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Search results for: BIOGAS ANALYSIS
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Comparison of AHP and Numerical Taxonomy Methods Based on Biogas Plant Location Analysis
PublicationThe paper presents a comparison of the multi-criteria Analytic Hierarchy Process (AHP) method and numerical taxonomy in biogas plant location selection. Biogas plants are sources that will significantly contribute to the implementation of the provisions of the energy and climate package for Poland by 2030. Increasing the share of energy produced from renewable sources, e.g. biogas plants, will increase the country’s energy security....
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Application of FMEA analysis for assessing reliability and risk in biogas-fueled engines operation process
PublicationW pracy zamieszczono propozycję wykorzystania analizy FMEA (ang. Failure mode and effects analysis) - analizy rodzajów i skutków możliwych błędów występujących w instalacjach przemysłowych z silnikami spalinowymi. Obserwowany w ostatnich latach rozwój energetyki rozproszonej, opartej na tłokowych silnikach spalinowych jest wynikiem m.in. prowadzonej polityki rozwoju wykorzystania odnawialnych źródeł energii (OŹE) związanej z zagospodarowaniem...
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Identification analysis of dynamic changes in the composition of biogas and their impact on the operation of internal combustion engines
PublicationW pracy zamieszczono wyniki badań składu biogazu pozyskiwanego na komunalnym wysypisku śmieci. Pozyskiwany biogaz jest wykorzystywany do zasilania biogazowych zespołów prądotwórczych wyposażonych w silniki o zapłonie iskrowym dostosowanych do zasilania tym paliwem. Pozyskiwany biogaz powstaje w sposób naturalny w procesie beztlenowej fermentacji zachodzącej przez ok. 20 lat, w organicznej części pryzmy odpadów składowanych na wysypisku...
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Comparative analysis of preliminary identification and characteristic of odour sources in biogas plants processing municipal waste in Poland
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Data analysis of FTIR spectra for study of outlet gases of Solid Oxide Fuel Cells fuelled by biogas
PublicationW pracy przedstawiono system umożliwiający połączenie spektroskopii FTIR z specjalnie zaprojektowanym oprogramowaniem w celu uzyskania informacji o stężeniach gazów wylotowych z ogniw paliwowych SOFC. Przebadane zostały główne produkty reformingu biogazu: tlenek węgla, dwutlenek węgla, metan oraz wodór. Opisane oprogramowanie umożliwia w prosty i szybki sposób uzyskanie informacji o gazach wylotowych ogniwa paliwowego.
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Techno-economic analysis of a hybrid energy system for electrification using an off-grid solar/biogas/battery system employing HOMER: A case study in Vietnam
PublicationThe electrification of off-grid /island villages is a critical step towards improving the techno-economic circumstances of rural regions and the overall general growth of the country. However, consistent supply from a single source is not possible in these areas. Thus, a hybrid renewable energy system performs better in these conditions. The research challenge now is to identify the optimal combinations of HRES from the available...
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Process Control of Biogas Purification Using Electronic Nose
PublicationNowadays, biogas produced from landfills and wastewater treatment plants or lignocellulosic biomass is important sustainable and affordable source of energy. Impurities from biogas stream can cause a serious odor problem, especially for residents of areas immediately adjacent to production plants. Therefore, biogas pre-treatment is necessary to protect engines that convert biogas into energy and in order to increase the specific...
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Lignocellulosic waste biosorbents infused with deep eutectic solvents for biogas desulfurization
PublicationThis paper introduces an innovative method for treating biogas streams, employing lignocellulosic biosorbents infused with environmentally friendly solvents known as deep eutectic solvents (DES). The primary focus of this study was the elimination of volatile organosulfur compounds (VSCs) from model biogas. Biosorbents, including energetic poplar wood, antipka tree, corncobs, and beech wood, were used, each with varying levels...
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Nitrogen transformation during fermentation in agricultural biogas plants
PublicationThe aim of the present study was to determine changes in the organic nitrogen fraction in the liquid fraction of the digestate during laboratory tests of mono- and co-digestion. Three agricultural wastes were tested: distillery residue, cattle slurry and corn silage. In the mono-fermentation tests, the initial total nitrogen concentration depended on the feedstock used. As a result of the hydrolysis and ammonification of the organic...
