Wyniki wyszukiwania dla: IONIC LIQUID SUPPORTED IONIC LIQUID MEMBRANE TOLUENE SEPARATION SELECTIVITY VOC

• Separation of toluene from gas phase using supported imidazolium ionic liquid membrane

  Publikacja

  • I. Cichowska-Kopczyńska
  • M. Joskowska
  • B. Dębski
  • R. Aranowski
  • J. Hupka

  - JOURNAL OF MEMBRANE SCIENCE - Rok 2018

  Investigation on utilization of supported ionic liquids membranes for hydrocarbon separation from the gas phase was performed. Properties of membrane phase, wettability of supports, swelling effects and solubility of toluene were taken into account. Toluene permeation rates were significantly higher than those of pure nitrogen, the selectivity in a range of 17–341 was satisfying for separation. Despite the increase of viscosity...

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• Effectiveness of toluene separation from gas phase using supported ammonium ionic liquid membrane

  Publikacja

  • I. Cichowska-Kopczyńska
  • R. Aranowski

  - CHEMICAL ENGINEERING SCIENCE - Rok 2020

  Ammonium ionic liquids (ILs) are relatively cheap in synthesis and environmentally benign and despite that they have been very rarely used in gas separation. In this research we used several ammonium ILs as liquid membranes for removal of residual toluene from gas phase. Ionic liquids used in this study were composed of bis(trifluoromethylsulfonyl)imide anion [Tf2N] and trimethylbutylammonium [N1114], trietylbutylammonium [N2224],...

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• Influence of Ionic Liquid Structure on Supported Ionic Liquid Membranes Effectiveness in Carbon Dioxide/Methane Separation

  Publikacja

  • I. Cichowska-Kopczyńska
  • M. Joskowska
  • B. Dębski
  • J. Łuczak
  • R. Aranowski

  - Journal of Chemistry - Rok 2013

  This paper indicates the possibility of application of imidazolium ionic liquids immobilized in polymeric supports—supported ionic liquid membranes—in CO2 separation from gaseous streams (e.g., biogas). Imidazolium salts containing alkyl fluoride anions, bis(trifluoromethylsulfonyl)imide and trifluoromethanesulfonate, selectively separating CO2 were used. The permeability of CO2 through membranes was investigated under gas pressure...

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• Tunable properties of ionic liquids in supported ionic liquid membranes technology

  Publikacja

  • I. Cichowska-Kopczyńska

  - Rok 2012

  Immobilizowane membrany ciekłe są układem, gdzie ciecz osadzona jest w porach porowatego nośnika i jest tam utrzymywana przez siły kapilarne. Takie rozwiązania wykazują wiele zalet, jak zużycie niewielkich ilości fazy membranowej, niska lotność cieczy jonowych,. Efektywność separacji związków z użyciem membran ciekłych zależy głównie od właściwości fazy membranowej. Praca opisuje modyfikacje struktury cieczy jonowych, a zatem ich...

• Wetting processes in supported ionic liquid membranes technology

  Publikacja

  • I. Cichowska-Kopczyńska
  • M. Joskowska
  • R. Aranowski

  - Physicochemical Problems of Mineral Processing - Rok 2014

  Ciecz jonowe znajdują szerokie zastosowanie w technologii membran ciekłych, szczególnie w procesach separacji i oczyszczania gazów. Praca opisuje zdolność cieczy jonowych do zwilżania komercyjnie dostępnych porowatych nośników stosowanych w technologii membran ciekłych. Wyznaczenie charakterystyki nośników pozwoliło na wskazanie czynników mających wpływ na procesy zwilżania. Do wyznaczenia kątów zwilżania zastosowano metodą siedzącej...

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• Spectroscopic Studies of Amino Acid Ionic Liquid-Supported Schiff Bases

  Publikacja

  • P. Ossowicz
  • E. Janus
  • G. Schroeder
  • Z. Rozwadowski

  - MOLECULES - Rok 2013

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• Biogas upgrading using supported liquid membranes based on ionic liquids

  Publikacja

  • I. Cichowska-Kopczyńska
  • M. Joskowska
  • B. Dębski
  • R. Aranowski

  - Rok 2012

  Zastosowanie cieczy jonowych osadzonych w porach nośników polimerowych bądź ceramicznych jest nowoczesnym podejściem do separacji ditlenku węgla z mieszanin gazowych. Znikoma prężność par cieczy jonowych i możliwość modyfikacji budowy kationu i wyboru anionu wchodzących w skład cieczy jonowych sprawiają, że związki te mogą zastąpić obecnie stosowane w procesach separacji aminy. W publikacji przedstawiono wpływ struktury chemicznej,...

