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Search results for: IMMISCIBLE POLYMER BLENDS
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Rheology of polymer blends
PublicationPolymer blends are physical mixtures of two or more homopolymers or copolymers. This type of materials have wide spectrum of technological applications, and their properties are influenced, e.g., by the properties of single components and morphology of final material. The rheology of polymer blends is connected with the processing of polymer blends and is influenced by thermodynamics, morphology, and their evolution during testing....
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Interface analysis of compatibilized polymer blends
PublicationThis chapter seeks to address the interface location in the compatibilized polymer blends and paves the way for quantitative analysis of interface in terms of interfacial tension and interfacial adhesion to provide support for understanding the relationship between morphology and ultimate properties in the compatibilized polymer blends through the lens of interface. Since understanding and analysis of interfacial phenomena in the...
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Synergistic effect of MWCNTs and MA-g-PP on the thermal and viscoelastic properties of immiscible PTT/PP blends
PublicationThe properties of immiscible blends of PTT and PP were modified by grafting and nanoparticle inclusion. The observed synergistic effect of MWCNTs and MA-g-PP on the thermal and viscoelastic properties of PTT/PP blends was studied in detail and the properties of the composites were compared with those of ungrafted PP.
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Reactive extrusion of bio-based polymer blends and composites – Current trends and future developments
PublicationReactive extrusion is a cost-effective and environmentally-friendly method to produce new materials with enhanced performance properties. At present, reactive extrusion allows in-situ polymerization, modification/functionalization of polymers or chemical bonding of two (or more) immiscible phases, which can be carried out on commonly used extrusion lines. Although reactive extrusion has been known for many years, its application...
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Planetary roller extruders in the sustainable development of polymer blends and composites – Past, present and future
PublicationScrew extruders as continuous flow reactors allow the synthesis of new polymers, preparation of polymer blends and composites, and modification or functionalization of commercially available polymers. Literature data shows that the twin screw extrusion is the most popular solution used for this purpose. In contrast, the number of scientific papers on alternative methods, such as multi-screw extruders, is somewhat limited. This...
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Water Footprint Assessment of Selected Polymers, Polymer Blends, Composites, and Biocomposites for Industrial Application
PublicationThis paper presents a water footprint assessment of polymers, polymer blends, composites, and biocomposites based on a standardized EUR-pallet case study. The water footprint analysis is based on life cycle assessment (LCA). The study investigates six variants of EUR-pallet production depending on the materials used. The system boundary included the production of each material and the injection molding to obtain a standardized...
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Phase behavior of π-conjugated polymer and non-fullerene acceptor (PTB7-Th:ITIC) solutions and blends
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Characterization of structure and properties of polymer films made from blends of polyethylene with poly(4-methyl-1-pentene)
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Novel porous carbon/clay nanocomposites derived from kaolinite/resorcinol-formaldehyde polymer blends: synthesis, structure and sorption properties
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Obtaining of Coumarone-Indene Resins Based on Light Fraction of Coal Tar. 4. Bitumen-Polymer Blends with Participation of Coumarone-Indene Resins with Epoxy Groups
PublicationUsing light fraction of coal tar (5.75 wt % of coumarone and 44.45 wt % of indene), glycidyl methacrylate and styrene, the coumarone-indene resin with epoxy groups (CIRE) has been synthesized. Monoperoxy derivative of diglycidyl ether Bisphenol A (PO) was used as an initiator. The possible formation of CIRE has been studied on the model systems consisting of PO, glycidyl methacrylate, indene or coumarone, or styrene, or mixture...
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iPP/HDPE blends compatibilized by a polyester: An unconventional concept to valuable products
PublicationPolyolefins are the most widely used plastics accounting for a large fraction of the polymer waste stream. Although reusing polyolefins seems to be a logical choice, their recycling level remains disappointingly low. This is mainly due to the lack of large-scale availability of efficient and inexpensive compatibilizers for mixed polyolefin waste, typically consisting of high-density polyethylene (HDPE) and isotactic polypropylene...
