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Search results for: KEPLER
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Characterization of Small Azocrown Ether Stereoisomers.
PublicationWyizolowano i zbadano metodą X-ray, 1H NMR i UV-Vis trwałe izomery E i Z 10-członowej azokorony. Ich struktura w stanie stałym świadczy o naprężonej konformacji w przypadku izomeru trans i nie naprężonej dla izomeru cis. Jest to efektem sprzężenia p grupy azowej z benzenem i naprężenia sterycznego konformacji cząsteczki.
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Entrepreneurial Failure: A Synthesis and Conceptual Framework of its Effects
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A recent developments in polyurethane foams containing a low-cost and pro-ecological modifiers
PublicationDiversity of the polyurethane (PU) foams applications cause that investigation of the relationships between their structure and properties is currently very popular topic among the many research institutions and companies. At the turn of the last years many scientific papers about PU foams and their composites were published. The one of the main research trends in this field is related to the reduction of production costs of...
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Kanał żeglugowy w polskiej części Mierzei Wiślanej
PublicationOmówiono celowość oraz aspekty społeczno-gospodarcze i polityczne budowy kanału żeglugowego. Podano główne funkcje oraz wymiary kanału. Przedstawiono ideę i zasady zrównoważonego rozwoju. Przeanalizowano prognozę wpływu kanału na hydrodynamikę i ekologię wód Zalewu Wiślanego oraz ochronę przeciwpowodziową terenów przyzalewowych. Wskazano możliwości i propozycje wykorzystania urobku z budowy kanału dla celów zagospodarowania turystycznego...
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Recycling of Waste Rubber by the Manufacturing of Foamed Polyurethane-Based Composites—Current State and Perspectives
PublicationWorn car tires are disruptive waste, and the issue of their management is crucial for the natural environment. In many countries, the primary method of end-of-life tires utilization is energy recovery. However, more effective and beneficial for the environment is material recycling. Using them for the production of polymer-rubber composites seems to be an auspicious direction of research. Incorporation of ground tire rubber into...
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Relatively high-Seebeck thermoelectric cells containing ionic liquids supplemented by cobalt redox couple
PublicationMeanwhile no general and reliable equation determining the Seebeck coefficient (S e ) and involving electro-chemical reaction effects was derived for solutions. We reported the database of 15,000 ionic liquids supplemented by three different redox couple systems: 0.01 mol/l Co 3+/2+ (bpy) 3 , 0.01 mol/l I 3-/3I- and 0.2 mol/l 3- /3I- , and the corresponding estimated Seebeck coefficients. We also reported methods for estimating...
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THE IMPACT OF GROUND TIRE RUBBER TREATMENT ON THE THERMAL CONDUCTIVITY OF FLEXIBLE POLYURETHANE/GROUND TIRE RUBBER COMPOSITES
PublicationWaste car tires are burdensome waste, and their utilization is crucial for the natural environment. In many countries, the primary method of their recycling is energy recovery, performed by simple combustion. However, material recycling is much more effective and significantly more beneficial for the natural environment. It results in the generation of ground tire rubber, which can be used to produce polymerrubber composites. It...
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OIL-ASSISTED THERMO-MECHANICAL RECLAMATION OF GROUND TIRE RUBBER
PublicationNowadays, it is crucial to seek for the methods of by-products and waste utilization, considering both environmental and economic factors. The example of waste material generated in the massive amounts, which requires the attention is ground tire rubber generated during recycling of post-consumer car tires. It can be applied as a filler into different polymer matrices, but to enhance its effectivity proper modifications should...
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The Impact of Ground Tire Rubber Oxidation with H2O2 and KMnO4 on the Structure and Performance of Flexible Polyurethane/Ground Tire Rubber Composite Foams
PublicationThe use of waste tires is a very critical issue, considering their environmental and economic implications. One of the simplest and the least harmful methods is conversion of tires into ground tire rubber (GTR), which can be introduced into different polymer matrices as a filler. However, these applications often require proper modifications to provide compatibility with the polymer matrix. In this study, we examined the impact...