• Development of an asymmetric cellulose acetate-ionic liquid P6,6,6,14[PHOS] gel membrane for the perstraction of succinic acid from a model fermentation solution of yarrovia lipolytica

  Publikacja

  • E. Zurob
  • E. Quijada-Maldonado
  • R. Castro Munoz
  • J. Romero
  • A. Plaza
  • R. Cabezas

  - SEPARATION AND PURIFICATION TECHNOLOGY - Rok 2025

  This study introduces a novel approach to separate succinic acid (SA) from fermentation mixtures using an asymmetric membrane based on the gelation of the ionic liquid [P6,6,6,14][PHOS] coated with two layers of cellulose acetate. The membrane was designed to explore the synergistic effect of polymer-ionic liquid interfaces according to the solution-diffusion theory. The gelation of the ionic liquid was achieved using 12-hydroxystearic...

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• Use of pyridinium and pyrrolidinium ionic liquids for removal of toluene from gas streams

  Publikacja

  • I. Cichowska-Kopczyńska
  • R. Aranowski

  - JOURNAL OF MOLECULAR LIQUIDS - Rok 2020

  Separation of toluene from a toluene/N2 gas mixture using supported liquid membranes based on a series of pyridinium (1-butylpyridinium- bis(trifluoromethylsulfonyl)imide - [C4Py][Tf2N], 1-hexylpyridinium trifluoromethanesulfone [C6Py][Tf2N]) and pyrrolidinium (1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide - [C4Pyrr][Tf2N], 1-hexyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide - [C6Pyrr][Tf2N], 1-butyl-1-methylpyrrolidinium...

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• Separation of nicotinic acid and its structural isomers using 1-ethyl-3-methylimidazolium ionic liquid as a buffer additive by capillary electrophoresis

  Publikacja

  • M. Marszałł
  • M. Markuszewski
  • R. Kaliszan

  - Journal of Pharmaceutical and Biomedical Analysis - Rok 2006

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• CO2 Separation Using Supported Deep Eutectic Liquid Membranes Based on 1,2-propanediol

  Publikacja

  • B. Nowosielski
  • D. Warmińska
  • I. Cichowska-Kopczyńska

  - ACS Sustainable Chemistry & Engineering - Rok 2023

  In this work, deep eutectic solvents (DESs) composed of choline chloride, acetylcholine chloride or tetrabutylammonium chloride, and 1,2-propanediol were used as a liquid phase for polypropylene-based supported liquid membranes (SLMs) and evaluated for the separation of carbon dioxide from CO2/N2 mixtures. Fourier transform infrared spectra were obtained to confirm DES formation, and the thermal stability of solvents was investigated...

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• Usuwanie lotnych związków organicznych z fazy gazowej z zastosowaniem cieczy jonowych

  Publikacja

  • I. Cichowska-Kopczyńska

  - Rok 2014

  Użycie cieczy jonowej do usuwania LZO jest limitowane przez rozpuszczalność usuwanych związków. Dane literaturowe sugerują, że ciecze jonowe jako faza membranowa mogą być z powodzeniem stosowane do selektywnej separacji węglowodorów aromatycznych z mieszanin węglowodorów aromatycznych i alifatycznych. Przedmiotem pracy było kompleksowe opisanie procesu separacji LZO z fazy gazowej z uwzględnieniem czynników wpływających na efektywność...

• Transport properties of microemulsions with ionic liquid apolar domains as a function of ionic liquid content

  Publikacja

  • J. Piekart
  • J. Łuczak

  - RSC Advances - Rok 2016

  The specific conductivity, dynamic viscosity and apparent diffusion coefficient of each of four aqueous ionic liquid microemulsions (IL-MEs) were measured as a function of ionic liquid (IL) content. The investigated systems were composed of water, hydrophobic ILs (1-butyl-3-methylimidazolium hexafluorophosphate or bis(trifluoromethanesulphonyl)imide) and the nonionic surfactant Triton X-100 or its mixture with cosurfactant (butanol)....

