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Wyniki wyszukiwania dla: fluoride ion
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Azomacrocyclic derivatives of imidazole: synthesis, structure, and metal ion complexation properties
PublikacjaOtrzymano nowe azokorony zawierające resztę imidazolu w makropierścieniu. Na drodze sprzęgania z solami diazoniowymiotrzymano pochodne imidazolu 2-metylo, 4-metylo oraz 4-fenyloimidazolu. Synteza była prowadzona w warunkach wysokiego ciśnienia. Dla 21-członowej pochodnej 4-metyloimidazolu określono strukturę jej adduktu z wodą przy pomocy metod rentgenograficznych.Zdolność kompleksowania jonów metali badano spektrofotometrycznie...
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Aquatic biomass containing porous silica as an anode for lithium ion batteries
PublikacjaA composite electrode was manufactured by pyrolysis of Red Algae (Polysiphonia fucoides) covered by diatoms (Diatomophyceae). Electrodes were tested as a half cell with capacity of 500 mA h g−1 after 80 cycles. XPS analysis shows formation of lithium silicate under reduction of silica in an aprotic electrolyte containing LiPF6 salt.
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Silicon Oxycarbide (SiOC) Ceramic Materials as Anodes for Lithium Ion Batteries
PublikacjaPolymer derived ceramics (PDCs) have attracted attention as alternative anode material for Li-ion batteries. It has been found that ternary SiOC and SiCN ceramics obtained through pyrolysis of various preceramic polymers display high reversible capacities of 500 – 650 mAh/g. In this work we try to correlate the electrochemical performance of polymer derived silicon oxycarbide with its chemical composition and microstructural features....
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Functionalized azobenzocrown ethers as sensor materials—The synthesis and ion binding properties
PublikacjaNew 13- and 16-membered azobenzocrown ethers with aromatic amino, amide, ether–ester or ether–amide residue in para position to an azo moiety were obtained. Acid–base properties and ion binding ability of the colored compounds were studied by spectroscopic methods: UV–vis, fluorimetry and 1H NMR spectroscopy. Selected azobenzocrowns were tested as ionophores in ion-selective membrane electrodes (ISEs) – classic and miniature all...
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Is the Solid Electrolyte Interphase an Extra-Charge Reservoir in Li-Ion Batteries?
PublikacjaAdvanced metal oxide electrodes in Li-ion batteries usually show reversible capacities exceeding the theoretically expected ones. Despite many studies and tentative interpretations, the origin of this extra-capacity is not assessed yet. Lithium storage can be increased through different chemical processes developing in the electrodes during charging cycles. The solid electrolyte interface (SEI), formed already during the first...
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Charge dependence of fragmentation process induced by ion collisions with furan molecule
PublikacjaThe goal of this work is to describe the system evolution after ion-molecule interaction. We combine different quantum chemistry and statistical mechanics approaches in order to give extended description of the process. Herein we report on a recent study of the fragmentation mechanism of neutral, singly- and doubly-ionized furan molecule in the gas phase.
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Structural and Transportation Properties of Strontium Titanate Composites with Ion Conductive Oxides
PublikacjaThis paper has been written based on the author’s doctoral dissertation “Structural and transportation properties of strontium and titanate composites with ion conductive oxides”, prepared under the supervision of Prof. Dr. Hab. Eng. Bogusław Kusz at the Department of Solid State Physics of Gdańsk University of Technology. It reports the idea of the thesis and conclusions from the study. Niobium doped strontium titanate (Sr(Ti,Nb)O3)...
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Advanced Lithium-Ion Battery Model for Power System Performance Analysis
PublikacjaThe paper describes a novel approach in battery storage system modelling. Different types of lithium-ion batteries exhibit differences in performance due to the battery anode and cathode materials being the determining factors in the storage system performance. Because of this, the influence of model parameters on the model accuracy can be different for different battery types. These models are used in battery management system...
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Mobile Gas Chromatographs Coupled with Mass and Ion Mobility Spectrometers and their Applications
PublikacjaThe articles describes the developments un combining of mass and ion mobility spectrometers (MS, IMS0 with miniature gas chromatographs (GC). The examples of applications of miniaturised GC-MS and GC-IMS devices are presented.
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Signature of Oxide-Ion Conduction in Alkaline-Earth-Metal-Doped Y3GaO6
PublikacjaWe have studied alkaline-earth-metal-doped Y3GaO6 as a new family of oxide-ion conductor. Solid solutions of Y3GaO6 and 2% −Ca2+-, −Sr2+-, and −Ba2+-doped Y3GaO6, i.e., Y(3−0.06)M0.06GaO6−δ (M = Ca2+, Sr2+, and Ba2+), were prepared via a conventional solid-state reaction route. X-ray Rietveld refined diffractograms of all the compositions showed the formation of an orthorhombic structure having the Cmc21 space group. Scanning electron...
