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Search results for: NBR-G-GMA COMPATIBILIZER
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Morphology and mechanical properties of polyamide/clay nanocomposites toughened with NBR/NBR-g-GMA: A comparative study
PublicationThis work highlights the importance of nanoclay dispersion state in the nanocomposites containing polyamide 6 (PA6), nanoclay and elastomers as well as clay localization at the interface of thermoplastic/elastomer. Morphology and mechanical properties of a series of nanocomposites containing acrylonitrile butadiene rubber (NBR), glycidyl methacrylate-grafted NBR (NBR-g-GMA), and combined NBR/NBR-g-GMA were compared and discussed...
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An investigation on the role of GMA grafting degree on the efficiency of PET/PP-g-GMA reactive blending: morphology and mechanical properties
PublicationGlycidyl methacrylate (GMA) has been grafted on polypropylene (PP) with the aid of styrene (St) comonomer, by changing dicumyl peroxide initiator content, GMA level, and St concentration. The performance of the resulting PP-g-GMA reactive material towards static and dynamic mechanical properties of poly (ethylene terephthalate) (PET) was monitored in terms of grafting reaction variables and compatibilizer content. Fourier transform...
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NMR-Based Structural Insight into DNA G-Quadruplex
PublicationEmerging as a promising area in anticancer research, noncanonical DNA structures such as G-quadruplexes are studied using NMR spectroscopy. NOESY spectra reveals crucial interactions between ligands and G-quadruplexes, helping to understand non-covalent binding mechanisms. This knowledge is essential for rational drug design targeting these structures.
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Isothermal Vulcanization and Non-Isothermal Degradation Kinetics of XNBR/Epoxy/XNBR-g-Halloysite Nanotubes (HNT) Nanocomposites
PublicationThe effect of several concentrations of carboxylated nitrile butadiene rubber (XNBR) functionalized halloysite nanotubes (XHNTs) on the vulcanization and degradation kinetics of XNBR/epoxy compounds were evaluated using experimental and theoretical methods. The isothermal vulcanization kinetics were studied at various temperatures by rheometry and differential scanning calorimetry (DSC). The results obtained indicated that the...
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Interface analysis of compatibilized polymer blends
PublicationThis chapter seeks to address the interface location in the compatibilized polymer blends and paves the way for quantitative analysis of interface in terms of interfacial tension and interfacial adhesion to provide support for understanding the relationship between morphology and ultimate properties in the compatibilized polymer blends through the lens of interface. Since understanding and analysis of interfacial phenomena in the...
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Synergistic effect of MWCNTs and MA-g-PP on the thermal and viscoelastic properties of immiscible PTT/PP blends
PublicationThe properties of immiscible blends of PTT and PP were modified by grafting and nanoparticle inclusion. The observed synergistic effect of MWCNTs and MA-g-PP on the thermal and viscoelastic properties of PTT/PP blends was studied in detail and the properties of the composites were compared with those of ungrafted PP.
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Preparation of Well-Compatibilized PP/PC Blends and Foams Thereof
PublicationThe performance of polypropylene-poly(ethylene brassylate) block and graft copolymers and a polypropylene-polycaprolactone graft copolymer as compatibilizers for polypropylene-rich polypropylene/bisphenol A polycarbonate (PP/PC, 80/20 wt/wt) blends was elucidated. The copolymers were synthesized either by metal-catalyzed ring-opening polymerization or transesterification of a presynthesized polyester, initiated by hydroxyl-functionalized...
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Hybridization-driven gap in U3Bi4Ni3: A 209Bi NMR/NQR study
PublicationZostały przeprowadzone badania jądrowego rezonansu magnetycznego (na jądrach 209Bi) na kryształach U3Bi4Ni3. U3Ni4Bi3 jest tzw. izolatorem typu Kondo.
