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Search results for: Iran
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Syntheses, Structures and Reactivity of Terminal Phosphido Complexes of Iron(II) Supported by a β-Diketiminato Ligand
PublicationWe report the synthesis of the first series of terminal phosphido iron complexes supported by a β‐diketiminato ligand (Dippnacnac) and their catalytic activity in dehydrocoupling of secondary phosphines. Anionic and neutral mono‐ or diphosphido complexes were obtained from the reaction of [(Dippnacnac)FeCl2Li(dme)2] with the R2PLi (R = iPr, tBu, Cy, Ph) phosphides by tuning the stoichiometric ratio, polarity of the solvent, and...
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Study on 19th-century cast iron columns from the former financial office building in Kwidzyn
PublicationThe article presents the results for cast iron columns used as floor supports in the former financial office building in Kwidzyn (Poland).The stocktaking drawings provided the general and detailed data about the 19th century designer’s decisions. During the research, architectural and structural analysis was carried out. The graphics were used as a starting material for preparing 3D calculation models. The FEM-based numerical simulations...
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EXTREME RAINFALLS AS A CAUSE OF URBAN FLASH FLOODS; A CASE STUDY OF THE ERBIL-KURDISTAN REGION OF IRAQ
PublicationAim of the study The current paper aims to give a detailed evaluation and analysis of some extreme rainfall events that happened in the last decade in terms of spatial and temporal rainfall distribution, intensity rate, and exceedance probability. Moreover, it examines the effects of each analysed aspect on the resulting flash floods in the studied area. Material and methods In their glossary of meteorology, American Meteorology...
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SEAISI Quarterly (South East Asia Iron and Steel Institute)
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Facile synthesis of porous iron oxide/graphene hybrid nanocomposites and potential application in electrochemical energy storage
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Effect of Converting Enzyme Inhibitor on Copper and Iron Concentrations of Blood Plasma in Calves During the Neonatal Period
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Impedance spectroscopy studies on hybrid materials consisting of poly(3,4-ethylenedioxythiophene) and iron, cobalt and nickel hexacyanoferrate
PublicationBadania warstw polimeru pEDOT modyfikowanego heksacyjanożelazianami żelaza, kobaltu i niklu przeprowadzono za pomocą spektroskopii impedancyjnej (SI). Wykazano, że materiały hybrydowe charakteryzują się dobrą stabilnością. Warstwy testowano w zakresie temperatur od 283 do 313K. w kontakcie z wodnym roztworem KCl. Wysokie współczynniki dyfuzji wskazują na możliwości wykorzystania układów jako przewodników jonowych.
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Influence of geometry of iron poles on the cogging torque of a field control axial flux permanent magnet machine
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Oscillatory Mechanism of α-Fe(N) ↔ γ’-Fe4N Phase Transformations during Nanocrystalline Iron Nitriding
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The effect of the iron oxidation degree on distribution of promotors in the fused catalyst precursors and their activity in the ammonia synthesis reaction
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Investigation of Iron and Zinc Concentrations in Human Milk in Correlation to Maternal Factors: An Observational Pilot Study in Poland
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Influence of iron content on water uptake and charge transport in BaCe0.6Zr0.2Y0.2−xFexO3−δ triple-conducting oxides
PublicationIn this work, we studied the BaCe0.6Zr0.2Y0.2−xFexO3−δ system which belongs to the triple-conducting oxides (TCOs) group. The electrochemical properties of BaCe0.6Zr0.2Y0.2−xFexO3−δ were investigated using electrochemical impedance spectroscopy (EIS) and the water uptake was analyzed using thermogravimetry (TG). All investigated materials exhibited water uptake, with proton concentration increasing with decreasing iron content....
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Homoleptic mono-, di-, and tetra-iron complexes featuring phosphido ligands: a synthetic, structural, and spectroscopic study
PublicationWe report the first series of homoleptic phosphido iron complexes synthesized by treating either the β-diketiminato complex [(Dippnacnac)FeCl2Li(dme)2] (Dippnacnac = HC[(CMe)N(C6H3-2,6-iPr2)]2) or [FeBr2(thf )2] with an excess of phosphides R2PLi (R = tBu, tBuPh, Cy, iPr). Reaction outcomes depend strongly on the bulkiness of the phosphido ligands. The use of tBu2PLi precursor led to an anionic diiron complex 1 encompassing a planar...
