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Search results for: MIXED CONDUCTOR SOFC
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Squashed entanglement for multipartite states and entanglement measures based on the mixed convex roof
PublicationNew measures of multipartite entanglement are constructedbased on two definitions of multipartite information anddifferent methods of optimizing over extensions of the states. Oneis a generalization of the squashed entanglement where one takesthe mutual information of parties conditioned on the state's extensionand takes the infimum over such extensions. Additivity ofthe multipartite squashed entanglement is proved for both versionsof...
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Application of Complementary Signals in Built-In Self Testers for Mixed-Signal Embedded Electronic Systems
PublicationThis paper concerns the implementation of shape-designed complementary signals (CSs), matched to the frequency characteristic of the circuit under test, in built-in self testers (BISTs), dedicated to mixed-signal embedded electronic systems for testing their analog sections. The essence of the proposed method and solution of CS BIST is low-cost realization on the base of hardware and software resources of microcontrollers used...
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The Palais–Smale condition for the Hamiltonian action on a mixed regularity space of loops in cotangent bundles and applications
PublicationWe show that the Hamiltonian action satisfies the Palais-Smale condition over a “mixed regular- ity” space of loops in cotangent bundles, namely the space of loops with regularity H^s, s ∈ (1/2, 1), in the baseand H^{1−s} in the fiber direction. As an application, we give a simplified proof of a theorem of Hofer-Viterbo on the existence of closed characteristic leaves for certain contact type hypersufaces in cotangent bundles.
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Mn-Co spinel coatings on Crofer 22 APU by electrophoretic deposition: Up scaling, performance in SOFC stack at 850 °C and compositional modifications
PublicationCeramic coatings for metallic interconnects play a key role in limiting corrosion and chromium evaporation in solid oxide cells. This study presents the upscaling of the electrophoretic deposition (EPD) technique to process Mn-Co spinels on real-dimension Crofer 22 APU interconnects and the test in a SOFC stack. Area specific resistance of long-term test conducted for 5000 h at 850 °C demonstrated that two-steps sintering has a...
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Exsolution of Ni nanoparticles on the surface of cerium and nickel co-doped lanthanum strontium titanate as a new anodic layer for DIR-SOFC. Anti-coking potential and H2S poisoning resistance of the prepared material
PublicationThe aim of this study was to evaluate a new catalytic material for biogas fueled DIR-SOFC. This material was a perovskite-type SrTiO3 doped with La, Ce and Ni of a general formula La0.27Sr0.54Ce0.09Ni0.1Ti0.9O3-σ (LSCNT). Additional preparation steps were undertaken to promote a nickel exsolution process. Heat post-treatment of powders in a humidified H2 resulted in an intensive growth of nickel nanoparticles (NPs) while the temperature...
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Zirconia-based mixed potential sensor with Pt electrode prepared by spin-coating of polymeric precursor
PublicationMany types of yttria-stabilized zirconia (YSZ) based gas sensors have been explored extensively in recent years. Great attention have been directed to mixed-potential-type gas sensors. It is due to growing concerns with environmental issues. Not without a significance is the fact of very attractive performance of this type of sensor allowing to detect low concentration of pollutant gases. In this paper two types of YSZ based mixed-potential...
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Rheology of Variable Viscosity‐Based Mixed Convective Inclined Magnetized Cross Nanofluid with Varying Thermal Conductivity
PublicationCross nanofluid possesses an extraordinary quality among the various fluidic models to explore the key characteristics of flowing fluid during very low and very high shear rates and its viscosity models depend upon shear rate. The current study establishes the numerical treatment regarding variable viscosity‐based mixed convective inclined magnetized Cross nanofluid with var‐ ying thermal conductivities over the moving permeable...
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Fabrication and structural properties of Y and Fe co-doped SrTiO3 nanoceramics for SOFC
PublicationYttria and iron co-doped strontium titanate perovskites, (Y0,07Sr0,93Ti1-xFexO3-δx=0,1; 0,2) samples were fabricated by two methods: solid-state synthesis (SS) and the Pechinisol-gel modified method. The morphology of samples were measured by SEM and X-raydiffraction. Results were compared and discussed. The strong relationship between fabricationprocedure and microstructure has been proven. It was also observed, that the nanoceramicsobtained...
