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Latest Insights on Novel Deep Eutectic Solvents (DES) for Sustainable Extraction of Phenolic Compounds from Natural Sources
PublikacjaPhenolic compounds have long been of great importance in the pharmaceutical, food, and cosmetic industries. Unfortunately, conventional extraction procedures have a high cost and are time consuming, and the solvents used can represent a safety risk for operators, consumers, and the environment. Deep eutectic solvents (DESs) are green alternatives for extraction processes, given their low or non-toxicity, biodegradability, and reusability....
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The impact of cooking method on the phenolic composition, total antioxidant activity and starch digestibility of rice (Oryza sativa L.)
PublikacjaThis study investigated changes in the phenolic composition, total antioxidant activity (TAA) and starch digestibility in white and brown rice due to three different cooking procedures, and subsequent reheating of cooked rice after storage. Among the analyzed samples, brown rice showed the highest TAA and phenolic content (622.5 mg kg-1 DW). All cooking methods resulted in significant decrease of phenolic content and TAA of rice...
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Design and synthesis of TiO2/Ti3C2 composites for highly efficient photocatalytic removal of acetaminophen: The relationships between synthesis parameters, physicochemical properties, and photocatalytic activity
PublikacjaIn this study, we report the potential of TiO2/Ti3C2 composite fabricated by oxidation of MXene for degradation of persistent organic pollutants. The effect of the synthesis conditions (time, temperature, and reaction environment) on the morphology, physicochemical properties, and photocatalytic activity was investigated. It was found that acetaminophen degradation was positively correlated with TiO2 content in the composite structure. Furthermore,...
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Polyfunctional chemically bonded stationary phase for reversed phase high-performance liquid chromatography
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Unveiling of polymer/fullerene blend films morphology by ellipsometrically determined optical order within polymer and fullerene phases
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Ab initio studies of the structure, physicochemical properties and behavior of lead chlorides and chloroplumbate anions in gaseous and aqueous phases
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Colonization of axenic beet by rhizosphere bacteria takes place in discreet phases regardless of bioinculation with next generation bioinoculant
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Separation of Volatile Oxygen-containing Organic Compounds by Gas Chromatography - selectivity comparison of different polarity stationary phases
PublikacjaThis paper present a results of the separation of 36 reference compounds belonging to the group of Volatile Oxygen-Containing Organic Compounds (OVOCs) using capillary gas chromatography with flame ionization detector (GC-FID) and three stationary phases of different polarity. A selectivity has been studied regarding to OVOCs and n -alkanes. The most useful for the separation of the group OVOCs is a polar ionic liquid stationary...
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Characteristic of Morpholinium Ionic Liquids as Gas Chromatography Stationary Phases with McReynolds Constants and Activity Coefficients at Infinite Dilution
PublikacjaIn this work, four ionic liquids based on N-alkyl-N-methylmorpholinium cation ([Mor1,R] where R= 2, 4, 8, 10) and bis(trifluoromethanesulfonyl)imide anion [TFSI] were synthesized. Using gas-liquid chromatography a number of parameters describing the sorption properties of the investigated ionic liquids were determined. The values of Kovats indices, McReynolds constants, and activity coefficients at infinite dilution were the basis...
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Numerical modeling of exciton impact in two crystalographic phases of the organo-lead halide perovskite (CH3NH3PbI3) solar cell
PublikacjaTo improve the power conversion efficiency of solar cells based on organo–lead halide perovskites, a detailed understanding of the device physics is fundamental. Here, a computational analysis of excitons impact is reported for these types of photocell. Numerical calculations based on the model, which take into account electronic charge carriers (electrons and holes), excitons and ions, have been carried out. The role of excitons...
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Propriétés macroscopiques équivalentes pour représenter les pertes dans les bobines conductrices
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High-Frequency Proximity Losses Determination for Rectangular Cross-Section Conductors
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Importance of ventilation in modulating interaction between sympathetic drive and cardiovascular variability
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Cointegration Modelling for Health and Condition Monitoring of Wind Turbines - An Overview
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Removal of phenolic inhibitor compounds from hydrolysates and post-fermentation broths by using a Hydrophobic Magnetic Deep Eutectic Solvent
PublikacjaHydroxymethylfurfural (HMF), furfural (FF), hydroquinone (HQ), and vanillin (VAN) are among the main inhibitors generated during most of biomass pre-treatments prior to fermentation processes. They are recognized as toxic to several fermentative microorganisms and therefore cause a decrease in biohydrogen or biofuel production (after hydrolysis). Moreover, if they are released into aqueous solutions (after fermentation), they can...
