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Search results for: OER/ HER reactions
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Ewa Hope dr
People -
HERZ
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Interaction of Acoustic and Thermal Modes in the Gas with Nonequilibrium Chemical Reactions: Possibilities of Acoustic Cooling
PublicationNonlinear generation of thermal mode during propagation of dominative sound in a chemically reacting gas is considered. The dynamic equation of excess temperature associated with the thermal mode is derived. It is instantaneous and includes quadratic nonlinear acoustic source reflecting the nonlinear character of interaction between acoustic and non-acoustic types of gas motion. Both periodic and aperiodic sound may be considered...
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Selective monoprotection of 1,4,7,10-tetraazacyclododecane via direct reactions with 4-nitrophenyl active esters
Publication1,4,7,10-tetraazacyklododekan jest cykliczną tetraaminą. Z chemicznego punktu widzenia wszystkie atomy azotu posiadają takie same właściwości fizykochemiczne. Jedyną różnicę stanowią ich właściwości kwasowo-zasadowe. Cyklen posiada dwa atomy azotu o obniżonej zasadowości. Właściwość ta z powodzeniem wykorzystywana jest w reakcjach jednoczesnej selektywnej substytucji dwóch atomów w pozycji 1 i 7. W przypadku bezpośredniej reakcji...
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Proton transfer reactions from NH acid to various N-bases in acetonitrile
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High catalytic performance of tungsten disulphide rodes in oxygen evolution reactions in alkaline solutions
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Monitoring of Caged Bluefin Tuna Reactions to Ship and Offshore Wind Farm Operational Noises
PublicationUnderwater noise has been identified as a relevant pollution affecting marine ecosystems in different ways. Despite the numerous studies performed over the last few decades regarding the adverse effect of underwater noise on marine life, a lack of knowledge and methodological procedures still exists, and results are often tentative or qualitative. A monitoring methodology for the behavioral response of bluefin tuna (Thunnus thynnus)...
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Invasive micropapillary carcinoma of breast - Female, 64 - Tissue image [4250730010193061]
Open Research DataThis is the histopathological image of BREAST tissue sample obtained in Medical University Gdańsk and deposited in ZMDL-GUMED. The sample image was taken using: Pannoramic 250 3DHistech slide scanner (20x magnification) and saved to DICOM format.
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Carbon Nanohorns as Reaction Nanochambers – a Systematic Monte Carlo Study
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The overabundance of excited hydrogen atoms produced in the H2++ furan reaction
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Fast method for the determination of the charge transfer coefficient of an electrode reaction
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Photochemical and thermal reaction of intermediates in the phenylnitrene rearangment inside a hemicarcerand
PublicationBroadband irradiation (λ > 320 nm) of hemicarceplex H1 between −74 °C and −84 °C, produces encapsulated didehydroazepine (2), triplet phenylnitrene (3PN), 2-azabicyclo[3.2.0]hepta-1,3,6-triene (6), and 4-azaspiro[2.4]hepta-1,4,6-triene (7). The highly strained anti-Bredt imine 6 is formed from 2 via a photochemical four-electron electrocyclization. Under the irradiation conditions, 6 rearranges further to azaspirene 7. In addition,...
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Promotion of borophene/NiO-based electrocatalyst for oxygen evolution reaction
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Promotion of borophene/NiO-based electrocatalyst for oxygen evolution reaction
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Arylation of enelactams using TIPSOTf: reaction scope and mechanistic insight
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Frequency distribution of chemical oscillations in the closed Belousov Zhabotinsky reaction.
PublicationW publikacji przedstawiono wykorzystanie metody STFT (krótkoczasowej transformaty Fouriera) do analizy oscylacji chemicznych. Badano rejestry potencjałowe reakcji Biełousowa Żabotyńskiego. Wykazano niestacjonarność analizowanych przebiegów. Wykazano liniową zależność pomiędzy częstotliwością oscylacji a stężeniem jednego z komponentów reakcji (bromian potasu). Udowodniono przydatność analizy czasowo-częstotliwościowej do analizy...
