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Wyniki wyszukiwania dla: ELECTRON TRANSFER PROCESS
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Beyond Antioxidant Activity: Redox Properties of Catechins May Affect Changes in the DNA Methylation Profile—The Example of SRXN1 Gene
PublikacjaThe role of catechins in the epigenetic regulation of gene expression has been widely studied; however, if and how this phenomenon relates to the redox properties of these polyphenols remains unknown. Our earlier study demonstrated that exposure of the human colon adenocarcinoma HT29 cell line to these antioxidants affects the expression of redox-related genes. In particular, treatment with (−)-epigallocatechin (EGC) downregulated...
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SoundShape - Headphone Transfer Function database
Dane BadawczeThis publication introduces the SoundShape database, which contains closed-ear headphone transfer functions (HpTF) for fifteen headphone models. Several models included in this database are also found in other well-known databases, such as Virtuoso and Binaural Decoders. However, for some models found in the literature, HpTF filters were unavailable,...
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Low-strain sensor based on the flexible boron-doped diamond-polymer structures
PublikacjaA free-standing high boron-doped diamond nanosheet (BDDNS) has been fabricated for the development of a flexible BDDNS strain senor. High boron-doped diamond was initially grown on a tantalum substrate in a microwave plasma-assisted chemical vapor deposition method, and was then transferred to a Kapton polymer substrate to fabricate the flexible BDDNS/Kapton device. Before performing the transfer process, the thin BDDNS’s morphology...
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Combined effect of nitrogen-doped functional groups and porosity of porous carbons on electrochemical performance of supercapacitors
PublikacjaIn this work, nitrogen-doped porous carbons obtained from chitosan, gelatine, and green algae were investigated in their role as supercapacitor electrodes. The effects of three factors on electrochemical performance have been studied— of the specific surface area, functional groups, and a porous structure. Varying nitrogen contents (from 5.46 to 10.08 wt.%) and specific surface areas (from 532 to 1095 m2g−1) were obtained by modifying...
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Nickel-based catalysts for electrolytic decomposition of ammonia towards hydrogen production
PublikacjaNickel is an attractive metal for electrochemical applications because it is abundant, cheap, chemically resilient, and catalytically active towards many reactions. Nickel-based materials (metallic nickel, its alloys, oxides, hydroxides, and composites) have been also considered as promising electrocatalysts for ammonia oxidation. The electrolysis of ammonia aqueous solution results in evolution of gaseous hydrogen and nitrogen....
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Highly Occupied Surface States at Deuterium-Grown Boron-Doped Diamond Interfaces for Efficient Photoelectrochemistry
PublikacjaPolycrystalline boron-doped diamond is a promising material for high-power aqueous electrochemical applications in bioanalytics, catalysis, and energy storage. The chemical vapor deposition (CVD) process of diamond forma-tion and doping is totally diversified by using high kinetic energies of deu-terium substituting habitually applied hydrogen. The high concentration of deuterium in plasma induces atomic arrangements and steric...
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Conductive printable electrodes tuned by boron-doped nanodiamond foil additives for nitroexplosive detection
PublikacjaAn efficient additive manufacturing-based composite material fabrication for electrochemical applications is reported. The composite is composed of commercially available graphene-doped polylactide acid (G-PLA) 3D printouts and surface- functionalized with nanocrystalline boron-doped diamond foil (NDF) additives. The NDFs were synthesized on a tantalum substrate and transferred to the 3D-printout surface at 200 °C. No other electrode...
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Spinel-Type Structured Phosphor Near-Infrared-II Emission: Intervalence Charge Transfer and Hetero-Valent Chromium Pairs
Dane BadawczeNear-infrared (NIR) emitting phosphors draw much attention because they show great applicability and development prospects in many fields. Herein, a series of inverse spinel-type structured LiGa5O8 phosphors with a high concentration of Cr3+ activators is reported with a dual emission band covering NIR-I and II regions. Except for strong ionic exchange...
