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Search results for: KATION HYDROFOBOWY
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DEM-FEM model of highly saturated soil motion due to seepage force
PublicationArtykuł poświęcono nowej propozycji rozwiązania problemu modelowania zjawiska transportu, które występuje wewnątrz wysoko-nawodnionego gruntu ziarnistego na skutek ciśnienia spływowego. Teoria oparta została na połączeniu metody elementów skończonych (FEM - Finite Element Method) - rozwiązania równań poro-elastycznych oraz metody poszczególnych elementów (DEM - Distinct Element Method), które dały podwójny model numeryczny. FEM...
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Feasibility of combined diesel engine - steam turbine in power station operating in the maritime
PublicationCompression-ignition engines used in ship technology as main propulsion engines are large units reaching even to 50-60 MW. Currently, the efficiency of such engines amounts to 45-50%. With such a large power unit, exhaust gases leaving the engine contain very large quantities of heat available for further treatment. Exhaust gases from the piston engine contain about 25% of the heat supplied to the engine in the fuel. Using the...
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Studies of the complex formation between some proton sponges and Cu(II) cations
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Chromatographic behaviour of ionic liquid cations in view of quantitative structure-retention relationship
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Isothiocyanates as effective agents against enterohemorrhagic Escherichia coli: insight to the mode of action
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Various modes of action of dietary phytochemicals, sulforaphane and phenethyl isothiocyanate, on pathogenic bacteria
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Parametric method for determination of motion characteristics of underwater vehicles, applicable in preliminary designing.
Publicationartykuł zawiera opis metody wstępnego projektowania autonomicznych pojazdów podwodnych (auv), przydatnej szczególnie w przypadku, gdy w założeniach projektowych stawiane są wymogi dotyczące parametrów kinematyczno-dynamicznych ruchu pojazdu. koncepcja metody zasadza się na równaniach dynamiki opisujących ruch płaski pojazdu w kierunku poziomym i pionowym, wywołanych odpowiednio napędem śrubowym lub balastem wodnym. równania ruchu...
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Study of pozzolanic action of ground waste expanded perlite by means of thermal methods
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Towards trustworthy multi‐modal motion prediction: Holistic evaluation and interpretability of outputs
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The Thermal Parameters of Mortars Based on Different Cement Type and W/C Ratios
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An Intergrated Model of Motion, Steering, Positioning and Stabilization of an Unmanned Autonomous Maritime Vehicle
PublicationIn the paper the aim of an interdisciplinary research is presented. The research method is introduced. An object the unmanned autonomous maritime vehicle is briefly described. The key research problem concerns a combined model of the vehicle motion including the loads of lift and hydrodynamic nature. The model takes into account the gravity and displacement forces, resistance and thrust forces, lift and other hydrodynamic forces....
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Determining and visualizing safe motion parameters of a ship navigating in severe weather conditions
PublicationThe paper presents a method of determining, organizing and displaying ship collision avoidance information, which is based on the Collision Threat Parameters Area (CTPA) technique. The method makes it possible to visualize navigational threats as well as possible collision avoidance manoeuvres. The solution is focused on supporting navigation in severe weather conditions. Normally collision avoidance decisions are made taking into...
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Rough Set-Based Classification of EEG Signals Related to Real and Imagery Motion
PublicationA rough set-based approach to classification of EEG signals registered while subjects were performing real and imagery motions is presented in the paper. The appropriate subset of EEG channels is selected, the recordings are segmented, and features are extracted, based on time-frequency decomposition of the signal. Rough set classifier is trained in several scenarios, comparing accuracy of classification for real and imagery motion....
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A method of determining and visualizing safe motion parameters of a ship navigating in restricted waters
PublicationThe paper presents a method of displaying ship collision avoidance information which is based on an unconventional Collision Threat Parameters Area (CTPA) technique. The solution presented here extends CTPA's functionality from past works by supporting navigation in restricted waters and handling ship domains analytically instead of numerically. It visualizes potential navigational threats as well as possible collision avoidance...
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Database of speech and facial expressions recorded with optimized face motion capture settings
PublicationThe broad objective of the present research is the analysis of spoken English employing a multiplicity of modalities. An important stage of this process, discussed in the paper, is creating a database of speech accompanied with facial expressions. Recordings of speakers were made using an advanced system for capturing facial muscle motion. A brief historical outline, current applications, limitations and the ways of capturing face...
