Search results for: AU-TI HETEROSTRUCTURE
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Proton-Electron Hole Interactions in Sr(Ti,Fe)O3−δ Mixed-Conducting Perovskites
PublicationOxides in which total electrical conductivity is determined by the partial conductivities of three types of charge carriers i.e. holes/ electrons, oxygen ions, and protons are key components of well-functioning proton ceramic fuel cells. Apart from electrochemical properties also easily modified microstructure is an important feature of the electrodes. In the paper, a group of SrTi1−xFexO3−δ (STF, x = 0.2–0.8) perovskites prepared...
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Growth and properties of Ti-Cu films with respect to plasma parameters in dual-magnetron sputtering discharges
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Catalytic activity of Ni-MgAl2O4 modified with transition metal (Ti, Mo, W) carbides as potential catalysts for resource recovery via dry reforming of waste plastics
PublicationThe growing amounts of plastic waste and CO2 emissions are two environmental threats that require urgent attention. Pyrolysis combined with dry reforming (PCDR) is a technology that allows both CO2 utilization and resource recovery from waste plastic. New catalysts for PCDR are crucial for developing efficient and stable processes that can be widely implemented in the industry. In this study, Ni/MgAl2O4 catalysts modified using different...
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Canadian Ethnic Studies-Etudes Ethniques au Canada
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π-Stacking attraction vs. electrostatic repulsion: competing supramolecular interactions in a tpphz-bridged Ru(ii)/Au(iii) complex
PublicationThe synthesis and characterization of a mixed metal ruthenium(II)/gold(III) complex bridged by tetrapyridophenazine (tpphz) are described. It is isostructural and isoelectronic to the well-known photocatalysts with palladium(II) or platinum(II). Concentration dependent 1H-NMR spectroscopy and XRD studies show that the electrostatic repulsion between the gold(III) moieties exceeds the attractive π-stacking interaction. Theoretical...
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Tailoring the Stability of Ti-Doped Sr2Fe1.4TixMo0.6−xO6−δ Electrode Materials for Solid Oxide Fuel Cells
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Yield surface identification of CP-Ti and its evolution reflecting pre-deformation under complex loading
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Core/shell structured Ti/Si/C composite for high-performance zinc-ion hybrid capacitor
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Ultrafine-Grained Ti-31Mo-Type Composites with HA and Ag, Ta2O5 or CeO2 Addition for Implant Applications
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Crystal structure and physical properties of Mg6Cu16Si7-type M6Ni16Si7, for M=Mg, Sc, Ti, Nb, and Ta
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Synthesis and properties of porous Sr 0.96 Y 0.04 Ti 1−x Nb x O 3
PublicationA series of porous, single phase Sr0.96Y0.04Ti1-xNbxO3 samples was obtained using a wet synthesis method (modified citrate sol-gel) method. Temperature-programmed reduction (TPR) and temperature-programmed oxidation (TPO) measurements have shown high stability of the obtained material in variable (oxidizing/reducing) atmospheres. All samples exhibit high conductivity in hydrogen atmosphere with the highest value (around 1S/cm)...
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Adhesion of AlCrN coating deposited on TiB2/Ti composites sintered by SPS dedicated for high temperature tribological applications
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Characterization and Wear Response of Magnetron Sputtered W–B and W–Ti–B Coatings on WC–Co Tools
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Ocena odporności na zużycie ścierne stopów Ti na elementy pary trącej endoprotez stawu kolanowego
PublicationNajczęściej stosowanym biomateriałem tytanowym na elementy endoprotez stawu kolanowego jest stop Ti6Al4V. Z uwagi na zawartość wanadu, zaliczanego do pierwiastków o dużej toksyczności podejmowane są działania w kierunku zastąpienia wskazanego stopu - stopami bezwanadowymi. Jednym z najbardziej obiecujących jest stop Ti13Nb13Zr zawierający w swoim składzie jedynie pierwiastki witalne, niewywołujące stanów zapalnych i odczynów...
