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Search results for: METAL−ORGANIC FRAMEWORKS
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New nanoadsorbent based on magnetic iron oxide containing 1,4,7,10-tetraazacyclododecane in outer chain (Fe3O4@SiO2-cyclen) for adsorption and removal of selected heavy metal ions Cd2+, Pb2+, Cu2+
PublicationMagnetic Fe3O4@SiO2-cyclen nanoparticles were prepared and used as adsorbent for Cd2+, Pb2+ and Cu2+ from aqueous solution removal process controlled with differential pulse anodic stripping voltammetry (DPASV) and hanging mercury drop electrode (HDME). Nanomaterial was synthesised in three-step process co-precipitation of Fe3O4 core, coating with silane and N-(3-(triethoxysilyl)propyl)-1,4,7,10-tetraazacyclododecane-1-carboxamide...
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Study of the selection mechanism of heavy metal (Pb 2+, Cu 2+, Ni 2+ and Cd2+) adsorption on clinoptilite
PublicationBadano proces adsorpcji jonów metali ciężkich (w warunkach statycznych) z wodnych roztworów jednoskładnikowych i wieloskładnikowych na klinoptylolicie zarówno surowym jak i po wstępnej obróbce. Proces sorpcji ma charakter procesu jonowymiennego i składa sie z trzech etapów:- adsorpcji na powierzchni mikokryształów,- inwersji,- adsorpcji wewnątrz mikrokryształów.Proces sorpcji może być dobrze opisany zarówno za pomocą modelu Frendlicha...
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Application of 3D digital image correlation for development and validation of FEM model of self-supporting metal plates structures
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Correlation between destruction of the metal surface caused by pitting corrosion and intensity of the observed electrochemical noise (Invited Paper)
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Nitrogen‐Doped Porous Graphene‐Based Aerogels toward Efficient Heavy Metal Ion Adsorption and Supercapacitor Applications
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The importance of evaluating metal exposure and predicting human health risks in urban–periurban environments influenced by emerging industry
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Silicon polypodands: powerful metal cation complexing agents and solid–liquid phase-transfer catalysts of new generation
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Study on the effect of the metal–support (Fe-MgO and Pt-MgO) interaction in alcohol-CVD synthesis of carbon nanotubes
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Broad-Range Spectral Analysis for Chiral Metal Coordination Compounds: (Chiro)optical Superspectrum of Cobalt(II) Complexes
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Volumes of N,N-dimethylacetamide solvated metal cations. Variation within the manganese(II) to zinc(II) series
PublicationDensities and apparent molar volumes for Mn(ClO4)2,Co(ClO4)2 , Ni(ClO4)2,Cu(ClO4)2 , and Zn(ClO4)2 in N, N -dimethylacetamide (DMA) solutions at T = 298.15 K are reported. Densities and apparent molar volumes of tetrabutylammonium tetraphenylborate...
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Estimation, optimization and analysis based investigation of the energy consumption in machinability of ceramic-based metal matrix composite materials
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Protective Effect of Aronia Melanocarpa Polyphenols on Cadmium Accumulation in the Body: A Study in a Rat Model of Human Exposure to this Metal
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Correlational nutritional relationships and interactions between expansive holoparasite Orobanche laxissima and woody hosts on metal-rich soils
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Effects of simulated pressure of wooden, plastic, and metal materials on the thermal insulation of cold-protective gloves of various designs
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Broadband mid-infrared emission in heavy metal oxide glasses triply-doped with Er3+/Ho3+/Yb3+ ions
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O-substituted tetrahydroxamate derivatives of p-tert-butylcalix[4]arene as receptors for transition and heavy metal cations
PublicationTetrasubstituted O-hydroxamate derivatives of p-tert-butylcalix[4]arene were applied as active materials in ion-selective membrane electrodes and were tested towards Pb-selectivity. The electrodes gave near-Nernstian characteristics for Pb2+ cations. The selectivity coefficients were determined. The influence of plasticizer on the electrode behaviour was studied. The dependence of the chemical structure on selectivity coefficients...