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Influence of Different Nanometals Implemented in PMMA Bone Cement on Biological and Mechanical Properties
PublikacjaCemented arthroplasty is a common process to fix prostheses when a patient becomes older and his/her bone quality deteriorates. The applied cements are biocompatible, can transfer loads, and dampen vibrations, but do not provide antibacterial protection. The present work is aimed at the development of cement with antibacterial effectivity achieved with the implementation of nanoparticles of different metals. The powders of Ag,...
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Singlet oxygen in the removal of organic pollutants: An updated review on the degradation pathways based on mass spectrometry and DFT calculations
PublikacjaThe degradation of pollutants by a non-radical pathway involving singlet oxygen (1O2) is highly relevant in advanced oxidation processes. Photosensitizers, modified photocatalysts, and activated persulfates can generate highly selective 1O2 in the medium. The selective reaction of 1O2 with organic pollutants results in the evolution of different intermediate products. While these products can be identified using mass spectrometry...
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Quenching effects in organic electroluminescence
PublikacjaWe examine various electronic processes that underlie the quenching of the emission from highly efficient phosphorescent and electrophosphorescent organic solid-state molecular systems. As an example, we study the luminescent efficiencies from the phosphorescent iridium (III) complex, fac tris (2-phenylpyridine) iridium [(Ir (ppy)3] doped into a diamine derivative doped polycarbonate hole-transporting matrix and in the form...
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Magdalena Szuflita-Żurawska
OsobyMagdalena Szuflita-Żurawska jest kierownikiem Sekcji Informacji Naukowo-Technicznej na Politechnice Gdańskiej oraz Liderem Centrum Kompetencji Otwartej Nauki przy Bibliotece Politechniki Gdańskiej. Jej główne zainteresowania badawcze koncentrują się w obszarze komunikacji naukowej oraz otwartych danych badawczych, a także motywacji i produktywności naukowej. Jest odpowiedzialna między innymi za prowadzenie szkoleń dla pracowników...
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Anna Lis dr hab. inż.
OsobyProfesor Politechniki Gdańskiej; wykładowca i badacz w zakresie współpracy międzyorganizacyjnej, zarządzania innowacjami, rozwoju nowych produktów i zarządzania środowiskowego; jej dorobek naukowy obejmuje ponad 80 publikacji; uczestniczyła w licznych projektach badawczych realizowanych w ośrodkach akademickich; była zaangażowana we współpracę międzynarodową - brała udział w programach europejskich (INNET, COSME, ERASMUS, LOCALISED...
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Valorization of waste plastics to a novel metal-organic framework derived cobalt/carbon nanocatalyst as peroxymonosulfate activator for antibiotics degradation
PublikacjaMetal-organic frameworks (MOFs), with excellent structural properties, exhibit unique advantages as promising catalysts in the degradation of emerging organic contaminants (EOCs) by PS-AOPs. Herein, Co-MOF-71 was prepared by hydrothermal method using terephthalic acid (TPA) obtained from the hydrolysis of waste PET plastics as an organic ligand, and the derived cobalt/carbon composite (PETC) was prepared by carbonizing Co-MOF-71...
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Adsorption behavior and corrosion inhibitive characteristics of newly synthesized cyano-benzylidene xanthenes on copper/sodium hydroxide interface: Electrochemical, X-ray photoelectron spectroscopy and theoretical studies
PublikacjaElegant process for synthesis of 3-(7H-dibenzo[c,h]xanthen-7-yl)benzaldehyde (3), as new starting material to create a set of novel xanthene analogues, 2-(3-(7H-dibenzo[c,h]xanthen-7-yl)benzylidene)malononitrile (4), 3-(3-(7H-dibenzo[c,h]xanthen-7-yl)phenyl)-2-cyanoacrylic acid (5), and Ethyl-3-(3-(7H-dibenzo[c,h]xanthen-7-yl)phenyl)-2-cyanoacrylate (6), was achieved starting with available materials under mild conditions. Various...
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Effects of Ni-NCAL and Ni–Ag electrodes on the cell performances of low-temperature solid oxide fuel cells with Sm0.2Ce0·8O2-δ electrolyte at various temperatures
PublikacjaThree low-temperature solid oxide fuel cells are built using Sm0.2Ce0·8O2-δ (SDC) as the electrolyte. Cell A is symmetrical and features Ni–LiNi0.8Co0·15Al0·05O2 (Ni–NCAL) electrodes, Cell B comprises a Ni–NCAL anode and a Ni–Ag cathode, and Cell C is fabricated using a Ni–NCAL cathode and a Ni–Ag anode. The ohmic resistance and polarization resistance (Rp) of Cells B and C are significantly higher than those of Cell A. The reduction...
