 168 000 godzin. Przeprowadzono badania metalograficzne za pomocą mikroskopu świetlnego oraz skaningowego i transmisyjnego mikroskopu elektronowego, a także badania własności mechanicznych materiału...
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General, Mild, and Metal-Free Functionalization of Indole and Its Derivatives Through Direct C3-Selenylation
PublicationA very mild method for the introduction of functionalized alkylselenyl group at C-3 position of the indole ring was developed. The proposed procedure consists of an electrophilic substitution of indole and its derivatives with bis(O,O-diisopropoxyphosphorothioyl) diselenide and subsequent cleavage of the P–Se bond with tetrabutylammonium fluoride in the presence of various electrophilic reagents. This method can be successfully...
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Chitosan-coated coconut shell composite: A solution for treatment of Cr(III)-contaminated tannery wastewater
PublicationTannery industry generates a large amount of Cr(III)-contaminated wastewater daily. Unless properly treated, not only this effluent contaminates the water body, but also damages the environment and threatens public health. This batch study investigates the feasibility of chitosan-coated coconut shells as a low-cost material for removing Cr(III) from tannery wastewater. Both chitosan and coconut shell (CS) waste are abundantly available...
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Electrochemical behaviour of Cr coating in acidic sulphate solution studied by cyclic polarization and impedance spectroscopy
PublicationOdporność korozyjną powłok chromowych w 0.01 M H2SO4 zbadano metodami woltamperometrii cyklicznej i spektroskopii impedancyjnej. Stwierdzono, że właściwości ochronne powłoki chromowej w kontakcie z powietrzem wzrastają dzięki tworzeniu się warstwy tlenkowej zapełniającej defekty w powłoce. W trakcie polaryzacji anodowej następuje częściowe roztwarzanie tej warstwy i penetracja agresywnego środowiska do podłoża (stali), co powoduje...
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Całkowite przekroje czynne na rozpraszanie elektronów na drobinach wieloatomowych
PublicationGłównym celem rozprawy doktorskiej było zmierzenie absolutnych całkowitych przekrojów czynnych (TCS) na rozpraszanie elektronów w szerokim zakresie energii (~1-400 eV) dla wybranych drobin: BCl3, B(CD3)3, NF3, N(CH3)3, P(CH3), SO2Cl2, SO2ClF, SF4, c-C2H4O oraz c-C3H6O (dla ośmiu drobin otrzymano całkowite przekroje czynne po raz pierwszy, natomiast dla dwóch pozostałych został znacznie rozszerzony zakres energii dostępnych danych)....
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Opposite pressure impact on electron-phonon coupling in Eu2+ and Ce3+ doped AlN
Open Research DataThis data analyzes the influence of pressure on electron–lattice interactions in the 5d excited states of Ce3+ and Eu2+ in the AlN host based on pressure-dependent photoluminescence and photoluminescence excitation spectra. High-pressure measurements on AlN samples doped with Eu2+ and Ce3+ ions reveal that the Stokes shift increases with pressure for...
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Effects of metallic silver island films on resonance energy transfer between N,N´-(dipropyl)-tetramethylindocarbocyanine (Cy3)- and N,N´-(dipro- pyl)-tetramethylindodicarbocyanine ( Cy5 )-labeled DNA.
PublicationZbadano nową metodę zwiększania odległości rezonansowego przekazywania energii poprzez umieszczanie znakowanych donorami i akceptorami oligomerów DNA pomiędzy dwoma płytkami pokrytymi nanocząsteczkami metalicznego srebra.
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CRC Press / Balkema
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Formation of 2-chloroallyl alcohol oligomers using a new crystalline dipicolinate complex of Cr(III) as a catalyst
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The effect of long-term service at elevated temperatures on structure and mechanical properties of Cr-Mo-V steel
PublicationPurpose: of this paper is to reveal the microstructural changes in 13HMF steel exposed to long-term service at elevated temperatures. The degradation of bainite structure was determined and carbides morphology has been examined. The influence of carbides evolution was discussed in dependence of creep rupture strength and mechanical properties of the steel.
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Adsorption of Cr(VI) in aqueous solution using sago bark (Metroxylon sagu) as a new potential biosorbent
PublicationThis paper investigated the ability of sago bark (Metroxylon sagu) as a new potential biosorbent in removing Cr(VI) in batch system. The optimum adsorption capacity of sago bark (Metroxylon sagu) was 61.73 mg/g achieved at pH 3, agitation rate of 100 rpm, contact time 60 min, particle size ≤32 μm, and initial concentration of Cr(VI) 1,000 mg/L at room temperature (25°C). The adsorbent regeneration was carried out using 0.01 M HNO3...
