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Wyniki wyszukiwania dla: oxygen storage materials
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Enhanced oxygen mobility by doping Yb in BaGd1-xYbxMn2O5+δ double perovskite-structured oxygen storage materials
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Evaluation of BaY1−Pr Mn2O5+δ oxides for oxygen storage technology
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Phase Change Thermal Energy Storage – The Experience of the Materials Preparation for the Specific Applications.
PublikacjaThermal energy storage and temperature stabilization is very important in many engineering applications. There are three kinds of thermal energy storage: sensible heat storage, latent heat storage and reversible chemical reaction heat storage. Phase change materials (PCM) absorb, store and release large amounts of energy in the form of latent heat, at constant temperature, called the transition temperature. The amount of heat...
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Phase change thermal energy storage – the experience of the materials preparation for the specific applications.
PublikacjaThermal energy storage and temperature stabilization is very important in many engineering applications. There are three kinds of thermal energy storage: sensible heat, latent heat and reversible chemical reaction heat. Phase change materials (PCM) absorb, store and release large amounts of energy in the form of latent heat, at constant temperature, called the transition temperature. Many innovative applications could be found...
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Organic-inorganic materials for fast charging-discharging processes in energy storage devices
PublikacjaPraca dotyczy materiału kompozytowego złożonego z poli(3,4-etylenodioksytiofenu) i heksacyjanokobaltanu żelaza. Materiał został otrzymany elektrochemicznie bezpośrednio na elektrodzie tytanowej metodą jednoetapowa z zawiesiny zawierającej monomer (EDOT) oraz Fe3[Co(CN)6]2 w postaci proszku. Warstwy pEDOT/FehcCo otrzymane potencjostatycznie ładunkiem od 0,6 do 1,5 C/cm2 charakteryzują się różną grubością (od 1,9 do 4 μm) zależną...
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Powering the Future by Iron Sulfide Type Material (FexSy) Based Electrochemical Materials for Water Splitting and Energy Storage Applications: A Review
PublikacjaWater electrolysis is among the recent alternatives for generating clean fuels (hydrogen). It is an efficient way to produce pure hydrogen at a rapid pace with no unwanted by-products. Effective and cheap water-splitting electrocatalysts with enhanced activity, specificity, and stability are currently widely studied. In this regard, noble metal-free transition metal-based catalysts are of high interest. Iron sulfide (FeS) is one...
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Influence of Storage Time and Temperature on the Toxicity, Endocrine Potential, and Migration of Epoxy Resin Precursors in Extracts of Food Packaging Materials
PublikacjaThe aim of the present study was to establish a standard methodology for the extraction of epoxy resin precursors from several types of food packages (cans, multi-layered composite material, and cups) with selected simulation media (distilled water, 5% ethanol, 3% dimethyl sulfoxide, 5% acetic acid, artificial saliva) at different extraction times and temperatures (factors). Biological analyses were conducted to determine the acute...
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Deep insight into the pore size distribution of N-doped porous carbon materials on electrochemical energy storage and CO2 sorption
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Polymer derived SiOC/Sn nanocomposites from a low-cost single source precursor as anode materials for lithium storage applications
PublikacjaMetal- based materials capable of lithium (Li) alloy formation are key to realization of the next generation of high-energy density anodes for Li-ion batteries, owing to their high storage capacity. Designing a good sup- porting matrix is essential for homogeneously nesting these metallic nanodomains, to effectively utilize their high capacity while tackling the volume expansion issues. Silicon oxycarbides (SiOC), obtained via...
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Enhanced electrochemical performance of partially amorphous La0.6Sr0.4CoO3-δ oxygen electrode materials for low-temperature solid oxide cells operating at 400 °C
PublikacjaThis work evaluates partially amorphous La0.6Sr0.4CoO3-δ (LSC) as a potential oxygen electrode for lowtemperature solid oxide cells. LSC was deposited using the spin-coating technique onto Ce0.8Gd0.2O2-δ (CGO) substrates. The optimal oxygen electrode thickness was determined as 500 nm. The electrochemical impedance spectroscopy (EIS) study showed a significant improvement in oxygen reduction/oxidation reaction kinetics when annealing...
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Deep learning for ultra-fast and high precision screening of energy materials
PublikacjaSemiconductor materials for energy storage are the core and foundation of modern information society and play important roles in photovoltaic system, integrated circuit, spacecraft technology, lighting applications, and other fields. Unfortunately, due to the long experiment period and high calculation cost, the high-precision band gap (the basic characteristic parameter) of semiconductor is difficult to obtain, which hinders the...
