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Search results for: MH HYDRIDE ELECTRODE
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Ultrasensitive electrochemical determination of the cancer biomarker protein sPD-L1 based on a BMS-8-modified gold electrode
PublicationThis work describes the modification of a gold electrode with the BMS-8 compound that interacts with the Programmed Death-Ligand 1 (PD-L1), an immune checkpoint protein. The results show that we can confirm the presence of the sPD-L1 in the concentration range of 10−18 to 10−8 M using electrochemical impedance spectroscopy (EIS) with a limit of detection (LOD) of 1.87 × 10−14 M for PD-L1 (S/N = 3.3) and at a concentration of 10−14...
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Influence of electrode size on a Jacobian properties.
PublicationW pracy oceniono wpływ geometrii elektrod na jakość obrazowania za pomocą TEI. W tym celu określono zależność pomiędzy uwarunkowaniem Jakobianu a geometrycznymi rozmiarami zastosowanych elektrod.
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Determination of pseudocapacitance chan ges of nickel oxide NiO electrode with use of dynamic electrochemical impedancje spectroscopy
PublicationThe electrochemical capacitors (ECs) are attractive energy storage devices which can be applied in many electronic products (e.g., cameras, laptops, cell phones) or hybrid electric vehicles (HEV). The energy storage in ECs is based on capacitive (the electrical double layer charging/discharging) and pseudocapacitive (additional charge provided by faradic reaction) phenomena. Considering the electrodes exhibiting pseudocapacitance,...
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Weldability of Underwater Wet-Welded HSLA Steel: Effects of Electrode Hydrophobic Coatings
PublicationThe paper presents the effects of waterproof coatings use to cover electrodes on the weldability of high-strength, low-alloy (HSLA) steel in water. With the aim of improving the weldability of S460N HSLA steel in water, modifications of welding filler material were chosen. The surfaces of electrodes were covered by different hydrophobic substances. The aim of the controlled thermal severity (CTS) test was to check the influence...
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Nanoporous TiO2 electrode grown by laser ablation of titanium in air at atmospheric pressure and room temperature
PublicationRecently, fabrication of the nanoporous TiO2 photoelectrode on metal foils by means of sputtering of the Ti film on preheatedmetal substrate followed by the TiO2 deposition (doctor blade technique) and sintering represents the frequently applied technique. This is despite the relatively complicated procedure and number of parameters to be controlled in order to fabricate films of required properties. In this work an approach is...
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The Influence of Iron Doping on Performance of SrTi1-XFexO3-δ Perovskite Oxygen Electrode for SOFC
PublicationSolid Oxide Fuel Cells (SOFC) are based on electrolytes and mixed ionic and electronic conductivity (MIEC) materials. The need to reduce costs causes an increase in interest of new compounds suitable for operating temperatures between 600 °C and 800 °C. The SrTi1-xFexO3 (STF) perovskite material is a perspective material that could be used for the oxygen electrodes. In this work STF materials with different content of iron (x =...
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Recent achievements in chemical hydride generation inductively coupled and microwave induced plasmas with optical emission spectrometry detection
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Flexible dye-sensitized solar cells based on Ti/TiO2 nanotubes photoanode and Pt-free and TCO-free counter electrode system
PublicationFlexible dye-sensitized solar cells (DSSCs) are getting more attention compared to standard glass covered DSSCs due to their unique commercial applications (e.g. tents or sail surfaces) and the possibility of rolling up into a small, portable device. In this work, titania nanotubes (TiO2 NT) modified with titania nanoparticles (TiO2 NP) were photoelectrochemically characterized as an anode for flexible dye-sensitized solar cells....
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Three-component NiO/Fe3O4/rGO nanostructure as an electrode material towards supercapacitor and alcohol electrooxidation
PublicationA nanocomposite made of nickel oxide and iron oxide (NiO/Fe3O4) and its hybrid with reduced graphene oxide (rGO) as a conductive substrate with a highly functional surface (NiO/Fe3O4/rGO) was synthesized using a simple hydrothermal approach. This study addresses the challenge of developing efficient materials for energy storage and alcohol fuel cells. After confirming the synthesis through structural analysis, the potential of...
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Structural and electrical transport properties of Pr-doped SrTi0.93Co0.07O3-δ a novel SOEC fuel electrode materials
PublicationSolid Oxide Electrolyzer Cells (SOECs) are very promising electrochemical devices for the production of syngas (H2/CO) by H2O and CO2 co-electrolysis. The structure, microstructure and electrical properties of the fuel electrode material play a crucial role in the performance of the whole cell and efficiency of electrocatalytic reduction of steam into hydrogen. In the present work, a novel Co and Pr co-doped SrTiO3-δ material attracted...
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Instantaneous electrochemical impedance spectroscopy of electrode reactions
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Continuous‐Frequency Method of Measurement of Electrode Impedance
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Continuous frequency method of measurement of electrode impedance.