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Numerical Analysis of Impact of Energy Buoy Anchoring Configurations on its Motion and Efficiency
PublicationThis paper presents a numerical analysis of the impact of energy buoy mooring configurations on its movement on the wave and effectiveness. The method used to analyse the buoy movement modelling in six degrees of freedom was described in a paper presented at the Conference 2011. Simulations of the buoy movement in regular wave and power calculations were conducted for several configurations of anchoring systems and position of...
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Novel therapeutic compound acridine–retrotuftsin action on biological forms of melanoma and neuroblastoma
PublicationPURPOSE: As a continuation of our search for anticancer agents, we have synthesized a new acridine-retrotuftsin analog HClx9-[Arg(NO2)-Pro-Lys-Thr-OCH3]-1-nitroacridine (named ART) and have evaluated its activity against melanoma and neuroblastoma lines. Both tumors develop from cells (melanocytes, neurons) of neuroectodermal origin, and both are tumors with high heterogeneity and unsatisfactory susceptibility to chemotherapies....
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Solvation of multivalent cations in methanol - apparent molar volumes, expansibilities, and isentropic compressibilities
PublicationWyznaczono gęstości roztworów trifluorometanosulfonianów galu, itru, lantanu, gadolinu i lutetu w metanolu w zakresie temperatur (283.15 to 313.15) K. Zmierzono prędkości dźwięku dla tych układów w temperaturze T = 298.15 K. Z uzyskanych danych wyznaczono standardowe cząstkowe objętości molowe i ich pochodne temperaturowe oraz standardowe cząstkowe molowe ściśliwości adiabatyczne badanych jonów. Wyniki omówiono stosując klasyczny...
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Chain Action - How Do Countries Add Value Through Digital Government?
PublicationThis study examineshow countries develop and benefit from Digital Government(DG).The literature proposes various conceptualizations of the value-adding logic of DG, but the benchmarking practice is not respondingto such proposals.For instance, the United Nations’E-Government Surveycombines the readiness and uptake indicatorsand failsto cover any impactindicators;thus,its diagnostic valueis limited. To overcome...
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The community involvement of courts: an action research study in the context of the Polish justice system
PublicationPurpose – As a rule, common courts are hermetic organizations, separated from their stakeholders by procedures based on legal provisions. For these reasons, they are often perceived as unreliable and non-transparent, and as such, they do not inspire trust among stakeholders. The authors posit that the court’s community involvement may lead to the increased accountability and legitimacy of courts, which should in turn result in...
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Recovering Sound Produced by Wind Turbine Structures Employing Video Motion Magnification
PublicationThe recordings were made with a fast video camera and with a microphone. Using fast cameras allowed for observation of the micro vibrations of the object structure. Motion-magnified video recordings of wind turbines on a wind farm were made for the purpose of building a damage prediction system. An idea was to use video to recover sound & vibrations in order to obtain a contactless diagnostic method for wind turbines. The recovered signals...
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Investigation of Weigh-in-Motion Measurement Accuracy on the Basis of Steering Axle Load Spectra
PublicationWeigh-in-motion systems are installed in pavements or on bridges to identify and reduce the number of overloaded vehicles and minimise their adverse eect on road infrastructure. Moreover, the collected trac data are used to obtain axle load characteristics, which are very useful in road infrastructure design. Practical application of data from weigh-in-motion has become more common recently, which calls for adequate attention to...
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Collision-induced luminescence spectra of pyridine bombarded by 1000 eV He+ cations
PublicationHere we show collision-induced luminescence spectra measured for collisions of the He+cations with thearomatic six-membered ring of the pyridine molecule (C5H5N). Distinct emission bands due to the CH(A2Δ→X2Πr;B2Σ+→X2Πr;C2Σ+→X2Πr), CN(B2Σ+→X2Σ+), C2(d3Πg→a3Πu), and NH(A3Π→X3Σ−) transitions, aswell as atomic H, He, and C lines have been observed. Apart from the He atoms, all the emitters arise from thefragmentation of the pyridine...
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Ultrafast Intramolecular Relaxation and Wave-Packet Motion in a Ruthenium-Based Supramolecular Photocatalyst
PublicationThe hydrogen-evolving photocatalyst [(tbbpy)2 Ru(tpphz)Pd(Cl)2 ](2+) (tbbpy=4,4'-di-tert-butyl-2,2'-bipyridine, tpphz=tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2''',3'''-j]phenazine) shows excitation-wavelength-dependent catalytic activity, which has been correlated to the localization of the initial excitation within the coordination sphere. In this contribution the excitation-wavelength dependence of the early excited-state relaxation...
