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Microbial fuel cell applications for removal of petroleum hydrocarbon pollutants: A review
PublicationBioelectrochemical systems (BESs) are considered as the potential approaches to remediate the environments contaminated by hydrocarbons. This review addresses the application of BESs particularly microbial fuel cells (MFCs) in degradation of petroleum hydrocarbons, including BTEXs, from soil, water, wastewater and sediments. Details on reactor design and critical issues are discussed. Aspects on electrodes, redox mediators and...
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ADAPTATION OF THE ACTIVATED SLUDGE TO THE DIGESTATE LIQUORS DURING THE NITRIFICATION AND DENITRIFICATION PROCESSES
PublicationThe activated sludge process of the digestate liquors after chemical separation was conducted using a 10 L lab-scale sequencing batch reactor (SBR) and a 0.50 m3 pilotscale SBR independently (with pH control). Due to the relatively high concentration of free ammonia (FA), clear inhibitory effects of the digestate liquors on the nitrifying bacteria were observed. The adaptation of the activated sludge to the toxicity was evaluated...
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A mechanistic model for fate and removal of estrogens in biological nutrient removal activated sludge systems
PublicationTwo estrogen fate and transformation models were integrated with a comprehensive activated sludge model (ASM) to predict estrogen removal based on biomass and solids production. Model predictions were evaluated against published full-scale plant data as well as results from a laboratory-scale sequencing batch reactor (SBR) fed synthetic wastewater. The estrogen fate model relating the rate of total estrogen degradation to soluble...
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Approximation of Fractional Order Dynamic Systems Using Elman, GRU and LSTM Neural Networks
PublicationIn the paper, authors explore the possibility of using the recurrent neural networks (RNN) - Elman, GRU and LSTM - for an approximation of the solution of the fractional-orders differential equations. The RNN network parameters are estimated via optimisation with the second order L-BFGS algorithm. It is done based on data from four systems: simple first and second fractional order LTI systems, a system of fractional-order point...
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The selective salinity and hydrazine parameters for the start-up of non-anammox-specific biomass SBR
PublicationThe presence of ammonium (NH 4+ ) in wastewater above the permissible limits leads to undesirable ecological impact and public health concerns. In this study, the anaerobic ammonium oxidizing (anammox) bacteria-mediated nitrogen removal was investigated using a sequential batch reactor (SBR). Effects of different salinity levels were evaluated on the bacterial activity at: mild (below 0.2 g NaCl/L), elevated (18.2 g NaCl/L) and...
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Degradation of Rhodamine dyes by Advanced Oxidation Processes (AOPs) – Focus on cavitation and photocatalysis - A critical review
PublicationThis review evaluates selected advanced oxidation processes (AOPs) - cavitation and photocatalysis - successfully used for wastewater treatment towards degradation of Rhodamine (Rh) dyes. Reactor configuration and impact of process parameters and oxidants addition (hydrogen peroxide, ozone, persulfates) on degradation effectiveness along with degradation mechanisms are discussed. Best technologies provide 100% degradation within...
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Static Model of Steam/Water Cycle for Thermal and Economic Analysis
PublicationThe thermodynamic efficiency of typical conventional and nuclear power plants is insufficient. A large amount of the generated heat is removed to the environment and regarded as a waste. A solution which is commonly used to increase the efficiency and profitability of the existing and planned power plants refers to cogeneration of heat and power. To prepare sophisticated thermodynamic and economic analyses, a precise static model...
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Inhibition of the granular anammox process by the high concentration of free ammonia.
PublicationHigh concentrations of ammonia and nitrite, typical for reject water treatment in the anammox process with the use of high temperatures and pH, may cause free ammonia (FA) inhibition. In this study, the inhibitory effect of FA on anammox process rate was investigated in a bench-scale sequencing batch reactor (SBR) with granular anammox biomass. Results of the study present that the anammox process could be successfully operated...
