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Search results for: wet-chemical synthesis
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Identification of chemical pollution problems and causes in the Baltic See in relation to socio-economic drivers
PublicationOpisano możliwość wykorzystania nowego narzędzia do zintegrowanej oceny stanu środowiska w akwenie Morza Bałtyckiego. Takie możliwości stwarza narzędzie znane jako DPSIR czyli Drivers (sfery działalności człowieka będące źródłem potencjalnych zznieczyszczeń)-Pressures (ksenobiotyki i specyficzne czynniki szkodliwe emitowane do środowiska)-Stata (stann środowiska)- Impact (efekty niekorzystego oddziaływania na część ożywioną i nieożywioną...
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Structural, physico-chemical and antioxidant characteristics of 2,2′-bipyridyl(iminodiacetato)oxidovanadium(IV) dihydrate
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Offal Chemical Composition from Veal, Beef, and Lamb Maintained in Organic Production Systems
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Estimation of the environmental risk posed by landfills using chemical, microbiological and ecotoxicological testing of leachates
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Soil chemical properties affect the reaction of forest soil bacteria to drought and rewetting stress
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Chemical composition of edible aerial parts of meadow bistort (Persicaria bistorta (L.) Samp.)
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Matcha Green Tea: Chemical Composition, Phenolic Acids, Caffeine and Fatty Acid Profile
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PHYSICO-CHEMICAL CHARACTERISTICS OF SELECTED HONEYS OF THE WEST POMERANIAN PROVINCE AND THE VALUE OF THEIR PRO-HEALTH
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Characteristics of microstructural phenomena occurring on the surface of protective gloves by the action of mechanical and chemical factors
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Chemical Characteristics and Sensory Evaluation of Raw and Roasted Buckwheat Groats Fermented by Rhizopus Oligosporus
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BelBuk System—Smart Logistics for Sustainable City Development in Terms of the Deficit of a Chemical Fertilizers
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Chemical Composition and Antioxidant Properties of Powders Obtained from Different Plum Juice Formulations
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Effect of chemical structure and deposition method on optical properties of polyazomethines with alkyloxy side groups
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Chemical recycling of plastic waste as a mean to implement the circular economy model in the European Union
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Decision Support System to Improve the Effectiveness of Chemical Control Against Cutworms in Sugar Beet
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Quality of groundwater contaminated by leachates from seven Polish landfills - chemical and ecotoxicological classifications
PublicationArtykuł prezentuje rezultaty badań toksyczności ostrej i chronicznej próbek wód podziemnych pobranych spod składowisk odpadów komunalnych. Uzyskane wyniki porównano z wynikami badań parametrów fizykochemicznych. Jednocześnie dokonano klasyfikacji jakości badanych próbek w oparciu o zalecenia Komisji Helsińskiej, system oparty na wyznaczaniu parametru pT i kryteria ustanowione przez Persoone'a i współpracowników.
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Effect of chemical composition on corrosion and wear behaviour of the composite Ni-Fe-Al2O3 coatings.
PublicationPrzedstawiono wyniki badań powłoki kompozytowej otrzymanej przez osadzanie katodowe galwaniczne w roztworze zawierającym sole niklu, żelaza oraz cząstki ceramiki Al2O3 o różnej wielkości i stężeniu. Wykazano, że charakterystyka ceramiki posiada wpływ na szybkość korozji i zużycia ściernego. W szczególności, zawartość ceramiki wpływa dodatnio na odporność na zużycie ścierne, ale nieco obniża odporność na zużycie korozyjne.
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Effect of glycols used as glycolysis agents on chemical structure and thermal stability of produced glycolysates
PublicationZaprezentowano warunki glikolizy poliuretanowych odpadów piankowych, przy użyciu różnych glikoli oraz wyniki badań budowy chemicznej glikolizatów oraz ich właściwości termicznych.
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Physico-chemical properties of three-component mixtures based on chitosan, hyaluronic acid and collagen
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Changes in Chemical Composition and Accumulation of Cryoprotectants as the Adaptation of Anholocyclic Aphid Cinara tujafilina to Overwintering
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On the Formation of Single-Walled Carbon Nanotubes in Pulsed-Laser-Assisted Chemical Vapor Deposition
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Effect of chemical structure on complexation efficiency of aromatic drugs with cyclodextrins: The example of dibenzazepine derivatives
PublicationIt is widely believed that the hydrophobic effect governs the binding of guest molecules to cyclodextrins (CDs). However, it is also known that high hydrophobicity of guest molecules does not always translate to the formation of stable inclusion complexes with CDs. Indeed, a plethora of other factors can play a role in the efficiency of guest–CD interactions, rendering structure-based prediction of the complexation efficiency with...