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DETERMINATION OF THE HYDROXYL NUMBER OF GROUND TIRE RUBBER PARTICLES VIA MODIFIED TEST METHOD FOR ISOCYANATE GROUPS
PublicationNowadays, considering the environmental trends and law regulations associated with the circular economy, it is very important to seek for the methods of by-products and waste utilization. The example of such material, which requires the attention and recycling method is ground tire rubber generated during recycling of post-consumer car tires. It can be introduced into various polymer matrices as a filler, but to enhance its effectivity...
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THERMOMECHANICAL PERFORMANCE OF FLEXIBLE POLYURETHANE FOAMS AS A FUNCTION OF THE ISOCYANATE INDEX
PublicationPolyurethane foams are very versatile materials applied in different branches of industry. Their popularity is attributed, among others, to the flexibility in engineering their mechanical performance by the adjustment of their formulations. One of the most crucial factors is the isocyanate index, determining the ratio between the free hydroxyl and isocyanate groups present in the polyurethane system. By the change of this ratio,...
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Microwave treatment in waste rubber recycling – recent advances and limitations
PublicationEnvironmentally-friendly microwave heating is increasingly used in polymer chemistry and technology. The selectivity and highly efficiency in the heat transfer present a huge advantage in systems based on recycling, improving their productivity and economic competitiveness. In case of the industrial recycling of waste rubbers, especially end-of-life tires, microwave-induced devulcanization and pyrolysis are nowadays considered...
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WPŁYW KOMUNIKACJI MARKETINGOWEJ NA KSZTAŁTOWANIE ARCHITEKTURY OBIEKTÓW SŁUŻBY ZDROWIA - THE EFFECT OF MARKETING COMMUNICATION ON SHAPING THE ARCHITECTURE OF HEALTHCARE FACILITIES
PublicationXX wiek wraz z rozwojem kultury masowej przyniósł gwałtowny wzrost znaczenia komunikacji marketingowej, która początkowo pełniła rolę głównie informacyjną, związaną z działaniami reklamowymi. Współcześnie można zauważyć zwiększone zainteresowanie specjalistów z dziedziny marketingu oddziaływaniem na człowieka poprzez przestrzeń, w której on przebywa. Podejmowanie działań marketingowych w ramach usług świadczonych przez jednostki...
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Proces zmiany sprzedawcy energii elektrycznej w Polsce
PublicationOstatnie kilkanaście lat w polskiej energetyce to okres dynamicznych zmian. Jednym z istotnych przykładów tych przemian jest liberalizacja rynku energii. Wprowadzone, w krajowej energetyce, mechanizmy rynku konkurencyjnego umożliwiają odbiorcom energii m.in. swobodny wybór sprzedawcy energii elektrycznej w formule TPA. W artykule przedstawiony został proces zmiany sprzedawcy bazujący na generalnej umowie dystrybucji (GUD). W trakcie...
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Vibration surveillance for efficient milling of flexible details fixed in adjustable stiffness holder
PublicationThe paper presents the results of research related to the possibility of using an intelligent workpiece holder with adjustable stiffness, during end milling process. Machining a one side supported flexible workpiece will be performed with constant spindle speed and feed speed. In order to avoid hazardous vibration, stiffness of the especially designed spring (mounted in a workpiece holder) will be modified off-line. In order to...
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Free Vibration of Flexomagnetic Nanostructured Tubes Based on Stress-driven Nonlocal Elasticity
PublicationA framework for the flexomagneticity influence is here considered extending the studies about this aspect on the small scale actuators. The developed model accommodates and composes linear Lagrangian strains, Euler-Bernoulli beam approach as well as an extended case of Hamilton’s principle. The nanostructured tube should subsume and incorporate size effect; however, for the sake of avoiding the staggering costs of experiments,...
