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Wyniki wyszukiwania dla: POLYMER MASS
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An experimental study on polymer mass
PublikacjaA new method of repairing damaged structures by filling the cracks with specially prepared polymer mass has been recently proposed. The technique is mainly dedicated to historical objects where minimum intervention is permitted. The flexible joint bonds the disrupted elements and ensures further safe exploitation of a damaged structure. The aim of the present paper is to show the results of an experimental study on polymer mass...
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Experimental study on static and dynamic properties of polymer mass
PublikacjaA new method of repairing damaged structures by filling the cracks with a specially prepared polymer mass has been recently proposed. This new and innovative technique, known as the Flexible Joint Method (FJM), is mainly dedicated to masonries and historical objects, where minimum intervention is permitted. The flexible joint bonds the disrupted elements and ensures further safe exploitation of a damaged structure. The aim of the...
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Experimental study on polymer mass used to repair damaged structures
PublikacjaA new method of repairing damaged structures by injecting the cracks with specially designed polymer mass (flexible two-component grout based on polyurethane resin) has been recently proposed. The technique is mainly dedicated to damaged masonries, especially historical structures where minimum intervention is permitted. The cracks are filled with the special injection, forming the flexible joints bonding the disrupted structural...
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Experimental Study on Polymer Mass Used to Repair Damaged Structures
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Experimental examination of an elastomeric polymer
PublikacjaA new method of repairing damaged structures by filling the cracks with a specially prepared elastomeric polymer mass has been recently proposed. This new and innovative technique, known as the Flexible Joint Method (FJM), is mainly dedicated to masonries and historical objects, where minimum intervention is permitted. The flexible joint bonds the disrupted elements and ensures further safe exploitation of a damaged structure....
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Emission Profiles of Volatiles during 3D Printing with ABS, ASA, Nylon, and PETG Polymer Filaments
PublikacjaIn this short communication we characterize the emission of volatile organic compounds (VOCs) from fused filament fabrication (FFF) 3D printing using four polymer materials, namely polyethylene terephthalate glycol-modified (PETG), acrylonitrile styrene acrylate (ASA), Nylon, and acrylonitrile butadiene styrene (ABS). Detailed emission profiles are obtained during thermal degradation of the polymers as a function of temperature...
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Experimental determination of basic mechanical properties of elastomeric polymer
PublikacjaThere are a lot of different methods of repairing and reinforcing damaged structures, but when it comes to historical buildings and other cultural heritage objects, it is as much about mechanical safety as the aesthetical aspects. Recently, a new and innovative method of repairing damaged structures by filling the cracks with a specially prepared polymer mass has been proposed. This new and innovative technique, known as the Flexible...
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Application of polymer element in reduction of temporary steel grandstand vibrations
PublikacjaThe numerical analysis focused on reduction of vibrations of a temporary steel scaffolding grandstand has been conducted in this paper. These types of structures are regularly subjected to dynamic loads which, in conjunction with light and quite slender structural members, may induce dangerous vibrations. To increase their safety, temporary steel grandstands are usually strengthened with the diagonal stiffeners of tubular cross...
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Experimental study on the effectiveness of polymer damper in damage reduction of temporary steel grandstand
PublikacjaA large number of accidents, involving collapses of temporary grandstands during different types of events, were observed in the past. If the synchronized movement of people is tuned with the natural frequency of the affected part of the structure, resonance might occur. It may lead to severe damages of grandstands, their collapse or panic among the spectators. The aim of the paper is to assess, through preliminary experimental...
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Experimental and numerical study on polymer element used for reduction of temporary steel grandstand vibrations
PublikacjaThe purpose of the paper is to analyse the effectiveness of a polymer damper in reduction of a temporary steel grandstand vibrations through the experimental and numerical study. The damper considered in the investigation is constructed out of two L-shape steel members bonded with polymer mass of high damping properties. The element has been installed as a diagonal one at the back part of the structure. The method has been compared...
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The influence of temperature on properties of the polymer flexible joint used for strengthening historical masonries
PublikacjaA new method of repairing damaged structures by filling the cracks with a specially prepared elastomeric polymer mass has been recently proposed. This new and innovative technique, known as the Flexible Joint Method (FJM), is mainly dedicated to masonries and historical objects, where minimum intervention is permitted. The flexible joint bonds the disrupted elements and ensures further safe exploitation of a damaged structure....
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Shaking table experimental study on the effectiveness of polymer bearings for seismic isolation of structures
PublikacjaSeismic isolation has been recognised to be a very effective way of protecting structures from damage during earthquakes. It allows us to extend the natural period of the structure and therefore avoid resonance with the ground motion. Moreover, by increasing damping in the isolation devices, more energy can be dissipated and thus the structural response can be further reduced. The aim of this paper is to show the results of the...