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iPP/HDPE blends compatibilized by a polyester: An unconventional concept to valuable products
PublicationPolyolefins are the most widely used plastics accounting for a large fraction of the polymer waste stream. Although reusing polyolefins seems to be a logical choice, their recycling level remains disappointingly low. This is mainly due to the lack of large-scale availability of efficient and inexpensive compatibilizers for mixed polyolefin waste, typically consisting of high-density polyethylene (HDPE) and isotactic polypropylene...
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Reactive Extrusion of Waste Plastics with Compatibilizer and Lightly Pyrolyzed Crumb Rubber for Asphalt Modification
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Analysis of IMS/NGN call processing performance using G/G/1 queuing systems approximations
PublicationThe paper concerns the Next Generation Network (NGN), which is standardized for distribution of multimedia services based on the IP Multimedia Subsystem (IMS). To guarantee quality, accurate traffic models of IMS/NGN should be proposed. In the paper we compare results obtained with our analytical and simulation model of a single IMS/NGN domain, where various queuing systems are used in the analytical model (M/G/1 and approximations...
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Problemy planowania rozwoju systemu transportowego w obszarach metropolitalnych – przykład Obszaru Metropolitalnego G-G-S
PublicationProblemy rozwoju systemów transportowych w metropoliach wynikają ze specyfiki tych obszarów, ich skali i struktury przestrzennej. Obszary te charakteryzują się dużą wewnętrzną integracją funkcjonalną oraz dobrze rozwiniętą siecią transportową. Dynamicznie rozwijające się obszary metropolitalne mają odrębne systemy zarządzania finansami, rozwią- zania prawne oraz administrację, a także własne organy planowania i zarządzania, które...
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Influence of microwave treatment conditions of GTR on physico-mechanical and structural properties of NBR/NR/GTR composites
PublicationThe increasing amount of tires used in the industry induces the researchers to find alternatives to the recycling of the end-of-life tires. Several alternatives in order to application of ground tire rubber GTR include their incorporation as a filler in composites. The main issue in this approach is the lack of compatibility between GTR and polymer matrix. In order to solve this problem the devulcanization by microwaves has been...
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Some remarks on the Euler ring U(G)
PublicationNiech G będzie zwartą grupą Liego i niech U(G) oznacza pierściń Eulera G skonstruoawany przez tom Diecka w [5,6]. Główny wynikpracy (Twierdzenie 4.1) opisuje homomorfizm pierścienia U(SO(3)) w pierścień U(SO(2))indukowany przez włożenie grupy SO(2) w grupę SO(3).
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New potent cathepsin G phosphonate inhibitors
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Minimization of label usage in (G)MPLS networks
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Why Are Left-Handed G-Quadruplexes Scarce?
PublicationG-quadruplexes (G4s) are nucleic acid structures crucial for the regulation of gene expression and genome maintenance. While they hold promise as nanodevice components, achieving desired G4 folds requires understanding the interplay between stability and structural properties, like helicity. Although right-handed G4 structures dominate the experimental data, the molecular basis for this preference over left-handed helicity is unclear....
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Analysis of structure and properties of DVB–GMA based porous polymers
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Effect of slightly crosslinked butyl rubber and compatibilizer additives on properties of recycled polyethylene-ground tire rubber blends
PublicationSlightly crosslinked butyl rubber, (PhMe2CO)(2) and maleic anhydride were added as compatibilizer to the recycled polyethylene-ground tire rubber blends. Recycled postprodn. and postconsumer (shredded bottle caps) polyethylene wastes were used. The thermoplastic compns. were studied for statistic and dynamic mech. properties and morphol. The addn. of butyl rubber resulted in a decrease of the tensile strength and hardness of the...
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Structural, mechanical and thermal behavior assessments of PCL/PHB blends reactively compatibilized with organic peroxides
PublicationThe efficiency of two commercially available organic peroxides, dicumyl peroxide (DCP) and di-(2-tert-butyl-peroxyisopropyl)-benzene (BIB), during reactive processing of poly (ε-caprolactone)/poly (3-hydroxybutyrate) (PCL/PHB) blends was investigated. The changes in chemical structure of PCL/PHB blends, as a function of organic peroxide type (DCP/BIB) and content (in range: 0–1.0 parts by weight - pbw), were characterized by Fourier...