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The phenomenon of increasing capacitance induced by 1T/2H-MoS2 surface modification with Pt particles – Influence on composition and energy storage mechanism
PublikacjaIn this paper, several approaches to the synthesis of molybdenum-based electrode materials for supercapacitors are presented, including anodization, hydrothermal process and annealing. For the material prepared via anodization of a molybdenum plate, followed by a hydrothermal process in thiourea aqueous solution, a thorough study of the Pt-surface modification through repetitive cycling in 1 M sulfuric acid with Pt acting as a...
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The Role of Proteins in Food
PublikacjaThis chapter describes the effect of proteins on the sensory attributes and the biological value and safety of foods. The role of proteins depends on their amino acid composition and structure, on changes due to storage and processing, as well as on interactions with other food components. The effect on the sensory quality of foods is brought about by hydrophobicity, solubility, water holding capacity, gelling, film formation,...
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Tuning the Laser-Induced Processing of 3D Porous Graphenic Nanostructures by Boron-Doped Diamond Particles for Flexible Microsupercapacitors
PublikacjaCarbon (sp3)-on-carbon (sp2) materials have the potential to revolutionize fields such as energy storage and microelectronics. However, the rational engineering and printing of carbon-on-carbon materials on flexible substrates remains a challenge in wearable electronics technology. This study demon-strates the scalable fabrication of flexible laser-induced graphene (LIG)-boron doped diamond nanowall (BDNW) hybrid nanostructures...
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Electroactive polymer/graphene oxide nanostructured composites; evidence for direct chemical interactions between PEDOT and GOx
PublikacjaThis work concerns electrochemical synthesis of nanocomposites consisting of conducting polymer and reduced graphene oxide (rGOx) as electrode materials for supercapacitors. The electrosynthesis was performed in an aqueous solution of the 3,4-ethylenedioxytiophene (EDOT) monomer and graphene oxide (GOx) without supporting electrolyte. The amount of GOx was optimized to obtain the best electrochemical performance of the nanocomposite...
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Performance of cryogenic oxygen production unit with exhaust gas bleed for sewage sludge gasification and different oxygen purities
PublikacjaThe paper presents a thermodynamic analysis of the integration of a cryogenic air separation unit into a negative CO2 emission gas power plant. The power cycle utilizes sewage sludge as fuel so this system fits into the innovative idea of bioenergy with carbon capture and storage. A cryogenic air separation unit integrated with the power plant was simulated in professional plant engineering and thermodynamic process analysis software....
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Partial inhibition of borohydride hydrolysis using porous activated carbon as an effective method to improve the electrocatalytic activity of the DBFC anode
PublikacjaCarbon materials are commonly used catalyst supports in various types of fuel cells. Due to the possibility of designing their properties, they seem to be attractive and functional additives. In Direct Borohydride Fuel Cells (DBFCs), the electrooxidation reaction of borohydride competes with the undesirable hydrolysis reaction, therefore our work aimed to modify anodes based on a multi-component hydrogen storage alloy with a small...
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Nanokrystaliczne warstwy ceramiczne otrzymywane metodą pirolizy aerozolowej w tlenkowych ogniwach paliwowych
PublikacjaNiniejsza rozprawa doktorska dotyczy badań materiałów wytwarzanych w postaci cienkich, nanokrystalicznych warstw ceramicznych metodą pirolizy aerozolowej dla zastosowań w tlenkowych ogniwach paliwowych (SOFC). Badane są trzy możliwe obszary zastosowań wytwarzanych warstw tj. osadzanie powłok ochronnych na stalowych interkonektorach dostarczających gazy do elektrody tlenowej, wytwarzanie bariery ochronnej zapobiegającej dyfuzji...
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Silicon oxycarbide ceramics as anodes for lithium ion batteries: influence of carbon content on lithium storage capacity
PublikacjaWe report here on the synthesis and characterization of silicon oxycarbide (SiOC) in view of its application as a potential anode material for Li-ion batteries. SiOC ceramics are obtained by pyrolysis of various polysiloxanes synthesized by sol–gel methods. The polysiloxanes contain different organic groups attached to silicon, which influence the chemical composition and the microstructure of the final ceramic product. The structure...
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Noise related to gas bottles explosions
PublikacjaModern industrialized world is in a never ending danger of accidents and catastrophes of technical nature. Some of them may involve fires and explosions of gas storage bottles or containers. Technical University of Gdansk, Poland performed numerous tests where bottles containing acetylene, oxygen, hydrogen, CO2, LPG, LNG or CNG were blown due to excessive temperature caused by fire. Although those experiments were not focused on...
