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Wyniki wyszukiwania dla: CLIMATE CHANGE, FRESHWATER, HEAVY METALS, INORGANIC CHEMISTRY, NORTH-EAST SIBERIA, PERMAFROST
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Graphitic Carbon Nitride Doped with the s-Block Metals: Adsorbent for the Removal of Methyl Blue and Copper(II) Ions
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Environmental impacts of food waste management technologies: A critical review of life cycle assessment (LCA) studies
PublikacjaFood waste is a serious global problem. Therefore, it is essential to reduce food waste and adopt recycling strategies to minimize its environmental impacts. However, conventional waste disposal methods emit harmful gases such as dioxin, CH4, N2O, and NH3, which contaminate the air and water resources. This work reviews the environmental consequences of food waste based on lifecycle assessment (LCA) techniques using methods such...
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Determination of metal content in sewage sludge and sewage sludge ash to find opportunities to use them in the construction industry
PublikacjaSewage sludge management is becoming an increasing problem in developed and developing countries. Due to their physicochemical properties (mainly high content of heavy metals) a safe method of utilization is sought. Considering environmental protection, energy recycling, reduction in use of the raw materials and the possibility of immobilization hazardous substances, the use of ashes in building materials becomes a very good way...
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Preliminary typology and contextual analysis of Roman and late antique cooking wares from the Roman rural settlement at Podšilo bay on the island of Rab (north–eastern Adriatic, Croatia)
PublikacjaThe paper presents a preliminary typology of coarse cooking ware from the Roman/late antique layers of the rural settlement at Podšilo bay on the island of Rab. The vessels have been associated with several basic shapes and divided by types, while fabrics have been described macroscopically. Analogies and a contextual analysis were used to propose dating and to assess provenience for well-known ware classes or to define areas...
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Microstructure and nanomechanical properties of single stalks from diatom Didymosphenia geminata and their change due to adsorption of selected metal ions
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Effects of Flywheel vs. Free-Weight Squats and Split Squats on Jumping Performance and Change of Direction Speed in Soccer Players
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Remediation of soils on municipal rendering plant territories using Miscanthus × giganteus
PublikacjaPhytoremediation, as a cost-effective, highly efficient, environmentally friendly, and green approach, gained attention to the removal of metals, including heavy metals, from contaminated soils. The toxic nature of heavy metals can have an adverse effect on human health and the ecosystem, and their removal remains a worldwide problem. Therefore, in this study, a field experiment was carried out to evaluate the potential of Miscanthus × giganteus...
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Electrochemical characterization of a composite comprising PEDOT/PSS and N doped TiO2 performed in aqueous and non-aqueous electrolytes
PublikacjaNitrogen doped titania (N-TiO2) was used as an inorganic component of composite electrodes containing poly(3,4-ethylenedioxythiophene) with poly(4-styrenesulphonate) PEDOT/PSS/N-TiO2. The composite materials were obtained by direct electrodeposition from an N-TiO2 suspension containing polyelectrolyte (NaPSS) and monomer EDOT. The electrodes were electrochemically tested in aqueous and non-aqueous electrolytes using cyclic voltammetry...
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CLICK 'n' Sleep: Light-Switch Behavior of Triazole-Containing Tris(bipyridyl)ruthenium Complexes
PublikacjaA set of RuII complexes incorporating triazole subunits are presented. They show a solvent-dependent light-switch effect. Theoretical calculations revealed the excited states involved in the emission process. The findings are highly important for future design of light-switch sensors and suggest a severe restriction for functional photomolecular devices synthesized by CLICK chemistry.
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Evaluation of the relative thermoluminescence efficiency of LiF:Mg,Ti and LiF:Mg,Cu,P TL detectors to low-energy heavy ions
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Catalytic carbonization of polypropylene into cup-stacked carbon nanotubes with high performances in adsorption of heavy metallic ions and organic dyes
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Unraveling the origin of the complex structure of the thorium Lγ x-ray lines in high-resolution spectra induced by heavy projectiles
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Use of Brassica plants in the phytoremediation and biofumigation processes
PublikacjaIn recent decades, serious contamination of soils by heavy metals has been reported. It is therefore a matter of urgency to develop a new and efficient technology for removing contaminants from soil. Another aspect to this problem is that environmental pollution decreases the biological quality of soil, which is why pesticides and fertilizers are being used in ever-larger quantities. The environmentally friendly solutions to these...