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Dynamic electrochemical impedance spectroscopy of the first order electrode reaction
PublicationCiągłe transformaty STFT sinusoidalnego sygnału pobudzenia i odpowiedzi prądowej zostały wyznaczone dla reakcji elektrodowej pierwszego rzędu. Wyznaczono impedancję elektrody w łącznej dziedzinie czasu i częstotliwości. Wykonano pomiary dla reakcji redukcji Cd(II) na rtęciowej elektrodzie kroplowej w funkcji potencjału. Przedstawiono możliwość wyznaczenia chwilowych widm impedancyjnych. Opisano zależność rezystancji przeniesienia...
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Unusual streaming in chemically reacting gases
PublicationNonlinear stimulation of the vorticity mode caused by losses in the momentum of sound in the chemically reacting gas, is considered. The instantaneous dynamic equation which describes the nonlinear generation of the vorticity mode, is derived. It includes a quadratic nonlinear acoustic source. Both periodic and aperiodic sound may be considered as the origin of the vorticity flow. In the non-equilibrium regime of the chemical reaction,...
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Weighted 2-sections and hypergraph reconstruction
PublicationIn the paper we introduce the notion of weighted 2-sections of hypergraphs with integer weights and study the following hypergraph reconstruction problems: (1) Given a weighted graph , is there a hypergraph H such that is its weighted 2-section? (2) Given a weighted 2-section , find a hypergraph H such that is its weighted 2-section. We show that (1) is NP-hard even if G is a complete graph or integer weights w does not exceed...
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River flow simulation based on the HEC-RAS system
PublicationThis work considers the problem of river floods, and presents a computer solution that can be used to predict such a threat. The basic tool, called Hydrologic Engineering Centers for River Analysis System (HEC-RAS), and created by the US Army Corps of Engineering, is well developed; and the models created in the system HEC-RAS are quite realistic. For the purpose of solving practical national flood problems, simplified static and...
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River Flow Simulation Based on the HEC-RAS System
PublicationThis work considers the problem of river floods, and presents a computer solution that can be used to predict such a threat. The basic tool, called Hydrologic Engineering Centers for River Analysis System (HEC-RAS), and created by the US Army Corps of Engineering, is well developed; and the models created in the system HEC-RAS are quite realistic. For the purpose of solving practical national flood problems, simplified static and...
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Structural, electrical, and magnetic study of La-, Eu-, and Er- doped bismuth ferrite nanomaterials obtained by solution combustion synthesis
PublicationIn this work, the multiferroic bismuth ferrite materials Bi0.9RE0.1FeO3 doped by rare-earth (RE = La, Eu, and Er) elements were obtained by the solution combustion synthesis. Structure, electrical, and magnetic properties of prepared samples were investigated by X-ray photoelectron spectroscopy, Mössbauer spectroscopy, electrical hysteresis measurement, broadband dielectric spectroscopy, and SQUID magnetometry. All obtained nanomaterials...
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Bayerische Akademie der Wissenschaften
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Towards Increasing Density of Relations in Category Graphs
PublicationIn the chapter we propose methods for identifying new associations between Wikipedia categories. The first method is based on Bag-of-Words (BOW) representation of Wikipedia articles. Using similarity of the articles belonging to different categories allows to calculate the information about categories similarity. The second method is based on average scores given to categories while categorizing documents by our dedicated score-based...
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Validation of atmospheric aerosols sampling in equivalent fractions
PublicationPhysical properties and chemical composition of atmospheric aerosols are of extreme importance, in many fields of interest, namely the Environment even with legal implications. Atmospheric sampling poses inherent problems with consequent demands on sampling optimisation, with sampling strategies requiring validation. In this work a study was conducted aiming at validating the collection of atmospheric aerosols in equivalent fractions....