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Investigation of behaviour of metal structures with polymer dampers under dynamic loads
PublikacjaA large number of accidents concerning structures subjected to dynamic loads have been recently observed. One of the examples of such a structure is a temporary steel grandstand erected using scaffolding system. Dynamic load that is generated by crowd movement has a significant influence on the behaviour of the structure and may lead to excessive structural vibrations. The aim of the study is to consider the idea of using polymer...
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Dynamic analysis of temporary steel grandstand equipped with different types of bracing system
PublikacjaIn the paper, behaviour of a temporary steel grandstand equipped with two different types of bracing system has been analysed through the numerical study. A typical solution concerning application of a diagonal tubular members has been compared with elements proposed by authors and called polymer dampers. A polymer element consists of two L-shape steel members bonded with polymer mass. The aim of the paper is to verify the effectiveness...
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THE INFLUENCE OF POLYMER STRIPS IN REDUCTION OF A STEEL GRANDSTAND VIBRATIONS
PublikacjaGrandstands are types of structures commonly used during sport events or music concerts. Dynamic loads generated by crowd movement may have significant influence on human perception as well as may lead to the destruction of a structure. Lighter and more slender structural steel members are more easily excitable by spectators. If the synchronized movement is tuned with the natural frequency of the affected part of the structure,...
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Preventing of earthquake-induced pounding between steel structures by using polymer elements – experimental study
PublikacjaPounding between two, or more, adjacent buildings during earthquakes has been identified as one of the reasons for substantial damage or even total collapse of colliding structures, so it has been the subject of numerous studies in the recent years. A major reason leading to interactions between adjacent, insufficiently separated structures results from the differences in their dynamic properties. A number of different methods...
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Morphology and properties of recycled polyethylene/ground tyre rubber/thermoplastic poly(ester-urethane) blends
PublikacjaThe growing amount of plastics waste produced every year resulted in development of mechanical and chemical recycling methods of polymers and their blends or composites. From the environmental point of view, the possibility of plastics waste reusing and recycling is desirable. In this study three polymer blends were obtained with using recycled polyethylene (RPE), ground tyre rubber (GTR) and thermoplastic poly(ester-urethane)...
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Study on polymer elements for mitigation of earthquake-induced pounding between buildings in complex arrangements
PublikacjaPounding between neighbouring buildings during earthquakes has been identified as one of the reasons for substantial damage or even total collapse of colliding structures, so it has been the subject of numerous studies in the recent years. A major reason leading to interactions between adjacent, insufficiently separated structures results from the differences in their dynamic properties. The problem is much more complicated for...
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Experimental Study on the Effectiveness of Polyurethane Flexible Adhesive in Reduction of Structural Vibrations
PublikacjaThe aim of the present study is to consider the idea of using polyurethane flexible adhesive in to reduce the vibrations in structures exposed to dynamic loads and evaluate their damping properties in relation to large deformations. Firstly, two aluminium cantilever beams, simulating structural elements (without and with polyurethane layer in the form of tape), were analysed, in order to check the damping of the unconstrained polymer...
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Real-time monitoring of the emission of volatile organic compounds from polylactide 3D printing filaments
PublikacjaEstablishing the emission profile of volatile organic compounds generated during fused deposition modeling 3D printing using polymer filaments is important in terms of both understanding the processes taking place during thermal degradation of thermoplastics, and assessing the user's exposure to potentially harmful volatiles. However, obtaining detailed, real-time qualitative and quantitative results poses a challenge. In this...
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Study of the influence of thermal factors on the welding process of polyethylene gas pipelines,
PublikacjaA one-dimensional calculation scheme is proposed with the help of which it is possible to determine and set the technological parameters with the accuracy to be realized in production conditions: the temperature of the heating element and the heating time, which allows maximum mechanization of the technological operations of polyethylene gas pipelines welding. The numerical value of the coefficient of temperature for polyethylene...
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Load capacity and serviceability conditions for footbridges made of fibre-reinforced polymer laminates = Warunki nośności i użytkowalności w odniesieniu do kładek z laminatów polimerowych
PublikacjaThe contribution is focused on derivation of the Ultimate Limit State (ULS) and Serviceability Limit State (SLS) design criteria for footbridges built of fibre-reinforced polymer matrix (FRP) laminates. The ULS design criterion is based on the design guidelines for above-ground, pressure, FRP composite tanks and the Tsai-Wu failure criterion, which is used to predict the onset of FRP laminates damage. The SLS criterion is based...