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The pulsed laser ablation synthesis of colloidal iron oxide nanoparticles for the enhancement of TiO2 nanotubes photo-activity
PublicationThe rapid, only a few minutes long synthesis of FeO, Fe3O4, and Fe2O3nanoparticles mixture utilizing the pulsedlaser ablation using simply pure iron target and water was demonstrated. The size and crystal phase of Fe-basedNPs were characterized using DLS and HR-TEM techniques, respectively. The metastable suspension of FeO,Fe3O4, and Fe2O3nanoparticles was used to the decoration of anodized TiO2nanotubes (TiO2-NTs) by means ofthe...
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Preparation and characterisation of iron substituted Mn1.7Cu1.3-xFexO4 spinel oxides (x = 0, 0.1, 0.3, 0.5)
PublicationSpinel oxides with the general formula Mn1.7Cu1.3-xFexO4 (x= 0, 0.1, 0.3, 0.5) were prepared and evaluated in this work for their properties at high temperatures. The effect of partially substituting Cu by Fe has not been studied so far for this group of materials and is thus evaluated in this work. Mn1.7Cu1.3-xFexO4 powders were synthesised by a soft chemistry process and studied in terms of crystallographic phase analysis, electrical...
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The Influence of the Co-Dopant Dexamethasone Phosphate on the Electrodeposition Process and Drug-Release Properties of Polypyrrole-Salicylate on Iron
PublicationIn this work, the influence of incorporation of two anti-inflammatory drugs dexamethasone phosphate and sodium salicylate on the electrodeposition process of polypyrrole (PPy) film on iron has been studied. The incorporation of the agents into PPy has been carried out in a one-step electropolymerization process on oxidizable iron. The role of each drug agent during the deposition process has been discussed. The morphological and...
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A Simple Replica Method as the Way to Obtain a Morphologically and Mechanically Bone-like Iron-Based Biodegradable Material
PublicationPorous iron-based scaffolds were prepared by the simple replica method using polyurethane foam as a template and applying the sintering process in a tube furnace. Their surface morphology was characterized using scanning electron microscopy (SEM) and phase homogeneity was confirmed using X-ray diffraction (XRD). Corrosion behavior was determined using immersion and potentiodynamic polarization methods in phosphate buffered saline...
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Zastosowanie metabolomiki jako przyszłego narzędzia w szybkiej diagnostyce ran przewlekłych
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Wielokrotne wykorzystanie częstotliwości w sieci wirtualnej sliced Cloud-RAN-5G
PublicationCelem referatu jest analiza problemu wirtualizacji sieci dostępowej 5G, w kontekście zwielokrotnienia użycia pasma częstotliwościowego w komórkach. W artykule przeanalizowano problem wirtualizacji w sieci oraz przed-stawiono wyniki badań efektywności metod zwielokrotnienia użycia pasma w komórkach, dla sieci z wirtualnymi warstwami programowymi
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XPS measurements of the iron elements covered by chromium
Open Research DataAnticorrosive coatings are an important issue in modern materials engineering. One of the most commonly used, for that coating materials, is chrome. Three metal elements were measured, named as Turcja, WB Tech and Nomet. Names were given according to producer of elements. XPS measurements of the Cr 2p region give an ansver concering on surface chemical...
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Trudy Instituta Matematiki i Mekhaniki UrO RAN
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Comparative studies of sorption of phenolic compounds onto carbon-encapsulated iron nanoparticles, carbon nanotubes and activated carbon
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Mobility and bioavailability of mercury in sediments of the southern Baltic sea in relation to the chemical fractions of iron: Spatial and temporal patterns
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The role of air masses on iron concentrations in wet atmospheric deposition over the urbanized coastal zone of the Gulf of Gdańsk
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Study of Phase Transformation Processes Occurring in the Nanocrystalline Iron/Ammonia/Hydrogen System by the Magnetic Permeability Measurement Method
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Association of Hepcidin mRNA Expression With Hepatocyte Iron Accumulation and Effects of Antiviral Therapy in Chronic Hepatitis C Infection
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Magnetic, Structural and Spectroscopic Properties of Iron(II)-Octacyanoniobate(IV) Crystalline Film Obtained by Ion-Exchange Synthesis
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Experimental study and numerical simulation on porosity dependent direct reducibility of high-grade iron oxide pellets in hydrogen
PublicationThe transition to more environmentally friendly steel production methods has intensified research into hydrogen-based direct reduction (HyDR) of iron oxide pellets. The aim of this study is to systematically investigate the kinetics of the reduction process, the evolution of porosity and the resulting microstructural changes on the reduction behavior of high-quality pellets during HyDR of iron ore at different temperatures. A modified...