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Etyka w zawodzie specjalistów public relations
PublicationKsiążka traktuje o zasadach,wartościach, normach, dylematach etycznych w zawodzie specjalisty PR, analizuje również rolę instytucji i dokumentów, które mogą pomóc w wyborach, podejmowanych decyzjach w pracy public relations.
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Pola nadużyć w działaniach public relations
Publicationartykuł przedstawia i analizuje najczęściej występujące dylematy etyczne specjalisty public relations, stara się nakreślić obszary, w których tych dylematów jest najwięcej i uzasadnia, dlaczego postępowanie zgodne z najwyższymi standardami w tej dziedzinie jest nie tylko gwarantem jej istnienia, ale i w kontekście szerszym - pomyślności społeczeństwa, w którym te działania są prowadzone.
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Karta Przejrzystości Mediów - Public Relations a dziennikarstwo.
PublicationArtykuł zawiera analizę nowo powstałego zbioru zasad regulujących pracę dziennikarz - Charter on Media Transparency, wskazującego na najczęściej występujące naruszenia norm moralnych w tym zawodzie i ich przyczyny, ze szczególnym uwzględnieniem relacji: dziennikarz - specjalista public relations.
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Public relations uczelni: kreowanie tożsamości wizualnej
PublicationPraca jest analizą podstawowych, najczęściej popełnianych błędów, w procesie kreowania tożsamości wizualnej przez uczelnie polskie. Praca jednocześnie podkreśla rangę umiejętnie wykreowanej i stosowanej tożsamości wizualnej jako jednego z elementów public relations.
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Political relations between Poland and the Republic of Azerbaijan
PublicationPoland was one of the first countries to recognize the independence of the Republic of Azerbaijan. However, the political co-operation between the two countries was established only at the end of the last decade of the 20th century, during the presidency of Aleksander Kwaśniewski. The next Polish president – Lech Kaczyński – intending to diversify the energy sources, maintained political relations between Poland and the Republic...
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Elemental and tight monogamy relations in nonsignaling theories
PublicationPhysical principles constrain the way nonlocal correlations can be distributed among distant parties. These constraints are usually expressed by monogamy relations that bound the amount of Bell inequality violation observed among a set of parties by the violation observed by a different set of parties. We prove here that much stronger monogamy relations are possible for nonsignaling correlations by showing how nonlocal correlations...
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Redox reactions of the FAD-containing apoptosis-inducing factor (AIF) with quinoidal xenobiotics: A mechanistic study
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Modelling of First- and Second-order Chemical Reactions on ARUZ – Massively-parallel FPGA-based Machine
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An investigation on the chemistry of the R2P=P ligand: reactions of a phosphanylphosphinidene complex of tungsten(VI) with electrophilic reagents
PublicationThe nucleophilic properties of the title compound [(2,6-i-Pr2C6H3N)2(Cl)W(η2-t-Bu2PvP)]Li·3DME (1) were investigated in reactions with selected electrophilic reagents such as MeI, M(CO)5THF (M = Cr, Mo, W), AlCl3, and GaCl3. Methylation of 1 by MeI yields phosphanylphosphido complexes [(2,6-i-Pr2C6H3N)2W(X)(1,2-η-t-Bu2PvP–CH3)] (X = Cl, I) (2-Cl/2-I) with the formation of a new P–C bond. Moreover, 1 reacts with electrophilic compounds...
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Facile Deposition of Pd Nanoparticles on Carbon Nanotube Microparticles and Their Catalytic Activity for Suzuki Coupling Reactions
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Influence of chloroform on crystalline products yielded in reactions of 5,10,15,20-tetraphenylporphyrin with HCl and copper(II) salts
PublicationStwierdzono, że chloroform wbudowuje się do sieci krystalicznej dichlorowodorku 5,10,15,20-tetrafenyloporfiryny, oraz że powoduje krystalizację nowej, jednoskośnej odmiany polimorficznej porfirynianu miedzi(II), CuTPP. W pracy opisano strukturę krystaliczną solwatu dichlorowodorku porfiryny z ośmioma cząsteczkami chloroformu, C44H32N42+·2Cl-·8CHCl3, i porównano ją...
