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Search results for: POLARIZATION AND SPECTROSCOPIC ANALYSIS
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Modeling of selected transducer designs for optical pressure sensors using polarization interferometry
PublicationW artykule przedstawiono wyniki modelowania metodą Elementów Skończonych wybranych konstrukcji membran do zastosowań w interferometrycznych czujnikach ciśnienia. Omówiono zależność prametrów membran od kształtu membrany, jej wymiarów i zastosowanego materiału. Zakres odkształcen badanych membran jest niezbyt duży, co może pogarszać dokładność pomiaru czujników ciśnienia, w których będą one stosowane Omówiono kierunki dalszych...
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Structural investigations of niobium-doped bioactive calcium-phosphate glass-ceramics by means of spectroscopic studies
PublicationSynthetic calcium-phosphate based glasses and glass-ceramics play a crucial role in the development of tissue engineering. These materials have a high biocompatibility with biological analogues, excellent ability to undergo varying degrees of resorbability and due to their non-toxicity and relatively high bioactivity they are commonly used as bone and dental implants. A substantial research effort is devoted to improve synthetic...
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FTIR- SPECTROSCOPIC CHARACTERISTICS OF THE DZHAKSY-KLYCH DEPOSIT SALTS
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Effect of ectoine on hydration spheres of peptides–spectroscopic studies
PublicationIn this paper, we use FTIR spectroscopy to characterize the hydration water of ectoine, its interactions with two peptides–diglycine and NAGMA, and the properties of water molecules in the hydration spheres of both peptides changed by the presence of the osmolyte. We found that the interaction of ectoine with the peptide hydration shells had no effect on its own hydration sphere. However, the enhanced hydration layer of the osmolyte...
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Heteropolyanions doped polyacetylene—Preparation, spectroscopic and catalytic properties
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Fe3–xInSnxO6 (x = 0, 0.25, or 0.5): A Family of Corundum Derivatives with Sn-Induced Polarization and Above Room Temperature Antiferromagnetic Ordering
PublicationThree new double corundum derivative compounds, Fe3−xInSnxO6 (x = 0. 0.25, or 0.5), were synthesized at high pressure and temperature (6 GPa and 1400− 1450 °C). All of the compounds order antiferromagnetically well above room temperature (TN = 608, 532, and 432 K for x = 0, 0.25, and 0.5, respectively). The x = 0 phase crystallizes as centrosymmetric R3̅c, but the inclusion of closed-shell d10 Sn4+ induces x = 0.25 and 0.5 to crystallize...
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Novel Coplanar-Strip-Based Excitation Technique for Design of Broadband Circularly Polarization Antennas with Wide 3-dB Axial Ratio Beamwidth
PublicationIn this paper, a novel excitation technique for design of a single-point-fed compact low-profile wide-slot antennas with broadband circular polarization (CP) and wide 3 dB axial ratio (AR) beamwidth is presented. Two inverted L-shape parasitic strips placed coplanar to the microstrip line of an asymmetric CPW, and a horizontal strip that protrudes from the vertical edge of the backside ground plane of the substrate are used for...
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A BODIPY‐Based Molecular Rotor in Giant Unilamellar Vesicles: A Case Study by Polarization‐Resolved Time‐Resolved Emission and Transient Absorption Spectroscopy
PublicationBODIPY and BODIPY-derived systems are widely applied as fluorophores and as probes for viscosity detection in solvents and biological media. Their orientational and rotational dynamics in biological media are thus of vital mechanistic importance and extensively investigated. In this contribution, polarization-resolved confocal microscopy is used to determine the orientation of an amphiphilic BODIPY-cholesterol derivative in homogeneous...
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Corrosion monitoring by harmonic analysis in aqueous environments
PublicationThis paper presents tests concerning the rate of corrosion in non-alloy steel (type S235JR) in an aqueous environment, with an additive of sodium chloride by means of polarization resistance measurements and harmonic analysis. The tests have been carried out for steel samples exposed to the testing environment for six weeks, in order to obtain a constant rate of corrosion in the function of time. The measurements have aimed at...
