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Wyniki wyszukiwania dla: POLY(PROPYLENE SUCCINATE)
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Electrochemical Characterization of Gelatine Derived Ceramics
PublikacjaNew materials obtained by pyrolysis of gelatine (G) and poly(1,2-dimethylsilazane) (PSN) (weight ratio: G/PSN 70/30) at temperatures 700 and 900 °C were characterized by SEM and Raman spectroscopy. The presence of ceramics influences on the cluster size of the materials. Electrochemical tests were performed by cyclic voltammetry and galvanostatic cyclic polarization. The capacity of G/PSN was 464 and 527 mAh/g for materials pyrolysed...
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The Influence of PEG on Morphology of Polyurethane Tissue Scaffold
PublikacjaIn this study, polyurethanes (PU) were synthesized from oligomeric dihydroxy(etylene-butylene adipate), poly(ethylene glycol) (PEG), hexamethylene diisocyanate (HDI), 1,4-butanediol (BDO) as chain extender and stannous octoate as catalyst. PEG due to its hydrophilic character influences physical and chemical properties of PU. For testing were used PU having the following weigh contents of PEG: 0%, 7%, and 14%. Porous scaffolds...
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Fabrication and photoactivity of organic-inorganic systems based on titania nanotubes and PEDOT containing redox centres formed by different Prussian Blue analogues
PublikacjaHerein, the heterojunction composed of an inorganic substrate: ordered hydrogenated titania nanotubes (H-TiO2NTs) and a deposited organic film: poly(3,4-ethylenedioxythiophene) (PEDOT) is reported. The conducting polymer is modified with different transition metal haxacyanoferrates (Mehcf), wherein as metal: copper, iron, cobalt and nickel are introduced. The presence of various metal centres provides characteristic redox activity...
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Influence of electropolymerization conditions on the morphological and electrical properties of PEDOT film
PublikacjaIn this work the effects of electropolymerization conditions on the morphological properties and conductivity of poly(3,4-ethylenedioxythiophene) (PEDOT) film have been studied. PEDOT films were electrochemically synthesized in a one step process from acetonitrile solution containing 3,4-ethylenedioxythiophene (EDOT) and lithium perchlorate. Based on atomic force microscopy, scanning electron microscopy, cyclic voltammetry and...
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Polyester-urethanes modified with gelatine for tissue scaffolds
PublikacjaNovel aliphatic PU foams, modified with gelatine, were obtained in a one-step polymerization process. Hard segments were obtained from 1,6-hexamethylene diisocyanate (HDI) and chain extenders 1,4-butanediol (BDO) or 2-(2-(2-hydroxyethoxy)ethoxy)ethanol (TG), soft segments were obtained from poly(ethylene-buthylene adipate) (EBO) polyol. We examined the PU foams for their sorption capability in canola oil, saline (0.9% NaCl water...
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Functionalized Polyolefins Produced by Post-Metallocenes; High Added Value Materials, but Can They Be Produced Efficiently?
PublikacjaRandomly functionalized polyolefins produced by catalysis have received increasing attention owing to their welldefined molecular structures, uniform distribution, and variety in types of functionalities. Herein, we investigate the scalability of the production of hydroxyl-functionalized propylene copolymers via a high temperature solution polymerization process using aluminum trialkyls as passivating agents. Initially, we evaluated...
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Synthesis of isotactic polypropylene- block -polystyrene block copolymers as compatibilizers for isotactic polypropylene/polyphenylene oxide blends
PublikacjaPoly(2,6-dimethyl-1,4-phenylene oxide) (PPO) and isotactic polypropylene (iPP) are highly incompatible and consequently their uncompatibilized blends are quite brittle regardless of the molecular weights and ductility of the individual components. Isotactic polypropylene-polystyrene block copolymers, to be applied as compatibilizers for a broad range of PPO/iPP blend compositions, were prepared by mechanism transformation from...
