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Search results for: adiabatic calorimetry
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Non-adiabatic coupling elements between the diatomic silver anion and neutral silver dimer plus continuum electron
Open Research DataThe process of a two-channel decay of the diatomic silver anion (Ag2-), namely the spontaneous electron ejection giving Ag2 + e- and the dissociation leading to Ag- + Ag is theoretically studied. The ground state potential energy curves (PECs) of the neutral silver dimer and anionic silver diatomic molecule are calculated using the single reference...
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Reflectance Measurements and iCone Calorimeter Burning Results of Charcoals Derived from Lake Żabińskie (North-Eastern Poland)
Open Research DataThe dataset presents the results of litter burning experiments using an iCone calorimeter to assess the flammability of the major tree species in the Lake Żabińskie catchment (NE Poland) and links this to the heat release during burning to understand the influence of fire and its effects on ecosystems. Samples of litter from Betula pendula, Pinus sylvestris,...
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Effect of temperature and ionic strength on volumetric and acoustic properties of solutions of urea alkil derivatives in aqueous NaCl
PublicationThe present work was undertaken to study volumetric and acoustic properties for diluted solutions of tetramethylurea in pure water and for urea, n-propylurea, n-butylurea and tetramethylurea in 0.5 or 1 moldm3 aqueous solutions of sodium chloride. This paper presents measured values of densities and sound velocities at T = (288.15, 298.15 and 308.15) K. From these data the apparent molar volumes, , adiabatic compressibilities,...
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Flowers and Leaves Extracts of Stachys palustris L. Exhibit Stronger Anti-Proliferative, Antioxidant, Anti-Diabetic, and Anti-Obesity Potencies than Stems and Roots Due to More Phenolic Compounds as Revealed by UPLC-PDA-ESI-TQD-MS/MS
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Possible schemes of photoassociation processes in the KLi molecule with newly calculated potential energy curves
PublicationWe present four promising schemes for photoassociative formation of KLi molecule in its ground electronic state. Analysis is based on newly calculated adiabatic potentials supported by transition dipole moments and Franck-Condon factors.
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Changes in heat flow of V2O5 nanorods under oxidizing atmosphere
Open Research DataThe DataSet contains the DSC curves of V2O5 nanorods obtained at 650°C. The information about nanorods synthesis is described in the Journal of Nanomaterials.
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Justyna Kucińska-Lipka dr hab. inż.
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The 41Σ+ electronic state of LiCs molecule
PublicationThe 41Σ+ state of LiCs molecule is observed experimentally for the first time. The inverted perturbation approach (IPA) method is used to derive the potential energy curve of the state from the measured spectra. The experiment is accompanied by theoretical calculations of adiabatic potentials for excited states in LiCs including 41Σ+, performed with the MOLPRO program package. The irregular shape of the 41Σ+ state potential predicted...
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Thermal behaviour of vanadium xerogel powder under different inert atmosphere
Open Research DataThe DataSet contains the results of the thermal behavior of the vanadium xerogel powder. The information about xerogel powder synthesis is described in the Journal of Nanomaterials.
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Crystallization kinetics of V2O5 nanorods
Open Research DataThe DataSet contains the DSC curves of As-prepared xerogel powder with different heating rates. The information about sol synthesis is described in the Journal of Nanomaterials.
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Changes in heat flow of V2O5 nanorods under inert atmosphere
Open Research DataThe DataSet contains the DSC curves of V2O5 nanorods obtained at 650°C. The information about nanorods synthesis is described in the Journal of Nanomaterials.
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Changes in heat of vanadium xerogel powder under different atmosphere
Open Research DataThe DataSet contains the DSC curves of the vanadium xerogel powder. The information about xerogel powder synthesis is described in the Journal of Nanomaterials.
