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Search results for: Supercapacitors
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MEASUREMENT OF NOISE IN SUPERCAPACITORS
PublicationA developed method and measurement setup for measurement of noise generated in a supercapacitor is presented. The requirements for noise data recording are considered and correlated with working modes of supercapacitors. An example of results of low-frequency noise measurements in commercially available supercapacitors are presented. The ability of flicker noise measurements suggests that they can be used to assess quality of tested supercapacitors.
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Model of noise sources in supercapacitors
PublicationThe paper presents detailed model of noise sources in supercapacitors. Noise phenomena observed in supercapacitors may be used as a diagnostic tool for assessment of supercapacitor quality or degradation mechanisms (e.g. corrosion of the electrodes or cloggin g up the pores) during ageing. Therefore, it is important to consider where noise is generated. The equivalent circuit of noise sources existing...
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Supercapacitors - charge redistribution and restoring voltage
PublicationThe charge in supercapacitor is stored on electrodes and in electrolyte. The charges on electrodes create the Helmholtz double layer which is formed immediately with time constant of the order of seconds, while the charge storage in electrolyte is going on with time constant of the order of hundreds seconds. When the charged supercapacitor is shorted for few seconds, the charge from electrodes is discharged while the charge in...
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GRAPHENE-BASED SUPERCAPACITORS APPLICATION FOR ENERGY STORAGE
PublicationRecent advances in graphene-based supercapacitor technology for energy storage application were summarized. The comparison of different types of electrode materials in such supercapacitors was performed. The supercapacitors with graphene-based electrodes exhibit outstanding performance: high charge-discharge rate, high power density, high energy density and long cycle-life, what makes them suitable for various applications, e.g....
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Temperature distribution of supercapacitors prepared by various technologies
PublicationSupercapacitors, also known by different names such as electrostatic double-layer capacitors (EDLCs) or ultra-capacitors, are electrical storage devices still in development. These devices require fast and reliable methods of assessing their state-of-health. Thermographic imaging is a method which can be applied with this aim due to its popularity, and the high negative impact of overheating on a supercapacitor’s parameters. Moreover,...
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Low cost set-up for supercapacitors parameters evaluation
PublicationSupercapacitors are capable to store relatively high amount of energy comparing to its mass. Growing number of these devices applications requires development of new testing methods. Standard methods of evaluation of supercapacitor parameters, as cycling voltammetry, CV, galvanostatic cycling with potential limitation, GCPL, impedance measurements, require equipment of high cost...
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Low cost set-up for supercapacitors parameters evaluation
PublicationWe propose a use of a power amplifier in the circuit of voltage to current converter (current driver) for supercapacitor charging/discharging in controlled conditions. The current driver is controlled by DAC output of DAQ board and voltage of DUT is measured and a control loop is realized by software. In the circuit the DC current method of evaluation of capacitance and equivalent series...
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Effects of mechanical stress on electrical arameters and noise of supercapacitors
PublicationResults of noise and electrical parameters measurements of prototype electrochemical double layer capacitors (EDLC) are reported at the presence of selected mechanical stress. This issue is of great importance due to future applications in wearable technology. The measurement results are compared, and we may conclude than flicker noise is more sensitive to any stress than other considered electrical parameters.
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Starch as a Green Binder for the Formulation of Conducting Glue in Supercapacitors
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CVD generated mesoporous hollow carbon spheres as supercapacitors
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Methods of Assessing Degradation of Supercapacitors by Using Various Measurement Techniques
PublicationThis article presents the qualitative analyses of the construction of supercapacitor samples. The analyses are based on the suggested thermographic measurements as well as the technique of testing the inherent noise of the investigated element. The indicated assessment methods have been referred to the currently used parameters for the qualitative evaluation of supercapacitors. The approach described in this paper, which introduces...
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N-doped carbon materials as electrodes for highly stable supercapacitors
PublicationThis article reports a strategy to use nitrogen-doped carbon materials as electrodes for supercapacitors. Depending on the carbon precursor, the porous structure is changed with specific surface area reached up to 2270 m2 g−1. The capacitance of carbon materials used as electrodes is related strictly to pore size. The microstructure and nitrogen functionalities enable a high capacitance (327 F g−1) and cycle durability. The nanoporous...
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Hybrid storage management system consisting of supercapacitors and AHI batteries
PublicationIn the article the hybrid storage, composed of Aqueous Hybrid Ion battery and supercapacitor was presented. The system was tested through simulation studies. The work also describes the construction and properties of the developed device meant to control the energy flow of the storage and a communication system for remote parameter supervision.