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Impact damage detection in smart composites using nonlinear acoustics—cointegration analysis for removal of undesired load effect
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Imidazole Hidden Polar Phase
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Mechanism of the phase transitions in MnAs
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Miniaturized solid phase extraction
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The Workshop on Multi-Phase Flows
PublikacjaPrzedstawiono ideę warsztatów ''Modelowanie przepływów wielofazowych w układach termochemicznych'' - organizowanych corocznie - od 2000 roku, przez Podsekcję Przepływów Wielofazowych Komitetu Mechaniki PAN. Omówiono tematykę VI Warsztatów, które były poświęcone głównie metodom eksperymentalnym.
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Asynchronous phase-location system
PublikacjaThis paper presents concept and implementation of digital phase-location system, designed as a navigational aid for marine applications. The main feature of the proposed system is the ability to work in both synchronous mode, with one master station and set of slave stations synchronised with master, and in asynchronous mode with independent clocking of all stations.
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Miniaturized solid phase microextratcion
PublikacjaWithout any doubt analytical laboratories have an essential role in environmental protection due to the fact that they takes an active part in the monitoring pollutants present in air, water or soil. From the other side, the analytical activity is involved in the generation of toxic waste what is associated with the use of not eco-friendly reagents and solvents. For these reasons, green analytical chemistry (GAC) was introduced...
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Ionization and fragmentation of the six-membered heterocycles containing oxygen – Comparative studies of electron and photon impact on the 3,4-dihydro-2H-pyran molecules
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One- and two-photon induced fluorescence of Pacific Blue-labeled human serum albumine deposited on different core size silver colloids
PublikacjaPublikacja opisuje jedno i dwufotonowo indukowaną Fluorescencje znakowanej barwnikiem ''Pacific Blue'' ludzkiej albuminy osadzonej na srebrnych koloidach różnych rozmiarów
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Exploring the Phenomenon of the Additive Colour Process While Using a Computer Programme by 7–8-Year-Old Students
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Neotenic phenomenon in gene expression in the skin of Foxn1- deficient (nude) mice - a projection for regenerative skin wound healing
PublikacjaMouse fetuses up to 16 day of embryonic development and nude (Foxn1- deficient) mice are examples of animals that undergo regenerative (scar-free) skin healing. The expression of transcription factor Foxn1 in the epidermis of mouse fetuses begins at embryonic day 16.5 which coincides with the transition point from scar-free to scar-forming skin wound healing. In the present study, we tested the hypothesis that Foxn1 expression...
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The Undisrupted Growth of the Airbnb Phenomenon between 2014–2020. The Touristification of European Cities before the COVID-19 Outbreak
PublikacjaAs a result of the Airbnb eruption, not only has the character of the short-term rental market been completely transformed, but the decades long growth in tourism has also been further accelerated. Therefore, due to the new demands of the tourism economy, the major shift in the usage of historic city centers occurred–the process of ‘touristification’, that results in the emergence of its new, unsustainable form. Despite the significance...
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Photovoltaic Maximum Power Point Technique based on Incremental Conductance (INCON) control algorithm
PublikacjaMaximum output power status can significantly improve the deployment rate of solar energy system. In order to get the maximum power output, issue of tracking maximum power point (MPP), reduced harmonics around MPP and improve efficiency of the solar power energy system, this paper presents the improved maximum power point tracking (MPPT) control...
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Photovoltaic effect in hybrid heterojunction formed from cadmium telluride and zinc perfluorophthalocyanine layers
PublikacjaPraca przedstawia wyniki badań zjawska fotowoltaicznego w planarnym układzie złożonym z następujących warstw: ITO, CdTe, perfluoroftalocyjanina cynku, BCP, Ag.
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Majbutnè fotoelektriki - sistemi, integrovanì z budnikom = Future of photovoltaic - building integrated systems
PublikacjaBIPV (ang. Building Integrated Photovoltaics) - architektoniczne, strukturalne i estetyczne systemy fotowoltaiczne zintegrowane z budynkami - to jedna z najbardziej obiecujących form wykorzystania energii odnawialnej, pozwalająca na połączenie systemu generującego energię elektryczną z obiektami takimi jak domy mieszkalne, szkoły i biurowce. Instalacje takie powstają na całym świecie, głównie w przypadku prestiżowych projektów,...