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Effects of Basalt and Carbon Fillers on Fire Hazard, Thermal, and Mechanical Properties of EPDM Rubber Composites
PublicationDue to growing restrictions on the use of halogenated flame retardant compounds, there is great research interest in the development of fillers that do not emit toxic compounds during thermal decomposition. Polymeric composite materials with reduced flammability are increasingly in demand. Here, we demonstrate that unmodified graphene and carbon nanotubes as well as basalt fibers or flakes can act as effective flame retardants...
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Application of surface active amino acid ionic liquids as phase-transfer catalyst
PublicationFive structurally related morpholinium derived ionic liquids containing N-acetyl-glycinate anion were synthesized and their thermal stability, surface properties and activity as phase transfer catalysts investigated. The thermal properties were studied by differential scanning calorimetry, while the adsorption at the air/water interface and micellization behavior was analyzed by surface tension measurements, conductometry and isothermal...
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Prevalence of diabetes in Poland: a combined analysis of national databases
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Updated 24-year trend of Type 1 diabetes incidence in children in Poland reveals a sinusoidal pattern and sustained increase
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Transition dipole moments of the lithium dimer
PublicationIn addition to knowledge of interatomic adiabatic potential energy curves of diatomic systems, it is essential to know electronic transition dipole moments. They are needed in understanding processes like photodissociation, photoassociation, cooling, and trapping. Here, we present electronic transition dipole moments calculated for 74 allowed transitions between 26 states of Li2 [P. Jasik, J.E. Sienkiewicz, Chem. Phys. 323 (2006)...
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Thermal stability analysis of poly(lactic acid)-carbon black-nanodiamond composite
Open Research DataThis dataset contains thermal stability tests carried out on new 3D printing-dedicated composites with poly-lactic acid (PLA), carbon black (CB) and nanodiamond fillers. Two types of nanodiamonds were studied: detonation nanodiamonds (DND) and boron-doped carbon nanowalls (BCNW). The investigated techniques include: thermogravimetric analysis (TGA)...
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DSC measurments of ammonium vanadate nanocrystals
Open Research DataThe DataSet contains the thermal behavior of the ammonium vanadate nanostructures obtained by the hydrothermal method with different conditions. Differential scanning calorimetry (DSC) measurement was carried out under an argon atmosphere from 40C to 560C (with a heating rate of 10 C/min) using Netzsch STA 449 F1. The results reveal the differences...
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Thermal behaviour of vanadium xerogel powder and V2O5 nanorods under helium atmosphere
Open Research DataThe DataSet contains the results of the thermal behavior of the vanadium xerogel powder and V2O5 nanorods obtained at 650C. The information about xerogel powder and V2O5 nanorods synthesis is described in the Journal of Nanomaterials.
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Photoelectron and threshold photoelectron valence spectra of pyridine
Publication. The pyridine molecule has been examined by the means of photoelectron and threshold photoelectron spectroscopies. Ionization energies were determined for both outer and inner valence orbitals and new adiabatic values were also resolved. Vibronic structure associated with several states was assigned mainly to be due to C–C stretches and ring bends. Additionally a Rydberg state converging to 7b2 state was ascribed. The data shown...
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Thermal properties of VO2 and V2O3 nanostructures
Open Research DataThe DataSet contains the DSC and TG curves of VO2 and V2O3 nanostructures obtained by the sol-gel with different reaction conditions. The information about xerogel powder synthesis is described in the Journal of Nanomaterials. The xerogel powder was annealing under argon atmosphere at the selected temperature: 500C, 600C, and 1000C.
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Correlation between Compressive Strength and Heat of Hydration of Cement Mortars with Siliceous Fly Ash
PublicationThis paper presents the results of calorimetric and strength tests of mortars with ordinary Portland cement and two substitution rates (10 and 20%) of cement by siliceous fly ash. The prepared samples were cured under isothermal conditions at four different temperatures: 23, 33, 43 and 53 °C. Heat of hydration was measured using an isothermal calorimeter dedicated to monitor the hydration process of cementitious composites such...