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Tool wear, surface roughness, cutting temperature and chips morphology evaluation of Al/TiN coated carbide cutting tools in milling of Cu–B–CrC based ceramic matrix composites
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High Pressure Luminescence of Cr-Related Centers in (3CaO-Ga 2 O 3 -3GeO 2 ) Glasses
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Morphology changes in Fe-Cr porous alloys upon high-temperature oxidation quantified by X-ray tomographic microscopy
PublicationThe effect of high-temperature oxidation at 850 C (10 h, 30 h, 100 h) and 900 C (10 h) on porous (30 % porosity) ferritic stainless steel (Fe22Cr) has been investigated using synchrotron tomographic microscopy, which allowed for visualisation, separation and quantitative analysis of the metallic core, closed pores, open pores and oxide scale phase. The same regions within the samples were investigated before and after oxidation...
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Rapid development of the photoresponse and oxygen evolution of TiO2 nanotubes sputtered with Cr thin films realized via laser annealing
PublicationRecently, earth abundant transition metal oxides have gained particular attention as potential catalyst candidates due to their availability and low-cost comparing to substrates containing precious Pt or Au species. Herein, we present characterization of morphology, structure and electrochemical properties of pulsed 532 nm laser treated TiO2 nanotubes (NT) sputtered by the thin film of chromium. Scanning electron microscopy enables...
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MODALITY corpus - SPEAKER 01 - COMMANDS C3
Open Research DataThe MODALITY corpus is one of the multimodal database of word recordings in English. It consists of over 30 hours of multimodal recordings. The database contains high-resolution, high-framerate stereoscopic video streams and audio signals obtained from a microphone array and a laptop microphone. The corpus can be employed to develop an AVSR system,...
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MODALITY corpus - SPEAKER 21 - COMMANDS C3
Open Research DataThe MODALITY corpus is one of the multimodal database of word recordings in English. It consists of over 30 hours of multimodal recordings. The database contains high-resolution, high-framerate stereoscopic video streams and audio signals obtained from a microphone array and a laptop microphone. The corpus can be employed to develop an AVSR system,...
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MODALITY corpus - SPEAKER 03 - COMMANDS C3
Open Research DataThe MODALITY corpus is one of the multimodal database of word recordings in English. It consists of over 30 hours of multimodal recordings. The database contains high-resolution, high-framerate stereoscopic video streams and audio signals obtained from a microphone array and a laptop microphone. The corpus can be employed to develop an AVSR system,...
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MODALITY corpus - SPEAKER 10 - COMMANDS C3
Open Research DataThe MODALITY corpus is one of the multimodal database of word recordings in English. It consists of over 30 hours of multimodal recordings. The database contains high-resolution, high-framerate stereoscopic video streams and audio signals obtained from a microphone array and a laptop microphone. The corpus can be employed to develop an AVSR system,...
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MODALITY corpus - SPEAKER 17 - COMMANDS C3
Open Research DataThe MODALITY corpus is one of the multimodal database of word recordings in English. It consists of over 30 hours of multimodal recordings. The database contains high-resolution, high-framerate stereoscopic video streams and audio signals obtained from a microphone array and a laptop microphone. The corpus can be employed to develop an AVSR system,...
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MODALITY corpus - SPEAKER 35 - COMMANDS C3
Open Research DataThe MODALITY corpus is one of the multimodal database of word recordings in English. It consists of over 30 hours of multimodal recordings. The database contains high-resolution, high-framerate stereoscopic video streams and audio signals obtained from a microphone array and a laptop microphone. The corpus can be employed to develop an AVSR system,...
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MODALITY corpus - SPEAKER 33 - COMMANDS C3
Open Research DataThe MODALITY corpus is one of the multimodal database of word recordings in English. It consists of over 30 hours of multimodal recordings. The database contains high-resolution, high-framerate stereoscopic video streams and audio signals obtained from a microphone array and a laptop microphone. The corpus can be employed to develop an AVSR system,...