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Tuning of microstructure in engineered poly (trimethylene terephthalate) based blends with nano inclusion as multifunctional additive
PublicationImmiscible blends and their composites are heterogeneous and have variable morphology due to variation in mesophase regions. Tuning, i.e. controlling the phase dimension is important, thereof we report a “super-combo” effect of multiwalled carbon nanotubes (MWCNTs) in poly (trimethylene terephthalate)/polypropylene (PTT/ PP) blend system. MWCNTs act as a good reinforcing agent and compatibilizer in the otherwise immiscible PTT/...
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Preparation of Well-Compatibilized PP/PC Blends and Foams Thereof
PublicationThe performance of polypropylene-poly(ethylene brassylate) block and graft copolymers and a polypropylene-polycaprolactone graft copolymer as compatibilizers for polypropylene-rich polypropylene/bisphenol A polycarbonate (PP/PC, 80/20 wt/wt) blends was elucidated. The copolymers were synthesized either by metal-catalyzed ring-opening polymerization or transesterification of a presynthesized polyester, initiated by hydroxyl-functionalized...
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Morphology and properties of recycled polyethylene/ground tyre rubber/thermoplastic poly(ester-urethane) blends
PublicationThe growing amount of plastics waste produced every year resulted in development of mechanical and chemical recycling methods of polymers and their blends or composites. From the environmental point of view, the possibility of plastics waste reusing and recycling is desirable. In this study three polymer blends were obtained with using recycled polyethylene (RPE), ground tyre rubber (GTR) and thermoplastic poly(ester-urethane)...
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Proposal of New Starch-Blends Composition Quickly Degradable in Marine Environment
PublicationThe aim of this paper was to obtain a quickly degradable in seawater polymer blend as an alternative proposal for classical polymer packaging. For preliminary studies: poly(lactic acid) (PLA), starch, calcium carbonate (CaCO3), gelatin and glycerol were chosen. PLA was pointed out due to its biodegradability and comparable properties to polyethylene or polypropylene. Whereas starch was chosen as abundant, renewable and cheap polymer...
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Recent Advances in Development of Waste-Based Polymer Materials: A Review
PublicationLimited petroleum sources, suitable law regulations, and higher awareness within society has caused sustainable development of manufacturing and recycling of polymer blends and composites to be gaining increasing attention. This work aims to report recent advances in the manufacturing of environmentally friendly and low-cost polymer materials based on post-production and postconsumer wastes. Sustainable development of three groups...
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The influence of polypropylene-block/graft-polycaprolactone copolymers on melt rheology, morphology, and dielectric properties of polypropylene/polycarbonate blends
PublicationThe paper discusses the relationship between rheology and morphology of immiscible polypropylene (matrix))/polycarbonate (dispersed phase) blends compatibilized with novel polypropylene-polycaprolactone block and graft copolymers. Transmission electron microscopy (TEM) experiments revealed uniform droplet morphologies and a reduction of the average size of the dispersed phase upon addition of the compatibilizer. The results suggested...
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Characterization and properties of LDPE/(ground tire rubber)/crosslinked butyl rubber blends
PublicationIn recent years, interest in used rubber recycling, mainly focusing on the utilization of end-of-life tires, has heightened. This interest, is owing to the activities related to environmental protection and economic factors, which both stimulate companies to reuse the high-quality rubber present in ground rubber scrap. In this study, the application of crosslinked butyl rubber in thermoplastic compositions of low-density polyethylene...
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Morphology, Thermo-Mechanical Properties and Biodegradibility of PCL/PLA Blends Reactively Compatibilized by Different Organic Peroxides
PublicationReactive blending is a promising approach for the sustainable development of bio-based polymer blends and composites, which currently is gaining more and more attention. In this paper, biodegradable blends based on poly(ε-caprolactone) (PCL) and poly(lactic acid) (PLA) were prepared via reactive blending performed in an internal mixer. The PCL and PLA content varied in a ratio of 70/30 and 55/45. Reactive modification of PCL/PLA...
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Recycled Polyurethane as a Second Phase in Thermoset Blends and Its Effect on Thermal Degradation Kinetics Studies
PublicationA new approach is introduced in the modification of thermosetting polymer by using different amount of polyurethane of waste origin. The post consumer polyurethane foam coatings are degraded using glycolysis process and the recycled product is further converted into new polyurethane. The blending of recycled polyurethane with epoxy exhibits transparency and produces nanostructures. The effective interaction between two polymers...