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Designing control strategies of aeration system in biological WWTP
PublicationThe paper presents the complete design processes of a novel aeration control systems in the SBR (Sequencing Batch Reactor) wastewater treatment plant (WWTP). Due to large energy expense and high influence on biological processes, the aeration system plays a key role in WWTP operation. The paper considers the aeration system for a biological WWTP located in the northeast of Poland. This system consists of blowers, the main collector...
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Activated Carbon Produced by Pyrolysis of Waste Wood and Straw for PotentialWastewater Adsorption
PublicationPyrolysis of straw pellets and wood strips was performed in a fixed bed reactor. The chars, solid products of thermal degradation, were used as potential materials for activated carbon production. Chemical and physical activation processes were used to compare properties of the products. The chemical activation agent KOH was chosen and the physical activation was conducted with steam and carbon dioxide as oxidising gases. The eect...
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Real-Time Basic Principles Nuclear Reactor Simulator Based on Client-Server Network Architecture with WebBrowser as User Interface
PublicationThe real-time simulator of nuclear reactor basic processes (neutron kinetics, heat generation and its exchange, poisoning and burn- ing up fuel) build in a network environment is presented in this paper. The client-server architecture was introduced, where the server is a pow- erful computing unit and the web browser application is a client for user interface purposes. The challenge was to develop an application running under the...
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Modeling bioaugmentation with nitrifiers in membrane bioreactors
PublicationBioaugmentation with nitrifiers was studied using two pilot-scale membrane bioreactors, with the purpose of assessing the suitability of state-of-the-art activated sludge models (ASMs) in predicting the efficiency of bioaugmentation as a function of operating conditions. It was demonstrated that the temperature difference between seeding and seeded reactors (ΔT) affects bioaugmentation efficiency. Experimental data were accurately...
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A hierarchical observer for a non-linear uncertain CSTR model of biochemical processes
PublicationThe problem of estimation of unmeasured state variables and unknown reaction kinetic functions for selected biochemical processes modelled as a continuous stirred tank reactor is addressed in this paper. In particular, a new hierarchical (sequential) state observer is derived to generate stable and robust estimates of the state variables and kinetic functions. The developed hierarchical observer uses an adjusted asymptotic observer...
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Pyrolysis Process of Whole Waste Tires as a Biomass Energy Recycling
PublicationThe article is devoted to the description of material recycling of whole waste tires, including a new method of pyrolysis process, resulting in the final products: technically oil fractions (rubber plasticizer of rubber compounds) or diesel fuels (light, medium and heavy), activated carbon, gas fuel and steel scrap. Operational and performance tests of the first version of the pilot plant, consisting of three contributions cooperating...
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Wieloobszarowa rozmyta regulacja PIλDμ mocy reaktora jądrowego
PublicationW artykule przedstawiono wieloobszarowy regulator rozmyty z lokalnymi regulatorami PIλDμ niecałkowitego rzedu. Regulator ten został zaprojektowany do sterowania mocą reaktora jądrowego typu PWR (Pressurized Water Reactor). Do syntezy wieloobszarowego regulatora PIDμ wykorzystano model matematyczny reaktora PWR o parametrach skupionych obejmujący procesy generacji i wymiany ciepła oraz efektów reaktywnościowych. Nastawy lokalnych...
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Effect of some organic solvent - water mixtures composion on precipitated calcium carbonate in carbonation process
PublicationPrecipitated calcium carbonate particles were obtained during carbonation of calcium hydroxide slurry with carbon dioxide. Aqueous solutions of isopropyl alcohol, n-butanol and glycerol were used as solvents. Concentration of organic additives in the reactive mixture was from 0 to 20 % (vol.). Precipitation process were performed in a stirred tank reactor equipped with gas distributor. Multimodal courses of particles size distribution...