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Modyfikacja kompozytów elastomerowych NR za pomocą ligniny i glicerolizatu
PublikacjaPrzedmiotem opisanych w niniejszym artykule badań są wulkanizaty kauczuku naturalnego. Celem pracy było zbadanie wpływu ligniny oraz glicerolizatu na wybrane właściwości kompozytów zawierających kauczuk naturalny. Strukturę chemiczną przygotowanych materiałów potwierdzono, wykorzystując analizę spektroskopową w podczerwieni (FTIR). Zbadano również właściwości mechaniczne przy statycznym rozciąganiu, twardość, ścieralność oraz odbojność...
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Negative CO2 Emission Gas Power Plant As Technology for Utilization of Sewage Sludge, Production of Electrical Energy, and CO2 Capture - Case of Chamber Under Transpiration Cooling
PublikacjaThis work focuses on the concept developed in the nCO2PP project, which aims to demonstrate a technology that allows to achieve negative CO2 emissions through Carbon Capture and Storage (CCS) applied to sewage sludge. A feedstock is first gasified, then the resulting syngas is burned in a semi-closed oxy-fuel gas turbine with pure oxygen and water, using the advantages of oxy-combustion, to ease the capture of CO2 in the resulting...
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Transparent nanocomposite coatings based on epoxy and layered double hydroxide: Nonisothermal cure kinetics and viscoelastic behavior assessments
PublikacjaLayered double hydroxide (LDH) has a particular place in clay family because of its flame retardant action. The nanoplatelet-like structure of LDH makes possible development of polymer composites with cationic or anionic nature structures in which macromolecules are positioned in between nanoplatelet galleries. In this work, neat epoxy and its transparent nanocomposite coatings with sodium dodecylbenzene sulfonate (SDBS)-modified...
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Hebb–Wagner polarization method for determining the oxygen ion conductivity in barium cerate-zirconate
PublikacjaIn this work, the partial conductivity of oxygen ions in BaCe0.6Zr0.2Y0.2O3 was studied at different temperatures and water partial pressures. For this purpose, a modified DC Hebb–Wagner polarization method with an electrode blocking for protons and electrons was used. A new type of measuring cell as well as a suitable calculation model were proposed for the determination of partial oxygen ionic conductivity in materials with three...
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Laser-Assisted Synthesis and Oxygen Generation of Nickel Nanoparticles
PublikacjaNowadays, more than ever, environmental awareness is being taken into account when it comes to the design of novel materials. Herein, the pathway to the creation of a colloid of spherical, almost purely metallic nickel nanoparticles (NPs) through pulsed laser ablation in ethanol is presented. A complex description of the colloid is provided through UV-vis spectroscopy and dynamic light scattering analysis, ensuring insight into...
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Effects of beach wrack on the fate of mercury at the land-sea interface – A preliminary study
PublikacjaSince the 1970s, the amount of aquatic plants and algae debris, called beach wrack (BW), has increased along the shores of industrialised regions. The strong ability of primary producers to accumulate pollutants can potentially result in their deposition on the beach along with the BW. Despite that, the fate and impact of such pollutants on sandy beach ecosystems have not been investigated so far. This study examines the fate...
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Oxygen sensitivity of hydrogenesis’ and methanogenesis’
PublikacjaIn the chapter, results of dark fermentation of sour cabbage in presence of oxygen with concentrations 2-9% are presented. The presence of oxygen in such concentration inhibits methanogesis (and methane production more than 2 times) and increases hydrogen production 6 times. It also shortens the fermentation process above 40%.
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Thermodynamic analysis of the Compressed Air Energy Storage system coupled with the Underground Thermal Energy Storage
PublikacjaImprovement of flexibility is one of the key challenges for the transformation of the Polish Power System aiming at a high share of renewable energy in electricity generation. Flexible and dispatchable power plants will contribute to this ongoing transformation process as they compensate for fluctuations in electricity generation from renewable energy sources such as wind and photovoltaics. In this context, CAES storage tanks are...
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GRAPHENE-BASED SUPERCAPACITORS APPLICATION FOR ENERGY STORAGE
PublikacjaRecent advances in graphene-based supercapacitor technology for energy storage application were summarized. The comparison of different types of electrode materials in such supercapacitors was performed. The supercapacitors with graphene-based electrodes exhibit outstanding performance: high charge-discharge rate, high power density, high energy density and long cycle-life, what makes them suitable for various applications, e.g....