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Graphene oxide, reduced graphene oxide and composite thin films NO2 sensing properties
PublikacjaA graphene oxide (GO), reduced graphene oxide (RGO) and poly(3,4-ethylenedioxytiophene)-reduced graphene oxide (PEDOT-RGO composite) gas sensors were successfully fabricated using an electrodeposition method. The electrodeposition was carried out in aqueous GO dispersions. To obtain RGO and PEDOT-RGO, the electrochemical reduction of GO and PEDOT-GO was carried out in 0.1 M KCl at a constant potential of −0.85 V. The GO, RGO and PEDOT-RGO...
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Electrical Interface Parameters of PEDOT: PSS: Effect of Electrodeposition Charge Evaluated Under Body Conditions for Neural Electrode Applications
PublikacjaThis study explores the influence of the deposition charge of poly(3,4-ethylenedioxythiophene) doped with polystyrene sulfonate (PEDOT:PSS) on its electrical interface parameters. For this purpose, PEDOT:PSS was fabricated by electrodeposition on commercial platinum electrodes with the time limited by different charges (1, 3, 6, 9 mC). Further, the electrodes were characterized regarding their electrical interface such as interfacial...
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Understanding the capacitance of thin composite films based on conducting polymer and carbon nanostructures in aqueous electrolytes
PublikacjaIn this work electrochemical performance of thin composite films consisted of poly(3,4-ethylenedioxythiophene) (PEDOT), graphene oxide (GOx) and oxidized multiwalled carbon nanotubes (oxMWCNTs) is investigated in various sulphates (Li2SO4, Na2SO4, K2SO4, MgSO4) and acidic (H2SO4) electrolytes. Capacitance values, rate capability and cycling stability achieved for the composite layers are correlated with the electrolytes’ properties...
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Volatile Compound Emissions from Stereolithography Three-Dimensional Printed Cured Resin Models for Biomedical Applications
PublikacjaStereolithography three-dimensional printing is used increasingly in biomedical applications to create components for use in healthcare and therapy. The exposure of patients to volatile organic compounds (VOCs) emitted from cured resins represents an element of concern in such applications. Here, we investigate the biocompatibility in relation to inhalation exposure of volatile emissions of three different cured commercial resins...
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In-Reactor Polypropylene Functionalization─The Influence of Catalyst Structures and Reaction Conditions on the Catalytic Performance
PublikacjaTo unravel the relationship between silylene-bridged metallocene catalyst structures and polymerization conditions and their effect on the performance in in-reactor functionalization of polypropylene, the behaviors of rac-Me2Si(2-Me-4-Ph-Ind)2ZrCl2/MMAO, rac-Me2Si(Ind)2ZrCl2, rac-Me2Si(2-Me-4-Ph-Ind)2HfCl2, and rac-Me2Si(Ind)2HfCl2 in propylene/aluminum alkyl-passivated 10-undecen-1-ol copolymerization were compared. Kinetic analysis...
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Models of Structures in Didactics
PublikacjaThe final aim of teaching students subjects, such as structural mechanics, reinforced concrete, and steel structures is to teach them how structures work in a given building as well as to provide them with skills enabling them to calculate and design structures. The behavioral model of the structure, contrary to the architectural model, which focuses mainly on the external form of the building, shows workings from both the static...
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Synthesis and electrochemical characteristics of novel dithiocarbamate polymers
PublikacjaNovel dithiocarbamate compounds have been obtained by reacting a linear poly(ethylenimine)polymer, MW 50,000, with CS2. The resulting anionic polymers contain, depending on the reaction conditions, up to two sulfur atoms per one nitrogen atom (approx. 40% w/w). The polymers are soluble in dimethylsulfoxide and insoluble in acetonitrile solutions. In both solvents they are electrochemically active, in the latter case as a cast film...
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Laser patterned platform with PEDOT–graphene composite film for NO2 sensing
PublikacjaThis work presents a simple and fully electrochemical route used for fabricating of a NO2 gas sensor made of reduced-graphene-oxide-poly(3,4-ethylenedioxythiophene) composite film. The sensing platform was fabricated from alumina substrate and equipped with gold interdigitated electrodes and built-in heater.The temperature distribution on the surface of interdigitated electrodes was investigated by a thermalimaging camera and compared...