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The preparation and evaluation of core-shell magnetic dummy-template molecularly imprinted polymers for preliminary recognition of the low-mass polybrominated diphenyl ethers from aqueous solutions
PublikacjaThe design, preparation process, binding abilities, morphological characteristic and prospective field of application of dummy-template magnetic molecularly imprinted polymer (DMMIP) for preliminary recognition of the selected low-mass polybrominated diphenyl ethers (PBDE-47 and PBDE-99) from aquatic environment were investigated. The surface of iron oxide (Fe3O4) nanopowder (50-100 nm particles size) was modified with tetraethoxysilane...
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Structure and Stability Characterization of Natural Lake Pigments Made from Plant Extracts and Their Potential Application in Polymer Composites for Packaging Materials
PublikacjaNatural dyes were extracted from various plant sources and converted into lake pigments based on aluminum and tin. Three different plants (weld, Persian berries, and Brazilwood) were chosen as representative sources of natural dyes. High-performance liquid chromatography (HPLC) and triple-quadrupole mass spectrometry (QqQ MS) were used to identify dyestuffs in the raw extracts. The natural dyes and lake pigments were further characterized...
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Synthetic Principles Determining Local Organization of Copolyesters Prepared from Lactones and Macrolactones
PublikacjaA highly effective and facile technique for catalytic ring-opening copolymerization (cROP) of lactones viz. ε- caprolactone and ε-decalactone with ω-pentadecalactone is being described. The reactions were mediated by Zn- and Cabased tridentate Schiff base complexes and benzyl alcohol as initiator. The catalysts were successfully employed for the preparation of numerous block and random copolymers. To unravel the composition of...
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Fabrication and photoactivity of organic-inorganic systems based on titania nanotubes and PEDOT containing redox centres formed by different Prussian Blue analogues
PublikacjaHerein, the heterojunction composed of an inorganic substrate: ordered hydrogenated titania nanotubes (H-TiO2NTs) and a deposited organic film: poly(3,4-ethylenedioxythiophene) (PEDOT) is reported. The conducting polymer is modified with different transition metal haxacyanoferrates (Mehcf), wherein as metal: copper, iron, cobalt and nickel are introduced. The presence of various metal centres provides characteristic redox activity...
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The impact of thermomechanical and chemical treatment of waste Brewers’ spent grain and soil biodegradation of sustainable Mater-Bi-Based biocomposites
PublikacjaDue to the massive plastic pollution, development of sustainable and biodegradable polymer materials is crucial to reduce environmental burdens and support climate neutrality. Application of lignocellulosic wastes as fillers for polymer composites was broadly reported, but analysis of biodegradation behavior of resulting biocomposites was rarely examined. Herein, sustainable Mater-Bi-based biocomposites filled with thermomechanically-...
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Structure-rheology relationship of fully bio-based linear polyester polyols for polyurethanes - Synthesis and investigation
PublikacjaThe synthesis of polyols from renewable substances as an alternative for petrochemical-based polyols play important matter in the polyurethane industry. In this work, the fully bio-based linear polyester polyols with different catalyst amounts were synthesized via two-step polycondensation method. The effect of various catalyst content on the structure and rheological behavior were established. Fourier Transform Infrared Spectroscopy,...
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Adsorption-assisted transport of water vapour in super-hydrophobic membranes filled with multilayer graphene platelets
PublikacjaThe effects of confinement of multilayer graphene platelets in hydrophobic microporous polymeric membranes are here examined. Intermolecular interactions between water vapour molecules and nanocomposite membranes are envisaged to originate assisted transport of water vapour in membrane distillation processes when a suitable filler-polymer ratio is reached. Mass transport coefficients are estimated under different working conditions,...
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The Effect of Polyurethane Glycolysate on the Structure and Properties of Natural Rubber/Carbon Black Composites
PublikacjaIn this work the use of polyurethane chemical recycling product (i.e. glycolysis of polyurethane waste realized with the mass excess of polymer) as a plasticizer for natural rubber-based composites was proposed. The effect of plasticizer type (napthenic oil and polyurethane foam glycolysate) and amount (2, 4, 6 or 8 parts per 100 parts of natural rubber) on the processing properties of rubber mixtures and chemical structure, swelling,...
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Preparation and characterization of dummy-template molecularly imprinted polymers as potential sorbents for the recognition of selected polybrominated diphenyl ethers
PublikacjaThe main aim of this work was to conduct the preliminary/basic research concerning the preparation process of a new dummy molecularly imprinted polymer (DMIP) materials. Developed DMIPs were proposed as a sorption material in solid-phase extraction (SPE) technique for recognition of selected low mass polybrominated diphenyl ethers (PBDEs) e PBDE-47 and PBDE-99. Four new DMIPs were synthesized employing bulky polymerization technique...