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Mobility and bioavailability of mercury in sediments of the southern Baltic sea in relation to the chemical fractions of iron: Spatial and temporal patterns
PublicationMarine sediments play a significant role as reservoirs for mercury (Hg), a bioaccumulative toxic pollutant that poses risks to human and ecosystem health. Iron (Fe) has been recognized as an influential factor in the complexation and bioavailability of Hg in sediments. However, limited studies have investigated the interactions between the chemical fractions of these elements in natural settings. This study aims to examine the...
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Investigation on structural, optical and anti-bacterial properties of organic additives iron oxide prepared by chemical route method
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Synthesis and adsorptive properties of sulfonated nanocomposites based on carbon-encapsulated iron nanoparticles and styrene-p-divinylbenzene copolymer
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Synthetic, Structural, and Spectroscopic Characterization of a Novel Family of High-Spin Iron(II) [(β-Diketiminate)(phosphanylphosphido)] Complexes
PublicationThis work describes a series of iron(II) phosphanylphosphido complexes. These compounds were obtained by reacting lithiated diphosphanes R2PP(SiMe3)Li (R = t-Bu, i-Pr) with an iron(II) β-diketiminate complex, [LFe(μ2-Cl)2Li(DME)2] (1), where DME = 1,2-dimethoxyethane and L = Dippnacnac (β-diketiminate). While the reaction of 1 with t-Bu2PP(SiMe3)Li yields [LFe(η1-Me3SiPPt- Bu2)] (2), that of 1 with equimolar amounts of i-Pr2PP(SiMe3)Li,...
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Iron–Sulfur Cluster Biogenesis Chaperones: Evidence for Emergence of Mutational Robustness of a Highly Specific Protein–Protein Interaction
PublicationBiogenesis of iron–sulfur clusters (FeS) is a highly conserved process involving Hsp70 and J-protein chaperones. However, Hsp70 specialization differs among species. In most eukaryotes, including Schizosaccharomyces pombe, FeS biogenesis involves interaction between the J-protein Jac1 and the multifunctional Hsp70 Ssc1. But, in Saccharomyces cerevisiae and closely related species, Jac1 interacts with the specialized Hsp70 Ssq1,...
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The Impact of Spatiotemporal Changes in Land Development (1984–2019) on the Increase in the Runoff Coefficient in Erbil, Kurdistan Region of Iraq
PublicationNowadays, geospatial techniques are a popular approach for estimating urban flash floods by considering spatiotemporal changes in urban development. In this study, we investigated the impact of Land Use/Land Cover (LULC) changes on the hydrological response of the Erbil basin in the Kurdistan Region of Iraq (KRI). In the studied area, the LULC changes were calculated for 1984, 1994, 2004, 2014 and 2019 using the Digital Elevation...
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Influence of reactive oxygen species during deposition of iron oxide films by high power impulse magnetron sputtering.
PublicationIron oxide films were deposited using high power impulse magnetron sputtering (HiPIMS) of an iron cathode in an argon/oxygen gas mixture at different gas pressures (0.5~Pa, 1.5~Pa, and 5.0~Pa). The HiPIMS system was operated at a repetition frequency $f = 100$~Hz with a duty cycle of 1~\%. A main goal is a comparison of film growth during conventional and electron cyclotron wave resonance-assisted HiPIMS. The deposition plasma...
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Jacek Tomków dr hab. inż.
PeopleEducation:1. 2018 - Ph.D. of Technical Sciencesin field of Materials Engineeringthesis: Influence of underwater welding conditions on cold cracking of high strength low alloy steel 2. 2012 - Master of Science Engineer, Gdansk University of Technologyin the field of: Mechanical Engineeringwith specialization in: Manufacturing Engineering and Computer Aided Manufacturing Processesthesis: Non-destructive testing of welding joints...
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Linear and nonlinear impedance of iron containing silicate glasses
Open Research DataThe linear and nonlinear impedance ofglasses doped with iron oxide were measured. Glass samples (50 SiO2-50-xPbO-xFe2O3 in mol%) were prepared by the conventional melt quenching technique. The substrates were powdered in a mortar and melted in Al2O3 crucibles. The melting was conducted in air at 1623K. The melts were poured out on plate heated up to...