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MODALITY corpus - SPEAKER 32 - COMMANDS C3
Open Research DataThe MODALITY corpus is one of the multimodal database of word recordings in English. It consists of over 30 hours of multimodal recordings. The database contains high-resolution, high-framerate stereoscopic video streams and audio signals obtained from a microphone array and a laptop microphone. The corpus can be employed to develop an AVSR system,...
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MODALITY corpus - SPEAKER 27 - COMMANDS C3
Open Research DataThe MODALITY corpus is one of the multimodal database of word recordings in English. It consists of over 30 hours of multimodal recordings. The database contains high-resolution, high-framerate stereoscopic video streams and audio signals obtained from a microphone array and a laptop microphone. The corpus can be employed to develop an AVSR system,...
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The new type of [Zr6(μ3-O)4 (μ3-OH)4] cluster core: Crystal structure and spectral characterization of [Zr6O4(OH)4(OOCR)12] (R = Bu^t^,C(CH3)2Et)
PublicationSześciojądrowe oxo karboksylowe kompleksy cyrkonu(IV) zostały otrzymane z Zr(OR')4 i odpowiednich kwasów organicznych HOOCR (R=t-Bu, CMe2Et) w stosunku molowym 1:2. Struktury krystaliczne dwóch związków o wzorze [Zr6O4(OH)4(OOCR)12] (1 dla R=t-Bu i 2 dla R=-CMe2Et) zostały rozwiązane w grupie przestrzennej R-3. Substancje zostały przebadane termograwimetrycznie (TGA/DTA) oraz przy użyciu spektroskopii w podczerwieni ze zmienną...
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Optimizing Ni–Cr patterned boron-doped diamond band electrodes: Doping effects on electrochemical efficiency and posaconazole sensing performance
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Optimizing Ni–Cr patterned boron-doped diamond band electrodes: Doping effects on electrochemical efficiency and posaconazole sensing performance
PublicationThere is growing interest in developing diamond electrodes with defined geometries such as, for example, micrometer-sized electrode arrays to acquire signals for electroanalysis. For electroanalytical sensing applications, it is essential to achieve precise conductive patterns on the insulating surface. This work provides a novel approach to boron-doped diamond patterning using nichrome masking for selective seeding on an oxidized...
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Properties of Spark Plasma Sintered Compacts and Magnetron Sputtered Coatings Made from Cr, Mo, Re and Zr Alloyed Tungsten Diboride
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Concentrations and loads of metals (V, Cr, Mn, Fe, Cu, Zn, As, Rb, Y, Zr) from the cliff erosion to the Gulf of Gdansk
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Experimental investigation on welding of 2.25 Cr-1.0 Mo steel with regulated metal deposition and GMAW technique incorporating metal-cored wires
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Transformation of polyvinyl chloride (PVC) into a versatile and efficient adsorbent of Cu(II) cations and Cr(VI) anions through hydrothermal treatment and sulfonation
PublicationThe reuse of waste polyvinyl chloride (PVC) has drawn much attention as it can reduce plastic waste and associated pollution, and provide valuable raw materials and products. In this study, sulfonated PVC-derived hydrochar (HS-PVC) was synthesized by two-stage hydrothermal treatment (HT) and sulfonation, and shown to be a versatile adsorbent. The reoval of Cu(II) cations and Cr(VI) anions using HS-PVC reached 81.2 ± 1.6% and 60.3...
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Enhancement of self-trapped excitons and near-infrared emission in Bi3+/Er3+ co-doped Cs2Ag0.4Na0.6InCl6 double perovskite
Open Research DataErbium (Er) complexes are used as optical gain materials for signal generation in the telecom C-band at 1540 nm, but they need a sensitizer to enhance absorption. Na+ substitution for Ag+ and Bi3+ doping at the In3+ site is a possible strategy to enhance the broadband emission of Cs2AgInCl6, which could be used as a sensitizer for energy transfer to...
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CrN coating in ring-on-ring sliding with distlled water lubrication 5MPa, 0.1m/s specimn. #A23/#B22
Open Research DataWear tests in sliding friction of CrN coating on 1.4021 (EN 10088-1) heat treated stainless steel. Ring - on - ring contact in unidirectional sliding, CrN over CrN . Mean contact stress: 5MPa. Sliding velocity: 0,1 m/s. Mean friction radius: 9.5mm. Lubricant: DISTILLED WATER. Tribometer: PT-3. Overall test time till coating penetration 12 min. The...