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Synthesis of isotactic polypropylene- block -polystyrene block copolymers as compatibilizers for isotactic polypropylene/polyphenylene oxide blends
PublicationPoly(2,6-dimethyl-1,4-phenylene oxide) (PPO) and isotactic polypropylene (iPP) are highly incompatible and consequently their uncompatibilized blends are quite brittle regardless of the molecular weights and ductility of the individual components. Isotactic polypropylene-polystyrene block copolymers, to be applied as compatibilizers for a broad range of PPO/iPP blend compositions, were prepared by mechanism transformation from...
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Fixed point index for $G$-equivariant multivalued maps
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Lactoferrin Is an Allosteric Enhancer of the Proteolytic Activity of Cathepsin G
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Low-Molecular-Weight Aldehyde Inhibitors of Cathepsin G
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Inhibitors of cathepsin G: a patent review (2005 to present)
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Wstępne badania technologii spawania złączy narożnych ze stali niskoweglowej i nierdzewnej o grubości g=6mm i g=10mm
PublicationCelem pracy był dobór parametrów spawania dla spoin narożnych o grubości 6mm i 10mm próbek wykonanych ze stali niskowęglowej S355 i stali nierdzewnej - typu 304 (X6CrNI18-10). Złącza były spawane laserowo, jednostronnie z pełnym przetopem a powierzchnie lica i grani zapewniają uzyskanie szczelności przylegającego elementu uszczelniającego. Próbki zostały dostarczone przez Zleceniodawcę. Próby zostały przeprowadzone na stanowisku...
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Morphology, Thermo-Mechanical Properties and Biodegradibility of PCL/PLA Blends Reactively Compatibilized by Different Organic Peroxides
PublicationReactive blending is a promising approach for the sustainable development of bio-based polymer blends and composites, which currently is gaining more and more attention. In this paper, biodegradable blends based on poly(ε-caprolactone) (PCL) and poly(lactic acid) (PLA) were prepared via reactive blending performed in an internal mixer. The PCL and PLA content varied in a ratio of 70/30 and 55/45. Reactive modification of PCL/PLA...
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Poly(ε-Caprolactone)/Poly(Lactic Acid) Blends Compatibilized by Peroxide Initiators: Comparison of Two Strategies
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Poly(ε-Caprolactone)/Poly(Lactic Acid) Blends Compatibilized by Peroxide Initiators: Comparison of Two Strategies
PublicationPoly(ε-caprolactone) (PCL) and poly(lactic acid) (PLA) blends were compatibilized by reactive blending and by copolymers formed during reaction in the solution. The reactive blending of PCL/PLA was performed using di-(2-tert-butyl-peroxyisopropyl)benzene (BIB) or dicumyl peroxide (DCP) as radical initiator. PCL-g-PLA copolymers were prepared using 1.0 wt. % of DCP or BIB via reaction in solution, which was investigated through...
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Solving nonlinear programming problems by using O&G software.
PublicationPraca opisuje pakiet optymalizacyjny oprogramowania O&G. Umożliwia on rozwiązywanie problemów programowania nieliniowego. Użytkownik może w wygodny sposób formułować rozwiązywane zadanie i dobierać metody obliczeniowe używając interaktywnego interfejsu.
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Cathepsin G activity lowers plasma LDL and reduces atherosclerosis
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Structurally well-defined functionalized polyolefins and graft copolymers thereof as bitumen modifiers
PublicationHere we demonstrate the application of hydroxyl-functionalized propylene-based copolymers, poly(propylene-co-1-hexene-co-10-undecen-1-ol) (FPP) and poly(styrene-co-maleic anhydride) (SMA) graft copolymers derived thereof, poly(propylene-co-1- hexene-graft-styrene-co-maleic anhydride) (FPP-g-SMA) as bitumen modifiers. The FPP samples were synthesized via solution copolymerization, while FPP-g-SMA products were obtained via transesterification...