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Quality Assurance and Quality Control in the Analytical Chemical Laboratory. A practical approach : Second edition
PublicationThe second edition defines the tools used in QA/QC, especially the application of statistical tools during analytical data treatment. Clearly written and logically organized, it takes a generic approach applicable to any field of analysis. The authors begin with the theory behind quality control systems, then detail validation parameter measurements, the use of statistical tests, counting the margin of error, uncertainty estimation,...
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The Impact of Long-Time Chemical Bonds in Mineral-Cement-Emulsion Mixtures on Stiffness Modulus
PublicationDeep cold in-place recycling is the most popular method of reuse of existing old and deteriorated asphalt layers of road pavements. In Poland, in most cases, the Mineral-Cement-Emulsion mixture technology is used, but there are also applications combining foamed bitumen and cement. Mineral-Cement-Emulsion mixtures contain two different binding agents – cement as well as asphalt from the asphalt emulsion. Asphalt creates asphalt...
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Storm petrels as indicators of pelagic seabird exposure to chemical elements in the Antarctic marine ecosystem
PublicationData on trace element bioavailability in the south-polar marine ecosystem is still scarce, compared to that relating to temperate zones. Seabirds can be used as indicators of ecosystem health and sentinels of environmental pollution, constituting a link between marine and terrestrial environments. Here, we analysed the concentration of 17 elements (with special emphasis on mercury, Hg) in feathers of adults and chicks of two pelagic...
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Synthesis of Titanium Dioxide via Surfactant-Assisted Microwave Method for Photocatalytic and Dye-Sensitized Solar Cells Applications
PublicationIn this study, titania nanoparticles were obtained using the microwave-assisted technique. Moreover, different surfactants (PEG (Mn = 400), Pluronic P123 and Triton X−100) were used during the synthesis in order to determine their impact on the crystallinity and morphology of the final products. Subsequently, techniques such as XRD, SEM and TEM (performed in high contrast and high-resolution mode), diffuse reflectance spectroscopy...
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Novel two-step synthesis method of thin film heterojunction of BiOBr/Bi2WO6 with improved visible-light-driven photocatalytic activity
PublicationA novel two-step ionic liquid assisted procedure was applied for a controllable synthesis of BiOBr/Bi2WO6 heterojunction thin films. The preparation route involved an anodic oxidation of tungsten foil and hydrothermal transformation of as-anodized oxide in the presence of bismuth precursor and ionic liquid, N-butylpyridinium bromide [BPy][Br]. The BiOBr plates with irregular shapes adhered to the surface of flower-like Bi2WO6 and...
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Synthesis, crystal structure and spectroscopic characterization of new anionic iridium(III) complexes and their interaction with biological targets
PublicationThe synthesis and characterisation of new anionic iridium(II) complexes (NH4)2[IrCl4(κ2N,N’-H2biim)]2 · 5H2O (1) and ((CH3)2NH2)[IrCl4(κ2N,N’-PyBIm)] · H2O (2) are presented in this article. Spectroscopic methods (1H, 13C and 15N NMR, FTIR, UV-Vis) were used to characterize these new complexes. Solid-state structural analysis (SC-XRD) of complexes 1 and 2 shows a slightly distorted octahedral geometry of Ir(III) ions, which is...
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Microbial and chemical quality assessment of the small rivers entering the South Baltic. Part II: Case study on the watercourses in the Puck Bay catchment area
PublicationDue to its location, Puck Bay is an area particularly vulnerable to pollution of anthropogenic origin. The aim of the study was to assess the water quality of small watercourses entering the inner part of Puck Bay. The paper presents the results of chemical and microbiological analyses of 10 rivers and canals at their estuaries located on the western shore of the internal Puck Bay. The following environmental parameters were analyzed:...
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Electrochemical synthesis of 2D copper coordination-polymers: Layer-stacking deviation induced by the solvent and its effect on the adsorptive properties
PublicationA 2D Cu-based Metal-Organic Framework (MOF), namely copper-terephthalate (Cu(1,4-BDC)), was successfully synthesized by electrochemical method for effective methylene blue (MB) sorption from aqueous solutions. The composition, morphology, and the presence of functional groups in the obtained material were verified by Fourier Transform Infrared spectroscopy (FTIR), Powder X-Ray Diffraction (PXRD), Thermal (TGA), and Elemental (EA)...
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Synthesis and Characterization of Poly(zwitterionic) Structures for Energy Conversion and Storage
PublicationZwitterions are unique class of molecules that possess two functional groups bearing electric charges, one positive and second negative. This setup results in peculiar properties such as high water retention and anti-fouling capability. Therefore, zwitterionic coatings and gels are commonly applied in e.g. biosensing and bioelectronic devices. Despite those applications, there are other perspectives for zwitterionic materials....
