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Isotope-labeled substances in analysis of persistent organicpollutants in environmental samples
PublicationUltratrace analysis of persistent organic pollutants (POPs) in environmental samples requires very sophisticated methods for both sample preparation and instrumental analysis. The complex matrix requires a multi-stage procedure. Each stage is a potential source of error, as a consequence of which the final result of analysis could be a source of misinformation rather than information. The individual stages and the procedure as...
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Comparison of different extraction techniques of polychlorinated biphenyls from sediments samples.
PublicationIn this work, problems that may occur during determination of trace levels of polychlorinated biphenyls in sediment samples are described. Main error sources are connected with extraction of analytes prior to final determination. During model studies, polychlorinated biphenyls have been extracted from sedimentreference material (METRANAL 2) with the use of different solvents (dichloromethane, hexsane, and toluene); the process...
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Green analytical chemistry : theory and practice
PublicationThis tutorial review summarises the current state of green analytical chemistry with special emphasis on environmentally friendly sample preparation techniques. Green analytical chemistry is a part of the sustainable development concept; its history and origins are described. Miniaturisation of analytical devices and shortening the time elapsing between performing analysis and obtaining reliable analytical results are important...
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Removal of sulfur from a solvent extract
PublicationThe presence of sulfur in a solvent extract that is to be analyzed chromatographically impairs and sometimes precludes properinterpretation of the chromatogram, as the sulfur peak masks the peaks of other compounds present in the sample, and sulfur alsodisrupts the operation of the mass detector. This means that discrepancies in the results can lead to erroneous interpretations andfalse assessments of environmental risk. For this...
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Rola związków znaczonych izotopowo w analityce środowiskowej
PublicationKażdą procedurę analityczną można potraktować jako łańcuch złożony z ogniw, które obrazują poszczególne czynności i operacje. Zgodnie ze znanym przysłowiem, które mówi, że ''Łańcuch jest tak mocny jak jego najsłabsze ogniwo'', także i w przypadku procedur analitycznych szczególną uwagę należy zwrócić na te czynności i operacje (wykonywane zarówno w terenie, czyli in situ, jak i w laboratorium), które wymagają szczególnej troski...
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Rola związków znaczonych izotopowo w analityce środowiskowej
PublicationEtap pobierania próbki oraz przygotowania jej do analizy często stanowią najtrudniejsze zadanie analityczne, które może być przyczyną niekontrolowanych strat analitów, a zatem i wzrostu niepewności oznaczania zawartości analitu. Dlatego wymagane jest kontrolowanie strat analitów na wszystkich etapach przygotowania próbki do analizy. Nie jest to jednak proste zadanie. Powszechnie stosowane techniki ekstrakcji analitów z próbek środowiskowych...
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Green Analytical Chemistry Approaches in Sample Preparation
PublicationThis chapter presents environmentally friendly solutions for sample preparation. Attention is focused on extraction techniques and the minimization of organic solvent consumption, as the large quantitiesused in analytical laboratories are a pressing environmental problem. Solventless sample preparation techniques, alternative solvents, mediated extractions are discussed. The principle of each technique isbriefly described, together...
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Mechanical testing of technical woven fabrics
PublicationThis article presents a review of technical fabrics testing methods used by the authors on the basis of their experience with research on properties of polytetrefluoroethylene-coated fabrics used for Forest Opera in Sopot (Poland). First, the different types of testing methods used for description of mechanical properties (uniaxial tensile tests, biaxial tensile tests and shear tests) of technical woven fabrics are described. The...
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Mechanical metamaterials manufactured by increasing technology
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Mechanical strength of stems in aquatic macrophytes
PublicationSummary: In populations of submerged macrophytes, individuals are selected in terms of resistance to the effect of hydrodynamic forces. The aim of this study was to check whether individuals growing in river water are more tensile and bending resistant than plants occurring in places not exposed to flow stress. We determined the ultimate tensile strength of stems in four macrophyte species, Potamogeton natans, P. pectinatus, Batrachium...
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Mechanical Properties of Human Abdominal Fascia
PublicationW pracy przedstawiono wyniki identyfikacji modułu sprężystosci i współczynnika Poissona próbek powięzi ściany brzucha człowieka, którą przeprowadzono na podstawie testów jednoosiowego rozciągania.
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The analysis of mechanical vibrations with use of the MATHCAD.
PublicationPrzedstawiono zagadnienie analizy drgań mechanicznych ze wspomaganiem komputerowym za pomocą programu MATHCAD. Omówiono zagadnienia zastosowania programu w edukacji i w obliczeniach inżynierskich.