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Assesment of (Mn,Co)3O4powders for possible coating material for SOFC/SOEC interconnects
PublicationIn this work (Mn,Co)3O4 spinel powders with different Mn:Co ratio (1:1 and 1:2) and from different commercial suppliers are evaluated for possible powder for production of interconnect coatings. Sinterability of the powders is evaluated on pressed pellets sintered in oxidizing and in reducing/oxidizing atmospheres. For selected powder, coatings are then prepared by the electrophoretic deposition method on Crofer 22 APU stainless...
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Wild oscillations in a nonlinear neuron model with resets: (II) Mixed-mode oscillations
PublicationThis work continues the analysis of complex dynamics in a class of bidimensional nonlinear hybrid dynamical systems with resets modeling neuronal voltage dynamics with adaptation and spike emission. We show that these models can generically display a form of mixed-mode oscillations (MMOs), which are trajectories featuring an alternation of small oscillations with spikes or bursts (multiple consecutive spikes). The mechanism by...
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SmallAngle Neutron Scattering Study of the Structure of Mixed Micellar Solutions Based on Nonionic and Two Cationic Surfactants
PublicationThe aggregation in mixed water systems based on nonionic surfactant, i.e., heptaethylene glycol monotetradecyl ether (C14E7), and cationic surfactants, i.e., cetyltrimethylammonium bromide (CTAB), and cetyltrimethylammonium chloride (CTAC) has been investigated using the smallangle neutron scattering method. The preliminary results of the study of the behavior of C14E7 aqueous solutions (for a concentration of 0.17%) when adding...
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Small-Angle Neutron Scattering Study of the Structure of Mixed Micellar Solutions Based on Heptaethylene Glycol Monotetradecyl Ether and Cesium Dodecyl Sulfate
PublicationThe micellization in mixed aqueous systems based on a nonionic surfactant, heptaethylene glycol monotetradecyl ether (C14E7), and an anionic surfactant, cesium dodecyl sulfate, has been investigated by small-angle neutron scattering. Preliminary data on the behavior of the C14E7 aqueous solutions (with three concentrations, 0.17, 0.5, and 1%) mixed with a small amount of anionic surfactant, cesium dodecyl sulfate, are reported.
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Distress and functioning in mixed anxiety and depressive disorder
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Mixed systems with minimal and maximal lifetime variances
PublicationRozważa się mieszane układy złożone ze stałej liczby składników, których czasy zycia są niezależnymi zmiennymi losowymi o jednakowym rozkładzie i dodatniej wariancji. Bada się minimalną i maksymalną wariancję czasu życia rozważanych układów.
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Fabrication of Bi6Fe2Ti3O18 Ceramics by Mixed Oxide Method
PublicationIn the present study Bi6Fe2Ti3O18 (BFTO) ceramics has been fabricated by solid state reaction from the mixture of simple oxides viz. Bi2O3, TiO2 and Fe2O3. Stoichiometric mixture of the powders was thermally analyzed so parameters of the thermal treatment were determined. The EDS measurements have shown conservation of the chemical composition of the ceramic powder after calcination. Hot-pressing method was used for final densification...
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A selectively reduced degree basis for efficient mixed nonlinear isogeometric beam formulations with extensible directors
PublicationThe effect of higher order continuity in the solution field by using NURBS basis function in isogeometric analysis (IGA) is investigated for an efficient mixed finite element formulation for elastostatic beams. It is based on the Hu–Washizu variational principle considering geometrical and material nonlinearities. Here we present a reduced degree of basis functions for the additional fields of the stress resultants and strains...
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DMSO hydration redefined: Unraveling the hydrophobic hydration of solutes with a mixed hydrophilic–hydrophobic characteristic
PublicationHydrophobic hydration of solutes with a mixed hydrophilic--hydrophobic characteristics is still poorly understood. This is because both experimental and theoretical methods find it difficult to see the ice-like water structure around the nonpolar solute groups, unlike hydrogen bonds with the hydrophilic groups. In order to unravel this problem, we have investigated DMSO hydration by means of infrared spectroscopy and theoretical...
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Structural and electrical properties of Sr(Ti,Fe)O3-δ materials for SOFC cathodes
PublicationW niniejszym artykule, dwa związki SrTiO3 domieszkowanego Fe przebadano pod względem przydatności na katody w tlenkowych ogniwach paliwowych. SrTi0.65Fe0.35O3 i SrTi0.5Fe0.5O3 zostały przebadane pod względem reaktywności chemicznej z elektrolitem YSZ. Stwierdzono, że przewodnictwo elektryczne tych związków jest stosunkowo niskie: 0,4 S/cm i 2 S/cm odpowiednio dla STF35 i STF50.