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Reduced graphene oxide/iron(II) porphyrazine hybrids on glassy carbon electrode for amperometric detection of NADH and L-cysteine
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Inulin-type fructans trigger changes in iron concentration and activity of bone metabolism biomarkers in blood plasma of growing pigs
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ATP4A autoimmunity in pediatric patients with type 1 diabetes and its relationship to blood count, iron metabolism, and vitamin B12
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Evaluation of physical indicators and tool wear during grooving of spheroidal cast iron with a novel WCCo/cBN (BNDCC) inserts
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The level of 8-oxo-7,8-dihydro-2′-deoxyguanosine is positively correlated with the size of the labile iron pool in human lymphocytes
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Model studies to identify input parameters of an algorithm controlling electric supply/consumption process by underground iron ore enterprises
PublicationPurpose is the development of the research format of a mathematical model to select and assess input parameters of an algorithm controlling distribution of electric energy flows in the monitoring structure of electricity supply/ consumption by using equipment of mining enterprises engaged in underground iron ore raw materials extraction. Methods. The analytical research involved a theory of random processes adapted to the real...
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Mapping of Flood-Prone Areas Utilizing GIS Techniques and Remote Sensing: A Case Study of Duhok, Kurdistan Region of Iraq
PublicationOne of the most common types of natural disaster, floods can happen anywhere on Earth, except in the polar regions. The severity of the damage caused by flooding can be reduced by putting proper management and protocols into place. Using remote sensing and a geospatial methodology, this study attempts to identify flood-vulnerable areas of the central district of Duhok, Iraq. The analytical hierarchy process (AHP) technique was...
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Acetate-Induced Disassembly of Spherical Iron Oxide Nanoparticle Clusters into Monodispersed Core−Shell Structures upon Nanoemulsion Fusion
PublicationIt has been long known that the physical encapsulation of oleic acid-capped iron oxide nanoparticles (OA−IONPs) with the etyltrimethylammonium (CTA+) surfactant induces the formation of spherical iron oxide nanoparticle clusters (IONPCs). However, the behavior and functional properties of IONPCs in chemical reactions have been largely neglected and are still not well-understood. Herein, we report an unconventional ligand-exchange...
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Experimental analysis of wear resistance of compacts of fine-dispersed iron powder and tungsten monocarbide nanopowder produced by impulse pressing
PublicationThe paper presents the results of studying the structure and wear resistance of compacts produced from fine dispersed reduced iron powder (average particle size 3–mu m) with the addition of tungsten carbide (WC) nanopowder with the average particle size of 25–30 nm. The mass fraction of tungsten carbide (wolfram carbide) in the powder composition was 5% and 10% of the total mass. Impulse pressing was conducted using the modified...
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Porosity and shape of airborne wear microparticles generated by sliding contact between a low-metallic friction material and a cast iron
PublicationThe wear of brakes in transport vehicles is one of the main anthropogenic sources of airborne particulate matter in urban environments. The present study deals with the characterisation of airborne wear microparticles from a low-metallic friction material / cast iron pair used in car brakes. Particles were generated by a pin-on-disc machine in a sealed chamber at sliding velocity of 1.3 m/s and contact pressure of 1.5 MPa. They...
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The Effect of Cobalt Incorporation into Nickel–Iron Oxide/(oxy)hydroxide Catalyst on Electrocatalytic Performance Toward Oxygen Evolution Reaction
PublicationThis work presents a study on the influence of the addition of cobalt into state-of-the-art nickel–iron (NiFe) mixed oxides/hydroxides/(oxy)hydroxides on their structural and morphological properties, and oxygen evolution reaction (OER) catalytic activity. A one-step electrodeposition process is performed without any additives to fabricate NiFe and x cobalt-doped nickel/iron (xCoNiFe) layer-double-hydroxide catalysts directly on...
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Folic Acid‐Navigated and β‐Cyclodextrin‐Decorated Carbon‐Encapsulated Iron Nanoparticles as the Nanotheranostic Platform for Controlled Release of 5‐Fluorouracil
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Ferrocene-Labeled Carbon-Encapsulated Iron Nanoparticles: The First Magnetic Nanocatalysts for C–H Arylation toward 1,1′-Biphenyl Formation
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