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Fruit Pomace as a Component Shaping the Content of Bioactive Compounds and Nutritional, Health-Promoting (Anti-Diabetic and Antioxidant) of Shortcrust Pastries Sweetened with Sucrose and Erythritol
Open Research DataIn this study, an attempt was made to develop shortcrust pastries containing different amounts of chokeberry, apple and blackcurrant pomace (0%, 10%, 30%, 50%), modulating their degree of sweetness via the application of sucrose or erythritol. The obtained products were assessed for their nutritional value (energy value, protein, fats, dietary fibre,...
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Theoretical study of highly-excited states of KRb molecule
PublicationSemi-empirical adiabatic potential energy curves of highly excited states of the KRb molecule are calculated as a function of the internuclear distance R over a wide range from 3 to 150 a0. The diatomic molecule is treated as an effective two-electron system by using the large core pseudopotentials and core polarization potentials. All calculations are performed by using the nonrelativistic CASSCF/MRCI method with accurate basis...
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Experimental investigations on pressure drop during the condensation in flow of HFE7000 in vertical minichannel
PublicationIn the work presented in the paper authors focused attention on the issues of flow resistance and pressure drop during condensation in the flow. The case of the descending flow through a cylindrical single-channel of 2.3 mm inner diameter was carefully analyzed. In the course of investigations a new working fluid HFE 7000 has been scrutinised which has a strongly differing properties in comparison to the other fluids that are commonly...
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Organic Supercritical Thermodynamic Cycles with Isothermal Turbine
PublicationOrganic Rankine cycles (ORC) are quite popular, but the overall efficiencies of these plants are rather very low. Numerous studies have been conducted in many scientific centers and research centers to improve the efficiency of such cycles. The research concerns both the modification of the cycle and the increase in the parameters of the medium at the inlet to the turbine. However, the efficiency of even these modified cycles rarely...
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Quantum-state transfer in spin chains via isolated resonance of terminal spins
PublicationWe propose a quantum-state transfer protocol in a spin chain that requires only the control of the spins at the ends of the quantum wire. The protocol is to a large extent insensitive to inhomogeneity caused by local magnetic fields and perturbation of exchange couplings. Moreover, apart from the free evolution regime, it allows one to induce an adiabatic spin transfer, which provides the possibility of performing the transfer...
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Electronic structure and time-dependent description of rotational predissociation of LiH
PublicationThe adiabatic potential energy curves of the ^1Sigma+ and ^1Pi states of the LiH molecule were calculated. They correlate asymptotically to atomic states, such as 2s + 1s, 2p + 1s, 3s + 1s, 3p + 1s, 3d + 1s, 4s + 1s, 4p + 1s and 4d + 1s. A very good agreement was found between our calculated spectroscopic parameters and the experimental ones. The dynamics of the rotational predissociation process of the 1^1Pi state were studied...
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EXPERIMENTAL VERIFICATION OF THE METHOD OF FLOW BOILING AND FLOW CONDENSATION HEAT TRANSFER PREDICTION FOR SELECTED FLUIDS
PublicationIn the paper presented are the results of calculations using authors own model to predict heat transfer coefficient during flow boiling of different refrigerants. The experimental data from various research studies from literature were collected. Calculations were conducted for a full range of quality variation and a wide range of mass velocity. The aim of the study was to test the sensitivity of the in- house developed model....
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Fourier transform infrared spectroscopy (FTIR) of pre- PXBS (0 h) and PXBS during the crosslinking process (24 h–288 h)
Open Research DataThe goal of this research was developing biodegradable and biocompatibile xylitol-based copolymers with improved mechanical properties, and investigating the change in their thermal and chemical properties withprogress of the cross-linking process. Using a raw material of natural origin such as xylitol, a prepolymer wasobtained by esterification and...
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Thermal behaviour of vanadium xerogel powder under oxidizing atmosphere
Open Research DataThe DataSet contains the results of the thermal behavior of the vanadium xerogel powder. The information about xerogel powder synthesis is described in the Journal of Nanomaterials.