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Mechanical Properties of Aluminium Bracket Strengthening
PublicationThe aim of the research is laboratory investigation of aluminium brackets employed to fasten lightweight curtain walls to building facilities. Tensile loads perpendicular to end plates (vertical) were applied here. The author focused on the solutions intended to increase the load-carrying capacity of aluminium brackets applying the plain washer form A (DIN 125; ISO 7089), plain washer with an outer diameter about 3d (DIN 9021;...
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Application and mechanical properties of aluminium alloys
PublicationThe paper presents a short survey of the application and mechanical properties of aluminium alloys. This area of scientific research is still developing, the authors restricted it to about 30 papers. Numerical simulations of the aluminium bracket are also investigated. The authors propose a solution to increase the load capacity of aluminium brackets with application of the additional cover plates. This study is proposed as an...
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Mechanical Properties of Human Stomach Tissue
PublicationThe dataset entitled Determination of mechanical properties of human stomach tissues subjected to uniaxial stretching contains: the length of the sample as a function of the corresponding load (tensile force) and the initial values of the average width and average thickness of the sample. All tests were conducted in a self-developed tensile test machine: PG TissueTester. The dataset allows the coefficients of various models of...
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Mechanizmy wsparcia rozwoju wysokosprawnej kogeneracji i OZE oraz wykorzystania energii odpadowej w Polsce i UE
PublicationPrzedstawiono zobowiązania i główne wnioski zawarte w dyrektywach Komisji Europejskiej oraz w krajowych ustawach i rozporządzeniach ministerialnych, dotyczących wdrożenia mechanizmu wsparcia źródeł rozproszonego wytwarzania energii. Skupiono się głównie na wsparciu dla rozwoju wysokosprawnej kogeneracji. Zaprezentowano szanse wynikające dla małych i średnich przedsiębiorstw, działających w branży instalatorskiej i energetycznej,...
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A Mesh Deformation Technique Based on Solid Mechanics for Parametric Analysis of High-Frequency Devices With 3-D FEM
PublicationIn this paper, a versatile technique for mesh defor- mation is discussed, targeted at the electromagnetic (EM) field simulation of high-frequency devices using the 3-D finite element method (FEM). The approach proposed applies a linear elasticity model to compute the displacements of the internal mesh nodes in 3-D when the structure geometry is changed. The technique is compared with an alternative approach...
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Thermal Buckling Analysis of Circular Bilayer Graphene sheets Resting on an Elastic Matrix Based on Nonlocal Continuum Mechanics
PublicationIn this article, the thermal buckling behavior of orthotropic circular bilayer graphene sheets embedded in the Winkler–Pasternak elastic medium is scrutinized. Using the nonlocal elasticity theory, the bilayer graphene sheets are modeled as a nonlocal double–layered plate that contains small scale effects and van der Waals (vdW) interaction forces. The vdW interaction forces between the layers are simulated as a set of linear springs...
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A new hyperbolic-polynomial higher-order elasticity theory for mechanics of thick FGM beams with imperfection in the material composition
PublicationA drawback to the material composition of thick functionally graded materials (FGM) beams is checked out in this research in conjunction with a novel hyperbolic‐polynomial higher‐order elasticity beam theory (HPET). The proposed beam model consists of a novel shape function for the distribution of shear stress deformation in the transverse coordinate. The beam theory also incorporates the stretching effect to present an indirect...
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Cell-penetrating peptides – mechanism of transduction and synthesis – short review
PublicationPotential antimicrobial agents may be effective if they are delivered efficiently to their site of action. In many cases, lack of permeability through the cell membrane is the main problem. One of the possible solutions could be a novel intracellular delivery system involving cell-penetrating peptides (CPPs), which may improve the efficiency of many new biophar-maceuticals. Among other things, CPPs are capable of trans-porting...
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Distortion of speech signals in the listening area: its mechanism and measurements
PublicationThe paper deals with a problem of the influence of the number and distribution of loudspeakers in speech reinforcement systems on the quality of publicly addressed voice messages, namely on speech intelligibility in the listening area. Linear superposition of time-shifted broadband waves of a same form and slightly different magnitudes that reach a listener from numerous coherent sources, is accompanied by interference effects...
