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Wyniki wyszukiwania dla: cation substitution
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Improvement of electrochemical action of zinc-rich paints by addition of nanoparticulate zinc
PublikacjaThe influence of nanosized particles on electrochemical action of standard zinc-rich paints by means of SEM as well as potential and impedance measurements has been investigated. The motivation for doing this was to obtain additional electrical connection between the spherical microparticles themselves and zinc particles and steel substrate. Overall zinc content was at the level of 92% by weight. Samples with different concentration...
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Thermal self-action effects of acoustic beam in a vibrationally relaxing gas
PublikacjaThermal self-action of acoustic beam in a molecular gas with excited internal degrees of molecules’ freedom, is studied. This kind of thermal self-action differs from that in a Newtonian fluid. Heating or cooling of a medium takes place due to transfer of internal vibrational energy. Equilibrium and non-equilibrium gases, which may be acoustically active, are considered. A beam in an acoustically active gas is self-focusing unlike...
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State Interventionism in Tax System - Example of Action in a COVID-19 Crisis
PublikacjaThe following article presents and classifies changes in tax systems of selected countries as well as counts them as the response to the emergence of the crisis caused by the COVID-19 pandemic. Such actions were undertaken the context of state interventionism in the tax system. In order to achieve the objective of presenting the state interventionism in the context of tax rates, an analysis of the literature on the phenomenon described,...
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Optical Spectroscopic Studies of Tetrahydrofuran Fragmentation Induced by Collisions with Dihydrogen Cations
PublikacjaCollisions of dihydrogen cations with tetrahydrofuran molecules have been studied. Luminescence spectra and the emission functions of the excited products at projectile energies ranging from 8 to 1000 eV have been measured using collision-induced emission spectroscopy. The recorded spectra are dominated by the atomic lines of the hydrogen Balmer series, whose intensities decrease more quickly than derived by the quantum-theoretical...
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EFFECT OF ANTIOXIDANTS ON THE STABILITY OF PITCH- BASED POLYMER TO THERMO-OXIDATIVE ACTION
PublikacjaThe influence of stabilizers – hydrogen donors – on the processes of thermooxidative destruction of pitch-based polymer has been investigated. It is shown that Irganox has not stabilizing effect on pitch-based polymer and melamine slightly retards the destructive process. A mixture of melamine and Irganox exhibits synergetic stabilizing effect and at the optimum ratio it can be used to prevent unwanted thermooxidative processes...
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Heterostructure based on exfoliated graphitic carbon nitride coated by porous carbon for photocatalytic H2 evolution
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Using of carbon nanotubes and nano carbon black for electrical conductivity adjustment of pressure-sensitive adhesives
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Effect of nanosized carbon black on thermal stability and flame retardancy of polypropylene/carbon nanotubes nanocomposites
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Catalytic carbonization of polypropylene by the combined catalysis of activated carbon with Ni2O3 into carbon nanotubes and its mechanism
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Recent advances in carbon-based renewable adsorbent for selective carbon dioxide capture and separation-A review
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A Noded Carbon Emission Tool (NCET) to Measure Embodied Carbon (EC) in Compositional Cementitious Materials
PublikacjaThe ever evolving modern construction industry is now producing the highest levels of carbon content adversely affecting the construction associated environment. Although, the impact of carbon induced emission is quite large, but still not enough measurable standards and tools to scale these emission are available. This study contributes to the body of knowledge by providing a Grasshopper based definition to calculate the embodied...
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Electrochemical performance of MOF-5 derived carbon nanocomposites with 1D, 2D and 3D carbon structures
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Mechanical Properties of Twisted Carbon Nanotube Bundles with Carbon Linkers from Molecular Dynamics Simulations
PublikacjaThe manufacturing of high-modulus, high-strength fibers is of paramount importance for real-world, high-end applications. In this respect, carbon nanotubes represent the ideal candidates for realizing such fibers. However, their remarkable mechanical performance is difficult to bring up to the macroscale, due to the low load transfer within the fiber. A strategy to increase such load transfer is the introduction of chemical linkers...
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Determination of carbon monoxide, methane and carbon dioxide in refinery hydrogen gases and air by gas chromatography
PublikacjaW pracy przedstawiono metodę oznaczania śladowych zawartości tlenku węgla, metanu oraz dwutlenku węgla w rafineryjnych gazach wodorowych oraz powietrzu; granica oznaczalności metody wynosi odpowiednio 0,15, 0,15 oraz 0,20 mikro-gram/litr. Zaprezentowano w pracy prostą modyfikację chromatografu gazowego wyposażonego w detektor płomieniowo-jonizacyjny (FID). Zastosowano kolumnę typu PorapakQ, dodatkowo połączono szeregowo z krótką...