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Reliable renewable energy – application of electrochemical capacitors for electrical energy storage
PublikacjaThis paper presents electrical energy storage devices such as electrochemical capacitors, their principle of operation and electrode materials most commonly used in their manufacturing technology. Moreover, our research on development of new nanocomposite materials based on multi-walled carbon nanotubes and conducting polymer is shown. Additionally, the possibility and advantages of application of supercapacitors for accumulation...
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Synthesis and Characterization of Poly(zwitterionic) Structures for Energy Conversion and Storage
PublikacjaZwitterions are unique class of molecules that possess two functional groups bearing electric charges, one positive and second negative. This setup results in peculiar properties such as high water retention and anti-fouling capability. Therefore, zwitterionic coatings and gels are commonly applied in e.g. biosensing and bioelectronic devices. Despite those applications, there are other perspectives for zwitterionic materials....
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Production of singlet oxygen atoms by photodissociation of oxywater
PublikacjaQuantum chemical calculations are reported for the energies of the few lowest electronic singlet states of oxywater along dissociation of the oxygen-oxygen bond into water and singlet oxygen using multistate multireference second-order Møller–Plesset perturbation theory. We compute an energy of 21 kcal/mol to remove one oxygen atom in the lowest singlet state. The two lowest excited singlet states have vertical excitation energies...
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Agricultural products' storage control system
PublikacjaThe paper discusses the idea and the design of a remote control system for storage management of agricultural products which temperature may rise as the result of biological processes during the storage. An actual potatoes storehouse is discussed as an application for the proposed automation system. Because of existing buildings and infrastructure at the farm, wireless data transfer system has been proposed for communication between...
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Platelets in fetal growth restriction: role of reactive oxygen species, oxygen metabolism, and aggregation.
PublikacjaFetal growth restriction (FGR) is mainly caused by failure of the uteroplacental unit. Theexact pathogenesis remains unclear. The cause is thought to be related to abnormal platelet activation,which may...
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Potentiometric Oxygen Sensor with Solid State Reference Electrode
PublikacjaThe concentration or the partial pressure of oxygen in an environment can be determined using different measuring principles. For high temperature measurements of oxygen, ceramic-based sensors are the most practical. They are simple in construction, exploration and maintenance. A typical oxygen potentiometric sensor consists of an oxygen ion conducting solid electrolyte and two electrodes deposited...
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Hydrogen Storage in Geological Formations—The Potential of Salt Caverns
PublikacjaHydrogen-based technologies are among the most promising solutions to fulfill the ze- ro-emission scenario and ensure the energy independence of many countries. Hydrogen is considered a green energy carrier, which can be utilized in the energy, transport, and chemical sectors. However, efficient and safe large-scale hydrogen storage is still challenging. The most frequently used hydrogen storage solutions in industry, i.e., compression...
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Development of iron doped strontium titanates as oxygen electrode for solid oxide fuel cells
PublikacjaProducing efficient solid oxide fuel cells (SOFC) without the use of harmful elements is one of the current challenges. Increasing the safety of people and reducing production costs is possible, among others, thanks to the use of iron doped strontium titanates as porous oxygen electrodes. In this thesis, the results of research on iron doped strontium titanates as potential oxygen electrodes for SOFC are presented. The research...
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The Influence of Iron Doping on Performance of SrTi1-XFexO3-δ Perovskite Oxygen Electrode for SOFC
PublikacjaSolid Oxide Fuel Cells (SOFC) are based on electrolytes and mixed ionic and electronic conductivity (MIEC) materials. The need to reduce costs causes an increase in interest of new compounds suitable for operating temperatures between 600 °C and 800 °C. The SrTi1-xFexO3 (STF) perovskite material is a perspective material that could be used for the oxygen electrodes. In this work STF materials with different content of iron (x =...
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Post-Pyrolytic Carbon as a Phase Change Materials (PCMs) Carrier for Application in Building Materials
PublikacjaThis article covers new application for char as a carrier of phase-change materials (PCM) that could be used as an additive to building materials. Being composed of bio-char and PCM, the granulate successfully competes with more expensive commercial materials of this type, such as Micronal® PCM. As a PCM carrier, char that was obtained from the pyrolysis of chestnut fruit (Aesculus hippocastanum) with different absorbances of the...
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Superimposed ice as nutrient storage
PublikacjaNutrient cycling in the glacial environment is known from the perspective of meltwater release and snowpack elution processes, but the superimposed ice temporary storage remains poorly understood. In this study, the enrichment of superimposed ice in nutrient ions: nitrite, nitrate and ammonium was studied in more detail. The release of these ions from superimposed ice into a supraglacial stream was considered also, additionally...