PublicationPrzedstawione zostały matematyczne podstawy nowej metody pomiaru impedancji elektrodowej. Metoda wykorzystuje sygnał pobudzenia którego częstotliwość zmienia się liniowo w czasie. Amplituda sinusoidalnego niestacjonarnego pobudzenia jest stała. Zapis i analiza sygnału pobudzenia i odpowiedzi pozwalana wyznaczenie ciągłego widma impedancyjnego. Jednoczesna analiza czasowo częstotliwościowa wykonano została przy użyciu transformacji...
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Instantaneous electrochemical impedance spectroscopy of electrode reactions.
PublicationUstalona została ciągła transformata STFT sinusoidalnego sygnału pobudzeniai odpowiedzi prądowej dla pierwszorzędowej reakcji elektrodowej. Impedancja elektrodowa wyznaczona została w łącznej dziedzinie czasowo-częstotliwościowej. Wykonano pomiary reakcji redukcji Cd(II) na kapiącej elektrodzie rtęciowej w funkcji czasu. Zaprezentowano możliwość wyznaczania chwilowych widm impedancyjnych. Opisano czasowe charakterystyki rezystancji...
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Pumping effect measured by PIV method in a multilayer spike electrode EHD device for air cleaning
PublicationDust particles can be harmful for human health when inhaled. Particularly dangerous are submicrometer dust particles, which can contain traces of toxic elements and can easily penetrate into the human respiratory system. Thus, efficient devices for the air cleaning from submicrometer dust particles are needed. Recently, Katatani and Mizuno have proposed an electrohydrody- namic (EHD) device for air cleaning for submicrometer particles....
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The electrochemical response to BDD electrode functionalization with CD147 receptor
Open Research DataThis dataset contains the results of the electrochemical impedance spectroscopy (EIS) measurements of the boron-doped diamond (BDD) electrode functionalization with CD147 receptor. The functionalized electrode was then used for the electrochemical detection of the SARS-CoV-2 virus S1 protein.
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The electrochemical response to BDD electrode functionalization with ACE2 receptor
Open Research DataThis dataset contains the results of the electrochemical impedance spectroscopy (EIS) measurements of the boron-doped diamond (BDD) electrode functionalization with ACE2 receptor. The functionalized electrode was then used for the electrochemical detection of the SARS-CoV-2 virus S1 protein.
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The electrochemical response to BDD electrode functionalization with IgG2B receptor
Open Research DataThis dataset contains the results of the electrochemical impedance spectroscopy (EIS) measurements of the boron-doped diamond (BDD) electrode functionalization with IgG2B receptor. The functionalized electrode was then used for the electrochemical detection of the SARS-CoV-2 virus S1 protein.
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Pumping effect measured by PIV method in multi-layer spike electrode EHD device for air cleaning
PublicationDust particles can be harmful for human health when inhaled. Especially dangerous are submicron dust particles, which can contain traces of toxic elements and can easily penetrate into human respiratory system. Thus, new devices for air cleaning are needed. In this work the flow velocity field patterns measured by Particle Image Velocimetry (PIV) method in an electrohydrodynamic (EHD) device for air cleaning are presented. The...
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Single-step grown boron doped nanocrystalline diamond-carbon nanograss hybrid as an efficient supercapacitor electrode
PublicationDirect synthesis of nano-structured carbon hybrid consisting of vertically aligned carbon nanograss on top of boron-doped nanocrystalline diamond is demonstrated and the carbon hybrid is further applied as an electrode material for the fabrication of supercapacitor. The hybrid film combines the dual advantages of sp2 (carbon nanograss) and sp3 (nanocrystalline diamond) bonded carbon, possessing not only the excellent electrical...
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The Influence of Titania Electrode Modification with Lanthanide Ions Containing Thin Layer on the Performance of Dye-Sensitized Solar Cells
PublicationThe lanthanide and scandium groups ions (except Pm and Ac) have been used as dopants of TiO2 film in dye-sensitized solar cells. The X-ray diffraction spectra show that the modification has no influence on the structure of the electrode; however, the diffuse reflectance UV-Vis measurements exhibit significant changes in the electronic properties of modified electrodes. The appearance of energy barrier preventing photoexcited electron...
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Electrochemical glucose sensor based on the glucose oxidase entrapped in chitosan immobilized onto laser-processed Au-Ti electrode
PublicationThe study on novel electrode material composed of structured titanium foil with embedded Au nanoparticles and modified with chitosan with entrapped glucose oxidase is presented. To confirm the successful immobilization of glucose oxidase FT-IR analysis was performed. The response of electrodes were tested towards glucose in the presence of different interference compounds and biological fluids. The prepared material exhibits excellent...