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Solid-Contact Ion-Selective Electrodes with Highly SelectiveThioamide Derivatives of p-tert-Butylcalix[4]arene for theDetermination of Lead(II) in Environmental Samples
PublikacjaThioamide derivatives of p-tert-butylcalix[4]arene were used as ionophores in the development of solid-contact ion-selective electrodes based on conducting polymer poly(3,4-ethylenedioxythiophene)/polystyrene sulfonate (PEDOT/PSS) which was synthesized by electrodeposition on the glassy carbon electrodes. The typical ion-selective membranes with optionally two different plasticizers [bis(2-ethylhexyl)sebacate (DOS) and 2-nitrophenyl...
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Novel Polyurethanes as Antifouling Paint Matrices
PublikacjaThe new poly(ester-ether urethane)s (PEEUR) were prepared in two stage synthesis from formerly obtained oligo(alkylene ester-ether)diols (OAEE) and 4,4‘-diphenylmethane diisocyanate (MDI). PEEUR samples were subjected to crosslinking with styrene in the presence of radical polymerization initiators: methyl ethyl ketone peroxide (MEKPO) or cobalt 2-ethyl cyclohexanoate (EtHCo). Crosslinked PEEUR were characterized by their physicochemical...
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Low-energy positron scattering from gas-phase benzene
PublikacjaIn this paper we are presenting calculations of the elastic cross section of positrons with gas-phase benzene for the energy range from 0.25 eV to 9.0 eV. The calculations are done with the molecular R-matrix method for positron-scattering from poly-atomic molecules using a scaling factor to scale the electron-positron interaction. The scaling factor influences the position of the poles of the R-matrix. We adjust the scaling factor...
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Wear in siding friction tests. Ring-on-ring contact. Sintered alumina ceramics (98%). Paraffin oil lubrication. Specim. sets #20-#21, #22-#23, #24-#25, #26-#27, #28-#29,#30 - #31. Run time: 4-8h.
Dane BadawczeWear in sliding friction tests in ring-on-ring contact. Sintered alumina ceramics (98%) in self-mated contact. Lubrication: paraffin oil. Sliding velocity: 0.2 m/s. Mean contact stress: 10 MPa. Test rig: PT-3 Tribometer.Running time: 4-8h.Specimen sets:Specim. sets (# [upper, rotating] - #[lower, non-rotating]):#20-#21, #22-#23, #24-#25, #26-#27,...
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Specimen running-in. Prep. to sliding friction tests. Ring-on-ring contact. Sintered alumina ceramics (98%). Paraffin oil lubrication. Specimen set #24 - #25.
Dane BadawczeSpecimen running-in procedure. Preparation to sliding friction tests in ring-on-ring contact. Sintered alumina ceramics (98%) in self-mated contact. Lubrication: paraffin oil. Sliding velocity: 0.2 m/s. Mean contact stress: 10 MPa. Test rig: PT-3 Tribometer. Specimen set #24 (upper, rotating), #25 (lower, non-rotating)CZ_PRZYS.MAT - accelerometerMOM_TAR.MAT...
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Specimen running-in. Prep. to sliding friction tests. Ring-on-ring contact. Sintered alumina ceramics (98%). Paraffin oil lubrication. Specimen set #28 - #29.
Dane BadawczeSpecimen running-in procedure. Preparation to sliding friction tests in ring-on-ring contact. Sintered alumina ceramics (98%) in self-mated contact. Lubrication: paraffin oil. Sliding velocity: 0.2 m/s. Mean contact stress: 10 MPa. Test rig: PT-3 Tribometer. Specimen set #28 (upper, rotating), #29 (lower, non-rotating)CZ_PRZYS.MAT - accelerometerMOM_TAR.MAT...
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Wear in siding friction tests. Ring-on-ring contact. Sintered alumina ceramics (98%). Paraffin oil lubrication. Specim. sets #20-#21, #22-#23, #24-#25, #26-#27, #28-#29,#30 - #31. Run time: 0-4h.