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CrN coating in ring-on-ring sliding with distlled water lubrication 5MPa, 0.1m/s specimn. #B22/#A23
Open Research DataWear tests in sliding friction of CrN coating on 1.4021 (EN 10088-1) heat treated stainless steel. Ring - on - ring contact in unidirectional sliding, CrN over CrN. Mean contact stress: 5MPa. Sliding velocity: 0,1 m/s. Mean friction radius: 9.5mm. Lubricant: DISTILLED WATER. Tribometer: PT-3. Overall test time till coating penetration 6 min. The test...
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Study on effectiveness of PVC/β-diketone sorbent in removing residue of Zn(II), Cr(III) and Ni(II) from post-galvanic wastewater
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A comparative study of sequential extraction methods for identification of trace elements fractions (Cr, Ni, Pb, Cd) in urban soils from several parks
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Characterization and properties of low-friction, multilayered Cr-doped diamond-like carbon coatings prepared by pulse biased filtered cathodic arc deposition
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CrN coating in ring-on-ring sliding with saline solution (0.9%) lubrication 5MPa, 0.1m/s specimn. #B21/#A21
Open Research DataWear tests in sliding friction of CrN coating on 1.4021 (EN 10088-1) heat treated stainless steel. Ring - on - ring contact in unidirectional sliding, CrN over CrN . Mean contact stress: 5MPa. Sliding velocity: 0,1 m/s. Mean friction radius: 9.5mm. Lubricant: SALINE SOLUTION (0.9%). Tribometer: PT-3. Overall test time till coating penetration 25 min....
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CrN coating in ring-on-ring sliding with saline solution (0.9%) lubrication 5MPa, 0.1m/s specimn. #A25/#B21
Open Research DataWear tests in sliding friction of CrN coating on 1.4021 (EN 10088-1) heat treated stainless steel. Ring - on - ring contact in unidirectional sliding, CrN over CrN . Mean contact stress: 5MPa. Sliding velocity: 0,1 m/s. Mean friction radius: 9.5mm. Lubricant: SALINE SOLUTION (0.9%). Tribometer: PT-3. Overall test time till coating penetration 9 min....
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Bamboo-biochar and hydrothermally treated-coal mediated geochemical speciation, transformation and uptake of Cd, Cr, and Pb in a polymetal(iod)s-contaminated mine soil
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Influence of Cd(II), Cr(VI) and Fe(III) on early steps of deetiolation process in wheat: fluorescence spectral changes of protochlorophyllide and newly formed chlorophyllide
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Reply to the ‘Comment on “Spectroscopic properties and location of the Ce3+ energy levels in Y3Al2Ga3O12 and Y3Ga5O12 at ambient and high hydrostatic pressure”’ by Y. Wang, M. Głowacki, M. Berkowski, A. Kamińska and A. Suchocki, Phys. Chem. Chem. Phys., 2019, 21, DOI: 10.1039/C8CP06154H
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In situ synthesis of micro-plastics embedded sewage-sludge co-pyrolyzed biochar: Implications for the remediation of Cr and Pb availability and enzymatic activities from the contaminated soil
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A fast time-frequency multi-window analysis using a tuning directional kernel
PublicationIn this paper, a novel approach for time-frequency analysis and detection, based on the chirplet transform and dedicated to non-stationary as well as multi-component signals, is presented. Its main purpose is the estimation of spectral energy, instantaneous frequency (IF), spectral delay (SD), and chirp rate (CR) with a high time-frequency resolution (separation ability) achieved by adaptive fitting of the transform kernel. We...
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Immunization with an anti-idiotypic antibody against the broadly lipopolysaccharide-reactive antibody WN1 222-5 induces Escherichia coli R3-core-type specific antibodies in rabbits
PublicationThe mouse monoclonal antibody (mAb) WN1 222-5 recognizes a carbohydrate epitope in the inner core region of LPS that is shared by all strains of Escherichia coli and Salmonella enterica and is able to neutralize their endotoxic activity in vitro and in vivo. Immunization of mice with mAb WN1 222-5 yielded several anti-idiotypic mAbs one of which (mAb S81-19) competitively inhibited binding of mAb WN1 222-5 to E. coli and Salmonella...
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Uptake, accumulation, and translocation of Zn, Cu, Pb, Cd, Ni, and Cr by P. australis seedlings in an urban dredged sediment mesocosm: Impact of seedling origin and initial trace metal content
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