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Enviromental factors az the elements determingthe development of floating homes
PublikacjaThe popularity of Floating Homes in Western Europe and North America is noticeable. The interest in thesefacilities in Poland is also constantly growing. The popularity of Floating Homes is due to climate change, risingland prices and population density in city centers. However, environmental factors play a significant role in theirdevelopment. The publication presents the results of research on the impact of environmental factors...
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Methane emissions from mangrove soils in hydrologically disturbed and reference mangrove tidal creeks in southwest Florida
PublikacjaStudies have suggested that some mangrove soils might contribute to wetland methane (CH4) production and emissions, especially when the mangroves are disturbed. CH4 emissions were measured seasonally from nine locations on two mangrove creeks on Naples Bay in southwest Florida, USA. One of the tidal creeks has been impacted in the past few decades with alteration of upstream watersheds and freshwater inflows; the other creek was...
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Positive and negative feedback loops in nutrient phytoplankton interactions related to climate dynamics factors in a shallow temperate estuary (Vistula Lagoon, southern Baltic)
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Social change: from the Solidarity y tmovement too urban movements -– a Design Thinking approach in co-producing city of Gdansk
PublikacjaThis paper presents a model of bottom-up revitalization of Gdansk's urban quarter using Design Thinking approach as users needs oriented method co-producing of space. This project is introduced as a possible canva to elaborate the model of intervention for other spaces in need of similar intervention.
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Determination of Fe2+/Fe3+ mole ratio based on the change of precursor lattice parameters of wustite based iron catalysts for the ammonia synthesis
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Selection of peptomeric inhibitors of bovine α-chymotrypsin and cathepsin G based on trypsin inhibitor SFTI-1 using a combinatorial chemistry approach
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Application of deep eutectic solvents in analytical sample pretreatment (update 2017–2022). Part A: Liquid phase microextraction
PublikacjaSustainable development in all branches of human activity has become an unequivocal necessity in the last two decades, and green chemistry goes hand in hand with it. Various ways have been proposed in analytical chemistry to meet the current requirements of green chemistry. One such approach is the research of new reagents and solvents for analytical purposes. Deep eutectic solvents (DESs) began being investigated and used in analytical...
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Defected Ag/Cu-MOF as a modifier of polyethersulfone membranes for enhancing permeability, antifouling properties and heavy metal and dye pollutant removal
PublikacjaIn this study, a novel bimetallic metal-organic framework (MOF) i.e. Ag/Cu-MOF was synthesized using a solvothermal method and later incorporated at different concentrations (0.1–2 wt%) using a phase inversion method for modification and antifouling property improvement of polyethersulfone (PES) membranes. The resulting Ag/Cu-MOF characteristics were investigated using different techniques, such as FTIR, XRD, FE-SEM and EDX. The...
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Wastewater reuse in agriculture: Prospects and challenges
PublikacjaSustainable water recycling and wastewater reuse are urgent nowadays considering water scarcity and increased water consumption through human activities. In 2015, United Nations Sustainable Development Goal 6 (UN SDG6) highlighted the necessity of recycling wastewater to guarantee water availability for individuals. Currently, wastewater irrigation (WWI) of crops and agricultural land appears essential. The present work overviews...
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Anthropopressure’s intensification with reference to Arctic ecosystems
PublikacjaThis paper concerns issue of long range atmospheric transport of pollutants to polar areas and intensification of their toxic effect on biota in the face of climate change. Arctic which was for years seen as a pristine and not affected by antropopressure region became a sink of xenobiotics. Atmospheric circulation facilitates transport of chemicals from Eurasia to Arctic. Influence of climate change on crucial balance of polar...
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Mocz jako źródło informacji o narażeniu zawodowym na metale = Urine as a source of information on occupational exposure to metals- a review
PublikacjaW pracy przedstawiono informacje na temat możliwości wykorzystywania próbek moczu ludzkiego jako materiału do badań analitycznych ukierunkowanych na uzyskanie informacji o narażeniu zawodowym na metale. Szczególną uwagę zwrócono na:-techniki izolacji i wzbogacania metali i ich metabolitów z próbek moczu,-techniki oznaczania metali w otrzymywanych ekstraktach,-zebranie informacji literaturowych odnośnie oznaczanych stężeń metali...