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Wieloobszarowa rozmyta regulacja PIλDµ mocy reaktora jądrowego
PublicationWartykule przedstawiono wieloobszarowy regulator rozmyty z lokalnymi regulatorami PIλDµ niecałkowitego rzędu. Regulator ten ostał zaprojektowany do sterowania mocą reaktora jądrowego typu PWR (Pressurized Water Reactor). Do syntezy wieloobszarowego regulatora PIλDµ wykorzystano model matematyczny reaktora PWR o parametrach skupionych obejmujący procesy generacji i wymiany ciepła oraz efektów reaktywnościowych. Nastawy lokalnych...
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Photocatalytic Decomposition of Air Pollutants using Electrodeposited Photocatalysts on Stainless Steel
PublicationThe aim of research was to develop an immobilization method for photocatalysts, which is an alternative to the sol-gel or dip coating methods and can be simply scaled up for technical applications. The investigated photocatalyst was TiO2, which was electrochemically deposited onto a cathode made of stainless steel. This deposited film was photocatalytically active. In order to enhance the photoactivity of the TiO2 film, commercially...
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Waste Rubber Pyrolysis: Product Yields and Limonene Concentration
PublicationTires, conveyor belts, floor mats, and shoe soles form a main-stream of rubber waste. The amount of these used materials continuously increases due to development of the rubber market. Therefore, pro-ecological utilization (i.e., energy recycling instead of burning) and recovering valuable and recyclable materials becomes an urgent necessity. In this regard, this work was devoted to the chemical recycling of selected used rubber...
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Pyrolysis of RDF and Catalytic Decomposition of the Produced Tar in a Char Bed Secondary Reactor as an Efficient Source of Syngas
PublicationOne of the technical limitations of refuse-derived fuel (RDF) pyrolysis is the high content of tar in its gas products. In order to resolve this problem, a two-stage RDF pyrolysis with a catalyst based on char from RDF pyrolysis is proposed. This paper presents the results of municipal waste pyrolysis beginning in an oven heated to 480 °C and ending with catalytic tar cracking carried out in the temperature range from 800 to 1000...
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An analysis of observability and detectability for different sets of measured outputs - CSTR case study
PublicationA problem of proving the observability/detectability at a given measured output for non-linear biochemical systems has been addressed in this paper. A theory of indistinguishable state trajectories has been used to prove the properties of the observability or detectability of this system. It is related to taking system dynamics into consideration depending on initial conditions and the impact of inputs taking into account a given...
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Analiza sterowania ułamkowego PIλDμ mocą reaktora jądrowego
PublicationW artykule przedstawiono syntezę regulatora PIλDμ niecałkowitego rzędu dla potrzeb sterowania mocą reaktora jądrowego lekko wodnego określanego, jako typu PWR (Pressurized Water Reactor). W tym celu wykorzystano nieliniowy model matematyczny reaktora PWR o parametrach skupionych obejmujący procesy generacji i wymiany ciepła oraz termicznych efektów reaktywnościowych. Nastawy regulatora PIλDμ niecałkowitego rzędu dobrano w sposób...
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Removal of Pharmaceutically Active Compounds in Sequencing Batch Reactor
PublicationIn recent years, considerable attention was paid to the presence of organic micro-pollutants such as Active Pharmaceutical Ingredients (API) in the aquatic environment due to their negative impact on public health and aquatic ecosystems. Numerous papers have pointed out API presence as common constituents of effluents from Wastewater Treatment Plants (WWTPs). This is the result of various efficiencies of API removal by conventional...
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Production of hydrogen from biomass and its separation using membranetechnology
PublicationHydrogen is an important raw material for chemical industry and feasible renewable energy carrier that could replace fossil fuels. However, the specie seldom exists in a form of pure H2. Therefore, to obtain hydrogen in volumes suitable to be used as a raw material it is necesary to decompose hydrogen-rich compounds. The carbohydrate-rich biomass can be an important source of hydrogen by applying the process of dark fermentation....
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Assessment of wastewater quality indicators for wastewater treatment influent using an advanced logistic regression model
PublicationInfluent quality indicators play a significant role in wastewater treatment plant performance due to their correlation with reactor operations and effluent quality. However, selecting a specific/best parameter indicator for predicting influent wastewater quality is one of the challenges in wastewa- ter treatment. This study, therefore, focused on determining suitable variables as influent quality indicators. For this purpose, a...