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• Analytical applications and physicochemical properties of ionic liquid-based hybrid materials: A review

  Publikacja

  • K. Yavir
  • Ł. Marcinkowski
  • R. Marcinkowska
  • J. Namieśnik
  • A. Kloskowski

  - ANALYTICA CHIMICA ACTA - Rok 2019

  Ionic liquids with their unique properties found so far numerous analytical applications. Among them ionic liquids immobilized on the surface or within the pores of a solid support were successfully utilized in extraction techniques dedicated to preconcentration of the analytes from food, environmental and biological samples. In this review we focus on comprehensive summarizing of available literature data on the examples of ionic...

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• Measurement of activity coefficients at infinite dilution of organic solutes in the ionic liquid 1-hexyl-1,4-diaza[2.2.2]bicyclooctanium bis(trifluoromethylsulfonyl)imide using gas–liquid chromatography

  Publikacja

  • Ł. Marcinkowski
  • A. Kloskowski
  • J. Namieśnik

  - JOURNAL OF CHEMICAL THERMODYNAMICS - Rok 2014

  Based on gas–liquid chromatography (GLC) retention data, activity coefficients at infinite dilution of 39 different solutes in the ionic liquid 1-hexyl-1,4-diaza[2.2.2]bicyclooctanium bis(trifluoromethylsulfonyl)imide ([HDABCO][NTf2]) have been determined. Measurements covered a broad range of types of organic solutes including alkanes, alcohols, ketones, benzene derivatives and McReynold’s compounds. Activity coefficients were...

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• Równolegle przebiegające procesy separacji pianowej jonów Al(III), Cu(II) i Zn(II) z roztworów ich mieszanin

  Publikacja

  • P. Rybarczyk

  - Rok 2015

  Metody flotacji jonowej i precypitacyjnej należą do procesów separacji pianowej, wykorzystujących zdolność selektywnej adsorpcji niektórych składników roztworu na powierzchni międzyfazowej gaz – ciecz. Do zalet separacji pianowej zalicza się m.in. niewysokie koszty inwestycyjne i eksploatacyjne oraz wysoką skuteczność w obróbce roztworów rozcieńczonych. Celem pracy jest ocena wpływu kluczowych parametrów na wydajność i przebieg...

• Highly Active TiO2 Microspheres Formation in the Presence of Ethylammonium Nitrate Ionic Liquid

  Publikacja

  • A. Gołąbiewska
  • C. Micaelaa
  • M. Paszkiewicz-Gawron
  • W. Lisowski
  • E. Raczuk
  • T. Klimczuk
  • Ż. Polkowska
  • E. Grabowska
  • A. Zaleska-Medynska
  • J. Łuczak

  - Catalysts - Rok 2018

  Spherical microparticles of TiO2 were synthesized by the ionic liquid-assisted solvothermal method at different reaction times (3, 6, 12, and 24 h). The properties of the prepared photocatalysts were investigated by means of UV-VIS diffuse-reflectance spectroscopy (DRS), Brunauer–Emmett–Teller (BET) surface area measurements, scanning electron microscopy (SEM), X-ray diffraction analysis (XRD), and X-ray photoelectron spectroscopy...

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• Visible light photocatalytic activity of ionic liquid-TiO2 spheres: effect of the ionic liquid's anion structure

  Publikacja

  • J. Łuczak
  • M. Paszkiewicz-Gawron
  • M. Długokęcka
  • W. Lisowski
  • E. Grabowska
  • S. Makurat
  • J. Rak
  • A. Zaleska-Medynska

  - CHEMCATCHEM - Rok 2017

  The effect of the ionic liquid’s (IL) anion type ([BIMIM][X], where X= [Br], [PF6] or [OctSO4]) and content on the morphology, surface properties and photoactivity of TiO2 obtained by solvothermal method has been systematically investigated. Our results revealed that the presence of [Br], [OctSO4] anions favors formation of anatase phase, while presence of [PF6] anion causes formation of mixture of anatase and Ti(OH)PO4 phases....