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Re-use of photovotaic [i.e. photovoltaic] crystalline silicon solar cells - technological possibilities
PublikacjaSystemy fotowoltaiczne są stosowane na całym świecie jako niezawodne i wydajne układy zasilania dla zastosowań przemysłowych, komunalnych i komercyjnych. Średni czas eksploatacji modułów fotowoltaicznych wynosi ponad 25 lat. Wyeksploatowane moduły oraz te, które uległy uszkodzeniu, są obecnie przeważnie składowane na wysypiskach jako odpady przemysłowe lub komunalne, np. jako szkło lub materiał rozbiórkowy, co było dopuszczalne...
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On photovoltaic effect in hybrid heterojunction formed from palladium phthalocyanine and titanium dioxide layers
PublikacjaPraca omawia własności fotowoltaiczne hybrydowego heterozłączy utworzonego z ftalocyjaniny palladu i dwutlenku tytanu. Warstwy TiO2 otrzymano metodą zol-żel, a warstwę organiczną nanoszono metodą próżniowego naparowywania. W pracy przedstawione są charakterystyki prądowo-napięciowe, zależność prądu zwarcia i napięcia rozwarcia od natężenia oświetlenia oraz spektralna charakterystyka prądu zwarcia.
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Recycling of raw materials, silicon wafers and complete solar cells from photovoltaic modules
PublikacjaPhotovoltaic modules (PVs) are an attractive way of generating electricity in reliable and maintenance-free systems with the use of solar energy. The average lifetime of photovoltaic modules is 25 to 30 years. To offset the negative impact of photovoltaic modules on the environment, it is necessary to introduce a long-term strategy that includes a complete lifecycle of all system components from the production phase through installation...
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Consequences of suboptimal design of Building Integrated Photovoltaic Installation – a case study for Gdansk, Poland
PublikacjaThe carried out analysis concerns 2 kWp building integrated photovoltaic installation (BIPV) at the Chemistry Faculty of Gdansk University of Technology. It was proven that the generated energy data for every month diverge significantly from the expected vales. It is corelated with suboptimal orientation of the installation itself, as well as with the tilt angle varying from optimal.
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Efficiency limit of excitonic photovoltaic cells under phosphor-based white LED illumination
PublikacjaThe limit of energy conversion of excitonic photovoltaic cells working under white light illumination generated by phosphor-based LED is analysed using the modified Giebink approach. Particularly, the impact of the optical energy gap and energy loss associated with the excitons dissociation at the heterojunction interface on power conversion efficiency of the device are discussed. From the results of our study it follows that the...
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Prototype design and development of low-load-roof photovoltaic modules for applications in on-grid systems
PublikacjaFour prototypes of lightweight photovoltaic modules for applications in on-grid systems have been designed, developed, manufactured and tested for compliance with relevant IEC standards. Selected, commercially available materials characterized by thermogravimetry, differential scanning calorimetry, dilatometry, scanning electron microscopy and nanoindentation technique were used in frameless, adhesively-bonded sandwich-structures...
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Heat recovery from the hybrid photovoltaic tile – experimental studies with the solar light simulator
PublikacjaConsidering the current development of micro-cogeneration energy sources, supported by the national prosumer policy and the act on the renewable energy sources, there is a great demand for the effective solar technologies. In this area, the photovoltaic cells with a combined conversion of the solar radiation energy into the electrical and thermal energy (PV/T cells) seem to be attractive. They are already widely available and treated...
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Degradation of electrical performance of a crystalline photovoltaic module due to dust deposition in northern Poland
PublikacjaThe reduction in power output caused by the accumulation of dust on the photovoltaic module surface is an important problem and should receive much more attention in the literature. This study was an evaluation of the performance degradation of crystalline photovoltaic modules due to natural and simulated dust deposition. Dust is created from powdered grains of sand and particles of different bodies. Dust originates from different...
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Analysis of electromagnetic disturbances in DC network of grid connected building-integrated photovoltaic system
PublikacjaThis paper focuses on conducted electromagnetic interference (EMI) emissions and propagation in the DC network of grid connected building integrated photovoltaic (PV) system. The investigated PV system, consists of ten solar panels, cabling and the grid-connected one phase inverter. The EMI simulation model of the real PV system has been developed with the aid of impedance analyzer measurements of solar panels and the DC network...
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Highly efficient rutile TiO2 photocatalysts with single Cu(ii) and Fe(iii) surface catalytic sites
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Preparation and characterization of monometallic (Au) and bimetallic (Ag/Au) modified-titania photocatalysts activated by visible light
PublikacjaThe Au-TiO2 and Ag/Au-TiO2 nanoparticles have been prepared using a water-in-oil microemulsion system of water/AOT/cyclohexane and water/Triton X-100/cyclohexane. The obtained photocatalysts were subsequently characterized by a BET method, DRS spectroscopy, X-ray photoelectron emission spectroscopy (XPS), scanning transmission electron microscopy (STEM) and X-ray powder diffraction analysis (XRD). For gold-doped titanium (IV) oxide...