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A comprehensive approach to SBR modelling for monitoring and control system design
PublicationThe aim of this research is to provide a comprehensive description of the Sequencing Batch Reactor (SBR) modelling for monitoring, control, and plant operational optimisation validation. The paper provides a detailed modelling of the SBR, its components and constituent processes. For this purpose, the mass balance principle and continuity equations were provided with a reactive term implemented using Activated Sludge Model (ASM)....
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A robust sliding mode observer for non-linear uncertain biochemical systems
PublicationA problem of state estimation for a certain class of non-linear uncertain systems has been addressed in this paper. In particular, a sliding mode observer has been derived to produce robust and stable estimates of the state variables. The stability and robustness of the proposed sliding mode observer have been investigated under parametric and unstructured uncertainty in the system dynamics. In order to ensure an unambiguous non-linear...
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Improving SBR Performance Alongside with Cost Reduction through Optimizing Biological Processes and Dissolved Oxygen Concentration Trajectory
PublicationAuthors of this paper take under investigation the optimization of biological processes during the wastewater treatment in sequencing batch reactor (SBR) plant. A designed optimizing supervisory controller generates the dissolved oxygen (DO) trajectory for the lower level parts of the hierarchical control system. Proper adjustment of this element has an essential impact on the efficiency of the wastewater treatment process as well...
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Effect of operating conditions on N 2 O production in an anammox sequencing batch reactor containing granular sludge
PublicationNitrous oxide (N2O) is one of the gases with the greatest impact in the atmosphere due to its persistence and significant contribution to the greenhouse effect. This study provides an insight into the dynamics of N2O production in wastewater nitrogen removal systems. A 10 L sequencing batch reactor containing enriched anammox biomass was subjected to different operational conditions, i.e., temperature, feed time, NO2 /NH4 þ ratio...
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Neural modelling of dynamic systems with time delays based on an adjusted NEAT algorithm
PublicationA problem related to the development of an algorithm designed to find an architecture of artificial neural network used for black-box modelling of dynamic systems with time delays has been addressed in this paper. The proposed algorithm is based on a well-known NeuroEvolution of Augmenting Topologies (NEAT) algorithm. The NEAT algorithm has been adjusted by allowing additional connections within an artificial neural network and...
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Symulator szybkich procesów dynamiki reaktora jądrowego wodno ciśnieniowego
PublicationArtykuł przedstawia symulator dynamiki reaktora jądrowego (RJ) zbudowany w oparciu o punktowe modele matematyczne procesów reaktora typu wodnego ciśnieniowego (ang. Pressurized Water Reactor – PWR) i zaimplementowany w środowisku MATLAB/Simulink. Symulator wykorzystywany jest obecnie jako narzędzie pomocne w dydaktyce i wstępnych badaniach w zakresie energetyki jądrowej na Politechnice Gdańskiej. W pierwszej części artykuł Autorzy...
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Comparison of state feedback and PID control of pressurizer water level in nuclear power plant
PublicationThe pressurizer water level control system in nuclear power plant with pressurized water reactor (PWR) is responsible for coolant mass balance. The main control goal is to stabilize the water level at a reference value and to suppress the effect of time-varying disturbances (e.g. coolant leakage in primary circuit pipeline system). In the process of PWR power plant operation incorrect water level may disturb pressure control or...
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Cross-Platform Real-Time Nuclear Reactor Basic Principle Simulator
PublicationAbstract—In the paper several approaches to building the real-time basic principle simulators of nuclear reactor processes are presented and their characteristics are analyzed. The characteristics of developed simulators for MATLAB/Simulink including their limitations, and the idea of a cross-platform simulator independent of specific hardware or software are presented. Mathematical models of selected nuclear reactor’s processes...