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The comparison of SrTi0.98Nb0.02O3-δ-CeO2 and SrTi0.98Nb0.02O3-δ-YSZ composites for use in SOFC anodes
PublicationWytworzono i przebadano właściwości strukturalne i elektryczne kompozytów SrTi0.98Nb0.02O3-δ-CeO2 i SrTi0.98Nb0.02O3-δ-YSZ. Przeprowadzono testy materiałów zastosowanych jako anody w tlenkowych ogniwach paliwowych.
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Mixed ionic-electronic conductivity and structural properties of strontium-borate glass containing nanocrystallites of Bi2 VO5.5
PublicationSamples of strontium borate glass containing bismuth vanadate nanocrystallites were prepared. Nanocomposites containing up to 45mol% of the Bi2VO5.5 phase exhibit electrical properties closer to the strontium-borate glass than to the ferroelectric Bi2VO5.5 ceramic. The glass matrix still may contain some part of bismuth and vanadium ions even after crystallization process and there is too little of crystalline phase to observe...
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Thermodynamic and geometrical characteristics of mixed convection heat transfer in the shell and coil tube heat exchanger with baffles
PublicationThe article presents passive heat transfer enhancement method in the form of baffles to increase the energy efficiency of the shell coil heat exchanger. Conducted literature review shows that, despite numer- ous studies, there is little work on the intensification of heat transfer at the shell side. Most of the work focuses on the impact of geometrical parameters of the coil itself. This article successfully proves that it is possible...
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Application of Fenton oxidation to reduce the toxicity of mixed parabens
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Substrate noise-aware floorplanning for mixed-signal SOCs.
PublicationOpisano nową metodę projektowania systemów na chipie z uwzglednieniem minimalizacji szumu podłożowego. Optymalizacje rozmieszczenia bloków układowych na chipie uzyskuje się dzieki wykorzystaniu algorytmu ewolucyjnego minimalizującego funkcję celu uwzględniającą poziom szumu podłożowego.
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Multi-Objective Portfolio Optimization by Mixed Integer Programming
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An active electrode for mixed measurement techniqes, with application to EIT
PublicationW pracy przedstawiono budowę elektrody aktywnej wraz z opisem procedur pomiarowych prowadzących do poprawy stosunku sygnał-szum. Elektroda zbudowana jest w technice cyfrowo analogowej.
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Weakly Hydrated Solute of Mixed Hydrophobic–Hydrophilic Nature
PublicationInfrared (IR) spectroscopy is a commonly used and invaluable tool in studies of solvation phenomena in aqueous solutions. Concurrently, density functional theory calculations and ab initio molecular dynamics simulations deliver the solvation shell picture at the molecular detail level. The mentioned techniques allowed us to gain insights into the structure and energy of the hydrogen bonding network of water molecules around methylsulfonylmethane...
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Scaling of signed residue numbers with mixed-radix conversion in FPGA with extended scaling factor selection
PublicationA scaling technique of signed residue numbers in FPGA is proposed. The technique is based on conversion of residue numbers to the Mixed-Radix System (MRS). The scaling factor is assumed to be a moduli product from the Residue Number System (RNS) base. Scaling is performed by scaling of MRS terms, the subsequent generation of residue representations of scaled terms, binary addition of these representations and generation of residues...
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Modelling reinforced concrete beams under mixed shear-tension failure with different continuous FE approaches
PublicationThe paper presents quasi-static numerical simulations of the behaviour of short reinforced concrete beams without shear reinforcement under mixed shear-tension failure using the FEM and four various constitutive continuum models for concrete. First, an isotropic elasto-plastic model with a Drucker-Prager criterion defined in compression and with a Rankine criterion defined in tension was used. Next, an anisotropic smeared crack...
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Forming Ni-Fe and Co-Fe Bimetallic Structures on SrTiO3-Based SOFC Anode Candidates
PublicationThe aim of this work was to verify the possibility of forming Ni-Fe and Co-Fe alloys via topotactic ion exchange exsolution in Fe-infiltrated (La,Sr,Ce)0.9(Ni,Ti)O3-δ or (La,Sr,Ce)0.9(Co,Ti)O3-δ ceramics. For this purpose, samples were synthesized using the Pechini method and then infiltrated with an iron nitrate solution. The reduction process in dry H2 forced the topotactic ion exchange exsolution, leading to the formation of...