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DIAGNOSES MADE BY LEADERS OF EMERGENCY MEDICA L SERVICES TEAMS WITHIN THE OPERAT ION AREA OF THE EMERGENCY MEDICA L SERVICES STAT ION IN MINSK MAZOWIECKI IN 2013-2017
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Uncertainty of Postmortem Time Estimation Based on Potassium Ion Determination in Vitreous Humor Using Potentiometric Ion-Selective Electrode and Microwave-Induced Plasma with Optical Emission Spectrometry Methods
PublikacjaThere is a need for a reliable and independent evaluation and confirmation of the post-mortem interval (PMI) based on objective factors other than only postmortem changes or temperature measurements. Estimating the PMI by examining the concentration of potassium ions in the vitreous humor (VH) has a tradition in forensic toxicology dating back to the mid-20th century. So far, the methods for determining the presence of potassium...
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The description of non-linear interactions of wave and non-wave modes in a non-adiabatic plasma flow
PublikacjaThe method of derivation of non-linear equations for interacting modes is explained and applied to a plasma's flow affected by a magnetic field. It is based on the linear projecting of the total perturbation field into specific variations of variables in individual modes of a flow. The method may be applied in many examples of fluid flows with different mechanisms of non-adiabaticity. It is of special importance in complex flows...
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Interferon lambda polymorphisms associate with body iron indices and hepatic expression of interferon-responsive long non-coding RNA in chronic hepatitis C
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Identification of Non-stationary and Non-linear Drying Processes
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Hollow carbon sphere/metal oxide nanocomposites anodes for lithium-ion batteries
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A review on the critical challenges and progress of SiOx-based anodes for lithium-ion batteries
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Solid-phase microextraction and ion chromatographic analysis of anions based on polypyrrole electrode
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Cell Membrane Transport Mechanisms: Ion Channels and Electrical Properties of Cell Membranes
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Poly(3-octylthiophene) as solid contact for ion-selective electrodes: contradictions and possibilities
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Gold-modified paper as microfluidic substrates with reduced biofouling in potentiometric ion sensing
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Structural and mechanical properties of hydroxyapatite coatings formed by ion-beam assisted deposition
PublikacjaThe ion-beam assisted deposition (IBAD) is an advanced method capable of producing crystalline coatings at low temperatures. We determined the characteristics of hydroxyapatite Ca10(PO4)6(OH)2 target and coatings formed by IBAD using X-ray photoemission spectroscopy (XPS), X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM) and energy dispersive X-ray (EDX). The composition of the coatings'...
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Determination of Selected Organic Acids in Animal Farm Water Samples by Ion Chromatography
PublikacjaLow molecular mass carboxylic acids (LCAs) occur in many environmental compartments due to natural processes and human activity. They are an important group of organic pollutants of waste water that mainly includes, volatile fatty acids, and also dicarboxylic, aromatic, hydroxy- and ketoacids. LCAs are present in the environment at concentrations between 1 to 5000 ppm and different methods have been reported for their determination...
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Tailoring of SiOC composition as a way to better performing anodes for Li-ion batteries
PublikacjaPolymer derived silicon oxycarbide (SiOC) ceramics are investigated as potential anodes for lithiumion batteries. Different SiOC ceramics are prepared by pyrolysis (1000 °C and 1400 °C under controlled argon atmosphere) of polysiloxanes ceramic precursors. Preceramic polymers are synthesized using the sol–gel method. Phenyltriethoxysilane (PhTES) and methyltriethoxysilane (MTES) have been used as starting precursors and mixed with...
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Synthesis and application of tetrazole di and triamide derivatives in ion-selective membrane electrodes
PublikacjaA number of tetrazole diamides and triamides have been synthesized and applied as ion carries in ion-selective membrane electrodes. Their selectivity and sensitivity were studied towards alkali, alkaline earth, transition and heavy metal cations. it was found that membranes doped with 3 and 2-nitrophenyl octyl ether exhibit an almost theoretial Nernstian response for NH+ over relatively wide concentration range. Elestrodes with...
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Lignin-based carbon fibers for renewable and multifunctional lithium-ion battery electrodes
PublikacjaLignin-based carbon fibers (LCFs) from the renewable resource softwood kraft lignin were synthesized via oxidative thermostabilization of pure melt-spun lignin and carbonization at different temperatures from 1000°C to 1700°C. The resulting LCFs were characterized by tensile testing, scanning electron microscopy (SEM), X-ray diffraction (XRD) and confocal Raman spectroscopy. The microstructure is mainly amorphous carbon with some...