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C-1311 (Symadex), a potential anti-cancer drug, intercalates into DNA between A and G moieties. NMR-derived and MD-refined stereostructure of the d(GAGGCCTC) 2 :C-1311 complex
PublicationImidazoacridinone C-1311 (Symadex®) is an antitumor agent which has been recommended for Phase II clinical trials a few years ago. Previously, it was shown experimentally that during the initial stage of its action C-1311 forms stable intercalation complexes with DNA duplexes. Herein, a NMR-derived stereostructure of d(GAGGCCTC)2:C-1311 complex was reported. The ligand was found locating itself between A and G moieties, forming...
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Compact-planar monopole loop antennas for 802.11b/g WLAN systems
PublicationZaproponowano planarne anteny monopolowe dla systemów komunikacji bezprzewodowej WLAN pracujących w pasmach 2.45GHz i 5.25GHz. W strukturze radiatorów zasilanych poprzez linię mikropaskową wykorzystano krzywe fraktalne: pętlę Kocha oraz pętlę Minkowskiego. W obu przypadkach uzyskano dwuzakresową pracę anten dzięki wprowadzeniu nowej konfiguracji zminiaturyzowanych transformatorów impedancji w układzie zasilania.
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MicroGal Gravity Measurements with MGS-6 Micro-g LaCoste Gravimeter
PublicationKnowing the exact number of fruit and trees helps growers to make better decisions about how to manage their production in the orchard and prevent plant diseases. The current practice of yield estimation is to manually count fruit or flowers (before harvesting), which is a very time-consuming and costly process. Moreover it’s not practical for large orchards. It also doesn’t allow to make predictions of plant development in a more...
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Enhanced interfacial and mechanical performance of styrene-butadiene rubber/silica composites compatibilized by soybean oil derived silanized plasticization
PublicationSilanized plasticizer (SP) was chemically derived and synthesized from soybean oil (SBO) co-vulcanized with bis-(3-(triethoxysilyl)-propyl) tetrasulfide (TESPT) by using the sulfur-accelerated curing system. SP extended styrene-butadiene rubber (SBR)/silica composites have been studied for their improved filler dispersion through coupling interaction at the SBR/silica interface. The effect of SP on cross-link density, thermal,...
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Jager W., Marzahn G.: Mauerwerk. Bemessung nach DIN 1053-100
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Development of sensitive cathepsin G fluorogenic substrate using combinatorial chemistry methods
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Synthesis and Characterization of Nitrogen-doped Carbon Nanotubes Derived from g-C3N4
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Drawing Functions and NLP Algorithm Steps for Optimization Problems by using O&G Software.
PublicationPraca opisuje program służący do wizualizacji problemów programowania nieliniowego (funkcja celu, ograniczenia) oraz pracy rozwiązującego je algorytmu. Wizualizacja może być realizowana w przestrzeni dwu- lub trójwymiarowej.
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Enhancement of photocatalytic hydrogen evolution with catalysts based on carbonized MOF-5 and g-C3N4
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On the Fenchel–Moreau conjugate of G-function and the second derivative of the modular in anisotropic Orlicz spaces
PublicationIn this paper, we investigate the properties of the Fenchel–Moreau conjugate of G-function with respect to the coupling function c(x, A) = |A[x]2 |. We provide conditions that guarantee that the conjugate is also a G-function. We also show that if a G-function G is twice differentiable and its second derivative belongs to the Orlicz space generated by the Fenchel–Moreau conjugate of G then the modular generated by G is twice differentiable...