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Visible light activity of rare earth metal doped (Er3+, Yb3+ or Er3+/Yb3+) titania photocatalysts
PublikacjaA series of Er3+-TiO2, Yb3+-TiO2 and Er3+/Yb3+-TiO2 photocatalysts were obtained via sol-gel method, using rare earth metal (RE) precursor ranging from 0.25 to 10 mol%. The experiments demonstrated that phenol in aqueous solutions was successfully degraded under visible light (> 450 nm) using RE3+-TiO2. The as-prepared samples were characterized by X-ray diffraction (XRD), X-ray photoelectron emission spectroscopy (XPS), UV-Vis...
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Mono- and bimetallic nanoparticles decorated KTaO 3 photocatalysts with improved Vis and UV–Vis light activity
PublikacjaNew mono- and bimetallic nanoparticle-decorated perovskite-type KTaO3 photocatalysts were successfully synthesized by hydrothermal reaction followed by photodeposition of MNPs/BNPs. The effect of noble metal type, amount of metal precursor as well as photoreduction method on the physicochemical and photocatalytic properties of MNPs- and BNPs-KTaO3 have been investigated. Photocatalytic activity under Vis light irradiation was estimated...
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Mono- and bi-metallic plasmonic photocatalysts for degradation of organic compounds under UV and visible light irradiation
PublikacjaTitania powders were surface modified with gold and/or silver nanoparticles (NPs) by photodeposition method. Gold modified titania exhibited much higher photocatalytic activity during methanol dehydrogenation under UV irradiation than titania modified with monometallic silver and bimetallic Au–Ag NPs. Bimetallic photocatalysts exhibited either enhanced or reduced visible light activity, depending on properties of noble metal NPs,...
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Visible-light-driven lanthanide-organic-frameworks modified TiO2 photocatalysts utilizing up-conversion effect
PublikacjaHighly efficient and quite stable composite with core-shell-like architecture reported herein, responds to the challenge of sunlight-driven photocatalysts. The Ln(ndc)/TiO2 photocatalytic system comprises active lanthanide-carboxylate coordination networks (Nd, Er, Ho, and Tm as metal ions, and 2,6-naphthalene dicar-boxylic acid as the organic linker) and inert titanium dioxide and allow to convert incompatible visible radiation...
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Design and Synthesis of NTU-9/C3N4 Photocatalysts: Effects of NTU-9 Content and Composite Preparation Method
PublikacjaHybrid materials based on graphitic carbon nitride (g-C3N4) and NTU-9 metal–organic frameworks (MOF) were designed and prepared via solvothermal synthesis and calcination in air. The as-prepared photocatalysts were subsequently characterized using Brunauer–Emmett–Teller (BET) analysis, UV-Vis diffuse reflectance spectroscopy (DRS), photoluminescence (PL) emission spectroscopy, X-ray diffraction (XRD), X-ray photoelectron spectroscopy...
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Wybrane wiadomości z etnobotaniki i etnofarmacji. Karty z dziejów lecznictwa naturalnego [Selected issues from ethnobotany and ethno-pharmacy. Pages from the history of natural medicine]
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Determination of twenty pharmaceutical contaminants in soil using ultrasound-assisted extraction with gas chromatography-mass spectrometric detection
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Treatment innovation using solar/UV In book: The Treatment of Pharmaceutical Wastewater: Innovative Technologies and the Adaptation of Treatment Systems
PublikacjaSince ancient times, sunlight irradiation has been widely used for water purification. Apart from solar water disinfection techniques, UV irradiation is of particular interest when considering the photodegradation of various classes of emerging pollutants. Pharmaceutically active compounds are one of the largest classes of micropollutants. The main sources of these contaminants in wastewater and aqueous environments are households,...
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Vibrational Sum-Frequency Generation Activity of a 2,4-Dinitrophenyl Phospholipid Hybrid Bilayer: Retrieving Orientational Parameters from a DFT Analysis of Experimental Data
PublikacjaThe vibrational nonlinear activity of films of 2,4-dinitrophenyl phospholipid (DNP) at the solid interface is measured by sum-frequency generation spectroscopy (SFG). Hybrid bilayers are formed by a LangmuirSchaefer approach in which the lipid layer is physisorbed on top of a self-assembled monolayer of dodecanethiol on Pt with the polar heads pointing out from the surface. The SFG response is investigated in two vibrational frequency...