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Recent Progress in Polymer Waste-Derived Porous Carbon for Supercapacitors
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Ag(e)ing and Degradation of Supercapacitors: Causes, Mechanisms, Models and Countermeasures
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Effect of iron oxide impregnated in hollow carbon sphere as symmetric supercapacitors
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Template method synthesis of mesoporous carbon spheres and its applications as supercapacitors
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Supercapacitors in stand-alone pv systems with instantaneus high output energy pulses
PublicationSuperkondensatory (ang. supercapacitors, ultracapacitors, double-layer capacitors, gold capacitors and power capacitors) stanowią stosunkową nowość w energetyce prądu stałego, zwłaszcza w dziedzinie magazynowania i oddawania energii. Podjęto próby zastosowania superkondensatorów jako jedynego lub wspierającego źródła, służącego do gromadzenia energii PV w autonomicznych instalacjach. Opracowany we własnym zakresie, wykonany i opisany...
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Eucalyptus derived heteroatom-doped hierarchical porous carbons as electrode materials in supercapacitors
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Insight into the Effect of ZIF‐8 Particle Size on the Performance in Nanocarbon‐Based Supercapacitors
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Transforming polystyrene waste into 3D hierarchically porous carbon for high-performance supercapacitors
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An Easy and Ecological Method of Obtaining Hydrated and Non-Crystalline WO3−x for Application in Supercapacitors
PublicationIn this work, we report the synthesis of hydrated and non-crystalline WO3 flakes (WO3−x) via an environmentally friendly and facile water-based strategy. This method is described, in the literature, as exfoliation, however, based on the results obtained, we cannot say unequivocally that we have obtained an exfoliated material. Nevertheless, the proposed modification procedure clearly affects the morphology of WO3 and leads to loss...
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Waste-based nanoarchitectonics with face masks as valuable starting material for high-performance supercapacitors
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Biomass-derived robust three-dimensional porous carbon for high volumetric performance supercapacitors
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Sustainable polylysine conversion to nitrogen‐containing porous carbon flakes: Potential application in supercapacitors
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Novel strategy for preparation of highly porous carbon sheets derived from polystyrene for supercapacitors
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Sustainable recycling of waste polystyrene into hierarchical porous carbon nanosheets with potential applications in supercapacitors
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Fabrication and characterization of composite TiO2 nanotubes/ boron-doped diamond electrodes towards enhanced supercapacitors
PublicationThe composite TiO2 nanotubes / boron-doped diamond electrodes were deposited using Microwave Plasma Enhanced Chemical Vapor Deposition resulting in the improved electrochemical performance. This composite electrode can deliver high specific capacitance of 7.46 mF cm‐− 2 comparing to boron-doped diamond (BDD) deposited onto flat Ti plate (0.11 mF cm‐− 2).The morphology and composition of composite electrode were characterized...
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Combined effect of nitrogen-doped functional groups and porosity of porous carbons on electrochemical performance of supercapacitors
PublicationIn this work, nitrogen-doped porous carbons obtained from chitosan, gelatine, and green algae were investigated in their role as supercapacitor electrodes. The effects of three factors on electrochemical performance have been studied— of the specific surface area, functional groups, and a porous structure. Varying nitrogen contents (from 5.46 to 10.08 wt.%) and specific surface areas (from 532 to 1095 m2g−1) were obtained by modifying...
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Silica nanospheres as a key process element in the Green engineering for the synthesis of carbon nanotubes as a supercapacitors additives
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Electrochemical Characteristics of Discrete, Uniform, and Monodispersed Hollow Mesoporous Carbon Spheres in Double‐Layered Supercapacitors
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Symmetric Supercapacitors Based on MnOOH‐Coated Nanoporous Carbon toward High Energy‐Storage Performance
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One-step converting biowaste wolfberry fruits into hierarchical porous carbon and its application for high-performance supercapacitors
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Nitrogen/Oxygen Enriched Hierarchical Porous Carbons Derived from Waste Peanut Shells Boosting Performance of Supercapacitors
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Electrochemical studies of symmetrical supercapacitors based on BDD, Mn-BDD, Mn-BDD(AN) electrodes
Open Research DataElectrochemical performance of a Supercapacitor device in PVA-H2SO4 gelled electrolyte: Cyclic voltammograms at varying scan rates ranging from 10 to 1000 mV s−1, galvanostatic charge-discharge curves with varying current density, cyclic stability (88000 charge-discharge cycles).
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Improving the Performance of a Graphite Foil/Polyaniline Electrode Material by a Thin PEDOT:PSS Layer for Application in Flexible, High Power Supercapacitors
PublicationIn this study, we present a novel strategy for enhancing polyaniline stability and thus obtaining an electrode material with practical application in supercapacitors. A promising (graphite foil/polyaniline/poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) GF/PANI/PEDOT:PSS) electrode material was characterized and used in the construction of a symmetric supercapacitor that provides an outstanding high power density. For this...