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Tailoring properties of reduced graphene oxide by oxygen plasma treatment
PublikacjaWe report an easily controllable, eco-friendly method for tailoring the properties of reduced graphene oxide (rGO) by means of oxygen plasma. The effect of oxygen plasma treatment time (1, 5 and 10 minutes) on the surface properties of rGO was evaluated. Physicochemical characterization using microscopic, spectroscopic and thermal techniques was performed. The results revealed that different oxygen-containing groups (e.g. carboxyl,...
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The Influence of Storage on Human Milk Lipidome Stability for Lipidomic Studies
PublikacjaHuman milk (HM) lipidome stability during storage is crucial in lipidomic studies to avoid misinterpretations. Facing the lack of comprehensive work on the HM lipidome stability, we performed a study on a potential alteration in the lipid profiles of HM samples stored under different conditions. An untargeted LC-Q-TOF-MS-based approach was applied to study the influence of storage conditions as well as the interaction of the storage...
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Effect of Storage Conditions of Rutile Flux Cored Welding Wires on Properties of Welds
PublikacjaThe influence of storage locations of two grades of rutile flux cored welding wires on their surface condition and the strength of the welds made with them were studied. Wires were stored in real urban conditions (Gdańsk and Katowice) for 1 month, simultaneously recording changes in conditions: temperature and relative humidity of the environment. Visual tests of wires in the delivered and stored condition as well as visual and...
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Mobile wireless measurement system for potatoes storage management
PublikacjaThe paper discusses the idea and the design of a remote control system for a storage management of agricultural products which temperature may rise in a result of biological processes during the storage. Exemplary potatoes storehouse is discussed as an application of the automation system. Because of existing buildings and infrastructure in the farm, wireless data transfer system has been proposed for both sensors to data acquisition...
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New technologies for green hydrogen activation, storage, and transportation
PublikacjaDeveloping new green hydrogen activation, storage, and transportation technologies is a highly complex and multidisciplinary endeavor. This challenge arises from integrating various scientific, engineering, and environmental considerations. Effective evaluation of green hydrogen technologies involves a holistic approach that considers not only the technical aspects but also economic, environmental, and social factors. These criteria...
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ECONOMICAL AND SAFE METHOD OF GRANULAR MATERIAL STORAGE IN SILOS IN OFFSHORE PORT TERMINALS
PublikacjaThe article discusses issues related with storage of granular materials in silos made of corrugated sheets and reinforced with vertical ribs. Advantages and disadvantages of these structures are named, and typical technological solutions used by largest silo producers are presented. Moreover, basic assumptions of Eurocode 3 are discussed in the context of determining the buckling load capacity of a ribbed jacket. Alternative methods...
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Silicon Oxycarbide-Graphite Electrodes for High-Power Energy Storage Devices
PublikacjaHerein we present a study on polymer-derived silicon oxycarbide (SiOC)/graphite composites for a potential application as an electrode in high power energy storage devices, such as Lithium-Ion Capacitor (LIC). The composites were processed using high power ultrasound-assisted sol-gel synthesis followed by pyrolysis. The intensive sonication enhances gelation and drying process, improving the homogenous distribution of the graphitic...
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Hybrid storage management system consisting of supercapacitors and AHI batteries
PublikacjaIn the article the hybrid storage, composed of Aqueous Hybrid Ion battery and supercapacitor was presented. The system was tested through simulation studies. The work also describes the construction and properties of the developed device meant to control the energy flow of the storage and a communication system for remote parameter supervision.
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A review of phase change materials and heat enhancement methodologies
PublikacjaPhase change materials (PCMs) are an efficient alternative to store and release heat at a specific range of temperature. Here PCMs and heat enhancement methodologies for PCM storage are reviewed. A short overview of PCMs and their applications is presented in addition to the progress during the last 10 years. Heat enhancement techniques, that is, extended surfaces, multiple and composite PCMs, and encapsulation techniques, are...
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Shape Memory Materials from Rubbers
PublikacjaSmart materials are much discussed in the current research scenario. The shape memory effect is one of the most fascinating occurrences in smart materials, both in terms of the phenomenon and its applications. Many metal alloys and polymers exhibit the shape memory effect (SME). Shape memory properties of elastomers, such as rubbers, polyurethanes, and other elastomers, are discussed in depth in this paper. The theory, factors...