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Binder-induced surface structure evolution effects on Li-ion battery performance
PublikacjaA comparative investigation on binder induced chemical and morphological evolution of Li4Ti5O12 electrodes was performed via X-ray photoemission spectroscopy, scanning electron microscopy, and electrochemical measurements. Composite electrodes were obtained using three different binders (PAA, PVdF, and CMC) with 80:10:10 ratio of active material:carbon:binder. The electrochemical performances of the electrodes, were found to be...
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Determination of cyanide in urine and saliva samples by ion chromatography with pulsed amperometric detection
PublikacjaCommonly known as a highly toxic chemical, cyanide is also an essential reagent for many industrial processes. It naturally occurs in plant seeds as a cyanogenic glycosides. Another relatively common mode of cyanide exposure is inhalation of environmental tobacco smoke. This study concerns importance to determine cyanide ion in human biological samples. Urine and saliva samples were collected healthy volunteers exposed to tobacco...
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Diatoms Biomass as a Joint Source of Biosilica and Carbon for Lithium-Ion Battery Anodes
PublikacjaThe biomass of one type cultivated diatoms (Pseudostaurosira trainorii), being a source of 3D-stuctured biosilica and organic matter—the source of carbon, was thermally processed to become an electroactive material in a potential range adequate to become an anode in lithium ion batteries. Carbonized material was characterized by means of selected solid-state physics techniques (XRD, Raman, TGA). It was shown that the pyrolysis...
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Potentiometric Solid-Contact Ion-Selective Electrode for Determination of Thiocyanate in Human Saliva
PublikacjaA new solid-contact potentiometric ion-selective electrode for the determination of SCN− (SCN-ISE) has been described. Synthesized phosphonium derivative of calix[4]arene was used as a charged ionophore. The research included selection of the ion-selective membrane composition, determination of the ISEs metrological parameters and SCN-ISE application for thiocyanate determination in human saliva. Preparation of the ISEs included...
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Ion Chromatography with Pulsed Amperometric Detection for Determining Cyanide in Urine and Meconium Samples
PublikacjaThe parents’ addictions and eating habits have a significant influence on the child’s growth. The first stool of a newborn baby provides a large amount of information about xenobiotics transmitted by the mother’s body. The analytical technique used in the study is ion chromatography with pulsed amperometric detection (IC-PAD). The biological samples, which were obtained from women staying in a maternity ward and their partners,...
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Li nucleation on the graphite anode under potential control in Li-ion batteries
PublikacjaApplication of Li-ion batteries in electric vehicles requires improved safety, increased lifetime and high charging rates. One of the most commonly used intercalation anode material for Li-ion batteries, graphite, is vulnerable to Li nucleation, a side reaction which competes with the intercalation process and leads to loss of reversible capacity of the battery, ageing and short-circuits. In this study, we deploy a combined grand...
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Tin Oxide Encapsulated into Pyrolyzed Chitosan as a Negative Electrode for Lithium Ion Batteries
PublikacjaTin oxide is one of the most promising electrode materials as a negative electrode for lithium-ion batteries due to its higher theoretical specific capacity than graphite. However, it suffers lack of stability due to volume changes and low electrical conductivity while cycling. To overcome these issues, a new composite consisting of SnO2 and carbonaceous matrix was fabricated. Naturally abundant and renewable chitosan was chosen...
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Con l’introduzione
PublikacjaNata nel 1953 con l’obiettivo di portare l’Italia tra le nazioni avanzate anche in campo energetico, Eni rappresenta una delle principali imprese ad aver influenzato l’innovazione economica del Paese. La sua storia, legata a doppio filo alla figura di Enrico Mattei, consente di seguirne le traiettorie di sviluppo e le strategie di internazionalizzazione, nel quadro di un contesto in continua evoluzione. Questo volume ripercorre...
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Composites of tin oxide and different carbonaceous materials as negative electrodes in lithium-ion batteries
PublikacjaAbstract Tin and tin oxide have been considered as suitable materials with high theoretical capacity for lithium ion batteries. Their low cost, high safety and other technical benefits placed them as promising replacements for graphite negative electrodes. The problem to overcome with tin oxide, as well as with other metallic materials, is high volume changes during alloying/dealloying, subsequent pulverization, delamination from...
