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Wyniki wyszukiwania dla: TRIMETHYLAMINE-N-OXIDE
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Effect of sintering temperature on electrochemical performance of porous SrTi1-xFexO3-δ (x = 0.35, 0.5, 0.7) oxygen electrodes for solid oxide cells
PublikacjaThis work evaluates the effects of the sintering temperature (800 °C, 900 °C, 1000 °C) of SrTi1-xFexO3-δ (x = 0.35, 0.5, 0.7) porous electrodes on their electrochemical performance as potential oxygen electrode materials of solid oxide cells. The materials were prepared by a solid-state reaction method and revealed the expected cubic perovskite structure. After milling, the powders were characterised by a sub-micrometre particle...
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Effect of composition on the thermal properties and structure of M-Al-Si-O-N glasses, M = Na, Mg, Ca
PublikacjaThe primary objective of this study is to explore the relationship between the composition, structure, and thermal characteristics of M-Al-Si-O-N glasses, with M representing sodium (Na), magnesium (Mg), or calcium (Ca). The glasses were prepared by melting in a quartz crucible at 1650 °C and AlN precursor (powder) was utilized as a nitrogen source. The measured thermal properties studied were glass transition temperature (Tg),...
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In situ study of a composition of outlet gases from biogas fuelled Solid Oxide Fuel Cell performed by the Fourier Transform Infrared Spectroscopy
PublikacjaThe purpose of this study was to develop a method and software based on the Fourier Transform Infrared Spectroscopy for the in-situ, quantitative analysis of the composition of outlet gases from Solid Oxide Fuel Cell (SOFC). The calibration procedure performed at the beginning of the experiment indicated a polynomial dependence between the concentration of a calibrating gas (CO, CO2, CH4) and the corresponding integrated absorbance in...
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Simultaneous determination of individual isothiocyanates in plant samples by HPLC-DAD-MS following SPE and derivatization with N-acetyl-l-cysteine
PublikacjaThe procedure for the isothiocyanates (ITCs) determination that involves derivatization with N-acetyl-l-cysteine (NAC) and separation by HPLC was developed. Prior to derivatization, plant ITCs were isolated and purified using solid-phase extraction (SPE). The optimum conditions of derivatization are: 500 μL of isopropanolic eluate obtained by SPE combined with 500 μL of derivatizing reagent (0.2 M NAC and 0.2 M NaHCO3 in water)...
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Ni/cerium Molybdenum Oxide Hydrate Microflakes Composite Coatings Electrodeposited from Choline Chloride: Ethylene Glycol Deep Eutectic Solvent
PublikacjaCerium molybdenum oxide hydrate microflakes are codeposited with nickel from a deep eutectic solvent-based bath. During seven days of exposure in 0.05 M NaCl solution, the corrosion resistance of composite coating (Ni/CeMoOxide) is slightly reduced, due to the existence of some microcracks caused by large microflakes. Multielemental analysis of the solution, in which coatings are exposed and the qualitative changes in the surface...
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Corncob-supported calcium oxide nanoparticles from hen eggshells for cadmium (Cd-II) removal from aqueous solutions; Synthesis and characterization
PublikacjaThis study investigated the efficient removal of cadmium ions from aqueous solutions using calcium oxide nanoparticles (CaO NPs) synthesized from waste hen eggshells using a Sol-gel method and supported on corncob bio-adsorbent. The synthesized CaO NPs were characterized using FT-IR, XRD, specific surface area, and TGA. Batch adsorption experiments were conducted to examine the influence of process parameters such as adsorbent...
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High-performance anode-supported solid oxide fuel cells with co-fired Sm0.2Ce0.8O2-δ/La0.8Sr0.2Ga0.8Mg0.2O3−δ/Sm0.2Ce0.8O2-δ sandwiched electrolyte
PublikacjaIn this study, intermediate-temperature solid oxide fuel cells (IT-SOFCs) with a nine-layer structure are constructed via a simple method based on the cost-effective tape casting-screen printing-co-firing process with the structure composed of a NiO-based four-layer anode, a Sm0.2Ce0·8O2-δ(SDC)/La0·8Sr0.2Ga0.8Mg0·2O3−δ (LSGM)/SDC tri-layer electrolyte, and an La0·6Sr0·4Co0·2Fe0·8O3-δ (LSCF)-based bi-layer cathode. The resultant...
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The Occurrence of Cancer and of Adenomae in the Large Bowel and the Concentration of N -Nitrosamines in the Gastric Juice
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Starch-grafted-N-vinylformamide copolymers manufactured by reactive extrusion: synthesis and characterization
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Sensitivity of binomial N‐mixture models to overdispersion: The importance of assessing model fit
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Conformers and hydrogen bond transformations in N-methylpiperidine betaine 2,4-dinitrophenolate crystals
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The existence and gas phase acidity of the HAlnF3n+1 superacids (n=1–4)
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New preparation of a carbon-TiO2 photocatalyst by carbonization of n-hexane deposited on TiO2
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Ontology supported selection of versions for N-version programming in semantic web services
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Action of an Antiserum to a-Tocoquinone on Photosystem II-Particle Preparations of N icotiana tabacum
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Generation and stability of N-phenacyl-4-R-pyridinium ylides in silicon polypodands
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Complexes of manganese(II) tri-tert-butoxysilanethiolate with chelating N-donor ligands.