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Współczesna sytuacja socjolingwistyczna Finlandii na tle zmian demograficznych [Contemporary Demographic and Sociolinguistic Situation in Finland against the background of the demographic change]
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CYP3A4 overexpression enhances apoptosis induced by anticancer agent imidazoacridinone C-1311, but does not change the metabolism of C-1311 in CHO cells
PublikacjaWe examine whether CYP3A4 overexpression influences the rate and pattern of antitumor imidazoacridinone C-1311 metabolism, in relation to the impact of this overexpression on cell cycle progression and final cellular response of CHO cells following C-1311 treatment. Methods: Three CHO cell lines: CHO-WT, wild type, CHO-HR, overexpressing cytochrome P450 reductase (CPR) and CHO-HR-3A4, coexpressing CPR and CYP3A4 were applied....
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Methods of Assessment of Metal Contamination in Bottom Sediments (Case Study: Straszyn Lake, Poland)
PublikacjaThe concentrations of six metals (Zn, Cu, Pb, Ni, Cr, and Cd) were investigated in bottom sediments of Straszyn Lake (North Poland). This study was designed to determine a total content of metals and to assess their mobility and bioavailability. The sequential extraction was used to fractionate metals into five fractions: exchangeable, bound to carbonates, bound to Fe–Mn oxides, bound to organic matter, and residual. The evaluation...
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The First Dinuclear Nickel(II) Thiosulfate Obtained From Oxidation of Tri-tert-butoxysilanethiol. Contributions to the Chemistry of Silicon-Sulfur Compounds No. 78[1]
PublikacjaPrezentowany związek {[Ni2(μ-S2O3)2(C7H9N)4-H2O]C7H8} (1) jest pierwszym tiosiarczanem metalu otrzymanym w wyniku utlenienia silanotiolu. Mechanizm tej reakcji zakłada powstawanie (RO)3SiSSSi(OR)3 jako jako produktu pośredniego. Bimetaliczny związek niklu(II) posiada dwie reszty tiosiarczanowe pełniące rolę liganda zarówno -S,O chelatującego jak i S-mostkującego łączącego oba centra metaliczne. Związek krystalizuje jako dimer z...
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Artemisia abrotanum L. (Southern Wormwood)—History, Current Knowledge on the Chemistry, Biological Activity, Traditional Use and Possible New Pharmaceutical and Cosmetological Applications
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The structure of dimethylsulfoxide-solvated magnesium and calcium ions in solution and the solid state, and overview of the coordination chemistry of hydrated and solvated alkaline earth metal ions
PublikacjaOznaczono strukturę w stanie stałym i ciekłym solwatowanych jonów magnezu i wapnia w dimetylosulfotlenku. Stwierdzono, ze jony te tworzą sześciokoordynacyjne solwaty ze średnią długością wiązań Mg-O i Ca-O 2.062(4) i 2.303(5)A. Przegląd literaturowy ukazał, że jony berylu i magnezu we wszystkich rozpuszczalnikach tworzą odpowiednio cztero- i sześciokoordynacyjne solwaty, podczas gdy jony wapnia i strontu istnieją jako ośmiokoordynacyjne...
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A multi-analytical approach to the characterization of natural organic dyestuffs and inorganic substrates present in the 19th-century artistic oil paints manufactured by a French art materials supplier Richard Aines
PublikacjaThis paper presents a comprehensive analysis of artistic paints produced in the 19th century by a French art materials supplier Richard Ain`es. Improved mild extraction with hydrofluoric acid enabled the observation of intact organic dyes. Reversed-phase liquid chromatography with diode-array and mass spectrometry detection was utilised for the identification of 35 dyes present in yellow and red paint samples, and in selected plant...
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Do We Need a Lighting Detox for Sustainable Cities in the 21st Century?
PublikacjaThis article looks at relearning our connection to light and dark in context of sustainability, climate change and urban lighting.
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The Polish Version of the Yale-Brown Obsessive-Compulsive Scale, Modified to Reflect Obsessions and Compulsions Related to Heavy Drinking (YBOCS-hd-PL)
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Radial distribution of dose within heavy charged particle tracks – Models and experimental verification using LiF:Mg,Cu,P TL detectors
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Concentrations and loads of metals (V, Cr, Mn, Fe, Cu, Zn, As, Rb, Y, Zr) from the cliff erosion to the Gulf of Gdansk
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High prevalence of carriers of variant c.1528G>C of HADHA gene causing long-chain 3-hydroxyacyl-CoA dehydrogenase deficiency (LCHADD) in the population of adult Kashubians from North Poland
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Is the microfiltration process suitable as a method of removing suspended solids from rainwater?
PublikacjaDue to climate change and anthropogenic pressure, freshwater availability is declining in areas where it has not been noticeable so far. As a result, the demands for alternative sources of safe drinking water and effective methods of purification are growing. A solution worth considering is the treatment of rainwater by microfiltration. This study presents the results of selected analyses of rainwater runoff, collected from the...