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Rapeseed oil methyl ester production in an individual household
PublicationFatty acid methyl esters, commonly known as biodiesel, are a cheap and environmental-friendly fuel substitute for diesel engines. Aside from industrial production, individual biodiesel manufacturing is also and important method of fulfilling the requirements of EU Parliament directive no. 2003/30/WE about supporting the use of renewable fuels in transport. Individual FAME production guarantees easy access to the main raw material...
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Magazynowanie energii cieplnej w gaczu parafinowym. Cz.2
PublicationPrzedstawiono wyniki badań eksploatacyjnych zasobnika ciepła z gaczem parafinowym. Źródłem ciepła był kolektor słoneczny pracujący w warunkach rzeczywistych oraz wytwornica ciepła modelująca jego pracę.
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Magazynowanie energii cieplnej w gaczu parafinowym. Cz.1
PublicationPrzedsatwiono sposoby magazynowania energii z położeniem nacisku na energię cieplną. Scharakteryzowano materiały do magazynowania energii cieplnej i przedstawiono kryteria ich doboru. Następnie skupiono się na gaczu parafinowym, jednym z produktów w przemyśle rafineryjnym. Przeprowadzono badania fizykochemiczne gaczu lekkiego z zawartością 4% oleju, który zastosowano do magazynowania energii cieplnej z kolektora słonecznego. Przedstawiono...
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Projekt zespołowy - Inżynieria Materiałowego II st. - specjalizacja: Inżynieria Materiałów Polimerowych
e-Learning CoursesKurs pt. "Projekt zespołowy" dla kierunku Inżynieria Materiałowego II st. dedykowany dla specjalizacji: Inżynieria Materiałów Polimerowych
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Efecto contagio en el uso del voto electrónico en Estonia: de las elecciones a otros niveles de la administración pública y la sociedad
PublicationEstonia, cuarto país más pequeño de la Unión Europea tras Luxemburgo, Chipre y Malta, con una población que no alcanza el millón y medio de habitantes, ha sido en los últimos años objeto de atención mediática internacional por considerarlo the World’s more digital country (GREENWALD, 2018) , the first “Digital” Country (LUFKIN, 2017) o the Digital Republic (HELLER, 2017); así como uno de los referentes en el mundo académico en...
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A Developer's View of Application Servers Interoperability
PublicationThe paper describes analysis of application servers interoperability that considers both the available level of integration and the required level of development complexity. Development complexity ranges from simple GUI operations to changes of undocumented features in configuration files. We verify if an integration can be established on a given level of development complexity, rather than verify if it is objectively feasible....
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Mono- and bimetallic (Pt/Cu) titanium(IV) oxide photocatalysts. Physicochemical and photocatalytic data of magnetic nanocomposites’ shell
PublicationSurface modification of titania with noble and semi-noble metals resulted in significant enhancement of photocatalytic activity. Presented data, showing the photocatalytic properties of TiO2-M (where M is Pt and/or Cu) photocatalysts were further used as Fe3O4@SiO2/TiO2-M magnetic nanocomposites shells in "Mono- and bimetallic (Pt/Cu) titanium(IV) oxide core-shell photocatalysts with Vis light activity and magnetic separability"...
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Discrete-time estimation of nonlinear continuous-time stochastic systems
PublicationIn this paper we consider the problem of state estimation of a dynamic system whose evolution is described by a nonlinear continuous-time stochastic model. We also assume that the system is observed by a sensor in discrete-time moments. To perform state estimation using uncertain discrete-time data, the system model needs to be discretized. We compare two methods of discretization. The first method uses the classical forward Euler...
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On the Buckling Response of Axially Pressurized Nanotubes Based on a Novel Nonlocal Beam Theory
PublicationIn the present study, the buckling analysis of single-walled carbon nanotubes (SWCNT) on the basis of a new refined beam theory is analyzed. The SWCNT is modeled as an elastic beam subjected to unidirectional compressive loads. To achieve this aim, the new proposed beam theory has only one unknown variable which leads to one equation similar to Euler beam theory and is also free from any shear correction factors. The equilibrium...