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Structural and catalytic properties of ceria layers doped with transition metals for SOFCs fueled by biogas
PublicationThe aim of this paper was to investigate an influence of the nanocrystalline Ce0.8A0.2O2-δ (A = Mn, Fe, Co, Ni, Cu) materials on the direct internal reforming of biogas in SOFC. Structural analysis of fabricated compounds has been done. An in-situ analysis of a composition of outlet gases from operating SOFC was performed using FTIR spectroscopy with simultaneous electrical tests. It was found out, that type of dopant strongly...
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Production of Biogas from Distillation Residue as a Waste Material from the Distillery Industry in Poland
PublicationIn this paper, the possibility to obtain an alternative source of energy from methane fermentation, catalysed by biomass, has been discussed in detail. As a main substrate, the distillation residue from the distillery industry was taken in the case of mono-fermentation and its co-fermentation with sewage sludge. The results showed that higher biogas and methane production can be obtained in a mono-fermentation process. Fermentation...
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Removal of Siloxanes from Model Biogas by Means of Deep Eutectic Solvents in Absorption Process
PublicationThe paper presents the screening of 20 deep eutectic solvents (DESs) composed of tetrapropylammonium bromide (TPABr) and glycols in various molar ratios, and 6 conventional solvents as absorbents for removal of siloxanes from model biogas stream. The screening was achieved using the conductor-like screening model for real solvents (COSMO-RS) based on the comparison of siloxane solubility in DESs. For the DES which was characterized...
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Green monoterpenes based deep eutectic solvents for effective BTEX absorption from biogas
PublicationThe combustion of biogas which contains significant amounts of monoaromatic hydrocarbons, i.e. benzene, ethylbenzene, toluene, and xylene (BTEX) can cause many technological, environmental, and health problems. Therefore, in these studies, a new physical absorption method based on deep eutectic solvents (DES) consisting of monoterpenes and carboxylic acids was developed for BTEX removal. A total of 39 DES were synthesized, of which...
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Absorptive Desulfurization of Model Biogas Stream Using Choline Chloride-Based Deep Eutectic Solvents
PublicationThe paper presents a synthesis of deep eutectic solvents (DESs) based on choline chloride (ChCl) as hydrogen bond acceptor and phenol (Ph), glycol ethylene (EG), and levulinic acid (Lev) as hydrogen bond donors in 1:2 molar ratio. DESs were successfully used as absorption solvents for removal of dimethyl disulfide (DMDS) from model biogas steam. Several parameters affecting the absorption capacity and absorption rate have been...
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Theoretical and Economic Evaluation of Low-Cost Deep Eutectic Solvents for Effective Biogas Upgrading to Bio-Methane
PublicationThis paper presents the theoretical screening of 23 low-cost deep eutectic solvents (DESs) as absorbents for effective removal of the main impurities from biogas streams using a conductor-like screening model for real solvents (COSMO-RS). Based on thermodynamic parameters, i.e., the activity coefficient, excess enthalpy, and Henry’s constant, two DESs composed of choline chloride: urea in a 1:2 molar ratio (ChCl:U 1:2), and choline...
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Deep eutectic solvents – based green absorbents for effective volatile organochlorine compounds removal from biogas
PublicationVolatile organochlorine compounds (VOXs) presented in biogas can cause many technological and environmental problems. During the combustion of biogas containing VOXs, the corrosion of installation, as well as the formation of toxic by-products (polyhalogenated dioxins and furans) and further emission to the atmosphere, may occur. Therefore, in this study, a new procedure based on physical absorption was developed. In order to meet...
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BIOGAS PRODUCTION FROM BAKERY WASTES -DYNAMICS, RETENTION TIME AND BIOGAS POTENTIAL
PublicationThis paper presents results of bakery-waste methane-fermentation. The scope of the study covers the determination of basic physicochemical parameters, process dynamics and retention time as well as biogas composition and biogas efficiency. Methane fermentation process was carried out in accordance with German Standard DIN 38414 S8 and under condition of 38°C. Conclusion: bakery wastes have big potential for biogas production.