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Polyurethane glycolysate from industrial waste recycling to develop low dielectric constant, thermally stable materials suitable for the electronics
PublicationWe are utilizing a new method to improve the dielectric properties of a conventional polymer using a recycled polymer product. The polyurethane foams are recycled by glycolysis process and the derived material was applied to improve the dielectric properties of the brittle DGEBA epoxy resin. Two main parameters that determine the applicability of the material as a dielectric (the dielectric constant and dielectric loss), were studied...
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Study on polymer modified road asphalt mixture
PublicationThe formulation of ternary asphalt-additives blend composed of crumb rubber : low-density polyethylene (CR : LDPE) and crumb rubber : textile fiber (CR : TF) couples, and quaternary asphalt additives-blend composed of (CR : LDPE : TF) triplets on the virgin asphalt to optimize the asphalt basic and rheological properties and to use the extrusion process of two or three additives to obtain composite materials of them, as well as...
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The possibility of application of the potentiometric sensor with all-solid-state electrodes containing lipid-polymer membranes for classification of tested black leaf teas in terms of their quality
PublicationPotentiometric sensor with all-solid-state electrodes containing lipid-polymer membranes for a set of black leaf teas coming from four countries (China, India, Sri Lanka and Kenia) classification was applied. The tested tea samples were reassigned to quality classes marked with numbers I–V according to the information available. The sensor results of tea samples are presented in the form of radar charts. It was observed that, in...
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Rubber wastes recycling for developing advanced polymer composites: A warm handshake with sustainability
PublicationRecycling and management of rubber wastes experiences an early-stage maturity in the quest for sustainable and circular materials. Up to now, solutions proposed for sustainable development of rubber wastes are limited, so that properties and performance features of recycled products are inadequate for practical applications. Herein, an experimental protocol is introduced for manufacturing semi-sustainable polymer composites based...
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Toward Polyethylene–Polyester Block and Graft Copolymers with Tunable Polarity
PublicationThe synthesis and characterization of polyethylene–polyester block and graft copolymers and their potential as compatibilizers in polyethylene-based polymer blends are being described. The various routes to functionalized polyethylenes and the corresponding block/graft copolymers have been compared and evaluated for their scalability to industrial scale production. Hydroxyl chain-end and randomly OH-functionalized HDPE as well...
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Polyurethanes modified with natural polymers for medical application. I. Polyurethanes/ Chitosan and polyurethane/collagen.
PublicationFor over three decades polyurethanes (PUR or PU) have been reported for application in a variety of medical devices. These polymers consist of hard and soft segments, which allow for more subtle control of their structure and properties. By varying the composition of the different segments, properties of PURcan be tuned up for use in many areas of medicine. Recently there is a great interest in modification of biomedical PUR with...
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Silicon Oxycarbide-Graphite Electrodes for High-Power Energy Storage Devices
PublicationHerein we present a study on polymer-derived silicon oxycarbide (SiOC)/graphite composites for a potential application as an electrode in high power energy storage devices, such as Lithium-Ion Capacitor (LIC). The composites were processed using high power ultrasound-assisted sol-gel synthesis followed by pyrolysis. The intensive sonication enhances gelation and drying process, improving the homogenous distribution of the graphitic...
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New insights on lithium storage in silicon oxycarbide/carbon composites: Impact of microstructure on electrochemical properties
PublicationIn this work, we study the impact of the preceramic precursor vinyltriethoxysilane (VTES) on the electrochemical performance of silicon oxycarbide (SiOC) glass/graphite composites. We apply an innovative approach based on high-power ultrasounds in order to obtain highly homogenous composites with a uniform distribution of small graphitic flakes. This procedure enhances gelation and drying of VTES-based preceramic polymer/graphite...
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Integration of antifouling properties into epoxy coatings: a review
Publicationhe need for nontoxic antifouling coatings has encouraged material scientists to develop a class of organic coatings for diverse applications. As a versatile thermosetting resin and well known for coating application, antifouling characteristics have been integrated into epoxy along with anticorrosion and adhesive functions. Accordingly, both micro- and macro-biofoulings have been successfully controlled by using epoxy-based antifouling...