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Influence of vacuum sublimation deposited metal layer thickness on metrological parameters of the amperometric gas sensor with Nafion membrane
PublicationThe paper presents the results of investigation on an influence of vacuum sublimation deposited platinum layer thickness on the signal, sensitivity and response time of a prototype of sulphur dioxide sensor with Nafion membrane. The working electrode was made by vacuum sublimation deposition of platinum on a surface of Nafion membrane. Pt layers deposited changed an initial structure of Nafion membrane and that phenomenon was utilized...
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Solvation of alkaline earth metal ions in N,N-dimethylformamide and N,N-dimethylacetamide – A volumetric and acoustic study
PublicationDensities and sound velocities at temperatures (298.15, 303.15, 308.15, 313.15 and 318.15) K of magnesium(II), calcium(II) and strontium(II) rifluoromethanesulfonates (triflates), as well as barium(II) perchloratein N,N-dimethylformamide (dmf) and N,N-dimethylacetamide (dma) have been measured over the composition range studied. From these results, apparent molar volumes and apparent molar isentropic compressibilities at infinite...
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Metal ion directed template synthesis using 2-acetyl-1,3-indandione and ethylenediamine: steric and electronic restrictions
PublicationA template synthesis using 2-acetyl-1,3-indandione and ethylenediamine results in formation of octahedral Ni complex, whose crystal structure has been resolved using single crystal X-ray diffraction. The structure indicates that only exocyclic enolic oxygen atom of the triketone takes part in the condensation with ethylenediamine.
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The effects of urban vehicle traffic on heavy metal contamination in road sweeping waste and bottom sediments of retention tanks
PublicationDiffuse pollution formed during a surface runoff on paved surfaces is a source of heavy metals (HMs) of various origin. This research study indicates the connection between bottom sediments of retention tanks located on urban streams and road sweeping wastes (RSW) that migrate during surface runoff to the stormwater drainage systems with discharge to the retention tanks. Moreover, we test the primary sources of HMs in RSW by analysing...
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A pilot study to assess an in-process inspection method for small diameter holes produced by Direct Metal Laser Sintering
PublicationPurpose The purpose of this research is to evaluate the geometric quality of small diameter holes in parts printed by DMLS technology. An in-process optical inspection method is proposed and assessed during a pilot study. The influence of the theoretical hole diameter assumed in a CAD system and the sample thickness (hole length) on the hole clearance was analysed. Design/methodology/approach The samples made of two different...
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Gas‐Phase Removal of Indoor Volatile Organic Compounds and Airborne Microorganisms Over Mono‐ and Bimetal‐Modified (Pt, Cu, Ag) Titanium(IV) Oxide Nanocomposites
PublicationThe photocatalytic deactivation of volatile organic compounds and mold fungi using TiO2 modified with mono‐ and bimetallic (Pt, Cu, Ag) particles is reported in this study. The mono‐ and bimetal‐modified (Pt, Cu, Ag) titanium(IV) oxide photocatalysts were prepared by chemical reduction method and characterized using XRD, XPS, DR/UV‐Vis, BET and TEM analysis. The effect of incident light, type and content of mono‐ and bimetallic...
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Measurement of activity coefficients at infinite dilution of organic solutes in the ionic liquid 1-hexyl-1,4-diaza[2.2.2]bicyclooctanium bis(trifluoromethylsulfonyl)imide using gas–liquid chromatography
PublicationBased on gas–liquid chromatography (GLC) retention data, activity coefficients at infinite dilution of 39 different solutes in the ionic liquid 1-hexyl-1,4-diaza[2.2.2]bicyclooctanium bis(trifluoromethylsulfonyl)imide ([HDABCO][NTf2]) have been determined. Measurements covered a broad range of types of organic solutes including alkanes, alcohols, ketones, benzene derivatives and McReynold’s compounds. Activity coefficients were...