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Development of a simple biogas analyzer module (BAM) for real-time biogas production monitoring
PublicationAnaerobic digestion (AD) relies on the cooperation of specific microbial communities, making it susceptible to process disruptions that could impact biogas production. In this regard, this study presents a technological solution based on the Arduino platform, in the form of a simple online monitoring system that can track the produced biogas profile, named as biogas analyzer module (BAM). The applicability of the BAM focused on...
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In situ study of a composition of outlet gases from biogas fuelled Solid Oxide Fuel Cell performed by the Fourier Transform Infrared Spectroscopy
PublicationThe purpose of this study was to develop a method and software based on the Fourier Transform Infrared Spectroscopy for the in-situ, quantitative analysis of the composition of outlet gases from Solid Oxide Fuel Cell (SOFC). The calibration procedure performed at the beginning of the experiment indicated a polynomial dependence between the concentration of a calibrating gas (CO, CO2, CH4) and the corresponding integrated absorbance in...
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Biomass in biogas production: Pretreatment and codigestion
PublicationGlobally, there is increasing awareness that the implementation of ‘waste to energy’ technology is one of the best means to achieve sustainable energy development. The most popular approach is the conversion of organic-rich compounds into clean and renewable products by anaerobic digestion (AD). Biogas can be produced from agricultural residues, municipal/industrial biowastes, and sustainable biomass, especially materials that...
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Utilization of ionic liquids for the enrichment of biogas
PublicationThis article discusses the dependence of biogas composition on organic feed material. High amounts of CO2 decrease the calorific value of biogas. Several technologies are reviewed which can be used to increase the calorific value. Special emphasis is laid on ionic liquids as a new absorbing material. ILs have a number of advantages due to their unique properties such as: low melting point, high thermal conductivity, no flammability,...
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Solid and liquid fractionation of sugarcane and Agave bagasse during ozonolysis and enzymatic hydrolysis: Impact on biohydrogen and biogas production
PublicationSustainable and cost-efficient lignocellulosic biomass-to-energy bioprocesses require assessing the main components released during biomass fractionation. This study assessed the mesophilic biochemical potential of biohydrogen (BHP) and methane production (BMP) from sugarcane bagasse (SCB) and cooked (CAB) and uncooked (UAB) Agave bagasse. A systematic comparative analysis was performed for the liquid and solid fractions derived...
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Seaweed utilization issues in biogas production
PublicationMacroalgae can be seen as a renewable feedstock for the production of biofuels in many coastal areas around the World and especially in Baltic Sea region where the eutrophication is particularly troublesome. The investigation of anaerobic digestion technologies for extracting inexhaustible bioenergy from seaweed was conducted in many research institutions mainly in laboratory scale. Although seaweeds seem to have a great potential...
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FORECASTING BIOGAS FORMATION IN LANDFILLS
Publication: The aim of the present research was to develop a mathematical model for estimating the amount of viscous gas generated as a function of weather conditions. Due to the lack of models for predicting gas formation caused by sudden changes in weather conditions in the literature, such a model was developed in this study using the parameters of landfills recorded for over a year. The effect of temperature on landfill gas production...
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Silver nanoparticles incorporated with superior silica nanoparticles-based rice straw to maximize biogas production from anaerobic digestion of landfill leachate
PublicationTreating hazardous landfill leachate poses significant environmental challenges due to its complex nature. In this study, we propose a novel approach for enhancing the anaerobic digestion of landfill leachate using silver nanoparticles (Ag NPs) conjugated with eco-friendly green silica nanoparticles (Si NPs). The synthesized Si NPs and Ag@Si NPs were characterized using various analytical techniques, including transmission electron...
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Real-time simulator of agricultural biogas plant
PublicationThis article presents a real-time simulator of an agricultural biogas plant. The project contains biogas and biomass circuits simulation, as well as heating circuit simulation with a complete control system and visualization interface of the whole process. The software tool used to simulate the plant work is CFD (Computational Fluid Dynamics), which enables a user to create and test simulation objects based on fundamental physical...