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A Model-Based Improved Control of Dissolved Oxygen Concentration in Sequencing Wastewater Batch Reactor
PublicationBiochemical processes at wastewater treatment plant are complex, nonlinear, time varying and multivariable. Moreover, relationships between processes are very strong. One of the most important issues is exerting proper control over dissolved oxygen levels during nitrification phase. This parameter has a very large impact on activity of microorganisms in activated sludge and on quality of pollution removal processes. Oxygen is supplied...
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An observability and detectability analysis for non-linear uncertain CSTR model of biochemical processes
PublicationThe problem of proving observability/detectability properties for selected non-linear uncertain model of biochemical processes has been addressed in this paper. In particular, the analysis of observability/detectability in the face of parametric and unstructured uncertainty in system dynamics transformed into unknown inputs, and unknown initial conditions has been performed. Various sets of system measured outputs were taken into...
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Adaptive stochastic and hybrid nonlinear optimization algorithms for improving the effectiveness of the biological processes at WWTP
PublicationWastewater treatment plays an important factor in the modern world. Insufficient treatment may result in environmental pollution which can further lead to disasters and diseases. However, processes that take place inside wastewater treatment plants (WWTP) are highly complex in nature, therefore it is difficult to design an efficient, optimal control system. The problem regarding biochemical reactions inside Sequential Batch Reactor...
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Evaluation and start-up of an electro-Fenton-sequencing batch reactor for dairy wastewater treatment
PublicationThis study examined the performance of an integrated wastewater (WW) treatment system, namely an electro-Fenton (EF)-sequencing batch reactor (SBR), for dairy industry WW. The EF process was used as the first stage of the SBR. It degrades bio-refractory compounds via advanced oxidation processes, thereby resulting in the formation of simple biodegradable intermediates. Several factors, including the hydraulic retention time (HRT),...
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Studies on the utilization of post-distillation liquid from Solvay process to carbon dioxide capture and storage
PublicationIn this work, a method of precipitated calcium carbonate production from the post-distillation liquid created in the Solvay process and waste carbon dioxide was proposed and investigated. Precipitation was carried out in a model solution of calcium chloride containing ammonia at various molar ratios in relation to Ca2+ ions, while gaseous carbon dioxide was supplied to the reactor as a pure gas or as a mixture with air. It was...
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Recent advances in hydrodynamic cavitation-based pretreatments of lignocellulosic biomass for valorization
PublicationRecently, the hydrodynamic cavitation (HC)-based pretreatment has shown high effectiveness in laboratories and even in industrial productions for conversion of lignocellulosic biomass (LCB) into value-added products. The pretreatment capability derives from the extraordinary conditions of pressures at ∼500 bar, local hotspots with ∼5000 K, and oxidation (hydroxyl radicals) created by HC at room conditions. To promote this emerging...
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Recurrent Neural Network Based Adaptive Variable-Order Fractional PID Controller for Small Modular Reactor Thermal Power Control
PublicationThis paper presents the synthesis of an adaptive PID type controller in which the variable-order fractional operators are used. Due to the implementation difficulties of fractional order operators, both with a fixed and variable order, on digital control platforms caused by the requirement of infinite memory resources, the fractional operators that are part of the discussed controller were approximated by recurrent neural networks...
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Two-Step Model Based Adaptive Controller for Dissolved Oxygen Control in Sequencing Wastewater Batch Reactor
PublicationDissolved Oxygen (DO) concentration is a crucial parameter for efficient operation of biological processes taking place in the activated sludge Wastewater Treatment Plant (WWTP). High-quality DO control is difficult to achieve because of complex nonlinear behavior of the plant and substantial influent disturbances. A method to improve the Direct Model Reference Adaptive Control (DMRAC) technology in application to DO tracking for...
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Comparison analysis of selected nuclear power plants supplied with helium from high-temperature gas-cooled reactor
PublicationThe article presents results of efficiency calculations for two 560 MW nuclear cycles with high-temperature gas-cooled reactor (HTGR). An assumption was made that systems of this type can be used in so-called marine nuclear power plants. The first analysed system is the nuclear steam power plant. For the steam cycle, the efficiency calculations were performed with the code DIAGAR, which is dedicated for analysing this type of systems....