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• Spectroscopic and photophysical properties of ZNTPP in a room temperature ionic liquid

  Publikacja

  • J. Szmytkowski
  • T. Bond
  • M. Paige
  • R. Scote
  • R. Steer

  - JOURNAL OF PHYSICAL CHEMISTRY A - Rok 2010

  The steady-state absorption and emission spectra and the time-resolved Soret- and Q-band excited fluorescence profiles of the model metalloporphyrin, ZnTPP, have been measured in a highly purified sample of the common room temperature ionic liquid, [bmim][PF(6)]. S(2)-S(0) emission resulting from Soret-band excitation behaves in a manner completely consistent with that of molecular solvents of the same polarizability. The ionic...

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• Theoretical investigation of the structural insights of the interactions of γ-Fe2O3 nanoparticle with (EMIM TFSI) ionic liquid

  Publikacja

  • A. Sieradzan
  • C. Czaplewski
  • A. Bielicka-Gieldon
  • M. Bobrowski
  • A. Gieldon

  - JOURNAL OF MOLECULAR LIQUIDS - Rok 2021

  One of the possible applications of ionic liquids is to produce electricity from heat. The iron oxide nanoparticle is a potent electrical particle, which is expected to improve the heat’s efficiency to electricity conversion, however, it is prone to aggregation and sedimentation, which hamper its application. One of the methods to enhance the nanoparticle’s solubility and electrical properties is the use of a stabilizing component...

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• Transport properties of aqueous ionic liquid microemulsions: influence of the anion type and presence of the cosurfactant

  Publikacja

  • J. Łuczak
  • J. Piekart

  - SOFT MATTER - Rok 2015

  Transport properties, viz. specific conductivity, dynamic viscosity and apparent diffusion coefficients, were measured as a function of water content in aqueous ionic liquid microemulsions containing 1-butyl-3- methylimidazolium hexafluorophosphate, [BMIM][PF6] and bis(trifluoromethanesulphonyl)imide, [BMIM][Tf2N], stabilized by the nonionic surfactant TX-100, or its mixture with a cosurfactant, i.e. butanol. The investigation covered...

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• Application of chemometric modeling for ionic liquid-based ultrasonic-assisted dispersive liquid-liquid microextraction: Analysis of fosetyl-aluminum in fruit and vegetable samples

  Publikacja

  • H. Haq
  • A. Elik
  • H. Durukan
  • H. Sarac
  • A. Demirbas
  • G. Boczkaj
  • N. Gürsoy
  • N. Altunay

  - JOURNAL OF FOOD COMPOSITION AND ANALYSIS - Rok 2023

  This manuscript presents a new method for selective extraction and determination of fosetyl-aluminum in fruits and vegetable samples based on ultrasonic-assisted dispersive liquid-liquid microextraction method using ionic liquids (IL-UA-DLLME). A UV-Visible spectrophotometer was used for detection and quantification. Plants used for sample collection were grown under controlled conditions in a greenhouse. Central composite design...

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• Physical and Thermophysical Properties of 1-Hexyl-1,4-diaza[2.2.2]bicyclooctanium Bis(trifluoromethylsulfonyl)imide Ionic Liquid

  Publikacja

  • Ł. Marcinkowski
  • A. Kloskowski
  • J. Namieśnik

  - JOURNAL OF CHEMICAL AND ENGINEERING DATA - Rok 2014

  Owing to their unique properties, ionic liquids (ILs) have become a real alternative to organic compounds. Nowadays, ILs are commonly used in a number of areas such as chemical synthesis and separation techniques. However, ionic liquids continue to have a limited applicability in industry because the information on their physical and chemical properties is not readily available. This paper presents, for the first time, the results...

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• The new silica-based coated SPME fiber as universal support for the confinement of ionic liquid as an extraction medium

  Publikacja

  • K. Delińska
  • K. Yavir
  • M. Kermani
  • A. D. Mielewczyk-Gryń
  • A. Kloskowski

  - SEPARATION AND PURIFICATION TECHNOLOGY - Rok 2020

  The new silica-based SPME fiber coating is reported for the first time as universal support purposed to confinement of ionic liquid as an extraction medium. Fiber coating was prepared by the sol-gel process, using potassium silicate (K2SiO3) as a precursor and dimethylformamide (DMF) as a pore-forming medium. The concept of synthesis assumes obtaining a solid porous material on the surface of the glass rod and, being characterized...