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Development of an asymmetric cellulose acetate-ionic liquid P6,6,6,14[PHOS] gel membrane for the perstraction of succinic acid from a model fermentation solution of yarrovia lipolytica
PublikacjaThis study introduces a novel approach to separate succinic acid (SA) from fermentation mixtures using an asymmetric membrane based on the gelation of the ionic liquid [P6,6,6,14][PHOS] coated with two layers of cellulose acetate. The membrane was designed to explore the synergistic effect of polymer-ionic liquid interfaces according to the solution-diffusion theory. The gelation of the ionic liquid was achieved using 12-hydroxystearic...
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Solid-Contact Ion-Selective Electrodes with Highly SelectiveThioamide Derivatives of p-tert-Butylcalix[4]arene for theDetermination of Lead(II) in Environmental Samples
PublikacjaThioamide derivatives of p-tert-butylcalix[4]arene were used as ionophores in the development of solid-contact ion-selective electrodes based on conducting polymer poly(3,4-ethylenedioxythiophene)/polystyrene sulfonate (PEDOT/PSS) which was synthesized by electrodeposition on the glassy carbon electrodes. The typical ion-selective membranes with optionally two different plasticizers [bis(2-ethylhexyl)sebacate (DOS) and 2-nitrophenyl...
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The use of chain extenders as processing aids in the valorization of single-use polylactide (PLA) products by rotomolding
PublikacjaBiodegradable plastics in single-use products have increased in popularity as a way to reduce the negative environmental impact of conventional plastics and meet the tightening law regulations. However, their recyclability needs to be assessed, as the environmental behavior of single-use plastics, even if compostable, is not negligible. Polylactide (PLA) is susceptible to thermal, oxidative, hydrolytic, and mechanical degradation...
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Synthesis and structural characterization of bio-based bis(cyclic carbonate)s for the preparation of non-isocyanate polyurethanes
PublikacjaBio-based cyclic carbonates are of significant research interest as monomers for non-isocyanate polyurethane (NIPU) synthesis. This research describes the synthesis of a series of five-membered bis(cyclic carbonate)s using bio-based polyether polyols (PO3G) with different molecular weights (250, 650 and 1000 g mol−1) and carbon dioxide as green feedstocks. The utilization of CO2 as a source of carbon in the chemical reaction is...
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Thermal properties. DSC analysis of poly(xylitol sebacate-co-butylene sebacate) PXBS.
Dane BadawczeIn this work, a bio-based copolyester with good mechanical properties was synthesized andcharacterized in terms of structure, main properties and biodegradability Determining the chemicalstructure of such materials is important to understand their behavior and properties. Performingan extraction of insoluble cross-linked polymer using di erent solvents...
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Polymer biodegradable coatings as active substance release systems for urological applications
PublikacjaCatheter-associated urinary tract infections are the result of catheterization of the bladder. The risk of infection is directly proportional to the length of the bladder catheterization. Bacteria cells have the ability to adhere and create the biofilm on the surface of catheter materials. Bacteria’s biofilm is an extremely beneficial environment of existence for microorganisms. Microorganisms that are an integral part of the biofilm...
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Effect of ground tire rubber on structural, mechanical and thermal properties of flexible polyurethane foams
PublikacjaFlexible polyurethane foams were modified with two kinds of ground tire rubber, untreated and thermo-mechanically reclaimed. A reclamation process was performed in auto-thermal conditions, which reduced the cost of the process and decreased the environmental impact of devulcanization (e.g., emission of gases). The reclamation process was carried out in a continuous manner using a co-rotating twin screw extruder. The foams were...
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The potential of LC–MS technique in direct analysis of perfume content
PublikacjaPerfumes are products that consist of a wide range of natural and synthetic compounds. Due to complex composition, the determination of their ingredients is a difficult task. Most of the perfume components are either volatile or semi-volatile; however, most of the attention has been paid to volatile ones, and thus, gas chromatography or electronic noses are generally used. Nevertheless, in this study, liquid chromatography coupled...
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Usuwanie lotnych związków organicznych z fazy gazowej z zastosowaniem cieczy jonowych
PublikacjaUżycie cieczy jonowej do usuwania LZO jest limitowane przez rozpuszczalność usuwanych związków. Dane literaturowe sugerują, że ciecze jonowe jako faza membranowa mogą być z powodzeniem stosowane do selektywnej separacji węglowodorów aromatycznych z mieszanin węglowodorów aromatycznych i alifatycznych. Przedmiotem pracy było kompleksowe opisanie procesu separacji LZO z fazy gazowej z uwzględnieniem czynników wpływających na efektywność...