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Design, synthesis, and biological evaluation of tetrahydroquinolinones and tetrahydroquinolines with anticancer activity
PublicationColorectal cancer (CRC) is the most commonly diagnosed cancer in Europe and the United States and the second leading cause of cancer related mortality. A therapeutic strategy used for the treatment of CRC involves targeting the intracellular levels of reactive oxygen species (ROS). In this study, we synthesized a series of novel tetrahydroquinolinones and assessed their ability to inhibit CRC growth and proliferation by evoking...
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Chlorophylls c—Occurrence, synthesis, properties, photosynthetic and evolutionary significance
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Proximity: Synthesis, Six-Dimensional Typology, and Significance for Cooperation Performance
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Microwave solvothermal synthesis and characterization of manganese-doped ZnO nanoparticles
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Synthesis of novel, peptidic kinase inhibitors with cytostatic/cytotoxic activity
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The Influence of Synthesis Temperature on Manufacturing and Properties of SrSi2O2N2:Eu2+ Powders
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Tetrapyrazinoporphyrazine with eight peripheral adamantanylsulfanyl units – Synthesis and physicochemical study
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1,4,7,10-Tetraazacyclododecane incorporating salicyli acid moieties. Synthesis and properties
PublicationPochodne 1,4,7,10-tetraazacyklododekanu są związkami które znalazły szerokie zastosowanie w wielu dziedzinach: medycynie, chemii, farmacji, ochronie środowiska itd. Właściwości fizykochemiczne poszczególnych związków determinowane są przez pierścień makrocykliczny i podstawniki. Kwas salicylowy i salicylamid tworzą kompleksy chelatowe z kationami II grupy jak również z metalami przejściowymi. W reakcji acylowania cyklenu pochodnymi...
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ChemInform Abstract: Novel and Efficient Methods for the Synthesis of Symmetrical Trisulfides.
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Cell-penetrating peptides – mechanism of transduction and synthesis – short review
PublicationPotential antimicrobial agents may be effective if they are delivered efficiently to their site of action. In many cases, lack of permeability through the cell membrane is the main problem. One of the possible solutions could be a novel intracellular delivery system involving cell-penetrating peptides (CPPs), which may improve the efficiency of many new biophar-maceuticals. Among other things, CPPs are capable of trans-porting...
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Synthesis and biological activity of mycophenolic acid-amino acid derivatives
PublicationIn search of new immunosuppressants, mycophenolic acid (MPA) was coupled with amino acid methyl esters followed by hydrolysis to analogs bearing free carboxylic groups. The obtained compunds were tested in vitro as growth inhibitors of lymphoid cell line (Jurkat) and human peripheral blood mononuclear cells (PBMC) from healthy donors. According to obtained results recovering of free carboxylic group increased their activity. Additionally,...
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Thermally Induced Templated Synthesis for the Formation of SiC Nanotubes and more
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Synthesis and structure-activity studies of peptide-acridine/acridone conjugates
PublicationW artykule opisano strukturę, syntezę i biologiczną aktywność peptydowych koniugatów akrydyny i akrydonu jako potencjalnych leków o aktywności przeciwnowotworowej i przeciwwirusowej.
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Synthesis and properties of the double perovskites La2NiVO6, La2CoVO6 i La2CoTiO6
PublicationW publikacji przedstawiono sposób syntezy, analizę dyfrakcji rentgenowskiej (xrd) i badania podatności magnetycznej tzw. podwójnych związków perowskitowych La2NiVO6, La2CoVO6 i La2CoTiO6. Badane związki są półprzewodnikami ze stosunkowo wąską szerokością przerwy energetycznej dla La2NiVO6, La2CoVO6 i nieznacznie powyżej 1 eV powyżej La2CoTiO6.
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Modified polycarbonate urethane: synthesis, properties and biological investigation in vitro
PublicationNowy poliweglano uretan (PCU-I) otrzymano z alifatycznych monomerów: poliwęglanu heksanodiolu, 4,4'diizocyjanianu dicykloheksanometanu, mieszaniny małocząsteczkowych dioli i oleju rycynowego (zawierającego głównie trigliceryd kwasu 12-hydroksyoleinowego). PCU-II otrzymano analogicznie ale bez udziału oleju rycynowego. Obydwa PCU charakteryzowały się dobrą wytrzymałością na rozciąganie. PCU-I miał niższą temperaturę zeszklenia a...
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Synthesis and biological activity of mycophenolic acid-amino acid derivatives
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Motion laws synthesis for cam mechanisms with multiple follower displacement
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The synthesis of motion laws for cam mechanisms with additional movement of the follower
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Study of the Kinetics of Ammonia Synthesis and Decomposition on Iron and Cobalt Catalysts
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