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Enhanced Charge Storage Mechanism And Long-Term Cycling Stability In Diamondized Titania Nanocomposite Supercapacitors Operating In Aqueous Electrolytes
PublicationThe long cycle life stability jointly with high energy density are limiting broader feasible applications of supercapacitors. The novel diamondized titania nanocomposite supercapacitors deliver high power and energy densities along with high capacitance retention rates. Supercapacitor electrodes were fabricated utilizing a combination of Ti anodization followed by chemical vapor deposition resulting in simultaneous growth of complex...
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Phosphorus, nitrogen and oxygen co-doped polymer-based core-shell carbon sphere for high-performance hybrid supercapacitors
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Mass production of hierarchically porous carbon nanosheets by carbonizing “real-world” mixed waste plastics toward excellent-performance supercapacitors
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Nanosized Carbon Black Combined with Ni2O3 as “Universal” Catalysts for Synergistically Catalyzing Carbonization of Polyolefin Wastes to Synthesize Carbon Nanotubes and Application for Supercapacitors
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One-Step Synergistic Effect to Produce Two-Dimensional N-Doped Hierarchical Porous Carbon Nanosheets for High-Performance Flexible Supercapacitors
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Diamond-Based Supercapacitors with Ultrahigh Cyclic Stability Through Dual-Phase MnO2-Graphitic Transformation Induced by High-Dose Mn-Ion Implantation
PublicationWhile occasionally being able to charge and dischargemore quickly than batteries, carbon-based electrochemical supercapacitors(SCs) are nevertheless limited by their simplicity of processing, adjustableporosity, and lack of electrocatalytic active sites for a range of redox reactions.Even SCs based on the most stable form of carbon (sp3carbon/diamond)have a poor energy density and inadequate capacitance retention during longcharge/discharge...
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Intumescent flame retardants inspired template-assistant synthesis of N/P dual-doped three-dimensional porous carbons for high-performance supercapacitors
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Na3PO4 assistant dispersion of nano-CaCO3 template to enhance electrochemical interface: N/O/P co-doped porous carbon hybrids towards high-performance flexible supercapacitors
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Anna Danuta Dettlaff dr inż.
PeopleShe received her Master of Science degree in engineering with honours in 2013 at the Gdańsk University of Technology at the Department of Analytical Chemistry. In 2013-2017, she was a PhD student in the field of Chemical Technology at Faculty of Chemistry. Her doctoral dissertation was entitled “Nanocomposites based on conducting polymer and carbon materials for supercapacitor application”. In 2015, she was doing a three-month...
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Microsphere structure application for supercapacitor in situ temperature monitoring
PublicationConstant, real-time temperature monitoring of the supercapacitors for efficient energy usage is in high demand and seems to be crucial for further development of those elements. A fiber-optic sensor can be an effective optoelectronic device dedicated for in-situ temperature monitoring of supercapacitors. In this work, the application of the fiber-optic microstrucutre with thin zinc oxide (ZnO) coating fabricated in the atomic layer...
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A dual-control strategy based on electrode material and electrolyte optimization to construct an asymmetric supercapacitor with high energy density
PublicationMetal-organic frames (MOFs) are regarded as excellent candidates for supercapacitors that have attracted much attention because of their diversity, adjustability and porosity. However, both poor structural stability in aqueous alkaline electrolytes and the low electrical conductivity of MOF materials constrain their practical implementation in supercapacitors. In this study, bimetallic CoNi-MOF were synthesized to enhance the electrical...
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Assessment of Supercapacitor’s Quality by Means of Low Frequency Noise
PublicationLow frequency noise is a well-known tool for quality and reliability assessment of electronic devices. This phenomenon is observed in different electrochemical devices as well (e.g., smart windows, electrochemical corrosion processes). Thus, we can assume that the same tool can be used to asses quality of supercapacitors. Their quality is usually determined only by capacitance and/or equivalent series resistance (ESR), or impedance....
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The phenomenon of increasing capacitance induced by 1T/2H-MoS2 surface modification with Pt particles – Influence on composition and energy storage mechanism
PublicationIn this paper, several approaches to the synthesis of molybdenum-based electrode materials for supercapacitors are presented, including anodization, hydrothermal process and annealing. For the material prepared via anodization of a molybdenum plate, followed by a hydrothermal process in thiourea aqueous solution, a thorough study of the Pt-surface modification through repetitive cycling in 1 M sulfuric acid with Pt acting as a...
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Nano-engineered diamond-based materials for supercapacitor electrodes: A review
PublicationOwing to the popularity of carbon-based supercapacitors, diamond has also been examined as a potential candidate with unique advantages such as a wide electrochemical potential window and stable capacitive behavior in both aqueous and non-aqueous electrolytes. Moreover, its chemical stability in harsh environments at extreme applied potential and current provides rare opportunities for designing new supercapacitors. Owing to the...