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Discrete-time estimation of nonlinear continuous-time stochastic systems
PublicationIn this paper we consider the problem of state estimation of a dynamic system whose evolution is described by a nonlinear continuous-time stochastic model. We also assume that the system is observed by a sensor in discrete-time moments. To perform state estimation using uncertain discrete-time data, the system model needs to be discretized. We compare two methods of discretization. The first method uses the classical forward Euler...
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Are IT professionals sensitive and happy leaders in Poland?
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Modification of Ground Tire Rubber—Promising Approach for Development of Green Composites
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Inhibition of cancer antioxidant defense by natural compounds
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Możliwości zastosowania urządzenia ultradźwiękowego w aspekcie zabiegów chirurgicznych.
PublicationPrezentujemy nowe badania w zakresie możliwości zastosowania alternatywnych urządzeń w aspekcie chirurgicznego cięcia tkanki kostnej w obrębie jamy ustnej. Dotychczasowo powszechnie stosowane urządzenia mechaniczno-obrotowe mają wiele wad: łatwość przegrzania tkanki kostnej, częste uszkodzenia tkanek miękkich okolicy operowanej oraz nierówne brzegi kostne podczas cięcia. Dynamiczny rozwój nauk technicznych pozwolił na wprowadzenie...
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Processing, physico-mechanical and thermal properties of reclaimed GTR and NBR/reclaimed GTR blends as function of various additives
PublicationIn this work, ground tire rubber (GTR) was mechano-chemically reclaimed in the presence of bitumen and various additives. During studies three types of processing and curing additives: (i) peptizer P300; (ii) vulcanization accelerator tetramethylthiuram disulfide (TMTD) and (iii) organic peroxide di(2-tert-butyl-peroxyisopropyl)benzene (BIB1) were applied to enhance reclaiming of GTR. Reclaiming process was evaluated by oscillating...
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Complexes of silanethiolate ligands: Synthesis, structure, properties and application
PublicationThe purposeful syntheses of silanethiolate complexes started approximately in the mid-eighties of the 20th century but no summary of the synthetic efforts has been reported till now. The synthetic methods and the resulting complexes have some common features, which are emphasized throughout the review. Thereby specific difficulties during synthesis are outlined and the structures, properties and possible applications of the resulting...
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Insights into the Thermo-Mechanical Treatment of Brewers’ Spent Grain as a Potential Filler for Polymer Composites
PublicationThis paper investigated the impact of twin-screw extrusion parameters on the properties of brewers’ spent grain. The chemical structure, antioxidant activity, particle size, and color properties, as well as the emission of volatile organic compounds during extrusion, were investigated. The main compounds detected in the air during modifications were terpenes and terpenoids, such as α-pinene, camphene, 3-carene, limonene, or terpinene....
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Modification of Ground Tire Rubber—Promising Approach for Development of Green Composites
PublicationGround tire rubber (GTR) was mechano-chemically modified using a road bitumen 100/150 and two types of organic peroxides: di-(2-tert-butyl-peroxyisopropyl)-benzene (BIB) and dicumyl peroxide (DCP). The impact of used additives on reactive sintering efficiency and physico-mechanical properties of modified GTR was investigated using oscillating disc rheometer measurements, followed by tensile tests and swelling behavior studies....
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Decreased levels of 6-tetrahydrobiopterin in psoriatic epidermis
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Analytical Buckling of FG Nanobeams on The Basis of A New One Variable First-Order Shear Deformation Beam Theory
PublicationIn this work, buckling analysis of functionally graded (FG) nanobeams based on a new refined beam theory has been analyzed. The beam is modeled as an elastic beam subjected to unidirectional compressive loads. To achieve this aim, the new obtained beam theory has only one variable which leads to one equation similar to the Euler beam theory and also is free of any shear correction factor. The equilibrium equation has been...