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FTIR spectroscopic and thermogravimetric characterization of ground tyre rubber devulcanized by microwave treatment
PublicationIn this work, the phenomena involved in the microwave devulcanization of ground tyre rubber (GTR) were investigated. Three types of GTR with different content of organic compounds (elastomers, plasticizers, etc.), carbon black and ash have been studied. The chemical structure of GTR before and after a microwave devulcanization process was analyzed by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA)...
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Spectroscopic properties and energy level location of Eu2+ in Sr2Si5N8 phosphor
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Spectroscopic and quantum chemical study of phthalocyanines with 1,4,7-trioxanonyl moieties
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Spectroscopic investigation of hydrothermally synthesized zeolites from expanded perlite
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Low-temperature spectroscopic and scintillation characterisation of Ti-doped Al2O3
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Raman spectroscopic study of Ni2+-DNA interactions in aqueous systems
PublicationMetodą ramanowskich widm różnicowych określono sposób oddziaływania jonu Ni2+ z DNA(CT) w układach wodnych. Kation Ni(II) koordynuje w pozycjach N7 guaniny (G) i adeniny (A) w powtarzających się sekwencjach GG, AA i GA cząsteczki DNA. Jednocześnie Ni2+ oddziałuje zewnątrz sferowo poprzez cząsteczki wody z grupami fosforanowymi DNA.
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Spectroscopic investigations into degradation of polymer membranes for fuel cells applications
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Doping-Induced Immobile Charge Carriers in Polyazomethine: A Spectroscopic Study
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Spectroscopic and Physicochemical Investigations of Azomethines with Triphenylamine Core towards Optoelectronics
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Spectroscopic and photophysical properties of ZNTPP in a room temperature ionic liquid
PublicationThe steady-state absorption and emission spectra and the time-resolved Soret- and Q-band excited fluorescence profiles of the model metalloporphyrin, ZnTPP, have been measured in a highly purified sample of the common room temperature ionic liquid, [bmim][PF(6)]. S(2)-S(0) emission resulting from Soret-band excitation behaves in a manner completely consistent with that of molecular solvents of the same polarizability. The ionic...
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Cobalt(II) silanethiolato complexes with dimethylpyridines:crystal structures and spectroscopic studies
PublicationTri-tert-butoksysilanotiolany kobaltu(II) z 2,5-dimetylopirydną, 3,4-dimetylopirydną i 3,5-dimetylopirydną jako dodatkowymi ligandami zostały zsyntetyzowane w reakcji z bimetalicznym [Co{SSi(OtBu)3}(NH3)]2 z odpowiednią pochodną pirydyny. Kompleksy zostały zcharakteryzowane za pomocą rentgenografii strukturalnej, analizy elementarnej, spektroskopii FT-IR oraz UV-vis. Prezentowane kompleksy są cztero- i pięciokoordynacyjne o rdzeniu...
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Spectroscopic Optical Coherence Tomography for Thin Layer and Foil Measurements
PublicationThe main goal of this research was to assess if it is possible to evaluate the thickness of thin layers (both thin films on the surface and thin layers below the surface of the tested object) and foils using optical coherence tomography (OCT) for thickness assessment under the resolution of the standard commercially available OCT measurement system. In the proposed solution, light backscattered from the evaluated thin layer has...
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Local Dye Concentration and Spectroscopic Properties of Monomer−Aggregate Systems in Hybrid Porous Nanolayers
PublicationAnalysis of absorption, fluorescence, and time-resolved emission spectra of rhodamine 6G in hybrid porous nanolayers at high dye concentration allowed identification of two fluorescent species: monomers and fluorescent aggregates. The method of determination of mean local concentration of aggregates in matrices is proposed based on the energy transfer process between monomers and fluorescent aggregates. Evaluation of aggregate...
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Synthetic, Structural, and Spectroscopic Characterization of a Novel Family of High-Spin Iron(II) [(β-Diketiminate)(phosphanylphosphido)] Complexes
PublicationThis work describes a series of iron(II) phosphanylphosphido complexes. These compounds were obtained by reacting lithiated diphosphanes R2PP(SiMe3)Li (R = t-Bu, i-Pr) with an iron(II) β-diketiminate complex, [LFe(μ2-Cl)2Li(DME)2] (1), where DME = 1,2-dimethoxyethane and L = Dippnacnac (β-diketiminate). While the reaction of 1 with t-Bu2PP(SiMe3)Li yields [LFe(η1-Me3SiPPt- Bu2)] (2), that of 1 with equimolar amounts of i-Pr2PP(SiMe3)Li,...