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• The effects of the IM1-12Br ionic liquid and the oxytetracycline mixture on selected marine and brackish microorganisms

  Publikacja

  • L. Sharma
  • B. Kudłak
  • G. Siedlewicz
  • K. Pazdro

  - SCIENCE OF THE TOTAL ENVIRONMENT - Rok 2023

  The number of applications and commercialized processes utilizing ionic liquids has been increasing, and it is anticipated that this trend will persist and even intensify in the future. Ionic liquids possess desirable characteristics, such as low vapor pressure, good water solubility, amphiphilicity, and stability. Nevertheless, these properties can influence their environmental behavior, resulting in resistance to biotic and abiotic...

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• Polymeric metal‐containing ionic liquid sorbent coating for the determination of amines using headspace solid‐phase microextraction

  Publikacja

  • K. Yavir
  • P. Eor
  • A. Kloskowski
  • J. Anderson

  - JOURNAL OF SEPARATION SCIENCE - Rok 2021

  This study describes the design, synthesis, and application of polymeric ionic liquid sorbent coatings featuring nickel metal centers for the determination of volatile and semivolatile amines from water samples using headspace solidphase microextraction. The examined polymeric ionic liquid sorbent coatings were composed of two ionic liquid monomers (tetra(3-vinylimidazolium)nickel bis[(trifluoromethyl)sulfonyl]imide [Ni2+(VIM)4]...

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• Multicomponent ionic liquid CMC prediction

  Publikacja

  • I. E. Kłosowska-Chomiczewska
  • W. Artichowicz
  • U. Preiss
  • C. Jungnickel

  - PHYSICAL CHEMISTRY CHEMICAL PHYSICS - Rok 2017

  We created a model to predict CMC of ILs based on 704 experimental values published in 43 publications since 2000. Our model was able to predict CMC of variety of ILs in binary or ternary system in a presence of salt or alcohol. The molecular volume of IL (Vm), solvent-accessible surface (Sˆ), solvation enthalpy (DsolvGN), concentration of salt (Cs) or alcohol (Ca) and their molecular volumes (Vms and Vma, respectively) were chosen...

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• Effect of multi-walled carbon nanotubes properties on the photocatalytic activity of bismuth-based composites synthesised via an imidazolium ionic liquid

  Publikacja

  • A. Bielicka-giełdoń
  • P. Wilczewska
  • M. Paszkiewicz
  • A. Malankowska
  • K. Szczodrowski
  • J. Ryl
  • E. Siedlecka

  - APPLIED SURFACE SCIENCE - Rok 2024

  The use of various types of multi-walled carbon nanotubes in the synthesis of bismuth oxybromide semiconductors via imidazolium ionic liquid was studied in detail. The effect of the MWCNT shape, specific surface area, and various diameters on the morphology, surface properties and photoactivity of the Bi-based composites has been investigated for the first time. So far, the literature has only shown the enhancement of photocatalytic...

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• Liquid chromatography techniques for separation of flavonoids from Droseraceae

  Publikacja

  • M. Jaszczołt
  • A. Skrzypczak
  • A. Królicka
  • L. Aleksander
  • M. A. Kamiński

  - PLANTA MEDICA - Rok 2011

  Flavonoids which are presented in insectivorous plants of the Droseraceae family have wide range of advantageous properties i.e. an antioxidant, anti-inflammatory and antimicrobial activities, antitumor activity was reported as well.The purpose of the research was to develop the most favourable conditions for liquid chromatographic separation and identification of myricetin and quercetin in extracts of insectivorous plants. In...