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Silicon polypodands: powerful metal cation complexing agents and solid–liquid phase-transfer catalysts of new generation
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Structure and characterization of physicochemical and magnetic properties of new complex containing monobridged oxygen copper(II) dinuclear cation
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Structure, Physicochemical and Biological Properties of an Aqua (2,2′,2′′-Nitrilotriacetato)-oxidovanadium(IV) Salt with 4-Methylpyridinium Cation
PublikacjaThe crystal structure of a nitrilotriacetate (nta) oxidovanadi-um(IV) salt with 4-methylpyridinium cation, [4-Me(Py)H]+, of [4-Me(Py)H][VO(nta)(H2O)] stoichiometry was determined. The com-plex comprises a discrete mononuclear [VO(nta)(H2O)]–coordinationentity that can be rarely found among other known compounds con-taining nitrilotriacetate oxidovanadium(IV) moieties. The complex wascharacterized by spectroscopic (IR and EPR) methods,...
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The anion [Mg6Cl8Cp*5]-: a final intermediate on the way to the molecular donor-free Grignard compound MgClCp*?
PublikacjaOtrzymano i scharakteryzowano strukturalnie rzadki przypadek związku Grignarda pozbawionego donora. Struktura krystaliczna [Mg6Cl8Cp*5][AlCp*2] C6H6 zawiera zarówno metallocen (Cp*AlCp*) jak i odwrócony metallocen (MgCp*Mg).
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Elimination of metal catalyst and carbon-like impurities from single-wall carbon nanotube raw material
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Nanoconfinement Induced Formation of Core/Shell Structured Mesoporous Carbon Spheres Coated with Solid Carbon Shell
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Graphitic Carbon Nitride and Titanium Dioxide Modified with 1 D and 2 D Carbon Structures for Photocatalysis
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Mesoporous carbon/graphitic carbon nitride spheres for photocatalytic H2 evolution under solar light irradiation
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Regulation of carbon catabolism in Lactococcus lactis
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Filling of carbon nanotubes for bio‐applications
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Geo-location of the commune of an IP user
PublikacjaThis paper describes a system of geo-location of an IP user that would enable VoIP users to call 112. Basic requirement is fast (under 50ms) determination of the commune of the subscriber. To obtain as accurate information as possible aggregation of several methods was proposed: using a database of locations of IP ranges created by specialized companies, traceroute using history of user locations to assume his current one.It is...
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Studies on the Preparation and Characterisation of Carbon Nanostructures
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Ecotoxicity of selected carbon-based nanomaterials
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Interdependence of Ratios in Banking Stability Pentagon
PublikacjaThe banking sector is one of the key sectors in every economy, therefore, the issue of stability is one of the main interests not only of researchers but also policy-makers. The stability of the banking sector is especially important during a process of transformation. The aim of this article is to present a new tool for estimating the stability of the banking sector as a whole. Although the tool can be used to estimate the level...
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On the plastic buckling of curved carbon nanotubes
PublikacjaThis research, for the first time, predicts theoretically static stability response of a curved carbon nanotube (CCNT) under an elastoplastic behavior with several boundary conditions. The CCNT is exposed to axial compressive loads. The equilibrium equations are extracted regarding the Euler–Bernoulli displacement field by means of the principle of minimizing total potential energy. The elastoplastic stress-strain is concerned...
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Functionalization of carbon encapsulated iron nanoparticles
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Optoelectronic properties of curved carbon systems
PublikacjaSystematic investigation of optoelectronic properties of curved carbon systems has been performed and the results have been compared with the representatives of flat carbon systems. Moreover, the application of third order dispersion corrected density functional tight binding method (with third order corrections of self-consistent charges) including Becke-Johnson dumping (DFTB3-D3(BJ)) has been validated in order to obtain reliable...
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Dynamical objectivity in quantum Brownian motion
PublikacjaClassical objectivity as a property of quantum states —a view proposed to explain the observer-independent character of our world from quantum theory, is an important step in bridging the quantum-classical gap. It was recently derived in terms of spectrum broadcast structures for small objects embedded in noisy photon-like environments. However, two fundamental problems have arisen: a description of objective motion and applicability...
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Vision-based motion analysis of kitesurfer
PublikacjaKitesurfing is a relatively recent phenomenon with raising popularity worldwide – a recently developed extreme water sport considered a high-risk injury sport. It combines elements of several other sports, in particular sailing, surfing, windsurfing, wakeboarding, and snowboarding. The main purpose of authors’ research in the present paper is to use a vision system technique for measuring a kitesurfer’s body movements in order...
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Advancements in Diamond-Like Carbon Coatings
PublikacjaAn essential resource for engineers and scientists in the coatings field, providing an in-depth examination of current and advanced technologies for industrially oriented nanoceramic and nanocomposite coatings
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Influence of the wall on vertical bubble motion
PublikacjaZaprezentowano model siły odpychającej, działającej na kulę podczas przepływu wzdłuż ściany pionowej. Modelowana siła ma charakter okresowy. Uzyskano satysfakcjonującą zgodność pomiędzy zmierzoną i obliczoną wartością tej siły.