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The luminescence study of Ga1.98–xAlxO3:0.02Cr3+ coumpounds.
Dane BadawczeA chemical and mechanical pressure-induced photoluminescence tuning method was developed through structural evolution and hydrostatic pressure involving phase transition. A series of Ga1.98−xAlxO3:0.02Cr3+ phosphors were synthesized by collaborators from National Taiwan University. Structural evolution reveals a crystal phase change with the incorporation...
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Paweł Możejko dr hab.
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Scanning electrochemical micrographs of poly(lactic acid) 3D printed electrodes ablated by femtosecond laser
Dane BadawczeThe dataset contains the scanning electrochemical micrographs of the femtosecond laser (FSL) ablation at the surface of commercially available carbon black-filled poly(lactic acid) 3D printed electrode. The process is used for the increase of the charge transfer of this electrode in electrochemical studies.
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European Economic Development 2023
Kursy OnlineMain aim of the subject is to transfer knowledge on theoretical and empirical aspects of economic development in Europe. Key topics: •concepts of economic development, alternative measures of development •factors of economic growth and development (‘determinants of growth’) •history of economic development in Europe •cross-country and cross-regional comparisons •sources: where to find information and data needed for empirical...
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Tomasz Majchrzak dr inż.
OsobyDr inż. Tomasz Majchrzak urodził się 29.01.1992 roku w Elblągu. W młodym wieku przejawiał zainteresowania z zakresu nauk społecznych i historii, stąd wykształcenie średnie uzyskał w I LO w Elblągu w klasie o profilu społeczno-prawnym. Jednak, rzucając sobie wyzwanie, zdecydował się wybrać studia na Wydziale Chemicznym Politechniki Gdańskiej, z którym związany jest do teraz. Swoją karierę naukową rozpoczął jeszcze na studiach inżynierskich...
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Nonradiative long range energy transfer in donor-acceptor systems with excluded volume
PublikacjaW pracy analizowano bezpromienisty długozasięgowy transfer energii w układach donor-akceptor z uwzględnieniem objętości wyłączonej. Stwierdzono, że zanik fluorescencji pierwotnie wzbudzonych donorów jest wolniejszy, jeżeli uwzględnia się objętość wyłączoną. Ten efekt jest znacznie wzmocniony, gdy akceptory znajdują się w pewnej objętości niedostępnej dla donorów. Analizę numeryczną przeprowadzono stosując metodę symulacji Monte...
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Wpływ azotowania jarzeniowego i laserowego nadtapiania na odporność kawitacyjną stali X5CrNi18-10
PublikacjaNierdzewne stale austenityczne charakteryzują się doskonałą odpornością korozyjną, aczkolwiek niskimi właściwościami mechanicznymi. W wielu przypadkach ogranicza to ich eksploatację w warunkach przemysłowych. Ponadto, nierdzewne stale austenityczne są wrażliwe na korozję lokalną w obecności jonów halogenkowych. Technologie materiałowe, które dają potencjalne możliwości otrzymywania korzystnego wpływu na właściwości mechaniczne...
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Robert Bogdanowicz prof. dr hab. inż.
OsobyRobert Bogdanowicz received his Ph.D. degree with honours in Electronics from the Gdansk University of Technology. He worked as a post-doc researcher in Ernst-Moritz-Arndt-Universität Greifswald Institut für Physik. He has initiated optical emission imaging of muti-magnetron pulsed plasma and contributed to the development of antibacterial implant coatings deposited by high-power impulse magnetron sputtering. He moved back to...
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Pollutants transfer phenomena
Kursy OnlineSubject considering fundamentals of the heat and mass transfer in the environment.
