Wyniki wyszukiwania dla: NIOBIUM-DOPED
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SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF NIOBIUM-DOPED HYDROXYAPATITE CERAMICS
PublikacjaHydroxyapatite (HAp) ceramic materials are considered as one of the most promising implant materials in bone surgery and in dentistry. They exhibit unique biocompatibility, bioactivity, and osteoconductivity, which are the most desirable biomaterial features. However, HAp itself is brittle, has low strength, high degree of crystallinity and low solubility at physiological pH. Doping synthetic HAp with metal ions plays an important...
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Structural investigations of niobium-doped bioactive calcium-phosphate glass-ceramics by means of spectroscopic studies
PublikacjaSynthetic calcium-phosphate based glasses and glass-ceramics play a crucial role in the development of tissue engineering. These materials have a high biocompatibility with biological analogues, excellent ability to undergo varying degrees of resorbability and due to their non-toxicity and relatively high bioactivity they are commonly used as bone and dental implants. A substantial research effort is devoted to improve synthetic...
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Two-step synthesis of niobium doped Na–Ca–(Mg)–P–Si–O glasses
PublikacjaNiobium doped biosolubility glasses in the Na–Ca–(Mg)–P–Si–O system were prepared by using an untypical two-step synthesis route. The parent glass was melted in air atmosphere at 1350 °C followed by re-melting the glass in Nb crucible with the addition of metallic Mg/Ca powder in the nitrogen atmosphere. The second melting step was carried out at 1450–1650 °C, using an induction furnace. The topography and structure of the obtained...
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Superconductivity in the niobium-rich compound Nb5Se4
PublikacjaThe niobium rich selenide compound Nb5Se4 was synthesized at ambient pressure by high-temperature solid–state reaction in a sealed Ta tube. Resistivity and heat capacity measurements reveal that this compound is superconducting, with a Tc = 1.85K. The electronic contribution to the specific heat γ and the Debye temperature are found to be 18.1 mJmol−1K−2 and 298 K respectively. The calculated electron-phonon coupling constant λep...
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Impedance Studies of Phosphate-iron Glasses Containing Niobium and Titanium
PublikacjaThe ac and dc conductivity in phosphate-iron-niobate glasses with addition of titanium oxide was investigated as a function of temperature and frequency with the use of impedance spectroscopy. The topography and microstructure of glasses were investigated by the means of X-ray diffraction (XRD), scanning electron microscopy (SEM), and confocal microscopy methods. The obtained results show that all samples are amorphous but they...
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Topography of iron-phosphate glasses doped with niobium and titanium tested by confocal microscope
Dane BadawczeThe topography of phosphate-iron glasses containing niobium and titanium were investigated with the use of confocal miscroscope. Glass samples of the composition of 35P2O5-30Fe2O3-35Nb2O5, 35P2O5-30Fe2O3-27.5Nb2O5-7.5TiO2 and 35P2O5-30Fe2O3-20Nb2O5-15TiO2 (in %mol) were prepared by the conventional melt quenching technique. Appropriate amounts of reagents...
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Degradacja stali austenitycznej stabilizowanej niobem.
PublikacjaAnalizowano mikrostrukturę i rozmieszczenie powierzchniowe pierwiastków stopowych w warstwach wierzchnich rur z żarowytrzymałej stali austenitycznej X6CrNiNb18-10 po długotrwałej eksploatacji.
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Optical transmission of the Niobium thin films
Dane BadawczeNiobium thin films with a thickness of 200nm were deposited n a Corning glass substrate by magnetron sputtering method. The optical transmission spectra in a visible light range were.recorded. Investigations showed a good optical transmission thru the layers for each samples, annealed at various temperatures. For measurements samples annealed at 500,...