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• Dependence between Ionic Liquid Structure and Mechanism of Visible-Light-Induced Activity of TiO2 Obtained by Ionic-Liquid-Assisted Solvothermal Synthesis

  Publikacja

  • M. Paszkiewicz-Gawron
  • M. Długokęcka
  • W. Lisowski
  • M. Paganini
  • E. Giamello
  • T. Klimczuk
  • M. Paszkiewicz
  • E. Grabowska
  • A. Zaleska-Medynska
  • J. Łuczak

  - ACS Sustainable Chemistry & Engineering - Rok 2018

  Because of the tremendous structural diversityof ionic liquids (ILs), simple transfer of observations performed for one IL used for IL-TiO2 preparation on different samples is not possible. Therefore, four ionic liquids, all containing distinct nitrogen-bearing organic cations (pyridinium, pyrrolidinium, ammonium, imidazolium), were used for the first time for the preparation of IL-TiO2 composites. The role of the individual IL...

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• Fabrication and photoactivity of ionic liquid–TiO2 structures for efficient visible-light-induced photocatalytic decomposition of organic pollutants in aqueous phase

  Publikacja

  • A. Gołąbiewska
  • M. Paszkiewicz-Gawron
  • A. Sadzińska
  • W. Lisowski
  • E. Grabowska
  • A. Zaleska-Medynska
  • J. Łuczak

  - Beilstein Journal of Nanotechnology - Rok 2018

  To investigate the effect of the ionic liquid (IL) chain length on the surface properties and photoactivity of TiO2, a series of TiO2 microspheres have been synthesized via a solvothermal method assisted by 1-methyl-3-octadecylimidazolium chloride ([ODMIM][Cl]) and 1-methyl-3-tetradecylimidazolium chloride ([TDMIM][Cl]). All as-prepared samples were characterized by X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy...

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• Free silanols and ionic liquids as their suppressors in liquid chromatography

  Publikacja

  • M. Buszewska-Forajta
  • M. Markuszewski
  • R. Kaliszan

  - Journal of Chromatography A - Rok 2018

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• Ionic liquid as morphology-directing agent of two-dimensional Bi2WO6: New insight into photocatalytic and antibacterial activity

  Publikacja

  • A. Pancielejko
  • J. Łuczak
  • W. Lisowski
  • G. Trykowski
  • D. Venieri
  • A. Zaleska-Medynska
  • P. Mazierski

  - APPLIED SURFACE SCIENCE - Rok 2022

  An efficient and durable utilization of light to drive photocatalytic reactions still requires the overcoming of barriers. Herein, two-dimensional (2D) ultrathin IL_Bi2WO6 (IL_BWO) photocatalysts were prepared for the first time via ionic liquid-assisted hydrothermal route by adjusting the amount of tetrabutylammonium chloride [TBA][Cl], synthesis temperature and duration. IL played the role of morphology-directing agent given...

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• Composite 2D Material-Based Pervaporation Membranes for Liquid Separation: A Review

  Publikacja

  • R. Castro Munoz

  - MOLECULES - Rok 2024

  Today, chemistry and nanotechnology cover molecular separations in liquid and gas states by aiding in the design of new nano-sized materials. In this regard, the synthesis and application of two-dimensional (2D) nanomaterials are current fields of research in which structurally defined 2D materials are being used in membrane separation either in self-standing membranes or composites with polymer phases. For instance, pervaporation...

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• Room temperature ionic liquid-based dispersive liquid–liquid microextraction of uranium in water samples before spectrophotometric determination

  Publikacja

  • M. Kaykhaii
  • E. Ghasemi

  - Analytical Methods - Rok 2013

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• Towards the Application of Structure-Property Relationship Modeling in Materials Science: Predicting the Seebeck Coefficient for Ionic Liquid/Redox Couple Systems

  Publikacja

  • A. Sosnowska
  • M. Barycki
  • A. Gajewicz
  • M. Bobrowski
  • S. Freza
  • P. Skurski
  • S. Uhl
  • E. Laux
  • T. Journot
  • L. Jeandupeux... i 2 innych

  - CHEMPHYSCHEM - Rok 2016

  This work focuses on determining the influence of both ionic liquid (IL) type and redox couple concentration on Seebeck coefficient values of such a system. The quantitative structure­ property relationship (QSPR) and read-across techniques are proposed as methods to identify structural features of ILs (mixed with LiI/I2 redox couple), which have the most influence on the Seebeck coefficient (Se) values of the system. ILs consisting...