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High temperature oxidation behavior of SUS430 SOFC interconnects with Mn-Co spinel coating in air
PublicationIn this study, SUS430 alloy is evaluated for its high temperature corrosion properties as a possible material for interconnects of solid oxide fuel cells (SOFCs). Samples are coated with Mn-Co by commercial physical vapor deposition (PVD) process and oxidized in air for 1250 h at 800 °C. A dense cubic Mn-Co-Fe spinel layer is formed on the surface, showing great effect on corrosion reduction compared with the samples without coating....
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Efficacious Alkaline Copper Corrosion Inhibition by a Mixed Ligand Copper(II) Complex of 2,2′-Bipyridine and Glycine: Electrochemical and Theoretical Studies
PublicationA mixed ligand copper(II) complex, namely, [Cu(BPy)(Gly)Cl]⋅2H2O (CuC) (BPy=2,2′-bipyridine and Gly=glycine), was synthesized and characterized. The synthesized CuC complex was tested as inhibitor to effectively mitigate the corrosion of copper in alkaline solutions using the linear sweep voltammetry (LSV) and linear polarization resistance (LPR) techniques. For the sake of comparison, such two D.C. electrochemical techniques were...
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EFFECTS OF DOPING ON STRUCTURE AND PHASE TRANSITION OF HIGH TEMPERATURE PROTON CONDUCTOR LaNb1-xMxO4-σ (M=As, Sb, V, Ta AND X=0,05 TO 0,3)
PublicationIn this work synthesis of lanthanum orthoniobate has been done. Doping by arsenic, antimony, vanadium or tantalum in 5% to 30% have been introduced. The relationship between doping type and percentage and structural properties of the material have been investigated.
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Antiferromagnetism and mixed valency in the new Kondo lattice compound Ce3Rh4Sn7
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Delay integro-differential equations of mixed type in Banach spaces
PublicationPraca zawiera warunki dostateczne na istnienie ekstremalnych rozwiązań problemów różniczkowo-całkowych typu opóźnionego z warunkami początkowymi. Powyższe zagadnienia rozważa się w przestrzeniach Banacha. Stosując metodę iteracji monotonicznych dowodzi się istnienie rozwiązania. Pewne nierówności różniczkowo-całkowe są też badane. Praca zawiera przykłady ilustrujące otrzymane wyniki.
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Badanie przewodnictwa jonowego materiału katodowego do ogniw SOFC na bazie La1-xSrxMnO3-δ
PublicationMieszane przewodniki jonowo-elektronowe na bazie domieszkowanego manganianu lantanu znajdują powszechne zastosowanie m.in. jako elektrody w ogniwach paliwowych, czujnikach gazów lub jako warystory. Jednak wciąż niepoznane do końca mechanizmy występowania zjawiska mieszanego przewodnictwa sprawiają, że prace nad tymi materiałami wciąż trwają. Określenie składowej jonowej tego typu materiałów perowskitowych wymaga zastosowania...
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Modeling and simulation of blood flow under the influence of radioactive materials having slip with MHD and nonlinear mixed convection
PublicationRadioactive materials are widely in industry, nuclear plants and medical treatments. Scientists and workers in these fields are mostly exposed to such materials, and adverse effects on blood and temperature profiles are observed. In this regard, objective of the current study is to model and simulate blood based nanofluid with three very important radioactive materials, named as Uranium dioxide (UO2), Thorium dioxide (ThO2) and...
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An experimental investigation on the effect of new continuous core-baffle geometry on the mixed convection heat transfer in shell and coil heat exchanger
PublicationIn the article, the authors presented the influence of continuous core-baffle geometry at mixed convection heat transfer in shell and coil heat exchanger. Experiments were carried out for a large power range, i.e. from 100W to 1200W and mass flow rates ranging from 0.01 kg/s to 0.025 kg/s. During the experiments, the mass flow rate of cooling water, the temperature of water at the inlet and outlet as well as the wall temperature...