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Thermal behaviour of vanadium xerogel powder under argon atmosphere
Open Research DataThe DataSet contains the results of the thermal behavior of the vanadium xerogel powder. The information about xerogel powder synthesis is described in the Journal of Nanomaterials.
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Experimental Investigation of the Thermal Performance of a Wickless Heat Pipe Operating with Different Fluids: Water, Ethanol, and SES36. Analysis of Influences of Instability Processes at Working Operation Parameters
PublicationIn this study, the influences of different parameters on performance of a wickless heat pipe have been presented. Experiments have been carried out for an input power range from 50 W to 300 W, constant cooling water mass flow rate of 0.01 kg/s, and constant temperature at the inlet to condenser of 10 C. Three working fluids have been tested: water, ethanol, and SES36 (1,1,1,3,3-Pentafluorobutane) with different filling ratios (0.32,...
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Threshold photoelectron studies of isoxazole over the energy range 9.9-30 eV
PublicationThe threshold photoelectron spectrum of the isoxazole molecule, C3H3NO has been measured over the photon energy range 9.9-30 eV with the use of synchrotron radiation. In the 9.9-10.8 eV range, corresponding to photoionization from the highest occupied molecular orbital 3a"(π3), seven well resolved vibrational series have been observed and their modes are tentatively assigned. A strong adiabatic ionization, with an energy of 11.132...
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On the Nonlinear Effects of Magnetoacoustic Perturbations in Optically Thin Quasi-Isentropic Plasmas
PublicationNonlinear effects of planar magnetosound perturbations in a plasma are discussed. Plasma is non-adiabatic due to optically thin radiation and external heating. For these reasons, thermal instability of a plasma may appear which makes it acoustically active. The plasma is assumed to be initially homogeneous ideal gas with infinite electrical conductivity permeated by a straight magnetic field which is orthogonal to the trajectories...
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Born–Oppenheimer potential energy curves of NaK from the optimised atomic basis sets
PublicationThe article presents adiabatic potential energy curves of the ground and excited electronic states for the diatomic NaK molecule. The calculations were made using the ab initio computational methods to include electron correlation. The studied molecule was calculated as the effective two-electron problem, in which only the valence electrons of the molecule are explicitly taken into account. The remaining electrons with atomic nuclei...
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Thermal behavior of TeOx xerogel powder under different atmospheres
Open Research DataThe DataSet contains the results of the thermal behavior of the TeOx xerogel powder measured under different atmospheres. The material was obtained by the sol-gel method. The starting solution was prepared by mixing telluric acid (precursor) with thetraetylene glycol, water, and ethanol. The sol was obtained by vigorously stirring precursor solution...
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Measurements of the Hydraulic Fluids Compressibility
PublicationPerformance of the hydrostatic high-pressure drive systems is affected by the changes of working fluid’s volume. Presence of air bubbles in the fluid cause this problem to be even more serious. To study this phenomenon precise measurements of fluid’s bulk modulus are necessary. Differ-ent measurement methods are applied, but they are either limited to low pressure range or give inaccurate results. To solve the problem the new...
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Betaine and L-carnitine ester bromides: Synthesis and comparative study of their thermal behaviour and surface activity
PublicationSix esters of both betaine and L-carnitine bromides, featuring alkyl groups ranging from C8 to C18 in length, have been synthesized. The thermal behaviour of these twelve bio-based salts has been analyzed and compared by thermal gravimetric analysis and differential scanning calorimetry. The L-carnitine alkyl ester bromides melted below 100 C and can hence be considered ionic liquids (ILs) with full rights. Conversely, the betaine...
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Surface active fatty acid ILs: Influence of the hydrophobic tail and/or theimidazolium hydroxyl functionalization on aggregates formation
PublicationNine structurally-related fatty acid ionic liquids have been prepared and their thermal behavior as well as their ability to self-assemble in water has been investigated. The thermal properties were studied by thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC), while the aggregation behavior was analyzed by tensiometry, isothermal titration calorimetry (ITC), conductometry, dynamic light scattering (DLS),...