Dane BadawczeWear in sliding friction tests in ring-on-ring contact. Sintered alumina ceramics (98%) in self-mated contact. Lubrication: paraffin oil. Sliding velocity: 0.2 m/s. Mean contact stress: 10 MPa. Test rig: PT-3 Tribometer.Running time: 0 - 4h.Specimen sets:Specim. sets (# [upper, rotating] - #[lower, non-rotating]):#20-#21, #22-#23, #24-#25, #26-#27,...
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Specimen running-in. Prep. to sliding friction tests. Ring-on-ring contact. Sintered alumina ceramics (98%). Paraffin oil lubrication. Specimen set #30 - #31.
Dane BadawczeSpecimen running-in procedure. Preparation to sliding friction tests in ring-on-ring contact. Sintered alumina ceramics (98%) in self-mated contact. Lubrication: paraffin oil. Sliding velocity: 0.2 m/s. Mean contact stress: 10 MPa. Test rig: PT-3 Tribometer. Specimen set #30 (upper, rotating), #31 (lower, non-rotating)CZ_PRZYS.MAT - accelerometerMOM_TAR.MAT...
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Specimen running-in. Prep. to sliding friction tests. Ring-on-ring contact. Sintered alumina ceramics (98%). Paraffin oil lubrication. Specimen set #20 - #21.
Dane BadawczeSpecimen running-in procedure. Preparation to sliding friction tests in ring-on-ring contact. Sintered alumina ceramics (98%) in self-mated contact. Lubrication: paraffin oil. Sliding velocity: 0.2 m/s. Mean contact stress: 10 MPa. Test rig: PT-3 Tribometer. Specimen set #20 (upper, rotating), #21 (lower, non-rotating)CZ_PRZYS.MAT - accelerometerMOM_TAR.MAT...
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Specimen running-in. Prep. to sliding friction tests. Ring-on-ring contact. Sintered alumina ceramics (98%). Paraffin oil lubrication. Specimen set #22 - #23.
Dane BadawczeSpecimen running-in procedure. Preparation to sliding friction tests in ring-on-ring contact. Sintered alumina ceramics (98%) in self-mated contact. Lubrication: paraffin oil. Sliding velocity: 0.2 m/s. Mean contact stress: 10 MPa. Test rig: PT-3 Tribometer. Specimen set #22 (upper, rotating), #23 (lower, non-rotating)CZ_PRZYS.MAT - accelerometerMOM_TAR.MAT...
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Specimen running-in. Prep. to sliding friction tests. Ring-on-ring contact. Sintered alumina ceramics (98%). Paraffin oil lubrication. Specimen set #28 - #29.
Dane BadawczeSpecimen running-in procedure. Preparation to sliding friction tests in ring-on-ring contact. Sintered alumina ceramics (98%) in self-mated contact. Lubrication: paraffin oil. Sliding velocity: 0.2 m/s. Mean contact stress: 10 MPa. Test rig: PT-3 Tribometer. Specimen set #28 (upper, rotating), #29 (lower, non-rotating)CZ_PRZYS.MAT - accelerometerMOM_TAR.MAT...
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Specimen running-in. Prep. to sliding friction tests. Ring-on-ring contact. Sintered alumina ceramics (98%). Paraffin oil lubrication. Specimen set #26 - #27.
Dane BadawczeSpecimen running-in procedure. Preparation to sliding friction tests in ring-on-ring contact. Sintered alumina ceramics (98%) in self-mated contact. Lubrication: paraffin oil. Sliding velocity: 0.2 m/s. Mean contact stress: 10 MPa. Test rig: PT-3 Tribometer. Specimen set #26 (upper, rotating), #27 (lower, non-rotating)CZ_PRZYS.MAT - accelerometerMOM_TAR.MAT...