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Adhesive compliance effect in mode I separation:Profilometry approach
PublicationThe effect of adhesive compliance on the deflection of a loaded, bonded beam was studied using laser profilometry. Experimental data obtained were compared with both Euler-Bernoulli (encastré) and Winkler (one parameter elastic foundation) models. A third, analytical, 2D model, based on shear within the adhesive layer (two parameter elastic foundation), was introduced. Finite element analysis (FEA) was also used to study the effect...
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On forced vibrations of piezo-flexomagnetic nano-actuator beams
PublicationThe effect of excitation frequency on the piezomagnetic Euler-Bernoulli nanobeam taking the flexomagnetic material phenomenon into consideration is investigated in this chapter. The magnetization with strain gradients creates flexomagneticity. We couple simultaneously the piezomagnetic and flexomagnetic properties in an inverse magnetization. Resemble the flexoelectricity, the flexomagneticity is also size-dependent. So, it has...
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ENERLIQ Energy conversion based on ionic liquids and novel SOLID technology
ProjectsProject realized in Faculty of Applied Physics and Mathematics according to 5/2012 agreement from 2012-02-13
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Multi-mode vibronic interactions in the five lowest electronic states of the fluorobenzene radical cation
PublicationThe multi-mode vibronic interactions between the five lowest electronic states of the fluorobenzene radical cation are investigated theoretically, based on ab initio electronic structure data, and employing the linear vibronic coupling model. Low-energy conical intersections, and strong vibronic couplings are found to prevail within the set of X-A and B-C-D cationic states, while the interactions between these two sets of states...
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Edyta Fila-Lepper mgr inż.
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Inorganic Chemistry, GT 2 sem 2021/2022
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Laboratorium z Chemii Nieorganicznej IM 2024
e-Learning CoursesProgram przedmiotu obejmuje 10 ćwiczeń z analizy jakościowej kationów, anionów i substancji nieorganicznych. Ćwiczenia te studenci wykonują indywidualnie. Każde ćwiczenie polega na przeprowadzeniu analizy jakościowej otrzymanej próbki oraz napisaniu sprawdzianu.
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Function and Frustration of Multi-Drug ABC Exporter Protein and Design of Model Proteins for Drug Delivery Using Protein Hydration Thermodynamics
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Molecular insights into receptor binding energetics and neutralization of SARS-CoV-2 variants
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Photophysics of a Ruthenium 4H-Imidazole Panchromatic Dye in Interaction with Titanium Dioxide
PublicationThe photophysics of bis(4,4′-di-tert-butyl-2,2′-bipyridine-κ2N,N′)[2-(4-carboxyphenyl)-4,5-bis(p-tolylimino-κN)imidazolato]ruthenium(II) hexafluorophosphate is investigated, both in solution and attached to a nanocrystalline TiO2 film. The studied substitution pattern of the 4H-imidazole ligand is observed to block a photoinduced structural reorganization pathway within the 4H-imidazole ligand that has been previously investigated....
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Chemical Composition of Industrial Wood Waste and the Possibility of its Management
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Facile and continuous synthesis of graphene nanoflakes in RF thermal plasma
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Synergistic Effects of Bitumen Plasticization and Microwave Treatment on Short-Term Devulcanization of Ground Tire Rubber
PublicationGround tire rubber (GTR) was mechano-chemically modified with road bitumen 160/220 and subsequently treated using a microwave radiation. The combined impact of bitumen 160/220 content and microwave treatment on short-term devulcanization of GTR was studied by thermal camera, wavelength dispersive X-ray fluorescence spectrometry (WD-XRF), static headspace, and gas chromatography-mass spectrometry (SHS-GC-MS), thermogravimetric analysis...
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A Novel Ru(II) Polypyridine Black Dye Investigated by Resonance Raman Spectroscopy and TDDFT Calculations
PublicationThe optical properties of a new(bipyridine)2Ru(4H-imidazole) complex presenting a remarkablebroad absorption in the visible range are investigated. Thestrong overlap of the absorption with the solar radiationspectrum renders the studied complex promising as a blackabsorber and hence as a starting structure for applications inthe field of dye-sensitized solar cells. The correlations betweenstructural and electronic features for...