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Doped-TiO2 :a review
PublikacjaTlenek tytanu(IV) jest efektywnym fotokatalizatorem do oczyszczania wody i powietrza oraz w powierzchniach samoczyszczących. TiO2 wykazuje stosunkowo wysoką reaktywność i stabilność chemiczną pod wpływem promieniowania UV, którego energia jest większa od pasma wzbronionego (3,3 eV dla czystego anatazu). Opracowanie metody otrzymywania fotokatalizatora wykazującego wysoką reaktywność pod wpływem światła widzialnego pozwoli na wykorzystanie...
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Nano - and microcrystals of doped niobates
PublikacjaPublikacja przedstawia wyniki analizy pomiarów wysokotemperaturowej rentgenografii strukturalnej niobanu lantanu domieszkowanego magnezem.
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Comparison of the paracetamol electrochemical determination using boron-doped diamond electrode and boron-doped carbon nanowalls
PublikacjaTwo different type of electrodes, boron-doped diamond electrode (BDD) and boron-doped carbon nanowalls (B:CNW) electrode, were used for the electrochemical determination of paracetamol using the cyclic voltammetry and the differential pulse voltammetry in phosphate buffered saline, pH = 7.0. The main advantage of these electrodes is their utilization without any additional modification of the electrode surface. The peak current...
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PROPERTIES OF DOPED ALKALINE-EARTH STANNATES
PublikacjaThe lanthanum doped barium stannate properties are investigated in this work. Including electrical and microstructural properties.
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Superconductivity and ferromagnetism in Pd doped Y9Co7
PublikacjaThe ferromagnetic superconductor Y9Co7 was chemically doped to yield the solid solution Y9Co7-xPdx for 0 < x < 0.4. The lattice parameter a does not depend on x, whereas c increases with increasing Pd content up to x ¼ 0.2, the palladium solubility limit. The transition from ferromagnetism (TC ¼ 4.25 K) to superconductivity (Tsc ¼ 2.4 K) was observed only for the parent Y9Co7 compound. For the lowest tested Pd doping level (x ¼...
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Equation of state for Eu-doped SrSi2O2N2
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Luminescence of LiBaF3 and KMgF3 doped with Eu2+
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The upper critical field in doped MgCNi3
PublikacjaDyskutowany jest wpływ domieszkowania MgCNi3 na górne pole krytyczne (H_c2). H_c2 monotonicznie maleje wraz ze wzrostem koncentracji domieszki. Silniejszy wpływ widoczny w przypadku domieszkowania Fe może być tłumaczony poprzez efekt rozrywania nadprzewodzących par Coopera poprzez centra magnetyczne tworzone przez domieszki Fe.
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Fabrication of La-Doped Bi4Ti3O12 Ceramics
PublikacjaLa-modified Bi4Ti3O12 is a typical ferroelectric, piezoelectric and electro-optic material, having relatively low coercive field, low dielectric constant, high Curie temperature and high breakdown strength. Goal of the present research was to apply mixed oxide method for fabrication of BiTLax ceramics, study its chemical composition, crystalline structure and microstructure. The compound BiTLax for x=0, 0.25, 0.5, 0.75 ceramic...
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Odporność kawitacyjna stali 2H13 przetapianej wiązką lasera i stopowanej niobem
PublikacjaPrzedstawiono badania odporności kawitacyjnej stali 2H13 po dwóch wariantach obróbki laserowej. W pierwszym wariancie powierzchnie stali przetapiano wiązką lasera CO2, a w drugim powierzchnie wzbogacano Nb w ilości 5% masowego.
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Topography and microstructure of phosphate-iron glasses containing niobium and titanium
Dane BadawczeThe topography and microstructure of phosphate-iron glasses containing niobium and titanium were investigated by the means of X-ray diffraction (XRD), scanning electron microscopy (SEM). Glass samples of the composition of 35P2O5-30Fe2O3-(35-x)Nb2O5-xTiO2 where x= 0; 7.5 and 15 (in %mol) were prepared by the conventional melt quenching technique. Appropriate...