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The effect of polyamide PA12 and polyester PBT blocks' lengths on the structure and propertries of multiblock terpoly(amide-block-ester-block-amide) (TPAEA)
PublikacjaThe ternary multiblock system terpoly(amide-b-ester-b-amide) (TPAEA) of the chemical structure: poly[(oligoamide-6.36)-block-(tetramethylene terephthalate)-block-laurolactam)] -(PA6.36-b-PBT-b-PA12)n- has been obtained (Table 1). In this system the third component (PBT block here), characterized with the proper molecular weight, is dissolved in hard phase of PA12 blocks and partially dissolved in soft phase of PA6.36. The effects...
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Universal Augmentation Schemes for Network Navigability
PublikacjaRozważano problem uzupełniania grafu (reprezentującego np. sieci społeczne) poprzez dodanie w każdym węźle jednego dodatkowego skierowanego połączenia (długodystansowego). Dokładniej, dla każdego węzła definiuje się listę prawdopodobieństw istnienia połączenia wychodzącego z danego węzła do wszystkich pozostałych węzłów; wartości tych prawdopodobieństw muszą sumować się do jedności. Routing zachłanny w takiej sieci polega na przekazywaniu...
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Gelatin-Modified Polyurethanes for Soft Tissue Scaffold
PublikacjaRecently, in the field of biomaterials, which are being designed for soft tissue scaffolding, is growing the interest of their modification with natural polymers. Synthetic polymers are often hard, not easy to process and they do not possess fine biodegradable profile. From the other hand natural polymers are biocompatible, but weak when used alone. The combination of natural and synthetic polymers gives the suitable properties...
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Modification of thermal and rheological characteristics of bitumen by waste PET/GTR blends
PublikacjaWaste poly(ethylene terephthalate) (wPET)/ground tire rubber (GTR) blends with variable compositions were applied as low-cost modifiers into bitumen and their performance has been evaluated via morphological, thermal and rheological analyses. Depending on the weight ratio of wPET/GTR, dispersion of single/composite domains of waste polymers in the bitumen has promoted the interaction between bitumen and blend components. Fourier...
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An investigation on the role of GMA grafting degree on the efficiency of PET/PP-g-GMA reactive blending: morphology and mechanical properties
PublikacjaGlycidyl methacrylate (GMA) has been grafted on polypropylene (PP) with the aid of styrene (St) comonomer, by changing dicumyl peroxide initiator content, GMA level, and St concentration. The performance of the resulting PP-g-GMA reactive material towards static and dynamic mechanical properties of poly (ethylene terephthalate) (PET) was monitored in terms of grafting reaction variables and compatibilizer content. Fourier transform...
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Porosity and swelling properties of novel polyurethane–ascorbic acid scaffolds prepared by different procedures for potential use in bone tissue engineering
PublikacjaIn this work, a novel polyurethane (PU) system based on poly(ethylene-butylene) adipate diol, 1,6-hexamethylene diisocyanate, 1,4-butanediol, and ascorbic acid was used to prepare scaffolds with potential applications in bone tissue engineering. Two fabrication methods to obtain porous materials were chosen: phase separation (PS)/salt particle leaching (PL) and solvent casting (SC)/salt PL. The calculated porosity demonstrated...
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Therapeutic intervention by the simultaneous inhibition of DNA repair and type I or type II DNA topoisomerases: one strategy, many outcomes
PublikacjaMany anticancer drugs reduce the integrity of DNA, forming strand breaks. This can cause mutations and cancer or cell death if the lesions are not repaired. Interestingly, DNA repair-deficient cancer cells (e.g., those with BRCA1/2 mutations) have been shown to exhibit increased sensitivity to chemotherapy. Based on this observation, a new therapeutic approach termed 'synthetic lethality' has been developed, in which radiation...
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Recycling of Polyurethanes Containing Flame-Retardants and Polymer Waste Transformed into Flame-Retarded Polyurethanes
PublikacjaThe growing number of polyurethanes (PUs) produced every year has developed methods for their mechanical and chemical recycling which yield valuable products like substitutes for commercial polyols or flame-retardants. PUs can be produced in different shapes and forms (i.e., elastomers, flexible or rigid foams, coatings, etc.) using several different components (i.e., di- or polyisocyanates, ester- or ether-based polyols, low-molecular...