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Badania kompozytów na bazie niestechiometrycznego tytanianu strontu -Sr1-xTi0,98Nb0,02O3- jako potencjalnej anody dla SOFC
PublicationW celu uzyskania jak najwyższej przewodności elektrycznej oraz ograniczenia procesu dyfuzji strontu do warstw sąsiadujących wytworzono tytanian strontu domieszkowany niobem z niedoborem strontu do 9% molowych. Następnie materiał ten zastosowano jako składnik przewodzący elektronowo w kompozytach z tlenkiem cyrkonu stabilizowanego tlenkiem itru (YSZ). Kompozyty scharakteryzowano pod względem właściwości istotnych z punktu widzenia...
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The E2 admixtures in mixed forbidden lines of Bi I and Pb I
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Scheduling with precedence constraints: mixed graph coloring in series-parallel graphs.
PublicationW pracy rozważono problem kolorowania grafów mieszanych, opisujący zagadnienie szeregowania zadań, w którym zależności czasowe zadań mają charakter częściowego porządku lub wzajemnego wykluczania. Dla przypadku, w którym graf zależności jest szeregowo-równoległy, podano algorytm rozwiązujący problem optymalnie w czasie $O(n^3.376 * log n)$.
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Mixed conductivity in tungstenite-phosphate glasses containing alkali metal ions
PublicationThe conductivity of glasses in the 50WO3-(50-x)P2O5-xA2O (A = Na, K, Cs) system has been investigated as a function of composition. It is shown that in tungstenite-phosphate glasses containing different alkali metal ions the conductivity decreases with an increase in the alkali metal ion content. A decrease in conductivity is larger for heavier ions and reaches more than seven orders of magnitude in the case of glass containing...
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A diagnosis method of analog parts of mixed-signal systems controlled by microcontrollers.
PublicationPrzedstawiono nową klasę K-D metod diagnostyki analogowych części mieszanych sygnałowo mikrosystemów bazujących na mikrokontrolerach. Metody składają się z trzech etapów: etapu przedtestowego tworzenia słownika uszkodzeń, etapu pomiarowego bazujacego na pomiarach próbek napięcia odpowiedzi układu analogowego na pobudzenie impulsem prostokątnym wykonywanych przez wewnętrzne zasoby mikrokontrolera i z etapu detekcji i lokalizacji...
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Metal complexes with mixed s-donor ligands - a route via silanethiolates
PublicationW ramach prezentowanej pracy przedstawiono pierwsze próby syntezy mieszanych układów zawierających jednocześnie przykoordynowane reszty ditiokarbaminianową oraz silanotiolanowych. W badaniach posłużono się - jako substratami tri-tert-butoksysilanotiolanami kompleksami Cd, Zn, Cu, Pb, Hg, Ag i Co, a także solami kwasów: dietyloditiokarbaminowego oraz pirolidynoditiokarbaminowego. W przypadku związku Ag nie udało się wyizolować stałych...
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Boundary value problems for first order differential equations of mixed type
PublicationPraca dotyczy równań różniczkowo-całkowych z nieliniowymi warunkami brzegowymi. Podano warunki dostateczne na istnienie jedynego rozwiązania oraz rozwiązań ekstremalnych takich problemów. Dyskutowane są nierówności różniczkowo-całkowe. Podano przykłady ilustrujące otrzymane wyniki teoretyczne.
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Reversible transformations from pure to mixed states and the unique measureof information.
PublicationWprowadzono protokół w którym kwantowe stany czyste są w sposób odwracalny przeprowadzane w stany mieszane. W oparciu o analizę protokołu wyprowadzono jednoznaczną miarę informacji. Dokonano porównania z innymi nieodwracalnymi protokółami przeprowadzającymi stany czyste w mieszane.
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Testing method of analog parts for mixed signal microsystems based on microcontrolles.
PublicationZaproponowano nową metodę detekcji i lokalizacji pojedynczych uszkodzeń parametrycznych, która może znaleźć zastosowanie do samo-testowania sieci analogowych w mikrosystemach mieszanych sygnałowo sterowanych mikrokontrolerami. Metoda ta jest oparta na przekształceniu transformującym próbki odpowiedzi czasowej na pobudzenie impulsem prostokątnym na krzywe identyfikacyjne na płaszczyźnie. Metoda pozwala na detekcję i lokalizację...
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Converting mixed plastics into mesoporous hollow carbon spheres with controllable diameter
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Seawater-mixed concretes containing natural and sea sand aggregates – A review
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Selected multiobjective methods for multiperiod portfolio optimization by mixed integer programming
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Survey of multi-objective portfolio optimization by linear and mixed integer programming
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