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Determination of stability constants of complexes of selected amide ionophores with alkali metal cations
PublicationPodano właściwości kompleksujące jony litowców czterech jonoforów typu amidów. Wyznaczono wartości stałych kompleksów z jonów Li+, Na+, K+ metodą potencjometryczną z zastosowaniem elektrod jonoselektywnych stosując dwie różne procedury: 1) stosując jako kation referencyjny TMA+, 2) stosując chromofor kompleksujący H+.
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Influence of the steam within seals and glands of the turbine on its rotor motion stability.
PublicationPrzedstawiono metodę obliczania charakterystyk dynamicznych wpływu parowych uszczelnień turbin na ich dynamikę i stateczność ruchu wirników. Zarysowano model ''masowy'' uszczelnienia. Podano przykłady zastosowań.
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Volumetric properties of tetraalkylammonium cations in N,N-dimethylformamide and N,N-dimethylacetamide
PublicationPraca dotyczy granicznych molowych objętości i ściśliwości adiabatycznych soli tetraalkiloamoniowych w N,N-dimetyloformamidzie i N,N-dimetyloacetamidzie. W pracy zostały przedstawione zależności granicznych molowych objętości kationów tetraalkiloamoniowych od temperatury oraz długości łańcucha alkilowego. Dodatkowo pokazano, że graniczne pozorne objętości molowe jonów tetraalkiloamoniowych tworzą taką samą sekwencję jak graniczne...
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Polish DGPS System: 1995-2018 – Studies of Reference Station Operating Zones
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Wpływ rodzaju kwaśnego dodatku do eluentu oraz właściwości fazy stacjonarnej na rozdzielanie średnio i nisko hydrofobowych kwaśnych organicznych związków chemicznych w odwróconych układach faz kolumnowej elucyjnej wysokosprawnej chromatografii cieczowej - RP HPLC
Publicationedna z serii prac badawczych nad opracowaniem optymalnych warunków rozdzielania, identyfikacji i oznaczania względnie, średnio i nisko polarnych składników mieszanin organicznych związków chemicznych otrzymywanych z procesu konwersji biomasy lignocelulozowej, lub suszu roślinnego z wykorzystaniem wysokosprawnej kolumnowej elucyjnej chromatografii cieczowej w odwróconych układach faz (RP-HPLC) z elucją izokratyczną, a wówczas gdy...
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Hydration of simple amides. FTIR spectra of HDO and theoretical studies
PublicationZastosowano metodę ważonych widm różnicowych do opisu hydratacji amidów w roztworach wodnych: formamidu, N-metyloformamidu, N,N-dimetyloformaidu, acetamidu, N-metyloacetamidu, N,N-dimetyloacetamidu. Narzędziem wspomagającym interpretację wyników eksperymentalnych są struktury agregatów solwatacyjnych wokół cząsteczki substancji rozpuszczonej uzyskane na podstawie obliczeń teoretycznych metodą ab initio z korelacją elektronową...
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Chromogenic amides of pyridine-2,6-dicarboxylic acid as anion receptors
PublicationThe synthesis of simple, chromogenic pyridine-2,6-dicarboxylic acid amides, derivates of isomeric nitroanilines and aminonitrophenols, and their ion binding properties are described. The ligands' response to ionic species was examined by naked eye and was studied with the use of UV-Vis spectroscopy in DMSO and its mixture with water. The effect of the localisation and the type of the substituents in aromatic rings were discussed....
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Theoretical interpretation of photoelectron spectra of the iridium neutral atom and anion
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Dissociative electron attachment and anion-induced dimerization in pyruvic acid
PublicationWe report partial cross sections for the dissociative electron attachment to pyruvic acid. A rich fragmentation dynamics is observed. Electronic structure calculations facilitate the identification of complex rearrangement reactions that occur during the dissociation. Furthermore, a number of fragment anions produced at electron energies close to 0 eV are observed, that cannot originate from single electron-molecule collisions....
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Photoresponsive, amide-based derivative of embonic acid for anion recognition
PublicationThe synthesis and ion-binding properties of amide-based derivative of embonic acid andp-aminoazobenzenewere described. The new compound was characterized by X-ray structural analysis and spectroscopic methods.Ligand interacts in acetonitrile with Y-shaped anions (benzoates and acetates) and dihydrogen phosphatesforming complexes of 1:1 stoichiometry. In more polar DMSO the complexes stoichiometry changes to 2:1(L:anion). Light-inducedtranstocisisomerization...
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Analysis of pressure ratio in the intake in dependence on high-voltage behaviours
PublicationPower control in spark ignition engines by regulating the intake air is performed. The control unit needs information about the air pressure conditions which then enters the combustion chamber. The information about the intake air pressure is an important quantity for optimal control of combustion mixtures. The paper describes some types of sensors that are used to measure the air intake temperature. Air pressure in the intake...