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Epoxidation of natural limonene extracted from orange peels with hydrogen peroxide over Ti-MCM-41 catalyst
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Metal (Mo, W, Ti) Carbide Catalysts: Synthesis and Application as Alternative Catalysts for Dry Reforming of Hydrocarbons—A Review
PublicationDry reforming of hydrocarbons (DRH) is a pro-environmental method for syngas production. It owes its pro-environmental character to the use of carbon dioxide, which is one of the main greenhouse gases. Currently used nickel catalysts on oxide supports suffer from rapid deactivation due to sintering of active metal particles or the deposition of carbon deposits blocking the flow of gases through the reaction tube. In this view,...
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Seismic Response Analysis of Knee-Braced Steel Frames Using Ni-Ti Shape Memory Alloys (SMAs)
PublicationShape Memory Alloys (SMAs) are known as active materials that can be widely used for structural purposes due to their flag-shape behavior under loading and reloading. Their unique characteristics provided a potential solution for civil engi-neers especially to model buildings with the capability of dissipating seismic en-ergy. In this study, the main purpose is to explore the seismic behavior of Knee-Braced Frames (KBFs) and...
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Application of Direct Current Atmospheric Pressure Glow Microdischarge Generated in Contact with a Flowing Liquid Solution for Synthesis of Au-Ag Core-Shell Nanoparticles
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Au nanoparticles identifiction with the use of AFM Volta potential mapping
Open Research DataThe specific physical, chemical and electrochemical electrical properties of gold nanoparticles have led to their extensive use as high-performance chemical and biochemical sensors. The described properties relate to surface plasmon resonance, fluorescence quenching or enhancement, high electrical conductivity and light scattering. The described nanoparticles...
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Ti-doped Sr2Fe1.4-xTixMo0.6O6-δ double perovskites with improved stability as anode materials for Solid Oxide Fuel Cells
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Evaluation of the relative thermoluminescence efficiency of LiF:Mg,Ti and LiF:Mg,Cu,P TL detectors to low-energy heavy ions
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Correlation between structural and electrical properties in highly porous (Y,Sr)(Ti,Nb)O3-delta SOFC anodes
PublicationIn order to find a relationship between structural and electrical properties, niobium and yttrium doped SrTiO3 ceramics were prepared via solid-state reaction. The samples were sintered in hydrogen and air conditions. The samples were also fabricated with a pore-former to obtain highly porous specimens. The electrical properties of Nb-doped SrTiO3 samples and yttrium and niobium co-doped SrTiO3 were compared. The comparable electrical...
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Synthesis, Characterization, and Catalytic Applications of the Ti-SBA-16 Porous Material in the Selective and Green Isomerizations of Limonene and S-Carvone
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Structural and Material Determinants Influencing the Behavior of Porous Ti and Its Alloys Made by Additive Manufacturing Techniques for Biomedical Applications
PublicationOne of the biggest challenges in tissue engineering is the manufacturing of porous structures that are customized in size and shape and that mimic natural bone structure. Additive manufacturing is known as a sufficient method to produce 3D porous structures used as bone substitutes in large segmental bone defects. The literature indicates that the mechanical and biological properties of scaffolds highly depend on geometrical features...
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Essais de fissuration sur adhésif au moyen d'un essai de clivage en coin instrumente, mise en œuvre et application.
PublicationL'essai de clivage en coin, plus communément appelle 'boeing wedge' test, est une méthode de référence pour qualifier la tenue mécanique a long terme des collages structuraux. Cette technique est particulièrement appréciée de par son faible cout et la simplicité de sa mise en ouevre. Elle consiste a précontraindre la colle en insérant un coin entre deux plaques assembles. L'énergie élastique ainsi stockée dans la structure...
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Badanie właściwości fotokatalitycznych, biobójczych i magnetycznych tlenku tytanu(IV) modyfikowanego nanocząstkami monoi bimetalicznymi Pt, Ag, Cu, Au oraz Pd
PublicationZakres badań obejmował otrzymywanie i charakterystykę nanokompozytów tlenku tytanu(IV) modyfikowanego mono- oraz bimetalicznymi nanocząstkami metali platyny, palladu, złota, srebra oraz miedzi. Zbadano wpływ zawartości metali, matrycy TiO2 oraz połączeniami metali na właściwości fotokatalityczne, biobójcze i magnetyczne otrzymanych nanokompozytów TiO2. Aktywność fotokatalityczną zbadano w reakcji degradacji modelowych związków oraz...