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Classification of different type of propeller ventilation and ventilation inception mechanism
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Classification of different type of propeller ventilation and ventilation inception mechanism
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Theoretical Study of Polymerization Mechanism of p-Xylylene Based Polymers
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Mechanism of Butanol Adsorption from Solution. 1. Calorimetric Measurements
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Influence of the counterweight model on optimization of balancing of four-bar mechanism
PublicationPraca opisuje rozważania na temat wyrównoważania płaskiego czworoboku przegubowego. Do wyrównoważenia wykorzystano metodę alokacji przeciwmas. Zadanie to wymagało połączenia procedur analizy dynamiki układów wielomasowych z procedurą optymalizacji. W pracy umieszczono opis metody dynamiki układów wielomasowych. W procesie optymalizacji skorzystano z metody sympleksów. Opisano model analizowanego układu składający się z dwóch sekcji...
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Kinetics and mechanism of the dehydrohalogenation of Ar2CHCX3 and Ar2CHCHX2 by strong N-bases
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The Role of pH in the Mechanism of .OH Radical Induced Oxidation of Nicotine
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Cam mechanism designing with account of the technological load and energy costs
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Mechanism of nitromethane liquid membrane oscillator containing sodium oleate
PublicationBadano osylacyjne zachowanie oscylatora z anionowym surfaktantem na poziomie molekularnym. Zastosowano przybliżenie oparte na zasadach kinektyki chemicznej. Membranę ciekłą stanowił nitrometan z 2,2' bipirydyną. Faza wodna domowa zawierała oleinian sodu i butanol, a faza wodna akceptora chlorek sodu. Ustalono, że oscylacje zachodzą na granicy fazy akceptorowej i membrany ciekłej. Zaproponowano 3-etapowy mechanizm oscylacji i potwierdzono...
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Theoretical study of polymerization mechanism of p-xylylene based polymers
PublicationObliczenia kwantowe mechanizmu polimeryzacji parylenów, opartych o cząsteczki p-ksylilenów. Praca zawiera wyniki szczegółowych obliczeń wszystkich etapów polimeryzacji, wnioski dotyczące znalezionych stanów kwantowych i energetyki poszczególnych etapów procesu.
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Mechanism of phenol photodegradation in the presence of pure and modified-TiO2: A review
PublicationW publikacji został przedstawiony przegląd i podsumowanie literaturowe na temat fotokatalitycznego utleniania fenolu w obecności TiO2. Opisano mechanizm rozkładu fenolu i tworzenia się rodników OH.
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Flow of liquid in flat gaps of the satellite motor working mechanism
PublicationThe article describes the methodology and results of investigations of the flow of oil and HFA-E emulsion in flat gaps of the working mechanism of a satellite motor. The flow of liquid in those gaps is turbulent and not fully developed. The article presents two methods of modelling this flow. Method I makes use of the Darcy-Weisbach formula, while Method II bases on the assumption that in the variable-length gaps the flow is turbulent...
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Proposal of improvement to fairness mechanism of Resilient Packet Ring networks
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Contribution to the mechanism of liquid membrane oscillators involving cationic surfactant.
PublicationIt is shown that liquid membrane oscillators with cationic surfactants havemore complex oscillation patterns than observed previously. The actual details of the oscillations depend strongly on the nature of the membrane material, dislosing even the presence of parallel molecular events. It appearsthat sampling topology also has a great influence on the observed oscillato-ry behaviour. Variation of oscillation patterns with...
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Mechanism of antifreeze protein functioning and the “anchored clathrate water” concept
PublicationIn liquid water, there is a natural tendency to form aggregates that consist of water molecules linked by hydrogen bonds. Such spontaneously formed aggregates are surrounded by a "sea" of disordered water molecules, with both forms remaining in equilibrium. The process of creating water aggregates also takes place in the solvation water of proteins, but in this case the interactions of water molecules with the protein surface shift...
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The excitation controller with gain scheduling mechanism for synchronous generator control
PublicationThe power systems, including the synchronous generators and power systems networks, are complex nonlinear systems with configuration and parameters which change through time. That leads to electromechanical oscillations occurring in that system. Thus synchronous generator excitation controller must be capable of providing appropriate stabilization signal over broad range of operating conditions and disturbances. In this paper,...
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On the durability of the hydraulic satellite motor working mechanism in overload condition
PublicationThe paper presents the newest construction of the hydraulic satellite pump/motor. In this study, the fracture of the hydraulic satellite motor working mechanism is investigated. Factors influencing the durability of satellite working mechanism have been described. The durability of the hydraulic satellite motor working mechanism at a load, corresponding to a pressure of 15 MPa supplied with refined rapeseed oil is very low. Analyses...