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Electrochemical behaviour of Cr coating in acidic sulphate solution studied by cyclic polarization and impedance spectroscopy
PublicationOdporność korozyjną powłok chromowych w 0.01 M H2SO4 zbadano metodami woltamperometrii cyklicznej i spektroskopii impedancyjnej. Stwierdzono, że właściwości ochronne powłoki chromowej w kontakcie z powietrzem wzrastają dzięki tworzeniu się warstwy tlenkowej zapełniającej defekty w powłoce. W trakcie polaryzacji anodowej następuje częściowe roztwarzanie tej warstwy i penetracja agresywnego środowiska do podłoża (stali), co powoduje...
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Reflection properties and lasing modes in the H-polarization case for an infinite chain of dielectric and silver nanowires
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Thermal and spectroscopic profiles variation of cold-pressed raspberry seed oil studied by DSC, UV/VIS, and FTIR techniques
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Chromatographic and Spectroscopic Identification and Recognition of Natural Dyes, Uncommon Dyestuff Components, and Mordants: Case Study of a 16th Century Carpet with Chintamani Motifs
PublicationA multi-tool analytical practice was used for the characterisation of a 16th century carpet manufactured in Cairo. A mild extraction method with hydrofluoric acid has been evaluated in order to isolate intact flavonoids and their glycosides, anthraquinones, tannins, and indigoids from fibre samples. High-performance liquid chromatography coupled to spectroscopic and mass spectrometric detectors was used for the identification of...
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Spectroscopic insight into supramolecular assemblies of boric acid derivatives and β-cyclodextrin
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Hybrid carbon-TiO2 spheres: Investigation of structure, morphology and spectroscopic studies
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Spectroscopic Studies of Amino Acid Ionic Liquid-Supported Schiff Bases
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Spectroscopic and microscopic study of Prussian blue film for electrochromic device application
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Indoor atmospheric degradation of historical metal objects studied by spectroscopic techniques
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Interactions in aqueous solutions of K-peptide and DMSO – spectroscopic and calorimetric studies
PublicationIntroduction K-peptide (GILQINSRW) – short 9 amino acid fragment of the hen egg white lysozyme has the ability to form amyloid structures. Dimethyl sulfoxide (DMSO) is an osmolyte which can alter this ability. Our goal was to get an insight into the mechanism of Kpeptide-DMSO interactions in aqueous solutions. Such a knowledge can be helpful to understand processes leading to various neurodegenerative diseases. Methods ATR-FTIR...
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Optical Spectroscopic Studies of Tetrahydrofuran Fragmentation Induced by Collisions with Dihydrogen Cations
PublicationCollisions of dihydrogen cations with tetrahydrofuran molecules have been studied. Luminescence spectra and the emission functions of the excited products at projectile energies ranging from 8 to 1000 eV have been measured using collision-induced emission spectroscopy. The recorded spectra are dominated by the atomic lines of the hydrogen Balmer series, whose intensities decrease more quickly than derived by the quantum-theoretical...
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Evaluation of hydrogen degradation susceptibility of high-strength weldable steel subjected to cathodic polarization in sea-water
PublicationOcenę podatności stali spawalnych o wysokiej wytrzymałości ich złączy spawanych na kruchość wodorową przeprowadzono z wykorzystaniem próby rozciągania ze stałą, niską szybkością odkształcenia w środowisku wody morskiej przy polaryzacji katodowej. Wykonano próby elektrochemiczne przenikania wodoru w wodzie morskiej dla oceny dyfuzji i pułapkowania wodoru. Badano wpływ bakterii redukujących siarczany na absorpcję wodoru w środowisku...
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Synthesis, Structure, and Spectroscopic Properties of Calcium Thiophenecarboxylate Polymers. Structural Comparison with Analogous Lead Complexes
PublicationThree novel calcium coordination polymers [Ca(2tpCOO)2(2mpa)(H2O)]n (1), [Ca(3tpCOO)2(2mpa)(H2O)]n (2), and {[Ca(3tpacCOO)2(H2O)2]⋅⋅⋅H2O}n (3) (2tpCOO− or 3tpCOO− – thiophene-2- or thiophene-3-carboxylate, 3tpacCOO− – thiophene-3-acetate, 2mpa – 2-methylpropanal), were synthesised using a self-assembly method. The obtained polymers were characterised using SC-XRD, FTIR, UV-Vis DRS, thermogravimetric and luminescence analyses. The...