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Water Footprint Assessment of Selected Polymers, Polymer Blends, Composites, and Biocomposites for Industrial Application
PublikacjaThis paper presents a water footprint assessment of polymers, polymer blends, composites, and biocomposites based on a standardized EUR-pallet case study. The water footprint analysis is based on life cycle assessment (LCA). The study investigates six variants of EUR-pallet production depending on the materials used. The system boundary included the production of each material and the injection molding to obtain a standardized...
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Synteza, struktura chemiczna i właściwości bezizocyjanianowych poliuretanów otrzymywanych z wykorzystaniem CO2 oraz surowców pochodzenia naturalnego.
PublikacjaZ uwagi na wciąż rosnącą świadomość proekologiczną, politykę zrównoważonego rozwoju, a także nurt zielonej chemii wiodącym trendem w przemyśle tworzyw sztucznych jest poszukiwanie alternatywnych metod otrzymywania materiałów polimerowych. Komercyjnie poliuretany otrzymywane są w wyniku reakcji poliaddycji di- lub poliizocyjanianów z poliolami i małocząsteczkowymi przedłużaczami łańcucha. Z uwagi na niekorzystne właściwości diizocyjanianów,...
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Unveiling per- and polyfluoroalkyl substances contamination in e-cigarette refill liquids: A comprehensive analytical assessment
PublikacjaA robust analytical method was developed for the determination of per- and polyfluoroalkyl substances (PFAS) in e-cigarette refill liquids using solid-phase extraction (SPE) with weak anion-exchange sorbent, followed by detection with high-performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS). The design of experiment approach was employed to optimize sample preparation, leading to the validation of the method...
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Wear in siding friction tests. Ring-on-ring contact. Sintered alumina ceramics (98%). Paraffin oil lubrication. Specim. sets #20-#21, #22-#23, #24-#25, #26-#27, #28-#29,#30 - #31. Run time: 0-4h. High frequency burst recording.
Dane BadawczeWear in sliding friction tests in ring-on-ring contact. Sintered alumina ceramics (98%) in self-mated contact. Lubrication: paraffin oil. Sliding velocity: 0.2 m/s. Mean contact stress: 10 MPa. Test rig: PT-3 Tribometer. High frequency burst recording.Running time: 0 - 4h.Specimen sets:Specim. sets (# [upper, rotating] - #[lower, non-rotating]):#20-#21,...
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Graphene oxide, reduced graphene oxide and composite thin films NO2 sensing properties
PublikacjaA graphene oxide (GO), reduced graphene oxide (RGO) and poly(3,4-ethylenedioxytiophene)- reduced graphene oxide (PEDOT-RGO composite) gas sensors were successfully fabricated using an electrodeposition method. The electrodeposition was carried out in aqueous GO dispersions. In order to obtain RGO and PEDOT-RGO, the electrochemical reduction of GO and PEDOT-GO was carried out in 0.1 M KCl at constant potential of −0.85 V. The GO, RGO...
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Novel Biodegradable Potato Starch-based Compositions as Candidates in Packaging Industry, Safe for Marine Environment
PublikacjaAbout 70 % of our planet’s surface is covered by seas and oceans to which even 10 million tons of waste go every year. It makes these places the largest global landfills, containing up to 90 % of plastic waste. In this article we present the results of research on novel starch-based compositions expected to be more safe for the marine environment. For these purpose biopolymers such as, thermoplastic starch (TPS), polylactide (PLA)...
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Bone healing under different lay‐up configuration of carbon fiber‐reinforced PEEK composite plates
PublikacjaSecondary healing of fractured bones requires an application of an appropriate fixa-tor. In general, steel or titanium devices are used mostly. However, in recent years,composite structures arise as an attractive alternative due to high strength to weightratio and other advantages like, for example, radiolucency. According to Food andDrug Administration (FDA), the only unidirectionally reinforced composite allowed tobe implanted...