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• Ordered TiO2 nanotubes with improved photoactivity through self-organizing anodization with the addition of an ionic liquid: effects of the preparation conditions

  Publikacja

  • A. Pancielejko
  • P. Mazierski
  • W. Lisowski
  • A. Zaleska-Medynska
  • J. Łuczak

  - ACS Sustainable Chemistry & Engineering - Rok 2019

  Modifying the geometric and surface parameters of oriented TiO2 nanotubes (NTs) is beneficial to the utilization of solar energy for chemical reactions, and this performance may be further improved. Thus, the effects of adding an ionic liquid (IL), 1-butylpiridinium chloride [BPy][Cl], and the effects of the water content and preparation conditions on the surface morphological, physicochemical, photocatalytic and photoelectrochemical...

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• Thermodynamic study of binary mixtures of toluene with ionic liquids, 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, 1-hexyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide and 1-butylpyridinium bis(trifluoromethylsulfonyl)imide

  Publikacja

  • D. Warmińska
  • I. Cichowska-Kopczyńska

  - JOURNAL OF MOLECULAR LIQUIDS - Rok 2020

  Densities, refractive indices and viscosities at 293.15, 298.15, 303.15, 308.15 and 313.15 K of binary mixtures of toluene with 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, 1-hexyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide and 1-butylpyridinium bis(trifluoromethylsulfonyl)imide have been measured over the miscible region at p = 0.1 MPa. From the experimental data, values of excess molar volume,...

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• Membrane distillation assisting food production processes of thermally sensitive food liquid items: a review

  Publikacja

  • E. Gontarek-Castro
  • R. Castro Munoz

  - CRITICAL REVIEWS IN FOOD SCIENCE AND NUTRITION - Rok 2023

  Physical separation technologies have become important tool for processing in the current food manufacturing industries, especially for the products containing bioactive compounds thanks to their health benefits in costumers. As for the processing of bioactive food ingredients implies the implementation of integrated systems oriented to their separation, fractionation, and recovery. In this field, membrane distillation (MD), which...

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• Facile formation of self-organized TiO2 nanotubes in electrolyte containing ionic liquid - ethylammonium nitrate and their remarkable photocatalytic properties

  Publikacja

  • A. Pancielejko
  • P. Mazierski
  • W. Lisowski
  • A. Zaleska-Medynska
  • K. Kosek
  • J. Łuczak

  - ACS Sustainable Chemistry & Engineering - Rok 2018

  The oriented TiO2 nanotube arrays (NTs) are identified as a stable, active and recyclable photocatalytic surface. However, their photoactivity is strictly depended on morphology (especially length), which could be controlled by anodic oxidation parameters, including electrolyte properties. To control the morphology, were successfully synthesized a series of NTs by a novel approach where ionic liquid (IL), ethylammonium nitrate...

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• Cytotoxicity, acute and subchronic toxicity of ionic liquid, didecyldimethylammonium saccharinate, in rats

  Publikacja

  • J. Jodynis-Liebert
  • M. Nowicki
  • M. Murias
  • T. Adamska
  • M. Ewertowska
  • M. Kujawska
  • H. Piotrowska
  • A. Konwerska
  • D. Ostalska-Nowicka
  • J. Pernak

  - REGULATORY TOXICOLOGY AND PHARMACOLOGY - Rok 2010

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• Amine-Based Ionic Liquid for CO2 Capture and Electrochemical or Thermal Regeneration

  Publikacja

  • S. Voskian
  • P. Brown
  • C. Halliday
  • K. Rajczykowski
  • T. Hatton

  - ACS Sustainable Chemistry & Engineering - Rok 2020

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• Contribution to the mechanism of liquid membrane oscillators involving cationic surfactant.

  Publikacja

  • M. Szpakowska
  • I. Czaplicka
  • E. Płocharska-Jankowska
  • O. B. Nagy

  - JOURNAL OF COLLOID AND INTERFACE SCIENCE - Rok 2003

  It is shown that liquid membrane oscillators with cationic surfactants havemore complex oscillation patterns than observed previously. The actual details of the oscillations depend strongly on the nature of the membrane material, dislosing even the presence of parallel molecular events. It appearsthat sampling topology also has a great influence on the observed oscillato-ry behaviour. Variation of oscillation patterns with...