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Evidence for electric field dependent dissociation of exciplexes in electron donor-acceptor organic solid films
PublicationBadano wpływ zewnętrznego pola elektrycznego na zanik luminescencji w układzie dendrymer aminowy m-MTDATA:fenantrolina BPT:poliwęglan PC oraz domieszkowanym organicznym kompleksem platyny. Zaobserwowano silne wygaszenie luminescencji na skutek dysocjacji ekscypleksów singletowych i trypletowych. Pole elektryczne obniżało zarówno amplitudę, jak i czas życia luminescencji.
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Determination of Volatile Organic Compounds in Indoor Air in the Gdansk Area Using Permeation Passive Samplers
PublicationPassive dosimetry — known for over a hundred years — is still a useful tool in monitoring air pollutants. In this work, permeation passive samplers were used to determine indoor air quality in 22 apartments located in the Gdansk area in the northern part of Poland. The results obtained by the passive sampling technique were compared to those obtained by dynamic sampling. Attempts were also made to identify indoor sources of...
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Elemental and organic carbon in aerosols over urbanized coastal region (southern Baltic Sea, Gdynia)
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A giant 2-dimensional dielectric response in a compressed hydrogen-bonded hybrid organic–inorganic salt
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Electric field effect on luminescence, and photoconduction in electron donor - electron acceptor organic solid films
PublicationZaobserwowano silne wygaszenie fotoluminescencji (80%) i duże fotoprądy (1mA/cm2) w układzie dendrymer aminowy m-MTDATA (donor elektronu) : pochodna fenantroliny BPT (akceptor elektronu) niedomieszkowanym oraz zawierającym domieszkę w postaci organicznego kompleksu platyny PtL2Cl. W interpretacji wyników uwzględniono elektrycznopolową dysocjację singletowych ekscypleksów m-MTDATA:BPT i trypletowych ekscypleksów m-MTDATA : PtL2Cl...
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Stability studies of selected polycyclic aromatic hydrocarbons in different organic solvents and identification of their transformation products
PublicationGłównym problemem w laboratoriach analitycznych jest konserwacja próbek i ekstraktów przeznaczonych do analizy. Rozpatrując procesy degradacji z analitycznego punktu widzenia i związanej z tym wiarygodności uzyskiwanych wyników pod uwagę należy wziąć wpływ procesów degradacji w badanym elemencie środowiska na poziom stężenia składników śladowych; wpływ tych samych procesów na poziom składników śladowych w już pobranych próbkach...
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Sample preparation for gas chromatographic determination of halogenated volatile organic compounds in environmental and biological samples
PublicationPodstawowym elementem przygotowania próbek środowiskowych i biologicznych do analizy jest etap izolacji i/lub wzbogacania polegający na przeniesieniu analitów z matrycy pierwotnej charakteryzującej się złożonym i często zmiennym składem (próbka oryginalna) do matrycy wtórnej z równoczesnym usunięciem substancji przeszkadzających (izolacja)i zwiększeniem stężenia analitów do poziomu powyżej granicy oznaczalności stosowanego przyrządu...
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Fluctuations of sodium, copper, zinc, iron and manganese in potato tubers in the organic and integrated production system
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Graphene nanoflakes functionalized with cobalt/cobalt oxides formation during cobalt organic framework carbonization
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Organic Rankine cycle turbogenerator cooling – Optimization of the generator water jacket heat exchange surface
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Ag Loading Enhanced Photocatalytic Activity of g-C3N4 Porous Nanosheets for Decomposition of Organic Pollutants
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Bio-mitigation of organic pollutants using horseradish peroxidase as a promising biocatalytic platform for environmental sustainability
PublicationA wide array of environmental pollutants is often generated and released into the ecosystem from industrial and human activities. Antibiotics, phenolic compounds, hydroquinone, industrial dyes, and Endocrine-Disrupting Chemicals (EDCs) are prevalent pollutants in water matrices. To promote environmental sustainability and minimize the impact of these pollutants, it is essential to eliminate such contaminants. Although there are...