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Ensuring the QoE-Related Fairness to Reduce the User Abandonment Ratio
PublicationThese days, it is quite a challenge for app owners to keep users engaged with an app. Currently, the level of user abandonment is one of the key parameters that application owners are interested in. To meet these challenges, we are conducting an extended study of a previously proposed solution that significantly reduces the abandonment rate of a given application. The investigated solution is based on the methods of fairness using...
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Influence of the initial void ratio on the evolution of the passive earth pressure
PublicationW artykule przedstawiono wyniki numerycznej analizy wpływu rozkładu początkowego wskaźnika porowatości i fluktuacji bieżącego wskaźnika porowatości w materiałach granulowanych na powstawanie lokalizacji odkształceń. Obliczenia wykonano dla ściskania dwuosiowego stosując metodę elementów skończonych na bazie mikropolarnego prawa hipoplastycznego.
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Crystal and molecular structure of lithium iodide complex of 13-membered azoxycrown ether
PublicationPublikacja zawiera uzupełniające informacje do znalezionej wcześniej korelacji między typem kationu, rozmiarem makrocyklu i cechami struktury krystalicznej kompleksów a selektywnością elektrod membranowych dotowanych odpowiednimi azo- lub azoksykoronami. Ustalono strukturę krystaliczną i molekularną kompleksu 13-członowej azoksykorony (L13-O) z jodkiem litu. Stechiometria kompleksu jest 1:1. Kryształ zbudowany jest z hydratowanych...
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Application of Monoferrocenylsumanenes Derived from Sonogashira Cross-Coupling or Click Chemistry Reactions in Highly Sensitive and Selective Cesium Cation Electrochemical Sensors
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Structural characterization and biological properties of a new dinuclear oxidovanadium(IV) N -(phosphonomethyl)iminodiacetate complex with the 4-amino-2-methylquinolinium cation
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Hydrological signals in polar motion excitation – Evidence after fifteen years of the GRACE mission
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Numerical Simulation of Temperature Field in Steel under Action of Electron Beam Heating Source
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State action aimed at limiting financial exclusion in Poland in terms of sustainable and inclusive development
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Range of motion of resistance exercise affects the number of performed repetitions but not a time under tension
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Preparation of DNA films for studies under vacuum conditions. The influence of cations in buffer solutions
PublicationBadania zostały przeprowadzone w celu określenia optymalnych warunków wymaganych do przygotowania jednolitych filmów superskręconego plazmidowego DNA do wykorzystania w doświadczeniach napromieniowania w warunkach wysokiej próżni. Badania pokazują, że znaczne szkody w DNA powstają w wyniku odpompowywania filmów DNA z roztworów zawierających jedynie czysta wodę.
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Wpływ smarowności na działania układu tribologicznego (impact of lubricity on the tribological system action)
Publicationthe paper presents analysis and evaluation, based on tests results, of the impact of lubricity of the used lubricating oils (shell argina t 40) on the action of boundary layer of sulzer 6zl40/48 engines aboard the ''włocławek'' sea-going ship. for comparison purposes, the same oils were tested with the ceramizer four-stroke engine (all types of the vidar four-stroke engines) regeneration agent added. so understood boundary layer...
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Investigation ofcis/trans ratios of peptide bonds in AVP analogues containingN-methylphenylalanine enantiomers
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Quantitative structure–retention relationships of ionic liquid cations in characterization of stationary phases for HPLC
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The Action Mechanisms, Anti-Cancer and Antibiotic-Modulation Potential of Vaccinium myrtillus L. Extract
PublicationHerbal medicinal products containing Vaccinium myrtillus L. (bilberry) fruits and fruit extracts are widely available in the market. Although bilberry leaves and stems are considered as bio-waste, they contain much higher levels of phenolic compounds than fruits. The study aimed to investigate the antimicrobial and anticancer potential of aerial part extracts from Vaccinium myrtillus L. (V. myrtillus, VM) plants harvested at high...
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Non-ergodic fragmentation upon collision-induced activation of cysteine–water cluster cations
PublicationCysteine–water cluster cations Cys(H2O)3,6 + and Cys(H2O)3,6H+ are assembled in He droplets and probed by tandem mass spectrometry with collision-induced activation. Benchmark experimental data for this biologically important system are complemented with theory to elucidate the details of the collisioninduced activation process. Experimental energy thresholds for successive release of water are compared to water dissociation energies...