• Liquid membrane oscillators

  Publikacja

  • M. Szpakowska

  - DESALINATION - Rok 2009

  Zaprezentowano krótki przegląd różnych podejść do opisu mechanizmu oscylacji róznicy potencjału elektrycznego między fazami wodnymi. Więcej uwagi zwrócono na mechanizm zaproponowany w zespole Szpakowskiej. Dla układu z kationowym surfaktantem nagła adsorpcja i desorpcja cząsteczek surfaktantu na granicy faza akceptorowa/ membrana ciekła poprzedzona dyfuzją jest odpowiedzialna za obserwowane oscylacje. W przypadku układu z anionowym...

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• New bulk liquid membrane oscillator composed of two coupled oscillators with diffusion-mediated physical coupling

  Publikacja

  • M. Szpakowska
  • E. Płocharska-Jankowska
  • B. Otto

  - CHEMICAL PAPERS - Rok 2015

  A new type of bulk liquid membrane system, which represents the first example of a bulk liquid membrane oscillator characterised by the presence of two coupled oscillators, is described. When the benzyldimethyltetradecylammonium chloride surfactant undergoes an oscillatory mass transfer through a nitromethane liquid membrane, a new liquid layer (phase X) appears between the membrane and the acceptor phase. Kinetic analysis provides...

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• The effect of imidazolium ionic liquid on the morphology of Pt nanoparticles deposited on the surface of SrTiO3 and photoactivity of Pt–SrTiO3 composite in the H2 generation reaction

  Publikacja

  • J. Zwara
  • M. Paszkiewicz-Gawron
  • J. Łuczak
  • A. Pancielejko
  • W. Lisowski
  • G. Trykowski
  • A. Zaleska-Medynska
  • E. Grabowska

  - INTERNATIONAL JOURNAL OF HYDROGEN ENERGY - Rok 2019

  Photocatalytic water splitting has great potential in solar-hydrogen production as a low-cost and environmentally friendly method. Different unique techniques used to obtain photocatalysts with various modifications to improve H2 generation have been introduced. In the present work, SrTiO3 was successfully synthesized via the solvothermal method in the presence of ionic liquid (IL) - 1-butyl-3-methylimidazolium bromide ([BMIM][Br])...

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• Review of the applicability of ionic liquid matrices for the quantification of small molecules by MALDI MS

  Publikacja

  • P. Kobylis
  • P. Stepnowski
  • M. Caban

  - Microchemical Journal - Rok 2021

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• Chromatographic behaviour of ionic liquid cations in view of quantitative structure-retention relationship

  Publikacja

  • M. Molíková
  • M. Markuszewski
  • R. Kaliszan
  • P. Jandera

  - Journal of Chromatography A - Rok 2010

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• Optimization of liquid chromatographic separation of pharmaceuticals within green analytical chemistry framework

  Publikacja

  • A. Dogan
  • M. Tobiszewski

  - MICROCHEMICAL JOURNAL - Rok 2020

  The contribution is aimed at the development of methodology that allows to consider green analytical chemistry criteria during optimization of liquid chromatographic separation with design of experiment. The objectives of the optimization are maximization of peak areas of five non-steroid anti-inflammatory drugs, maximization of resolution between peaks, with simultaneous shortening of chromatographic separation time and minimization...

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• Application of ionic liquids for gas separation processes

  Publikacja

  • B. Dębski
  • I. Cichowska-Kopczyńska
  • M. Gadaj
  • M. Joskowska
  • Ł. Heda
  • M. Klein
  • J. Klein

  - Rok 2011

  Nowym kierunkiem w procesach separacji dwutlenku węgla stało się w ostatnich latach zastosowanie cieczy jonowych. Niemierzalna prężność par i możliwość dostosowania ich właściwości czyni je idealnymi mediami zastępującymi lotne, korozyjne i toksyczne rozpuszczalniki. Ponadto ciecze jonowe wykazują niską współabsorpcję innych gazów. Dlatego też, możliwe jest selektywne odseparowanie dwutlenku węgla z mieszanin gazowych