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Correlation between structural and electrical properties in highly porous (Y,Sr)(Ti,Nb)O3-delta SOFC anodes
PublikacjaIn order to find a relationship between structural and electrical properties, niobium and yttrium doped SrTiO3 ceramics were prepared via solid-state reaction. The samples were sintered in hydrogen and air conditions. The samples were also fabricated with a pore-former to obtain highly porous specimens. The electrical properties of Nb-doped SrTiO3 samples and yttrium and niobium co-doped SrTiO3 were compared. The comparable electrical...
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Cerium-doped orthophosphates: new promising scintillators
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Raman Study on Doped Multiwalled Carbon Nanotubes
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High pressure spectroscopy of chromium doped LiTaO3crystals
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Spectroscopic properties of the Ce-doped borate glasses
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Electrical and structural properties of Nb-doped SrTiO3
PublikacjaNiobium-doped strontium titanate synthesized via conventional solid-state reaction has been studied. Influence of niobium content on the lattice parameters and electrical conductivity has been reported. Various reduction conditions have been investigated. For samples reduced in hydrogen at 1400°C, a transition from thermally activated to metallic behavior has been observed. Maximum electrical conductivity (ca. 55 Scm−1 at 650°C)...
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Heteropolyanions doped polyimine—Preparation and spectroscopic properties
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Non-adiabatic superconductivity in the electron-doped graphene
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Production and characterization of MWBNNT and B-doped SWCNT
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Visible light photoactivity and structure of doped TiO2
PublikacjaOmówiono strukturą i właściwości TiO2 domieszkowanego siarką, węglem oraz borem. Aktywność fotokatalityczna zbadano w reakcji degradacji fenolu pod wpływem światła z zakresu widzialnego (l > 400 nm). Aktywność fotokatalizatorów odniesiono do ich właściwości takich jak powierzchnia właściwa, struktura krystaliczna oraz charakter chemiczny domieszki. Stwierdzono, że fotokatalizatory o najwyższej aktywności mają strukturę anatazu...
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Photocatalytic performance of alkali metal doped graphitic carbon nitrides and Pd-alkali metal doped graphitic carbon nitride composites
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Investigation of manganese-doped iron ammonia synthesis catalysts
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Electrical properties of nanocrystalline Sm-doped ceria ceramics
PublikacjaWłaściwości ceramiki z cerii zależa zwykle silnie od struktury ziaren. W pracy przedstawiono właściwości elektryczne ceramiki z cerii domieszkowanej samarem wykonanje w technologii 'net shape' posiadającej strukturę nanokrystaliczną.
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Nanodiamonds Doped with Manganese for Applications in Magnetic Resonance Imaging
PublikacjaNanodiamonds (NDs) are emerging with great potential in biomedical applications like biomarking through fluorescence and magnetic resonance imaging (MRI), targeted drug delivery, and cancer therapy. The magnetic and optical properties of NDs could be tuned by selective doping. Therefore, we report multifunctional manganese-incorporated NDs (Mn-NDs) fabricated by Mn ion implantation. The fluorescent properties of Mn-NDs were tuned...
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DFT studies of the refractive index of boron-doped diamond
PublikacjaThe density functional theory is one of the optimal solutions in calculation of optical properties of materials on the quantum scale. In this paper, we have investigated the refractive index of a boron-doped diamond structure with the usage of Atomistic Toolkit software from Synopsys. During this study, various methods and pseudopotentials were checked to obtain an optimal performanceaccuracy method for calculation of such materials....
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Structural and electrical properties of titanium-doped yttrium niobate
PublikacjaIn this work, the influence of the substitution of niobium by titanium in Y3Nb1-xTixO7-δ on the structural and electrical properties is reported. Several experimental techniques, i.e. X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), X-Ray Photoelectron Spectroscopy (XPS) and Electrochemical Impedance Spectroscopy (EIS), were applied to investigate the system Y3Nb1-xTixO7-δ. Titanium in Y3Nb1-xTixO7-δ is an acceptor-type...