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On the mechanism of photocatalytic reactions on CuxO@TiO2 core–shell photocatalysts
PublicationTitania (titanium(IV) oxide) is a highly active, stable, cheap and abundant photocatalyst, and is thus commonly applied in various environmental applications. However, two main shortcomings of titania, i.e., charge carrier recombination and inactivity under visible-light (vis) irradiation, should be overcome for widespread commercialization. Accordingly, titania has been doped, surface modified and coupled with various ions/compounds,...
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A simple model of the trap-assisted recombination with the excitonic Auger mechanism
PublicationWe present a simple model of the trap-assisted recombination combined with the excitonic Auger mechanism. It has been shown that only six independent transitions of electrons and holes should be taken into account to describe a combination of the Shockley–Read–Hall (SRH) recombination with this excitonic process. This is in opposition to a well-known model of the SRH mechanism with the free carriers Auger effect via deep states,...
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Analysis of Failure Mechanism in Joints with Positive Eccentricity in CFS Truss
PublicationThe paper presents studies concerning the load-bearing capacity of truss joints with a positive eccentricity resulting from the arrangement of geometric members and the failure mechanisms observed in the joints. Based on the previously conducted experimental study, a numerical model of the tested fragment of the CFS truss with eccentricity in the joint was created and validated. All structural details of the tested truss and the...
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Atmospheric degradation mechanism of anthracene initiated by OH•: A DFT prediction
PublicationDensity functional theory (DFT) calculations at the M06-2X/def2-TZVP level have been employed to investigate the atmospheric oxidation mechanism of anthracene (ANT) initiated by HO•. Direct hydrogen atom abstraction from the ANT using HO• takes place hardly at ambient conditions while the addition of HO• to the C1, C2, and C4 sites are thermodynamically and kinetically more advantageous. The addition reactions are controlled by...
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The methodology of design of satellite working mechanism of positive displacement machine
PublicationIn this paper is described a methodology of design of satellite mechanism consisting of two noncircular gears (externally toothed rotor and internally toothed curvature) and circular gears (satellites). In the presented methodology is assumed that the rotor pitch line is known, and the curvature pitch line is necessary to designate. The presented methodology applies to mechanisms for which the number of the curvature humps is at...
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Towards spectral sensitivity curve for two-photon vision mechanism
PublicationAbstract Purpose: The perceived brightness of different visible light sources can be compared with photometric units based on the standardized luminosity curves (300-780nm range). As reported previously (PNAS 111(50), pp. E5445-E5454 (2014)), near-infrared (NIR) radiation can cause isomerization of visual pigments by one- or two-photon absorption. The perceived color of the stimulus is red in the case of one-photon vision (1PV)...
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METODA REDUKCJI PRAWDOPODOBIEŃSTWA BLOKOWANIA ŻĄDAŃ W SIECI SZKIELETOWEJ OPARTA O MECHANIZM PROGNOZOWANIA KONFLIKTÓW W ZASOBACH PRZEPUSTOWOŚCI
PublicationMetody doboru tras ukierunkowane na równoważenie obciążenia sieci (ang: Load-Balancing Routing; LBR) redukują prawdopodobieństwo blokowania żądań na instalację tras i tym samym podnoszą potencjalny przepływ transmisji, przy niezmiennej przepustowości sieci. Niniejsza praca prezentuje nową metodę LBR która prowadzi do istotnej redukcji prawdopodobieństwa blokowania (dla niektórych scenariuszy ponad 3.8 razy).
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Stability evaluation of the marine propulsion unit mechanical system bymeans of vibrations measurements and their analysis.
PublicationIn paper selected issues concerning vibration diagnosis of the mechanical system within marine propulsion units have been given. The analysis of vibration parameters was carried out on the basis of experimental examinations of a real object in which an exceedance of the allowable vibration's level had been observed. In the beginning, the vibration apparatus being on laboratory equipment of the Department of Ship Power Plants of...
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Blood–brain barrier permeability mechanisms in view of quantitative structure–activity relationships (QSAR)
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Effects of rapid heating on non-equilibrium microstructure evolution and strengthening mechanisms of titanium alloy
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Mechanisms of Plant Natural Immunity and the Role of Selected Oxylipins as Molecular Mediators in Plant Protection
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Mechanisms shaping the synergism of zeaxanthin and PsbS in photoprotective energy dissipation in the photosynthetic apparatus of plants
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