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Sustainable Chemically Modified Mater-Bi/Poly(ε-caprolactone)/Cellulose Biocomposites: Looking at the Bulk through the Surface
PublicationSustainable polymer composites are progressively under development in a technological paradigm shift from "just use more and more" to "convert into value-added products". The bio-based blends based on Mater-Bi bio-plastic (A) and poly(ε-caprolactone) (B), at a weight ratio of 70:30 (A:B) were developed, followed by the addition of UFC100 cellulose (C) filler to yield 70/30 (w/w) (A:B)/C sustainable biocomposites. The effects of...
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POLYMER TESTING
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POLYMER
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Chitosan-based nanomaterials for removal of water pollutants
PublicationThe rise of micropollutants presents a significant threat to both the environment and human well-being, requiring effective strategies for their mitigation. Chitin serves as the precursor for chitosan, composed of two monomers featuring acetamido and amino groups. Chitosan possesses several noteworthy attributes, including its ability to bind water and fat, humidity content, solubility, consistent molecular weight, and various...
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Ecological Aspects of Polymer Package Recycling
e-Learning CoursesEcological Aspects of Polymer Package Recycling dr hab. inż. Justyna Kucińska-Lipka
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Sustainable chemically modified poly(butylene adipate-co-terephthalate)/thermoplastic starch/poly(ε-caprolactone)/cellulose biocomposites: looking at the bulk through the surface
PublicationSustainable polymer composites (or biocomposites) based on renewable and green polymers are progressively under development in a technological paradigm shift from “just use more and more” to “convert into value-added products”. Therefore, significant efforts should focus not only on their reduced environmental impact but also on maximizing their performance and broadening their application range. Herein, the bio-based blends based...
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Thermal degradation of polylactic acid (PLA)/polyhydroxybutyrate (PHB) blends: A systematic review
PublicationPolylactic acid (PLA) and polyhydroxybutyrate (PHB) are two biopolyesters obtained from renewable resources like corn or sugar under bacterial fermentation. PLA is the most widely used biopolymer in diverse applications. Addition of PHB to PLA can improves the crystallinity of PLA, and thereby its mechanical strength. However, both PLA and PHB suffer from poor thermal stability, which limits their potential industrial application....
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Synthesis of isotactic polypropylene- block -polystyrene block copolymers as compatibilizers for isotactic polypropylene/polyphenylene oxide blends
PublicationPoly(2,6-dimethyl-1,4-phenylene oxide) (PPO) and isotactic polypropylene (iPP) are highly incompatible and consequently their uncompatibilized blends are quite brittle regardless of the molecular weights and ductility of the individual components. Isotactic polypropylene-polystyrene block copolymers, to be applied as compatibilizers for a broad range of PPO/iPP blend compositions, were prepared by mechanism transformation from...
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Structural, mechanical and thermal behavior assessments of PCL/PHB blends reactively compatibilized with organic peroxides
PublicationThe efficiency of two commercially available organic peroxides, dicumyl peroxide (DCP) and di-(2-tert-butyl-peroxyisopropyl)-benzene (BIB), during reactive processing of poly (ε-caprolactone)/poly (3-hydroxybutyrate) (PCL/PHB) blends was investigated. The changes in chemical structure of PCL/PHB blends, as a function of organic peroxide type (DCP/BIB) and content (in range: 0–1.0 parts by weight - pbw), were characterized by Fourier...
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POLYMER DEGRADATION AND STABILITY
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POLYMER BULLETIN
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Interrelationship between total volatile organic compounds emissions, structure and properties of natural rubber/polycaprolactone bio-blends cross-linked with peroxides
PublicationNatural rubber/polycaprolactone (NR/PCL) bio-based blends with different organic peroxides were prepared using an internal batch mixer and subsequently cross-linked at 170°C. Two types of commonly used organic peroxides, dicumyl peroxide and di(tert-butylperoxyisopropyl)benzene peroxide, were applied as free-radical initiator. Cross-linking efficiency of NR/PCL blends were investigated using oscillating disc rheometer measurements,...