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Boron doped carbon nanotubes via ceramic catalysts
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Absence of superconductivity in fluorine-doped neptunium pnictide NpFeAsO
PublikacjaX-ray diffraction, specific heat, magnetic susceptibility and inelastic x-ray scattering measurements on the transurarium oxypnictides NpFeAsO and NpFeAsO0.85F0.15 are presented. No superconductivity down to 2 K was observed upon fluorine doping, contrary to the structurally analogous rare-earth pnictides. No modification of the phonon density of states was observed upon doping with fluorine. We discuss our results in light of...
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WEAR OF Si OR B DOPED AMORPHOUS CARBON COATINGS
PublikacjaThe paper describes a complex wear research on DLC (amorphous carbon) moped with boron (B) and silicone (Si). The tests were carried out in two different sliping systems: flat–on–flat (ring contact, unidirectional sliding) and ball–on–flat (reciprocating sliding). Water and medical saline solutions were used as lubricants. A comparative analysis of the results revealed differences in the initiation and progress of wear and the...
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THE PROPERTIES OF NANOSILVER – DOPED NANOHYDROXYAPATITE COATING ON THE Ti13Zr13Nb ALLOY
PublikacjaThe aim of this research was to study the properties of nanohydroxyapatite (nanoHAp) and nanohydroxyapatite, doped with nanosilver (nanoHAp/nanoAg), coatings obtained by an electrophoretic deposition process. The suspensions was prepared by dispersing 0.1 g of HAp nanopowder for nanoHAp coatings and 0.1 g of nanoHAp and 0.025 g nanoAg for nanoHAp/nanoAg coatings. The deposition was carried out for 1 min at 50 V voltage followed...
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Luminescence and Luminescence Kinetics of Gd3Ga5O12Polycrystals Doped with Cr3+and Pr3+
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High Pressure Spectroscopy of Ce Doped Yag Crystal
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Dosimetric features of strontium orthosilicate (Sr2SiO4) doped with Eu2+
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Infrared Stimulated Luminescence of Ce3+ Doped YAG Crystals
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Heteropolyanion-doped polypyrrole as catalyst for ethyl alcohol conversion
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Study of radioluminescence in LiMgPO4 doped with Tb, B and Tm
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H3PMo12O40-doped polyacetylene as a catalyst for ethyl alcohol conversion
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Heteropolyanions doped polyacetylene—Preparation, spectroscopic and catalytic properties
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Electrical and structural properties of Nb-doped SrTiO3 ceramics
PublikacjaPrzebadano wpływ zawartości niobu na strukturę i własności elektryczne tytanianu strontu. Zbadany został wpływ warunków redukcji i porowatości na właściwości materiału. Za optymalne uznano domieszkowanie niobem w wysokości 2% molowych.
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Optimization of microstructure and properties of acceptor-doped barium cerate
PublikacjaThe presented research concerns acceptor doped barium cerate and the attempts of improvement of its production method that would allow obtaining the solid electrolyte characterized by the particular properties. The authors suggest combining two production methods, molten salt synthesis and self-combustion, in order to achieve the compound material that has some of the advantages of both of the initial methods. An impact of nickel...
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Preparation and photocatalytic activity of B-doped titanium dioxide
PublikacjaOtrzymano TiO2 domieszkowany borem, aktywny w reakcjach fotodegradacji pod wpływem światła widzialnego (λ>400 nm). Fotokatalizatory otrzymano poprzez hydrolizę tytanianu(IV) izopropylu w obecności związków boru lub poprzez ucieranie ST-01 z prekursorami B i następnie kalcynację w temperaturze 450stC. Jako źródło boru zastosowano kwas borowy (0,5 i 10%wag.) lub trietylo ester kwasu borowego (0,5; 1; 5 i 10%wag.). Najwyższą aktywność...