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Opracowanie ekspertyzy dotyczącej przyczyn pękania łopatek wirnika SP turbiny PG1 typu 13UP55
PublikacjaZakres badań i analiz dotyczył ustalenia przyczyn pękania elementów łopatek wirnika SPA5 turbiny TG1 typu 13UP55 obejmował: 1. wykonanie badań składu chemicznego stali, z której wykonano łopatki dostarczone przez Zleceniodawcę dwoma metodami, 2. badania mikroobszarów zniszczenia łopatek na mikroskopie elektronowym skaningowym z mikroanalizatorem EDS, 3. badania metalograficzne makroskopowe i mikroskopowe fragmentów...
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INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER
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HEAT TRANSFER ENGINEERING
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Aleksandra Teresa Wiśniewska dr inż.
Osobyeducation Postgraduate studies in “ Scandinavian Studies“ University of Gdańsk (2019-2020), Postgraduate studies in "Research Project Management and Commercialization of Research Results" Gdańsk University of Technology, Faculty of Management and Economics (2010–2011), Postgraduate studies "Control & Management of Lean Manufacturing in Network Systems", Fachhochschule Karlsruhe (1998–2000), Master's studies "Automation...
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SkinDepth - synthetic 3D skin lesion database
Dane BadawczeSkinDepth is the first synthetic 3D skin lesion database. The release of SkinDepth dataset intends to contribute to the development of algorithms for:
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SEM (scanning electron microscopy) and TEM (transmission electron microscopy) images of PMD and PMH
Dane BadawczeThese data contains SEM (scanning electron microscopy) and TEM (transmission electron microscopy) images of PMD and PMH. TEM was performed on a FEI Tecnai F30 transmission electron microscope operating at an acceleration voltage of 200 kV. SEM was done with a SEM, XL30ESEM-FEG with an acceleration voltage of 20 KV. Sample abbreviations (PMH, PMD) are...
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Natural convective heat transfer from isothermalconic
PublikacjaTheoretical considerations on convective heat transfer from isothermal upward conicalsurfaces have been presented. The physical model of this phenomenon consists of an isothermalcone of inclination angle (φ) between the cone generating line (X) and the radius (R) of the cone base. The angle is a parameter of conical surface which varied from (φ = 0−circular horizontal plate) to (φ = π/2—vertical cylinder) . Onthe basis of Navier–Stokes...
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Grzegorz Boczkaj dr hab. inż.
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Vident-synth: a synthetic intra-oral video dataset for optical flow estimation
Dane BadawczeWe introduce Vident-synth, a large dataset of synthetic dental videos with corresponding ground truth forward and backward optical flows and occlusion masks. It can be used for:
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Business process modelling
Kursy OnlineWelcome to the Business Process Modeling course! We will travel together among the business processes world and its modeling with the BPMN ;) I hope it will be valuable for your future. See you soon, Marzena Grzesiak
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Electron energy-loss spectroscopy of excited states of the diazine molecules: Pyridazine
PublikacjaExcitation of the valence electronic states of the pyridazine molecules in the gas phase have been studied using the technique of electron energy-loss spectroscopy. Varying the electron scattering conditions, the residual electron energy and scattering angle, enabled the optically-allowed and -forbidden excitations to be differentiated. The measured energy-loss spectra enabled the vertical excitation energies of the observed states...
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High Performance Tubular Heat Exchanger with Minijet Heat Transfer Enhancement
PublikacjaIn the paper, the original cylindrical heat exchanger with minijets (MJHE) was introduced. The systematic experimental analysis of the prototype heat exchanger was described with special attention paid to such parameters as the heat transfer effectiveness, heat transfer rates, overall heat transfer coefficients, and pressure drop. The heat transfer coefficients were determined based on Wilson plot method, the most suitable approach...
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A correlation between electron-hole pair radii and magnetomodulation of exciplex fluorescence in electron donor-electron acceptor organic systems
PublikacjaElectric field dependencies of electromodulated photoluminescence and magnitudes of the magnetic-field effect on photoluminescence havebeen measured in vacuum-evaporated films of m-MTDATA [4,4',4"-tris(N-(3-methylphenyl)-N-phenylamino)triphenylamine]:bathophe-nanthroline, m-MTDATA:BCP (bathocuproine), as well as 4,4',4"-tris[2-naphthyl(phenyl)amino]triphenylamine:BCP. The Sano-Tachiya-Noolandi-Hong extension of standard Onsager...