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Simple synthesis route for fabrication of protective photo‐crosslinked poly(zwitterionic) membranes for application in non‐enzymatic glucose sensing
PublikacjaThis work focuses on the fabrication of non-enzymatic glucose sensing materials based on laser-formed Au nanoparticles embedded in Ti-textured substrates. Those materials possess good catalytic activity toward glucose oxidation in 0.1 × phosphate buffered saline as well as resistance to some interferants, such as ascorbic acid, urea, and glycine. The electrodes are further coated with three different polymers, that is, Nafion,...
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PLA–Potato Thermoplastic Starch Filament as a Sustainable Alternative to the Conventional PLA Filament: Processing, Characterization, and FFF 3D Printing
PublikacjaThe growing popularity of the fused filament fabrication (FFF) 3D printing technology in science, industry, and in-home use is associated with an increased demand for high-quality polymer filaments. This study presents an in-depth characterization and analysis of a self-made bio-based polylactide (PLA)/thermoplastic potato starch (TPS) filament dedicated for the FFF 3D printing technology. The obtained results were compared with...
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The influence of the type of composition of PVA-chitosan blends on stability at elevated temperature
Dane BadawczeThe dataset shows the results of a visual evaluation of chitosan and polyvinyl alcohol composites. The composites were prepared by combining chitosan water solutions, dissolved in selected acids, and polyvinyl alcohol solution, freeze drying, and heating at 150°C dry composites. The results confirm that the chitosan / PVA composites, in which the first...
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A novel method for drop in drop edible oils encapsulation with chitosan using a coaxial technique
Dane BadawczeThe dataset present a novel one step method for oil encapsulation. In this coaxial system the oil constitutes the core of the capsule, while the chitosan solution is the polymer shell surrounding the core to provide separation of the core from the external environment. In comparison to other encapsulation methods, the presented technique is much simpler...
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Wave propagation signals for ultrasonic tomography of concrete during splitting
Dane BadawczeThe DataSet contains the results of the mechanical behaviour of a concrete cube with dimensions 70 x 70 x 70 cm3under the splitting test. Three cubes were tested: cube 1 (concrete with polymer fibres), cube 2 (concrete with steel fibres) and cube 3 (plain concrete).
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Enhancing the Seismic Resistance of Columns by GFRP Confinement Using Flexible Adhesive-Experimental Study
PublikacjaIn this paper, the results of two experiments, focused on testing the effectiveness of a method of enhancing the seismic (dynamic) resistance of masonry columns with the use of flexible polymer adhesive, are shown. The first experiment was devoted to investigate the damping properties of a polymer working between two stiff layers, whereas the aim of the second one was to verify if the identified damping properties of the polymer...
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Polymer electrolytes with ionic liquids
PublikacjaSolid polymer electrolytes are solutions of salts in the macromolecular polymeric compound. Excellent process ability, flexibility, non-flammability and non-reactivity make them ideal materials for electrochemical devices. The problem in their use is limited conductivity. It increases with increasing salt concentration in the polymer, but at the same time the condition is to increase the glass transition temperature of the polymer...
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How Chain Transfer Leads to a Uniform Polymer Particle Morphology and Prevents Reactor Fouling
PublikacjaABSTRACT: The effect of adding diethyl zinc as a chain transfer agent during the polymerization of propylene in heptane performed at 80 °C was studied. Although it was expected that the chain transfer would stop after precipitation of the polymer, the polymer molecular weight continued to increase throughout the whole of the polymerization. The presence of diethyl zinc had an additional effect that the polymerizations were devoid...
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Surface modifcation of PMMA polymer detected by XPS
Dane BadawczeIn order to obtain the experimental specimens, four PMMA/PC61BM samples with the following mass proportions were prepared: 10%, 20%, 30%, and 40%. In addition, as a reference, a PMMA sample without PC61BM was prepared as well. For the fabrication process, PC61BM 99.5% (Solenne BV), chloroform HPLC (Sigma Aldrich), and PMMA (commercially available...
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The innovative approach for using pavement as a fire prevention measure in tunnels
PublikacjaThe paper consists of two main parts: first presents study regarding the typically used pavement structures in tunnels and the second part: the first fire trials of the poroelastic SEPOR (Safe, Eco-friendly POroelastic Road Surface) mixture which was designed to be used among other uses in tunnels. In the first part of the paper different pavement materials, such as cement concrete, asphalt concrete, stone mastic asphalt and porous...