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Carbon nanotubes decorated by mesoporous cobalt oxide as electrode material for lithium-ion batteries
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Fabrication of 3D graphene/MoS2 spherical heterostructure as anode material in Li-ion battery
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Well-Designed Porous Graphene Flakes for Lithium-Ion Batteries with Outstanding Rate Performance
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Selective Synthesis of Magnetite Nanospheres with Controllable Morphologies on CNTs and Application to Lithium‐Ion Batteries
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Could graphene construct an effective conducting network in a high-power lithium ion battery?
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Porphyrazines Peripherally Functionalized with Hybrid Ligands as Molecular Scaffolds for Bimetallic Metal-Ion Coordination
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Ion-selective electrodes based on p-tert-butyl-homooxacalixarene di(ethyl) amides
PublikacjaPochodne dietyloamidowe p-tert-butylodihomooksakaliks[4]arenu (1), p-tert-butyloheksahomotrioksakaliks[3]arenu (2) oraz p-tert-butylokaliks[4]arenu (3) były wykorzystane jako materiał aktywny w membranach elektrod jonoselektywnych w celu sprawdzenia detekcji kationów różnych rodzajów (Na+, K+, Cs+, Mg2+, Ca2+, Mn2+, Cu2+, Zn2+, Cd2+, Pb2+ oraz kation tetrametyloammoniowy). Wyznaczono charakterystyki elektrod oraz współczynniki...
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Lithium ion insertion into poly(3,4-ethylenedioxythiophene) films from propylene carbonate electrolytes.
PublikacjaPolimerowa matryca złożona z poli(3,4-etylenodioksytiofenu z poli(styrenosulfonianem) otrzymana została na drodze syntezy elektrochemicznej. Transport jonowy w matrycy polimerowej w kontakcie z węglanem propylenu zawierającym LiClO4 został scharakteryzowany za pomocą metody impedancji ac oraz chronowoltoamperometrii. Wyznaczono przewodność jonową matrycy oraz efektywne współczynniki dyfuzji dla kationu Li+. Wielkości te...
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Evaluation, Pitfalls and Recommendations for the “Water Layer Test” for Solid Contact Ion‐selective Electrodes
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Ion-selective electrodes based on p-tert-butyl-homooxacalixarene di(ethyl)amides
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Comparison of Ion Chromatography and Isotachophoresis for the Determination of selected Anions in Atmospheric Wet Deposition Samples
PublikacjaW pracy przedstawiono porównanie wyników oznaczenia zawartości wybranych anionów w próbkach opadów atmoferycznych z zastosowaniem technik izotachoforezy i chromatografii jonowej. Na podstawie otrzymanych wyników można stwierdzić, że technika chromatografii jonowej charakteryzuje się niższymi wartościami granic wykrywalności i oznaczalności, szerokim zakresem pomiarowym i możliwością oznaczania analitów w próbkach o róznym składzie...
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Nonlinear Impedance as Possible Result of Ion-Polaron Interaction in Cu2O-Al2O3-SiO2 Glass
PublikacjaNonlinear a.c. impedance measurements were performed in Cu2O-Al2O3-SiO2 glass in wide frequency range. The obtained results shows that a large nonlinearity in the impedance signal is observed at moderate electric fields of an order 1V/mm. The contents of the third harmonics reaches about 10% and strongly depends on temperature and frequency. The investigated glass exhibits mixed electronic-ionic conductivity. Electronic conduction...
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Determination of Formaldehyde and Cyanide Ion in Human Nasal Discharge by Using Simple Spectrophotometric Methods
PublikacjaEnvironmental tobacco smoke (ETS) contains many toxic compounds which include substances classified as aldehydes (e.g. formaldehyde) and inorganic substances such as cyanide ions. The information on the determination of these compounds in water is available, but the monitoring data on the level of these substances in human body fluids are still lacking. In this work the procedure for determining cyanide ions and formaldehyde in...
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The influence of nanostructures size on V2O5 electrochemical properties as cathode materials for lithium ion battery
PublikacjaIn this paper, V2O5 nanostructures with a size depending on the annealing temperature are successfully synthesized by a sol-gel method. The crystal structure and morphology of samples are characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), selected area electron diffraction (SEAD) and scanning electron microscopy (SEM), respectively. Electrochemical testing such...
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Hebb–Wagner polarization method for determining the oxygen ion conductivity in barium cerate-zirconate
PublikacjaIn this work, the partial conductivity of oxygen ions in BaCe0.6Zr0.2Y0.2O3 was studied at different temperatures and water partial pressures. For this purpose, a modified DC Hebb–Wagner polarization method with an electrode blocking for protons and electrons was used. A new type of measuring cell as well as a suitable calculation model were proposed for the determination of partial oxygen ionic conductivity in materials with three...