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Processing, physico-mechanical and thermal properties of reclaimed GTR and NBR/reclaimed GTR blends as function of various additives
PublicationIn this work, ground tire rubber (GTR) was mechano-chemically reclaimed in the presence of bitumen and various additives. During studies three types of processing and curing additives: (i) peptizer P300; (ii) vulcanization accelerator tetramethylthiuram disulfide (TMTD) and (iii) organic peroxide di(2-tert-butyl-peroxyisopropyl)benzene (BIB1) were applied to enhance reclaiming of GTR. Reclaiming process was evaluated by oscillating...
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Thermal Properties of PLA/TPS Blends
PublicationFour types of polymer compositions having different amount of potato starch, glycerin and poly(lactic acid) was obtained and characterized by DSC. Adding of TPS to PLA lowered Tg.
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Emulsifying blends based on natural fats for eco-design of O/W emulsions
PublicationEmulsifier blends are most often used to stabilize and modulate the properties of cosmetic and pharmaceutical emulsions, such as skin care or application-related consistency. However, the rational design of such emulsifier blends is often not well understood, especially when their ingredients are natural raw materials. This study aimed to analyze the influence of natural fatty ingredients selected as emulsifiers on the emulsion...
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Development of nanoscale morphology and role of viscoelastic phase separation on the properties of epoxy/recycled polyurethane blends
PublicationA novel and cost-effective approach towards the modification of epoxy matrix has been developed using recycled polyurethane for the first time without sacrificing any of the intrinsic properties of the resin. Polyurethane, recycled from waste foam by glycolysis process (RPU), was found to be very effective in improving the properties of the thermosetting resin based on Diglycidyl ether of bisphenol-A (DGEBA). The effect of the...
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The influence of the type of composition of PVA-chitosan blends on stability at elevated temperature
Open Research DataThe dataset shows the results of a visual evaluation of chitosan and polyvinyl alcohol composites. The composites were prepared by combining chitosan water solutions, dissolved in selected acids, and polyvinyl alcohol solution, freeze drying, and heating at 150°C dry composites. The results confirm that the chitosan / PVA composites, in which the first...
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Assessment of microstructure, physical and thermal properties of bitumen modified with LDPE/GTR/elastomer ternary blends
PublicationLDPE/GTR/elastomer ternary blends with variable LDPE/GTR ratio and constant elastomer content were prepared via melt-compounding. Obtained LDPE/GTR/elastomer blends were applied as thermoplastic modifiers into bitumen. Microstructure, physical and thermal properties of the modified bitumen were determined. It was observed that chemical composition of LDPE/GTR/elastomer blends has significant influence on their density and rheological...
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Polymer electrolytes with ionic liquids
PublicationSolid polymer electrolytes are solutions of salts in the macromolecular polymeric compound. Excellent process ability, flexibility, non-flammability and non-reactivity make them ideal materials for electrochemical devices. The problem in their use is limited conductivity. It increases with increasing salt concentration in the polymer, but at the same time the condition is to increase the glass transition temperature of the polymer...
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Structure-property relationships in peroxide-assisted blends of poly(ε-caprolactone) and poly(3-hydroxybutyrate)
PublicationPoly(ε-caprolactone) and poly(3-hydroxybutyrate) (PCL/PHB) blends in two weight ratios (75/25 and 50/50) were reactively compatibilized in the presence of di-(2-tert-butyl-peroxyisopropyl)-benzene and dicumyl peroxide as free radical initiators. Rheological, mechanical, thermal properties and morphological features, as well as the chemical structure of PCL/PHB blends were investigated. It was found that regardless of PCL/PHB blend...
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Interfacial adhesion evaluation in (low-density polyethylene)/elastomer blends
PublicationLow-density polyethylene (LDPE) with different elastomers at a ratio of 50/50 wt% blends was prepared by using a co-rotating twin-screw extruder. Three kinds of elastomers were used: ground tire rubber (GTR), partially crosslinked butyl rubber (KalarVR ), and styrenebutadiene- rubber block copolymer (SBS; KratonVR ). For better characterization of interaction between polyethylene and elastomer, influence of the type of elastomer on...