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Antibacterial Porous Systems Based on Polylactide Loaded with Amikacin
PublikacjaThree porous matrices based on poly(lactic acid) are proposed herein for the controlled release of amikacin. The materials were fabricated by the method of spraying a surface liquid. Description is given as to the possibility of employing a modifier, such as a silica nanocarrier, for prolonging the release of amikacin, in addition to using chitosan to improve the properties of the materials, e.g., stability and sorption capacity....
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Variable Temperature Spectroscopic Ellipsometry as a Tool for Insight into the Optical Order in the P3HT:PC70BM and PC70BM Layers
PublikacjaTwo combined ellipsometric techniques—variable angle spectroscopic ellipsometry (VASE) and variable temperature spectroscopic ellipsometry (VTSE)—were used as tools to study the surface order and dielectric properties of thin films of a poly(3-hexylthiophene-2,5-diyl) (P3HT) mixture with a fullerene derivative (6,6-phenyl-C71-butyric acid methyl ester) (PC70BM). Under the influence of annealing, a layer of the ordered PC70BM...
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Bio-based semi-aromatic polyesters for coating applications
PublikacjaLinear and branched bio-based semi-aromatic (co)polyesters were evaluated as resins for solvent-basedand powder coatings. Dimethyl-2,5-furandicarboxylate (DMF), 2,3-butanediol and various multifunc-tional comonomers were used to synthesize amorphous hydroxyl-end-capped (co)polyesters. The resinswere cross-linked using the -caprolactam blocked trimer of isophorone diisocyanate. Both the solvent-based and powder coatings proved to...
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Recycled Polyethylene terephthalate (PET) as Construction Material in Civil Engineering: A Review
PublikacjaIn general, the quantity of plastics of all types consumed annually all over the world has been growing in a phenomenal way. The manufacturing processes, service industries and municipal solid wastes (MSW) generate numerous waste plastic materials. The increasing awareness about the environment has tremendously contributed to the concerns related with disposal of the generated wastes. It is believed that the management of solid...
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Preparation and Properties of Thermoplastic Polyurethane Composites Filled with Powdered Buckwheat Husks
PublikacjaBio-based fillers for the polymer composites are still interesting from the scientific and industrial point of view, due to their low cost and renewable nature. In this work partially green composites were obtained by the mixing of thermoplastic poly(ester-urethane) with the unmodified and modified (by acetylation) grinded buckwheat husks. Obtained biocomposites were characterized in the terms of their chemical structure (FTIR),...
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Eco-Friendly Ether and Ester-Urethane Prepolymer: Structure, Processing and Properties
PublikacjaThis study concerns bio-based urethane prepolymers. The relationship between the chemical structure and the thermal and processing parameters of bio-based isocyanate-terminated ether and ester-urethane prepolymers was investigated. Bio-based prepolymers were obtained with the use of bio-monomers such as bio-based diisocyanate, bio-based polyether polyol or polyester polyols. In addition to their composition, the bio-based prepolymers...
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Piotr Płotka dr hab. inż.
OsobyPiotr Płotka otrzymał tytuł zawodowy magistra inżyniera w 1976 r., a stopień doktora w dyscyplinie elektronika w 1985 r. – nadane przez Wydział Elektroniki Telekomunikacji i Informatyki Politechniki Gdańskiej. W 2008 r. otrzymał stopień doktora habilitowanego, także w dyscyplinie elektronika, nadany przez Instytut Technologii Elektronowej w Warszawie. Od 1977 r. pracował w Akademii Techniczno-Rolniczej w Bydgoszczy, a od 1981...
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Functionalization of Parylene During Its Chemical Vapor Deposition
PublikacjaTwo possible mechanisms for the reaction of four halogenated (metha)acrylate-based molecules with Parylene [poly (paraxylylene)] during its chemical vapor deposition were proposed. The chemical reactivity of acrylate double bond with the paraxylylene biradical was calculated for all four (metha)acrylate-based molecules. These calculations allowed the evaluation of the energetically favorable mechanism and indeed a direct correlation...