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Electron ionization and low energy electron attachment to molecules of biological interest
PublikacjaEthylenediaminetetraacetic acid (EDTA) and 2-amino-2-(hydroxymethyl)-1,3-propanediol (TRIS) were investigated by electron impact ionization and low energy electron attachment. Both compounds are components of biological buffers and often are used as DNA stabilizers in irradiation studies. hus it is of a great importance to understand their potential interactions with radiation. Our results revealed that at least one of them, EDTA, may...
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Electron ionization and low energy electron attachment to molecules of biological interest
PublikacjaEthylenediaminetetraacetic acid (EDTA) and 2-amino-2-(hydroxymethyl)-1,3-propanediol (TRIS) were investigated by electron impact ionization and low energy electron attachment. Both compounds are components of biological buffers and often are used as DNA stabilizers in irradiation studies. hus it is of a great importance to understand their potential interactions with radiation. Our results revealed that at least one of them, EDTA, may...
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Selected prtoblems of heat ans mass transfer
Kursy OnlineThew lecture presentes advanced topics in heat ans mass transfer
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Electron collisions with cyanoacetylene HC3N : Vibrational excitation and dissociative electron attachment
PublikacjaWe experimentally probe electron collisions with HC3N in the energy range from 0 to 10 eV with the focus on vibrational excitation and dissociative electron attachment. The vibrational excitation cross sections show a number of resonances which are mode specific: the two dominant π∗ resonances are visible in the excitation of all the vibrational modes; however, broad σ ∗ resonances are visible only in certain bond-stretching vibrational...
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Chemical and Process Engineering : New Frontiers
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Low energy elastic electron scattering from benzonitrile (C6H5CN)
PublikacjaWe present experimental differential elastic scattering cross sections (DCSs) for low energy electron scattering from benzonitrile along with integral and momentum-transfer cross sections that are determined from these DCSs. The measurements of DCSs are obtained using the relative flow method with helium as the standard gas, in a crossed electron-molecular gas beam arrangement. Our measurements are made at incident electron energies...
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JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA
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A semiempirical model for low energy electron–atom transport cross sections: The case of noble gases
PublikacjaA semiempirical approach to describe low energy electron–atom transport cross sections of easy implementation and reproduction is presented. The heart of the model is an energy independent two-parameter potential that was adjusted to reproduce the accurate total cross sections for He, Ne, Ar and Kr, measured with a threshold photoelectron source technique from meV up to 20 eV. Once the potential was conceived, the model was validated...
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Resonances and Dissociative Electron Attachment in HNCO
PublikacjaIn a combined experimental and theoretical study, we probe the dissociative electron attachment in isocyanic acid HNCO. The experimental absolute cross section for the NCO− fragment shows a sharp onset and fine structures near the threshold. The autoionizing state responsible for the dissociative attachment is found in both the R-matrix calculation and using analytic continuation in the coupling constant. The involved A' resonance...
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Business process modelling 2026
Kursy OnlineWelcome to the Business Process Modeling course! We will travel together among the business processes world and its modeling with the BPMN ;) I hope it will be valuable for your future. See you soon, Marzena Grzesiak
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Dissociative electron attachment and anion-induced dimerization in pyruvic acid
PublikacjaWe report partial cross sections for the dissociative electron attachment to pyruvic acid. A rich fragmentation dynamics is observed. Electronic structure calculations facilitate the identification of complex rearrangement reactions that occur during the dissociation. Furthermore, a number of fragment anions produced at electron energies close to 0 eV are observed, that cannot originate from single electron-molecule collisions....
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Carboxylation Enhances Fragmentation of Furan upon Resonant Electron Attachment
PublikacjaWe report a dissociative electron attachment study to 2-furoic acid (C5H4O3) isolated in a gas phase, which is a model molecule consisting of a carboxylic group and a furan ring. Dissociation of furan by low energy electrons is accessible only via electronic excited Feshbach resonances at energies of incident electrons above 5 eV. On the other hand, carboxylic acids are well- known to dissociate via attachment of electrons at subexcitation energies....