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Informal employment in Poland: an empirical spatial analysis
PublicationThe main goal of our article is to bridge the gap in the regional analysis of informal employment in Poland and in particular to indicate the propensity for informal work in the working-age population, to test if informal activities are typical for marginalized people (less educated, unemployed, older) and to identify the regional and spatial heterogeneity in the propensity. We use data from the ‘Human Capital Balance 2010–2014’...
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The influence of Si4+ co-doping on the spectroscopic properties of β-NaCaPO4:Eu2+/Eu3+
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Crystallographic and spectroscopic studies of 5-arylidene-2-amino-imidazol-4-ones
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Energy shifts of K- and L-lines as spectroscopic diagnostic of Z-pinch plasmas
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Spectroscopic and Spectroelectrochemical Studies on Redox Properties of Zinc Sulfide and Their Consequences on Photocatalytic Activity
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Experimental and theoretical studies of the spectroscopic properties of simple symmetrically substituted diphenylacetylene derivatives
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Cadmium tri-tert-butoxysilanethiolates. Structural and spectroscopic models of metal sites in proteins.
PublicationW publikacji opisano syntezy i struktury dla dwóch heteroleptycznych kompleksów kadmu z rdzeniem CdS2NO2 i CdS2N2. Bis(tri-tert-butoksysilanotiolato)(1-metyloimidazol)kadmu(II) oraz bis(tri-tert-butoksysilanotiolato)bis(1-metyloimidazol)kadmu(II) współistnieją w roztworze chloroformu przy różnych stężeniach Bis(tri-tert-butoksysilanotiolanu) kadmu(II) i 1 metyloimidazolu. Rotzwór ten został scharakteryzowany za pomocą analizy spektralnej...
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Spectroscopic studies of sol-gel derived thin film structures for integrated optics
PublicationPrzedstawiono wyniki badania struktur cienkowarstwowych wykonywanych dla zastosowań w optyce zintegrowanej z polimerów hybrydowych (np. w postaci ścieżek śwaitłowodów planarnych). Jakość i jednorodność stuktur badano za pomocą mikroskopii ramanowskiej, mikroskopii optycznej i profilometrii światła białego. Wykonano porównanie wyników uzyskanych tymi trzema metodami.
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Spectroscopic Methods in the Evaluation of Modified Vegetable Base Oils from Crambe abyssinica
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Spectroscopic Study of Plasma Polymerized a-C:H Films Deposited by a Dielectric Barrier Discharge
PublicationPlasma polymerized a-C:H thin films have been deposited on Si (100) and aluminum coated glass substrates by a dielectric barrier discharge (DBD) operated at medium pressure using C2Hm/Ar (m = 2, 4, 6) gas mixtures. The deposited films were characterized by Fourier transform infrared reflection absorption spectroscopy (FT-IRRAS), Raman spectroscopy, and ellipsometry. FT-IRRAS revealed the presence of sp3 and sp2 C–H stretching and...
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Synthesis and Spectroscopic Characterization of Selected Phenothiazines and Phenazines Rationalized Based on DFT Calculation
PublicationTwo unique structures were isolated from the phosphorylation reaction of 10H-phenothiazine.The 5,5-dimethyl-2-(10H-phenothiazin-10-yl)-1,3,2-dioxaphosphinane 2-oxide (2a) illustrates theproduct of N-phosphorylation of phenothiazine. Moreover, a potential product of 2a instability,a thiophosphoric acid 2b, was successfully isolated and structurally characterized. Molecule 2a,similarly to sulfoxide derivative...
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Comprehensive Spectroscopic Characterization of Finasteride Polymorphic Forms. Does the Form X Exist?
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P3HT:PCBM blend films phase diagram on the base of variable-temperature spectroscopic ellipsometry
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Phase diagram of P3HT:PC70BM thin films based on variable-temperature spectroscopic ellipsometry
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