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Ag modified ZnO microsphere synthesis for efficient sonophotocatalytic degradation of organic pollutants and CO2 conversion
PublicationThe synthesis and design of non-precious and efficient sonophotocatalyts by an environment friendly technique are requisites for solar energy conversion and environmental remediation. This work reports the preparation of Ag/ZnO microspheres with different Ag contents through deposition–precipitation method for pollutant degradation and CO2 conversion. Detail structural investigation reveals that ZnO microspheres and Ag-ZnO microspheres...
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Assessment of soil microbial diversity measurements as indicators of soil functioning in organic and conventional horticulture systems
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Volatile organic compounds in gastrointestinal stromal tumour tissue originating from patient-derived xenografts
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Effect of acid whey on physicochemical characteristics of dry-cured organic pork loins without nitrite
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Effect of Marination Time on the Antioxidant Properties of Peptides Extracted from Organic Dry-Fermented Beef
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Ag modified ZnO microsphere synthesis for efficient sonophotocatalytic degradation of organic pollutants and CO2 conversion
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Enhanced sunlight photo-catalytic performances of ZnO/ZnNb2O6/Nb2O5 composites for organic pollutant degradation
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OCCURENCE OF L. MONOCYTOGENES IN FRESH FRUITS AND VEGETABLES FROM ORGANIC FARMS IN WEST POMERANIAN REGION
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A targeted metabolomic protocol for quantitative analysis of volatile organic compounds in urine of children with celiac disease
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An Overview of Pest and Disease Occurrence in Organic Pome Fruit Orchards in Europe and on the Implementation of Practices for Their Control
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Insights into the Belowground Biodiversity and Soil Nutrient Status of an Organic Apple Orchard as Affected by Living Mulches
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Distribution of pollutants in the Odra River system part II. Organic pollutants in Odra River water
PublicationW pracy przedstawiono wyniki oznaczeń zanieczyszczeń organicznych (pestycydy, lotne związki chlorowcoorganiczne, wielopierścieniowe węglowodory aromatyczne, chlorobenzeny, polichlorowane bifenyle) w próbkach wody zebranych w trakcie 8 Kampanii (w okresie 1997-2000) zorganizowanej w ramach Międzynarodowego Projektu Badań Dorzecza Rzeki Odry (IOP).
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Automated analyser for monitoring trace amounts of volatile chloro-organic compounds in recirculated industrial water
PublicationOpisano konstrukcję oraz badania laboratoryjne modelu nowego automatycznego analizatora śladowych ilości lotnych związków chlorowco-organicznych w wodzie do celów przemysłowych (o wysokiej czystości). Praca analizatora oparta jest na: - przeciwprądowym ciągłym wypłukiwaniu analitów ze strumienia próbki, - okresowym zatrzymywaniu uwolnionych analitów na złożu sorbenta, - desorpcji termicznej, - oznaczaniu sumy związków chlorowco-organicznych...
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Effect of housing geometry on the performance of Chemcatcher passive sampler for the monitoring of hydrophobic organic pollutants in water
PublicationZaprojektowano nową obudowę próbnika typu Chemcatcher, tzw. próbnik typu Chemcatcher drugiej generacji. Większość badań kalibracyjnych przeprowadzono stosując próbnik typu Chemcatcher pierwszej generacji. Dlatego zbadano wpływ obudowy próbnika typu Chemcatcher na jego działanie.
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Excimer-based red-infrared organic light emitting diodes with very high quantum efficiency
PublicationW pracy opisano konstrukcję wydajnej organicznej ekscymerowej diody EL emitującej światło czerwone i podczerwone z wykorzystaniem organicznego kompleksu platyny.