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Pomiary naprężeń w warstwie wierzchniej stali duplex metodą dyfrakcji promieniowania rentgenowskiego g-sin2Ψ = Residual stress measurements in duplex steel surface layers by g-sin2Ψ x-ray diffraction method
PublicationPrzedstawiono wyniki pomiarów naprężeń w warstwie wierzchniej z wykorzystaniem metody dyfrakcji promieniowania rentgenowskiego g-sin2. Wyjaśniono zasady przeprowadzania pomiarów naprężeń na próbkach walcowych o małej średnicy. Badania prowadzono na próbkach okrągłych ze stali duplex, poddanych procesom nagniatania. Stwierdzono występowanie naprężeń ściskających w warstwach powierzchniowych wszystkich badanych próbek oraz istotne...
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Underwater robot actuated by shape memory alloy wires
PublicationW pracy przedstawiono koncepcję projektu robota podwodnego z napędem wykorzystującym materiały SMA ze stopów z pamięcią kształtu. Rozpatrywany układ ma budowę modułową złożoną z segmentów na podobieństwo do anatomicznej budowy dżdżownicy. Pojedyńczy segment składa się z dwóch okrągłych tarcz, pomiędzy którymi umieszczono balon wypełniony wodą. Wielkość balonu jest dopasowana w taki sposób do rozmiarów tarcz oraz długości sprężyn...
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The influence of polypropylene-block/graft-polycaprolactone copolymers on melt rheology, morphology, and dielectric properties of polypropylene/polycarbonate blends
PublicationThe paper discusses the relationship between rheology and morphology of immiscible polypropylene (matrix))/polycarbonate (dispersed phase) blends compatibilized with novel polypropylene-polycaprolactone block and graft copolymers. Transmission electron microscopy (TEM) experiments revealed uniform droplet morphologies and a reduction of the average size of the dispersed phase upon addition of the compatibilizer. The results suggested...
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New σ-phases in the Nb–X–Ga and Nb–X–Al systems (X = Ru, Rh, Pd, Ir, Pt, and Au)
PublicationPreviously unreported σ-phases in the ternary niobium-based systems Nb–X–Ga for X = Ru, Rh, Pd, Ir, Pt, Au, and Nb–X–Al for X = Ir, and Pt are presented, prepared by arc-melting followed by annealing at 1000 °C for 1 week. The phases are primitive tetragonal (P42/mnm, no. 136) with lattice parameters of a = 9.8336(2)–9.9432(1) Å and c = 5.1098(1)–5.1718(1) Å. Refinements of the single crystal X-ray diffraction data for the Ru and...
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A COMPARISON OF WEAR PROPERTIES OF WATER LUBRICATED NBR AND PTFE SLIDING BEARINGS
PublicationThe excessive wear of a journal shaft can be caused by many factors, for example, working conditions (e.g., temperaturę, slip speed, the type of lubricant), pressure, the type of material used on the bearings and shafts and their roughness, as well as contamination remaining in the system. This paper presents the roughness profiles co-operating with a rubber (NBR) and polytetrafluoroethylene (PTFE) bushes. The conditions of cooperation...
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Ag Loading Enhanced Photocatalytic Activity of g-C3N4 Porous Nanosheets for Decomposition of Organic Pollutants
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Performance Analysis of Multicast Video Streaming in IEEE 802.11 b/g/n Testbed Environment
PublicationThe aim of the work is to analyse capabilities and limitations of different IEEE 802.11 technologies (IEEE 802.11 b/g/n), utilized for both multicast and unicast video streaming transmissions directed to mobile devices. Our preliminary research showed that results obtained with currently popular simulation tools can be drastically different than these possible in real-world environment, so, in order to correctly evaluate performance...
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Nowe rozwiązania automatyzacji procesu łączenia obiektów elektroenergetycznych do pracy równoległej / G. Redlarski.
PublicationDoświadczenia ostatnich lat wskazują, że w licznych sytuacjach ruchowych proces wprowadzania do pracy równoległej kolejnego, elektroenergetycznego obiektu wytwórczego powinien być możliwie krótki, a przebieg tego procesu powinien być monitorowany. W dotychczasowych rozwiązaniach, metody synchronizacji czas trwania procesu synchronizacji traktują drugorzędnie, dążąc do realizacji procesu łączenia z jak największą dokładnością, a...