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A note on the pseudoinverse approach to estimating ratios.
PublikacjaArtykuł dotyczy metody porównań parami, stosowanej w metodzie AHP w celu uszeregowania skończonej liczby czynników. Do rozwiązania problemu stosowane są głównie trzy techniki estymacji macierzy ocen za pomocą macierzy ilorazów. Autorzy stosują metodę logarytmicznych najmniejszych kwadratów, ponieważ pozwala na rozwiązanie zagadnienia z brakującymi danymi oraz pokazują pewne wybrane własności rozwiązania. Zamieszczono przykładowe...
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Carbon isotope effect in superconducting MgCNi_3
PublikacjaPodstawienie izotopu węgla 13C w związku MgCNi_3 obniża temperaturę przejścia nadprzewodzącego o 300mK. Wyliczony na tej podstawie wspolczynnik izotopowy alfa(C) wynosi 0.54, co silnie potwierdza fononowy charakter nadprzewodnictwa.
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Simplified algorithm for location service for the UMTS
PublikacjaPrzedstawiono uproszczony algorytm lokalizowania terminala ruchomego w systemie UMTS. Algorytm ten umożliwia wyznaczanie pozycji geograficznej terminala ruchomego bez znajomości różnic czasowych w synchronizacji stacji bazowych RTD (Relative Time Differences). Opisany został model symulacyjny oraz przedstawiono wyniki efektywności lokalizowania terminala ruchomego w środowisku tzw. złym miejskim. otrzymane rezultaty dowodzą, że...
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Modelling of bubble motion in vicinity of the wall
PublikacjaArtykuł skupiony jest na analizie odchylenia trajektorii cząstki stałej (modelowanej kulą) na skutek obecnosci ścianki kanału. Przebadano eksperymentalnie trzy wymiary cząstek. W wyniku redukcji danych doświadczalnych wyprowadzono korelację opisującą oddziaływanie ścianki na ruch pojedynczej cząstki.
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Evaluation of Analytes Characterized with Potential Protective Action after Rat Exposure to Lead
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Studies of the complex formation between some proton sponges and Cu(II) cations
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Chromatographic behaviour of ionic liquid cations in view of quantitative structure-retention relationship
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Isothiocyanates as effective agents against enterohemorrhagic Escherichia coli: insight to the mode of action
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Various modes of action of dietary phytochemicals, sulforaphane and phenethyl isothiocyanate, on pathogenic bacteria
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Action of an Antiserum to a-Tocoquinone on Photosystem II-Particle Preparations of N icotiana tabacum
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Collision-induced luminescence spectra of pyridine bombarded by 1000 eV He+ cations
PublikacjaHere we show collision-induced luminescence spectra measured for collisions of the He+cations with thearomatic six-membered ring of the pyridine molecule (C5H5N). Distinct emission bands due to the CH(A2Δ→X2Πr;B2Σ+→X2Πr;C2Σ+→X2Πr), CN(B2Σ+→X2Σ+), C2(d3Πg→a3Πu), and NH(A3Π→X3Σ−) transitions, aswell as atomic H, He, and C lines have been observed. Apart from the He atoms, all the emitters arise from thefragmentation of the pyridine...
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Chain Action - How Do Countries Add Value Through Digital Government?
PublikacjaThis study examineshow countries develop and benefit from Digital Government(DG).The literature proposes various conceptualizations of the value-adding logic of DG, but the benchmarking practice is not respondingto such proposals.For instance, the United Nations’E-Government Surveycombines the readiness and uptake indicatorsand failsto cover any impactindicators;thus,its diagnostic valueis limited. To overcome...
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Solvation of multivalent cations in methanol - apparent molar volumes, expansibilities, and isentropic compressibilities
PublikacjaWyznaczono gęstości roztworów trifluorometanosulfonianów galu, itru, lantanu, gadolinu i lutetu w metanolu w zakresie temperatur (283.15 to 313.15) K. Zmierzono prędkości dźwięku dla tych układów w temperaturze T = 298.15 K. Z uzyskanych danych wyznaczono standardowe cząstkowe objętości molowe i ich pochodne temperaturowe oraz standardowe cząstkowe molowe ściśliwości adiabatyczne badanych jonów. Wyniki omówiono stosując klasyczny...
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Study of pozzolanic action of ground waste expanded perlite by means of thermal methods
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The community involvement of courts: an action research study in the context of the Polish justice system
PublikacjaPurpose – As a rule, common courts are hermetic organizations, separated from their stakeholders by procedures based on legal provisions. For these reasons, they are often perceived as unreliable and non-transparent, and as such, they do not inspire trust among stakeholders. The authors posit that the court’s community involvement may lead to the increased accountability and legitimacy of courts, which should in turn result in...