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Microstructure and Mechanical Properties of Combined GTAW and SMAW Dissimilar Welded Joints between Inconel 718 and 304L Austenitic Stainless Steel
PublikacjaA dissimilar welded joint of Inconel 718 and 304L austenitic stainless steel was prepared using a combined procedure with the gas tungsten arc welding and shielded metal arc welding processes by employing the Ni-based fillers: ERNiCr-3 and ENiCrFe-3. The welded joints were investigated for metallographic testing and mechanical properties, and a relationship was established between the microstructure and the resultant mechanical...
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Effects of sewage sludge supplementation on heavy metal accumulation and the expression of ABC transporters in Sinapis alba L. during assisted phytoremediation of contaminated sites
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Potential fertilizing properties of sewage sludge treated in the Sludge Treatment Reed Beds (STRB)
PublikacjaIn research the fertilizer value of sludge from reed beds is evaluated based on the sampling sludge on different depths from 4 Danish STRB after long periods of stabilization. The dewatering efficiency of sewage sludge in the STRB is comparable to mechanical dewatering. The long-term stabilization of sewage sludge progressively decreases the concentration of organic matter due to the process of humification. The aim of the work...
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A critical review on biochar-assisted free radicals mediated redox reactions influencing transformation of potentially toxic metals: Occurrence, formation, and environmental applications
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Occurrences, sources, and transport of organochlorine pesticides in the aquatic environment of Antarctica
PublikacjaWe review information on the concentration levels of organochlorine pesticides in the abiotic aquatic environment (in seawater, sea ice, surface freshwater, snow, firn, and glacial ice) and the organisms inhabiting those, in Antarctica. Particular attention is given to the environmental fate of these pollutants, which modifies their impact on the organisms living in the Antarctic. OCPs have been delivered to the Antarctic environment...
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Glaciers as an Important Element of the World Glacier Monitoring Implemented in Svalbard
PublikacjaGlaciers are not only contributors to the sea level rise but also important players in the circulation of pollutants. Over a billion people apply glacial waters for domestic purposes; hence, both the quality and quantity of this water should be monitored. In this chapter, we concentrate on the archipelago Svalbard in the Arctic, a typical target area for xenobiotics from long range atmospheric transport (LRAT), holding an important share...
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Polysaccharide nanocomposites in wastewater treatment: A review
PublikacjaIn modern times, wastewater treatment is vital due to increased water contamination arising from pollutants such as nutrients, pathogens, heavy metals, and pharmaceutical residues. Polysaccharides (PSAs) are natural, renewable, and non-toxic biopolymers used in wastewater treatment in the field of gas separation, liquid filtration, adsorption processes, pervaporation, and proton exchange membranes. Since addition of nanoparticles...
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New chromogenic substrates of human neutrophil cathepsin G containing non-natural aromatic amino acid residues in position P1 selected by combinatorial chemistry methods
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A new look at two polymorphic crystal structures of dibenzoylmethane: relationship between the crystal packing and the hydrogen atom position revealed by quantum chemistry and quantum crystallography methods
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Comparison of Cu1.3Mn1.7O4 spinels doped with Ni or Fe and synthesized via wet chemistry and solid-state reaction methods, designed as potential coating materials for metallic interconnects
PublikacjaThe influence of the method applied to synthesize Cu-Mn-O spinel was evaluated. The methods selected for the investigation were EDTA gel processes and solid-state reaction synthesis. From the obtained powders, sinters were prepared and assessed in terms of their properties as potential coating materials. Additionally, the influence of Ni and Fe dopants was evaluated. The results show that the EDTA gel processes method seems to...
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Operation of reed systems used to stabilization of sewage sludge
PublikacjaThe aim of this research was to determine the parameters of property operation of reed systems. It was also checked the possibility to use sludge in agriculture for the sake of heavy metal concentrations.The research was conducted in four Danish objects utilized sludge located in Helsinge, Vallo, Rudkobing and Nakskov near Copenhagen.It was found that correct operation of reed basins requires the determination of optimal doses...
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Simultaneous Recovery of Precious and Heavy Metal Ions from Waste Electrical and Electronic Equipment (WEEE) Using Polymer Films Containing Cyphos IL 101
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Protective effect of Aronia melanocarpa polyphenols against cadmium-induced disorders in bone metabolism: A study in a rat model of lifetime human exposure to this heavy metal
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