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Reactions of NO2 with chromium(III) complexes with histamine and pyridoxamine ligands studied by the stopped-flow technique
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New type of repeated Si–C-podand catalysts for solid–liquid phase transfer reactions
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Proton transfer reactions from some diarylcyanomethanes to cis 1,2-bis(diethylaminomethyl)cyclohexane in acetonitrile
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Reactions of solute species at an electrode modified with titanocene functionalized polypyrrole film: ferrocene and titanocene dichloride
PublicationPo raz pierwszy zbadano możliwość intermediacji ładunku poprzez centra tytanocenowe polimeru modyfikowanego chemicznie związanymi grupami dichloro tytanocenowymido polipirolu. Badano reakcje elektrodowe ferrocenu i dichlorotytanocenu. Wykazano aktywność elektrodową w zakresie potencjałów redoks pary Ti(IV/TiIII)w stosunku do reakcji redoks ferrocenu i reakcji dichlorotytanocenu. Wykazano, że centra TcCl2 polimeru są zadowalająco...
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Average number of hours worked per week by women aged 15 and older (Poland, Lithuania, Latvia, Estonia)
Open Research DataThe following dataset presents the average weekly number of hours worked by women in selected countries (Poland, Lithuania, Latvia, Estonia) in the years 1999 - 2016. The summary includes average weekly time worked in the main job, for women aged 15+. The estimates correspond to the declared amount. This includes part-time and full-time employment,...
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Invasive breast carcinoma of no special type - Female, 72 - Tissue image [5040730020275031]
Open Research DataThis is the histopathological image of BREAST tissue sample obtained in Medical University Gdańsk and deposited in ZMDL-GUMED. The sample image was taken using: Pannoramic 250 3DHistech slide scanner (20x magnification) and saved to DICOM format.
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Theoretical description of fundamental-harmonic impedance of a two-step electrode reaction
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Reaction of thio and seleno phosphoric acid derivatives with O-thioacylated hydroxylamine
PublicationZbadano reakcję siarkowych i selenowych analogów kwasu O,O-neopentylidenofosforowego z O-tiopiwaloilo-N-tert-butylohydroksyloaminą, w której to następuje rozszczepienie wiązania N-O. Znaleziono korelację pomiędzy potencjałem utleniającym anionu pochodnej kwasu fosforowego a przebiegiem badanej reakcji.
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Chiral Schiff base complexes as an effective catalyst in Diels-Alder reaction
PublicationDiels Alder reaction is a very important tool in carbon-carbon bond formation. It is a cycloaddition between a conjugated diene and a second compound called dienophile. Where one or more heteroatoms are present in the diene and/or dienophile framework, the cycloaddition is called hetero-Diels-Alder reaction (HDA). The asymmetric Diels-Alder reaction is among the most powerful available methodologies for that construction of optically...
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Studies on the application of the Passerini reaction and enzymatic procedures to the synthesis of tripeptide mimetics
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Reduction of the reaction torque of an in-line four-cylinder four-stroke engine
PublicationW pracy przedstawiono zarówno dokładne jak i uproszczone zależności na przebieg momentu reakcyjnego silnika, jedno i wielocylindrowego, przenoszonego na ramę pojazdu lub fundament. Wyprowadzono zależność na wartość przesunięcia wałków wyrównoważających zapewniającą całkowite wyeliminowanie wpływu sił bezwładności na przebieg momentu reakcyjnego w silnikach czterosuwowych czterocylindrowych. Wprowadzono kryteria doboru optymalnej...
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Kinetic studies of complexation reaction of polyoxaalkyl phosphates with Fe(III) in ethanol
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Photocatalytic performance of titania nanospheres deposited on graphene in coumarin oxidation reaction
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Fused FeCo catalysts for hydrogen production by means of the ammonia decomposition reaction
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