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ACS Materials Au
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Kα1,2x-ray linewidths, asymmetry indices, and[KM]shake probabilities in elements Ca to Ge and comparison with theory for Ca, Ti, and Ge
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Recent advances in the recovery of precious metals (Au, Ag, Pd) from acidic and WEEE solutions by solvent extraction and polymer inclusion membrane processes – a mini-review
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Synthesis and structural properties of (Y, Sr)(Ti, Fe, Nb)O3−δ perovskite nanoparticles fabricated by modified polymer precursor method
PublicationThe yttrium, iron and niobium doped-SrTiO3 powders have been successfully fabricated by a modified low–temperature synthesis method from a polymer complex. The usage of strontium hydroxide precursor instead of conventional strontium nitrate or strontium carbonate provides to the possibility of significant decrease of annealing temperature. It allows to prepare a material with sphere-shape grains of nanometric size (15–70 nm). The...
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Aitia-Regards sur la Culture Hellenistique au XXIe Siecle
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Canadian Biosystems Engineering / Le Genie des biosystems au Canada
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Fine-Tuning the Photocatalytic Activity of the Anatase {1 0 1} Facet through Dopant-Controlled Reduction of the Spontaneously Present Donor State Density
PublicationThe present study highlights the importance of the net density of charge carriers at the ground state on photocatalytic activity of the faceted particles, which can be seen as a highly underexplored problem. To investigate it in detail, we have systematically doped {1 0 1} enclosed anatase nanoparticles with Gd3+ ions to manipulate the charge carrier concentration. Furthermore, control experiments using an analogical Nb5+ doped...
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The conversion of multinuclear μ-oxo titanium(IV) species in the reaction of Ti(OiBu)4 with branched organic acids; results of structural and spectroscopic studies
PublicationW reakcji tetraizobutoksylanu tytanu z rozgałęzionymi kwasami karboksylowymi otrzymano szereg wielordzeniowych związków kompleksowych tytanu(IV). Otrzymane produkty scharakteryzowano wykorzystując techniki spektroskopowe: FTIR, 1H i 13C NMR oraz rentgenowską analizę strukturalną. Zaproponowano ścieżki reakcji prowadzące do konwersji poszczególnych związków w coraz stabilniejsze formy.
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Adrian Olejnik
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Electrostatic self-assembly approach in the deposition of bio-functional chitosan-based layers enriched with caffeic acid on Ti-6Al-7Nb alloys by alternate immersion
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Modyfikacja struktury i właściwości warstwy wierzchniej stopu tytanu Ti-6Al-4V otrzymywanej metod,a nadtapiania laserowego w warunkach ultraszybkiej krystalizacji
PublicationPokazano wyniki badań wpływu nadtapiania laserowego przy zastosowaniu różnej mocy lasera na grubość i mikrostrukturę warstwy wierzchniej oraz zużycie tribokorozyjne w roztworze Ringera. Wykazano, że nadtapianie, choć powoduje powierzchniowe spękanie, prowadzi do znacznego wzrostu odporności na zużycie tribokorozyjne. Przyczyną jest znaczny wzrost twardości materiału przy równoczesnym zacieraniu pęknięć.