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Hydrogen production from biomass using dark fermentation
PublicationHydrogen applicability in the power, chemical and petrochemical industries is constantly growing. Efficientmethods of hydrogen generation from renewable sources, including waste products, are currently being de-veloped, even though hydrogen is mainly produced through steam reforming or thermal cracking of natural gasor petroleum fractions. In paper alternative methods of hydrogen production with a particular emphasis on darkfermentation...
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Current harmonic controller in multiple reference frames for series active power filter integrated with 18-pulse diode rectifier
PublicationThe paper presents the control system and selected results of experimental tests of the AC/DC power converter consisting of an 18-pulse diode rectifier based on coupled reactors and a serial active power filter. Proportional integral controllers with decoupling components are implemented in multiple reference frames for selective line current harmonic suppression. The regulator is provided with a backtracking anti-windup mechanism...
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Activation of peroxymonosulfate using carbon black nano-spheres/calcium alginate hydrogel matrix for degradation of acetaminophen: Fe3O4 co-immobilization and microbial community response
PublicationHerein, we focused on the degradation of acetaminophen (ACT) drug in liquid phase by peroxymonosulfate (PMS) activated by carbon black nano-spheres (CBNS). The nanostructured activator was immobilized into calcium alginate hydrogel matrix (CAHM) to avoid the washout of the fine nanostructures. The Langmuir modeling showed an insignificant contribution to the adsorption process in the removal of ACT. The basic pH conditions favored...
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Model-Based Evaluation of N2O Production Pathways in the Anammox-Enriched Granular Sludge Cultivated in a Sequencing Batch Reactor
PublicationA mechanistic model was developed as an extension of the Activated Sludge Model No. 1 to describe three nitrous oxide (N2O) production pathways in a laboratory-scale anammox-enriched granular sequencing batch reactor. Heterotrophic denitrification and two processes mediated by ammonia oxidizing bacteria (AOB), that is, ammonia (NH4+) oxidation via hydroxylamine (NH2OH) and autotrophic denitrification, were considered. A systematic...
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An automatic selection of optimal recurrent neural network architecture for processes dynamics modelling purposes
PublicationA problem related to the development of algorithms designed to find the structure of artificial neural network used for behavioural (black-box) modelling of selected dynamic processes has been addressed in this paper. The research has included four original proposals of algorithms dedicated to neural network architecture search. Algorithms have been based on well-known optimisation techniques such as evolutionary algorithms and...
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Negative carbon dioxide gas power plant integrated with gasification of sewage sludge
PublicationOne of the primary objectives of the negative carbon dioxide gas power plant (nCO2PP) is to develop an innovative technology confirming the possibility of the use of sewage sludge to produce electricity while having a positive impact on the environment. In this paper, a mathematical model is presented to estimate thermodynamic parameters of the system in relation to the gasification process and changes in such parameters in the...
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Novel hierarchical nonlinear control algorithm to improve dissolved oxygen control in biological WWTP
PublicationWastewater treatment is a problem known to humankind for centuries. The quality of treated sewage determines the condition of reservoirs around the world. Control of such a complex and nonlinear system as a wastewater treatment plant requires thorough knowledge of the process. The paper presents a hierarchical control system of a Sequencing Batch Reactor (SBR) in Wastewater Treatment Plant (WWTP) taking into account a model based...
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Ammonia amendment promotes high rate lactate production and recovery from semi-continuous food waste fermentation
PublicationIn this study, a reliable approach using ammonia nitrogen was proposed to increase lactate production during semi-continuous food waste (FW) fermentation under mesophilic conditions. Both free ammonia nitrogen (FAN) and ammonium ion (NH4+-N) were present in mesophilic reactors, with a wide FAN/NH4+-N ratio variation due to the intermittent pH control. The investigation of responsible mechanisms revealed that the increased production...