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Thermal behavior of VO2/V2O3 nanostructures obtained at 500°C under argon atmosphere
Open Research DataThe DataSet contains the results of the thermal behavior of the VO2/V2O3 nanostructures. The vanadium oxides nanostructures were synthesized by the sol-gel method, where obtained xerogel powder was annealing at 500°C under an argon atmosphere. The information about xerogel powder synthesis is described in the Journal of Nanomaterials.
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Thermal behavior of VO2/V2O3 nanostructures obtained at 1000°C under argon atmosphere
Open Research DataThe DataSet contains the results of the thermal behavior of the VO2/V2O3 nanostructures. The vanadium oxides nanostructures were synthesized by the sol-gel method, where obtained xerogel powder was annealing at 1000°C under an argon atmosphere. The information about xerogel powder synthesis is described in the Journal of Nanomaterials.
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Thermal behavior of VO2/V2O3 nanostructures obtained at 650°C under reducing atmosphere
Open Research DataThe DataSet contains the results of the thermal behavior of the VO2/V2O3 nanostructures. The vanadium oxides nanostructures were synthesized by the sol-gel method, where obtained xerogel powder was annealing at 650°C under a reducing atmosphere (95% Ar 5% H2). The information about xerogel powder synthesis is described in the Journal of Nanomaterials.
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Thermal behavior of VO2/V2O3 nanostructures obtained at 400°C under argon atmosphere
Open Research DataThe DataSet contains the results of the thermal behavior of the VO2/V2O3 nanostructures. The vanadium oxides nanostructures were synthesized by the sol-gel method, where obtained xerogel powder was annealing at 400°C under an argon atmosphere. The information about xerogel powder synthesis is described in the Journal of Nanomaterials.
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Thermal behavior of VO2/V2O3 nanostructures obtained at 700°C under argon atmosphere
Open Research DataThe DataSet contains the results of the thermal behavior of the VO2/V2O3 nanostructures. The vanadium oxides nanostructures were synthesized by the sol-gel method, where obtained xerogel powder was annealing at 700°C under an argon atmosphere. The information about xerogel powder synthesis is described in the Journal of Nanomaterials.
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Thermal behavior of TeOx powder
Open Research DataThe DataSet contains the results of the thermal behavior of the TeOx powder. The material was obtained by the sol-gel method. The starting solution was prepared by mixing telluric acid (precursor) with thetraetylene glycol, water, and ethanol. The sol was obtained by vigorously stirring precursor solution at 50°C for 2h, then the temperature was raised...
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Thermal behavior of VO2/V2O3 nanostructures obtained at 800°C under argon atmosphere
Open Research DataThe DataSet contains the results of the thermal behavior of the VO2/V2O3 nanostructures. The vanadium oxides nanostructures were synthesized by the sol-gel method, where obtained xerogel powder was annealing at 800°C under an argon atmosphere. The information about xerogel powder synthesis is described in the Journal of Nanomaterials.
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Thermal behavior of VO2/V2O3 nanostructures obtained at 600°C under argon atmosphere
Open Research DataThe DataSet contains the results of the thermal behavior of the VO2/V2O3 nanostructures. The vanadium oxides nanostructures were synthesized by the sol-gel method, where obtained xerogel powder was annealing at 600°C under an argon atmosphere. The information about xerogel powder synthesis is described in the Journal of Nanomaterials.
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On the electronic structure of methyl butyrate and methyl valerate
PublicationWe present novel results of the analysis of the electronic structure of two aliphatic esters: methyl butyrate and methyl valerate. High-resolution photoabsorption spectra were collected and analyzed over the energy range 4.0–10.8 eV and showed for both the molecules not only a clear band of the HOMO to LUMO transition, but also vibronic structure associated with the first Rydberg-valence transition. Photoelectron spectra recorded...