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Alpha-pinene isomerization over Ti-SBA-15 catalysts obtained by the direct method: The influence of titanium content, temperature, catalyst amount and reaction time
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Effect of copper and silver modification of NH2-MIL-125(Ti) on the photoreduction of carbon dioxide to formic acid over this framework under visible-light irradiation
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Cahiers de Civilisation Espagnole Contemporaine-De 1808 Au Temps Present
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The Application of 2,6-Bis(4-Methoxybenzoyl)-Diaminopyridine in Solvent Extraction and Polymer Membrane Separation for the Recovery of Au(III), Ag(I), Pd(II) and Pt(II) Ions from Aqueous Solutions
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Impedance Evaluation of the Effect of Ru[sub 0.3]Ti[sub 0.7]O[sub 2] on Electrochemical Properties of Polymeric Conducting Electrodes Used in Cathodic Protection
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Absorbciâ vodoroda i povedenie vodoroda v slaâh titanovyh silavov s modificirovannoj poverhnost''û = Hydrogen absorption and hydrogen effects in the modified surface layers of Ti alloys
PublicationW pracy przedstawiono rezultaty badań absorpcji wodoru w stopach tytanu ze zmodyfikowaną za pomocą metod multipleksowych powierzchnią. W wyniku badań stwierdzono, iż po nadtapianiu laserowym w warunkach kriogenicznych, stopy tytanu wykazuja najwyższą zdolność absorpcji wodoru w wytworzonej warstwie wierzchniej.
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SEM images of tge gold nanostructures on silicon
Open Research DataAu nanostructures were prepared on Si(111) as a substrate. The substrates (1 × 1 cm2 of area) were cleaned with acetylacetone and then rinsed in ethanol. Thin Au films (with thicknesses in a range of 1.7–5.0 nm) were deposited using a table-top dc magnetron sputtering coater (EM SCD 500, Leica) under pure Ar plasma conditions (Argon, Air Products 99.999%)....
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The influence of synthesis method on the microstructure and catalytic performance of Y 0.07 Sr 0.93 Ti 0.8 Fe 0.2 O 3-δ in synthetic biogas operated solid oxide fuel cells
PublicationThe Y0.07Sr0.93Ti0.8Fe0.2O3-δ (YSTF) material was fabricated using three different synthesis methods: modified polymer precursor method (MPP), Pechini method and a solid state reaction method. It was applied as an anode catalytic material for biogas reforming in solid oxide fuel cells. Clear differences in the microstructure of fabricated catalytic layers were found, mainly with respect to a grain size and distribution of grains....
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Enhanced photocatalytic activity of transparent carbon nanowall/TiO2 heterostructures
PublicationThe synthesis of novel tunable carbon-based nanostructure represented a pivotal point to enhance the efficiency of existing photocatalysts and to extend their applicability to a wider number of sustainable processes. In this letter, we describe a transparent photocatalytic heterostructure by growing boron-doped carbon nanowalls (B-CNWs) on quartz, followed by a simple TiO2 sol-gel deposition. The effect on the thickness and boron-doping...
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Formation of gold anostructures detected by SEM microscope
Open Research DataGold nanostructures were prepared on silicon - Si(111) as a substrate. The substrates (1 × 1 cm2 of area) were cleaned with acetylacetone and then rinsed in ethanol. Thin Au films (with thicknesses in a range of 1.7–5.0 nm) were deposited using a table-top dc magnetron sputtering coater (EM SCD 500, Leica) under pure Ar plasma conditions (Argon, Air...
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Effect of the Cooling Time in Annealing at 350°C on the Phase Transformation Temperatures of a Ni<sub>5</sub><sub>5</sub>Ti<sub>4</sub><sub>5</sub> wt. Alloy
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Unités phraséologiques au pays de la traduction: transfert des collocations nomino-adjectivales avec le lexème «femme» dans la traduction de la littérature houellebecquienne du français vers l’italien et le polonais
PublicationThe present paper examines the transfer of nomino-adjectival collocations based on the word ‘femme’ (‘woman’) in the literary translation from French into Italian and Polish. The lexical connection analysed in the article can be defined as the habitual juxtaposition of a word with another word (or words) that has a significant frequency in a given language. The research corpus comprises seven Michel Houellebecq’s novels written...
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Simulation of signal acquisition from a rotary flowmeter
Open Research DataThe dataset contains results of simulation measuring the flow of homogeneous substances by rotational flow meter: a moment of impulse at the output of flow meter, time between successive pulses, number of pulses counted from standard generator and relative error of measurement.