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Size-controlled synthesis of gold nanoparticles by a novel atmospheric pressure glow discharge system with a metallic pin electrode and a flowing liquid electrode
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Frequency dispersion of harmonic components of the current of an electrode process
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Fundamental-harmonic impedance of first-order electrode reactions
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Determination of electrode impedance by means of exponential chirp signal
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An active electrode for mixed measurement techniqes, with application to EIT
PublicationW pracy przedstawiono budowę elektrody aktywnej wraz z opisem procedur pomiarowych prowadzących do poprawy stosunku sygnał-szum. Elektroda zbudowana jest w technice cyfrowo analogowej.
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Spatial sensitivity to the conductivity changes of a four electrode probe.
PublicationW artykule rozważana jest czułość przestrzenna, czteropunktowej, liniowej sondy na zmiany przewodności zachodzące w badanym materiale. Otrzymane wyniki wskazują, że czułość może być zarówno dodatnia i ujemna, tzn. wzrost przewodności może prowadzić zarówno do wzrostu lub do spadku mierzonej impedancji. W artykule rozważane są materiały zarówno izotropowe jak i anizotropowe. Uzyskane wyniki pozwalają wyjaśnić dlaczego niektóre...
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Determination of electrode impedance by means of exponential chirp signal.
PublicationPrzedstawiona została nowa metoda pomiaru impedancji elektrodowej. Jako pobudzenie zastosowany został niestacjonarny sygnał napięciowy, którego częstotliwość jest ekspotencjalną funkcją czasu. Zastosowanie zmodyfikowanej któtko-czasowej transformaty Fouriera (STFT) w analizie napięciowego pobudzenia i odpowiedzi prądowej pozwala na otrzymanie widma impedancyjnego.
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Functionalization of electrode surfaces with monolayers of azocompounds and gold clusters.
PublicationWłaściwości monowarstw z azokoron na powierzchni złota były badane przy pomocy woltametrii i STM. Powierzchnia przypadająca na cząsteczkę została wyznaczona przy pomocy woltametrii i wynosi 0,65 nm kwadratowych. Wartość ta jest zgodna z wyznaczoną w oparciu o monowarstwę utworzoną na granicy powietrze-woda techniką Langmir-Blodgett. Tworzenie się klasterów złota i innych struktur obserwowano przy pomocy STM w przypadku gdy złota...
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A probe for immittance spectroscopy based on the parallel electrode technique.
PublicationW pracy zaprezentowano konstrukcję sondy do spektroskopowych pomiarów immitancyjnych. Obliczono jej stałą, którą to wartość zweryfikowano eksperymentalnie. Pokazano przykładowe wyniki pomiarów in vivo.
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The Influence of Electrode Impedance on the Parameters of Visual Evoked Potentials
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Carbon Based Electrode Materials and their Architectures for Capacitive Deionization
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New ferromagnetic mesh electrode material for electroanalytical applications
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The Dependence of Electrode Impedance on the Number of Performed EEG Examinations
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The interference between electrode and poly(ethylene oxide) electrolytes
PublicationSpektroskopia impedancyjna zastosowana została do scharakteryzowania granicy faz elektroda-elektrolit poli(oksyetylenowy) zawierający sole litu. Udział rozpuszczalnika w pojemności wewnętrznej warstwy, Cs(σ), dla CH3(OCH2CH2 )nOCH3 DLA N=4,8,10 oraz dla PMEO [(CH2CH2O)mCH2O]m m=5-10 został wyznaczony z wartości pojemności warstwy sztywnej pomniejszonej o udział metalu CM. Wyznaczono wartość pojemności dipolowej Ci(dip) dla PEO...
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Electrochemical detection of bacterial endotoxin lipopolysaccharide (LPS) on gold electrode modified with DAL-PEG-DK5-PEG-OH - Antimicrobial peptide conjugate
PublicationThis work describes fabrication of gold electrodes modified with peptide conjugate DAL-PEG-DK5-PEG-OH that enables ultra-sensitive detection of lipopolysaccharide (LPS) isolated from the reference strain of Escherichia coli O26:B6. The initial step of the established procedure implies immobilization of the fully protected DAL-PEG-DK5-PEG-OH peptide on the surface of the gold electrode previously modified by cysteamine. Then side...
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A dual-control strategy based on electrode material and electrolyte optimization to construct an asymmetric supercapacitor with high energy density
PublicationMetal-organic frames (MOFs) are regarded as excellent candidates for supercapacitors that have attracted much attention because of their diversity, adjustability and porosity. However, both poor structural stability in aqueous alkaline electrolytes and the low electrical conductivity of MOF materials constrain their practical implementation in supercapacitors. In this study, bimetallic CoNi-MOF were synthesized to enhance the electrical...