PublikacjaTri-tert-butoksysilanotiolan manganu(II) jest związkiem wrażliwym i rozkładającym się w warunkach atmosferycznych. Z tego względu synteza jego pochodnych z chelatującymi zasadami heterocyklicznymi takimi jak 1,10-fenantrolinaza czy 2,2'-bipirydyl wydawał się dogodną metodą otrzymania bardziej stabilnych układów. Otrzymane w ten sposób krystaliczne proszki wykazują znacznie wyższą stabilność temperaturową, możliwe jest więc przechowywanie...
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Solvation of N-methylformamide by ethanol: a comparison of molecular dynamics calculations with the experimental data
PublikacjaWykonano obliczenia metodami dynamiki molekularnej dla tytułowego układu. Rezultaty porównano z uzyskanymi wcześniej wynikami pomiarów termodynamicznych oraz wnioskami z nich wyciągniętymi.
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A convenient synthesis of (S)-O-benzyl-N-tert-butoxycarbonyl-beta-tyrosine.
PublikacjaOpracowano dogodną metodę syntezy tytułowego aminokwasu z aldehydu 4-benzyloksybenzoesowego, kwasu malonowego i octanu amonu. Otrzymany aminokwasu rozdzielono na enancjomery poprzez krystalizację soli diastereoizomerycznej z kwasem L-winowym.
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Manganese–Cobalt Based Spinel Coatings Processed by Electrophoretic Deposition Method: The Influence of Sintering on Degradation Issues of Solid Oxide Cell Oxygen Electrodes at 750 °C
PublikacjaThis paper seeks to examine how the Mn–Co spinel interconnect coating microstructure can influence Cr contamination in an oxygen electrode of intermediate temperature solid oxide cells, at an operating temperature of 750 °C. A Mn–Co spinel coating is processed on Crofer 22 APU substrates by electrophoretic deposition, and subsequently sintered, following both the one-step and two-step sintering, in order to obtain significantly...
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Mono- and bimetallic (Pt/Cu) titanium(IV) oxide core–shell photocatalysts with UV/Vis light activity and magnetic separability
PublikacjaTitanium(IV) oxide is one of the most widely investigated photocatalysts. However, separation of nano-sized particulate titania might result in profitless technologies for commercial applications. Additionally, bare titania is almost inactive under the Vis range of solar spectrum due to its wide bandgap. Therefore, the present study aims to prepare novel coreinterlayer- shell TiO2 magnetic photocatalysts modified with metal nanoparticles...
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Evaluation of the effect of ruthenium oxide on the properties of composite electrodes used in cathodic protection
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Evaluation of La0.3Sr0.7Ti1−xCoxO3 as a potential cathode material for solid oxide fuel cells
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Efficient and Economically Favorable Co-Free Air Electrodes for Solid Oxide Cells
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Comparison of the Toxicity of Pristine Graphene and Graphene Oxide, Using Four Biological Models
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Influence of Magnesium Oxide on the Structure and Catalytic Activity of the Wustite Catalyst for Ammonia Synthesis
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Reduction Process of Iron Catalyst Precursors for Ammonia Synthesis Doped with Lithium Oxide
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Optically poled SHG and THG effects in cesium doped zinc oxide nanorods
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High temperature oxidation of porous alloys for solid oxide fuel cell applications
PublikacjaW pracy proszki PI600, 317L i 430L stali użyto do przygotowania porowatych metalowych podłoży dla tlenkowych ogniw paliwowych. Po spiekaniu w różnych temperaturach oceniana była ich porowatość i wysokotemperaturową odporność na korozję. Cykliczna analiza termograwimetryczna, dyfraktometria rentgenowska i obrazów SEM były używane do opisu właściwości tych porowatych stopów. Właściwości elektryczne badano dla wybranych próbek. Wpływ...
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Composite materials for Solid Oxide Fuel Cells - various ways of preparation and application
PublikacjaWykonano przeglad mozliwosci zastosowania materialow kompozytowych w wysokotemperaturowych tlenkowych ogniwach paliwowych oraz scharakeryzowano najbardziej popularne metody wytwarzania i nakladania tego typu materialow.
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Detection of thermal radiation using lanthanum-strontium-iron oxide (LSFO) bolometers
PublikacjaW artykule przedstawiono bolometr wykonany z tlenków lantanowo-strontowo-żelazowych zastosowany do detekcji promienowania podczerwonego. Parametry bolometru były badane za pomocą wzorcowego źródła poromieniowania o temperaturze 38°C (311 K) oddalonego od bolometru o 500 mm. W trakcie pomiarów uzyskano stosunek sygnał/szum wynoszący ok. 62 (tj. 35.9 dB). Na podstawie wyników pomiarów oszacowano dokładność pomiaru temperatury za...
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Fabrication of anti-corrosion nitrogen doped graphene oxide coatings by electrophoretic deposition
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Exhaled nitric oxide in smokers and former smokers with chronic obstructive pulmonary disease
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Neuronal Nitric Oxide Synthase Induction in the Antitumorigenic and Neurotoxic Effects of 2-Methoxyestradiol
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Tuning of the Titanium Oxide Surface to Control Magnetic Properties of Thin Iron Films
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Synthesis and antimicrobial and nitric oxide synthase inhibitory activities of novel isothiourea derivatives
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Novel Photocatalytic Nanocomposite Made of Polymeric Carbon Nitride and Metal Oxide Nanoparticles
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Significance of polymethylmethacrylate (PMMA) modification by zinc oxide nanoparticles for fungal biofilm formation
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Zinc oxide nanoparticles toxicity toDaphnia magna: size-dependent effects and dissolution
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A Review of Microwave Synthesis of Zinc Oxide Nanomaterials: Reactants, Process Parameters and Morphologies
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Mixed electronic-ionic conductivity in vanadate oxide glasses containing alkaline ions
PublikacjaZbadano mieszane przewodnictwo polaronowo-jonowe w szkłach wanadanowych zawierających jony metali alkalicznych.
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Single chamber solid oxide fuel cell - current stage of development and prospects
PublikacjaOgniwa paliwowe należą do jednego z najbardziej wydatnych żródeł energii. W konwencjonalnych ogniwach paliwo i powietrze są dostarczane do ogniwa oddzielnie. Jednokomorowych ogniwo dziala zasilane mieszanina paliwa i powietrza. W pracy przedstawiono obecny stan i perspektywy dlaszego rozwoju jednokomorowych tlenkowych ogniw paliwowych.
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Graphene oxide functionalized with methylene blue and its performance in singlet oxygen generation
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Hollow carbon sphere/metal oxide nanocomposites anodes for lithium-ion batteries
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Phage-Directed Synthesis of Photoluminescent Zinc Oxide Nanoparticles under Benign Conditions
PublikacjaBiological systems, especially bacteriophages and peptides, are an attractive green alternative to other known methods of nanoparticle synthesis. In this work, for the first time, bacteriophages were employed to synthesize a specific peptide, capable of producing nanoparticles (NPs). Derivatives of M13 bacteriophage exposing a ZnO-binding peptide (TMGA-LGLKWPV) on either pIII or pVIII phage coat protein were constructed and used...
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The outline of percolation theory in reference to Solid Oxide Fuel Cell composite anodes
PublikacjaPrzedstawiono podstawy teoretyczne dotyczące zjawiska perkolacji w układach nieuporządkowanych. Zaprezentowano obecny stan wiedzy na temat wykorzystania teorii perkolacji w materiałach elektrodowych dla tlenkowych ogniw paliwowych.
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Shape Memory Polyurethane Materials Containing Ferromagnetic Iron Oxide and Graphene Nanoplatelets
PublikacjaIntelligent materials, such as memory shape polymers, have attracted considerable attention due to wide range of possible applications. Currently, intensive research is underway, in matters of obtaining memory shape materials that can be actuated via inductive methods, for example with help of magnetic field. In this work, an attempt was made to develop a new polymer composite—polyurethane modified with graphene nanoplates and...
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Influence of hydrogen on a nanocrystalline high-entropy oxide with application potential in hydrogen technologies
PublikacjaThe influence of hydrogen on a (Co0⋅2Cu0⋅2Mg0⋅2Ni0⋅2Zn0.2)O HEO with a rock salt structure was studied. Two forms of this HEO (nanopowder and sinter) were prepared via mechanochemical synthesis (MS) and additional heat treatment, respectively. The chemical stability of the synthesized samples in a pure hydrogen atmosphere was investigated using Sievert’s technique. High-pressure hydrogenation at 250 ◦C had no noticeable effect...
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Effects of Micro-Arc Oxidation Process Parameters on Characteristics of Calcium-Phosphate Containing Oxide Layers on the Selective Laser Melted Ti13Zr13Nb Alloy
PublikacjaTitania-based films on selective laser melted Ti13Zr13Nb have been formed by micro-arc oxidation (MAO) at different process parameters (voltage, current, processing time) in order to evaluate the impact of MAO process parameters in calcium and phosphate (Ca + P) containing electrolyte on surface characteristic, early-stage bioactivity, nanomechanical properties, and adhesion between the oxide coatings and substrate. The surface...
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Enhanced electrochemical performance of partially amorphous La0.6Sr0.4CoO3-δ oxygen electrode materials for low-temperature solid oxide cells operating at 400 °C
PublikacjaThis work evaluates partially amorphous La0.6Sr0.4CoO3-δ (LSC) as a potential oxygen electrode for lowtemperature solid oxide cells. LSC was deposited using the spin-coating technique onto Ce0.8Gd0.2O2-δ (CGO) substrates. The optimal oxygen electrode thickness was determined as 500 nm. The electrochemical impedance spectroscopy (EIS) study showed a significant improvement in oxygen reduction/oxidation reaction kinetics when annealing...