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Fast method for the determination of the charge transfer coefficient of an electrode reaction
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Dynamic electrochemical impedance spectroscopy of the first order electrode reaction
PublicationCiągłe transformaty STFT sinusoidalnego sygnału pobudzenia i odpowiedzi prądowej zostały wyznaczone dla reakcji elektrodowej pierwszego rzędu. Wyznaczono impedancję elektrody w łącznej dziedzinie czasu i częstotliwości. Wykonano pomiary dla reakcji redukcji Cd(II) na rtęciowej elektrodzie kroplowej w funkcji potencjału. Przedstawiono możliwość wyznaczenia chwilowych widm impedancyjnych. Opisano zależność rezystancji przeniesienia...
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Properties of electrode modified with poly(3,4-ethylenedioxytiophene) and Pt particles.
PublicationWłaściwości warstw polimerowych poli(3,4-etylenodioksytiofenu)z cząstkami platyny zbadano pod względem zastosowania do reakcji utlenienia związków organicznych. Stwierdzono, bez wnikania w mechanizmy i kinetykę reakcji, że właściwości fizyczne jak i chemiczne (zdolność do katalizowania reakcji utlenienia alkoholi) zależą od materiału podłoża: Pt, węgiel szklisty, tytan, złoto.
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Paraxial parameters and aberration of seven-electrode axisymmetric cathodic lens
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On the coupling of hydride generation with atmospheric pressure glow discharge in contact with the flowing liquid cathode for the determination of arsenic, antimony and selenium with optical emission spectrometry
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Facile synthesis and characterization of graphene and N-doped graphene by CVD method from liquid precursors for promising electrode materials
PublicationIn this study, high-quality and few-layered graphene was synthesized using the chemical vapor deposition (CVD) method from liquid sources. Two different liquid carbon sources, pyridine, and benzene, were used and deposited on nickel foam under heat conditions using a bubbler in a quartz tube. X-ray diffraction (XRD) and Raman analysis confirmed the crystalline properties of graphene and N-doped graphene, demonstrating the high...
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Preparation and Characterization of Nanomaterial Consisting of Silica Aerogel & Carbon Tested as an Electrode in Non-Aqueous Media Containing Lithium Salt.
PublicationSilica aerogel (SiO2ag) was combined with carbonaceous material in the pyrolysis process of hydrocarbons. The obtained nanocomposite SiO2ag/C was amorphous, partially preserving the porous structure of SiO2ag. The specific surface area changes from 445.6 m2/g for pure SiO2ag to 205.52 m2/g SiO2ag/C. The 29Si MAS-NMR shows a three-dimensional matrix with silicon atoms connected to other silicon atoms by four...
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Enhanced electrochemical performance of partially amorphous La0.6Sr0.4CoO3-δ oxygen electrode materials for low-temperature solid oxide cells operating at 400 °C
PublicationThis work evaluates partially amorphous La0.6Sr0.4CoO3-δ (LSC) as a potential oxygen electrode for lowtemperature solid oxide cells. LSC was deposited using the spin-coating technique onto Ce0.8Gd0.2O2-δ (CGO) substrates. The optimal oxygen electrode thickness was determined as 500 nm. The electrochemical impedance spectroscopy (EIS) study showed a significant improvement in oxygen reduction/oxidation reaction kinetics when annealing...
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Study of oxygen electrode reactions on symmetrical porous SrTi0.30Fe0.70O3-δ electrodes on Ce0.8Gd0.2O1.9 electrolyte at 800 °C–500 °C
PublicationIron doped strontium titanates (SrTi1-xFexO3-δ) are an interesting mixed ionic-electronic conductor model used to study basic oxygen reduction/oxidation reactions. In this work, we performed an impedance spectroscopy study on symmetrical porous SrTi0.30Fe0.70O3-δ (STF70) electrodes on a ceriabased electrolyte. The sample was measured in varying oxygen concentration: from 0.3% to 100% in 800 °C - 500 °C temperature range. Low polarisation...
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The electrochemical response to Au electrode modification steps towards viral electrochemical immunosensor preparation
Open Research DataThe dataset contains the electrochemical measurements (CV/EIS) carried out for the consecutive steps of the Au electrode functionalization, in separate subfolders, as described. The cyclic voltammetry (CV) was conducted using a Palmsens 4 potentiostat/galvanostat system (Methrom, Autolab, Netherlands) in the standard three-electrode configuration, with...
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The electrochemical studies of CB-PLA electrode after surface activation by proteinase K digestion
Open Research DataThe dataset contains the electrochemical studies performed to evaluate surface activation of the CB-PLA 3D printed electrodes by enzymatic hydrolysis in a solution containing proteinase K (72h digestion period). Different enzyme concentrations were evaluated: 0.2, 0.4, 0.6 and 0.8 mg/ml. The studies were performed before surface activation, during and...
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Theoretical description of fundamental-harmonic impedance of a two-step electrode reaction
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