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Historical, technical and economic aspects of biogas development: Case Polanda and Ukraine
PublicationThe paper describes 3700 years of biogas manufacture with more details of last 120 years. Due to V. Omelianskij׳s researches 120 years ago, Ukrainians achieved a share in biogas manufacture in the overall biogas development. Poland started to take part in biogas development 96 years ago by finishing biogas plant in Posen 1928. History and current status of biogas plants achievements are collected and analyzed. Faults and achievements...
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Selected Problems of Cogeneration Energy Systems Designing, Fueled with Landfill Biogas
PublicationThe article discusses the impact of the quality of biogas fuel for operation of generating sets with internal combustion engines. There are presented selected investigation results of landfill biogas fueled gensets operation. The article includes also discussion of the possibility of increasing the efficiency of biogas fuelled cogeneration systems. It also presents guidelines for the optimal design of landfill biogas fueled engines,...
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Biogas Upgrading Using a Single-Membrane System: A Review
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Some problems with operation of engines fueled with landfill biogas
PublicationW referacie przedstawiono wybrane problemy związane z eksploatacją tłokowych silników spalinowych zasilanych biogazem pozyskiwanym z wysypiska śmieci. Biogaz wysypiskowy charakteryzuje się znaczną zmiennością zawartości metanu, co ma istostny wpływ na pracę silników zasilanych tym paliwem. W referacie przedstawiono wyniki badań przeprowadzonych na wysypisku śmieci, w wyniku których zaprezentowano zrówno wielkość zmian zawartości...
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Separation of CO2 from biogas using absorption columns
PublicationBiogaz zawiera ok. 50-70% metanu, 30-40% di tlenku węgla oraz niewielkie ilości innych związków jak siarkowodór czy amoniaku. Dla uzyskania wysokokalorycznego gazu konieczne jest usunięcie ze strumienia di tlenku węgla. Praca opisuje potencjał użycia do tego celu kolumn absorpcyjnych oraz cieczy jonowych jako absorbenta
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Purification of model biogas from toluene using deep eutectic solvents
PublicationBiogas from landfills and wastewater treatment facilities typically contain a wide range of volatile organic compounds (VOCs), that can cause severe operational problems when biogas is used as fuel. Among the contaminants commonly occur aromatic compounds, i.e. benzene, ethylbenzene, toluene and xylenes (BTEX). In order to remove BTEX from biogas, different processes can be used. A promising process for VOCs removal is their absorption...
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Environmental impact assessment of municipal biogas plants – case study
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Desiccant cooling system with direct fired biogas reactivitation heater.
PublicationPraca przedstawia możliwości wykorzystania w chłodnictwie i klimatyzacji gazu pochodzącego z biomasy. Spalanie gazu może zapewnić ciepło do zasilania zarówno absorpcyjnych urządzeń chłodniczych, jak i adsorpcyjnych urządzeń klimatyzacyjnych. Przedstawiono bieżące trendy występujące w konstrukcjach adsorpcyjnych urządzeń klimatyzacyjnych.
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CeCu2O4 as a functional layer on solid oxide fuel cells for synthetic biogas reforming
PublicationSolid Oxide Fuel Cells (SOFC) are one of the most promising electrochemical devices, which can convert chemical energy to the electrical energy these days. Their ability to work with different kind of fuel makes them noteworthy. SOFC can work with biogas. The problem arises when solid carbon starts to be deposited in anode. That leads to degradation of fuel cell. Simple solution is to apply catalytic functional layer, which is...
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Phosphorus and nitrogen forms in liquid fraction of digestates from agricultural biogas plants
PublicationThe novelty of the presented research is the determination of the nitrogen and phosphorus fraction in the liquid fraction of digestate from agricultural biogas plants. This information is important because it can help in proposing possible further liquid fraction management or developing of new technologies for their purification. The research covered digestates from agricultural biogas plants, obtained from the fermentation of...
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Sustainable energy system combined biogas-feedSolid Oxide Fuel Cell and Microalgae technology
PublicationIn the new frontier of energy and environmental safety, new efficient and clean safe energy conversion systems are required. In this sense, the present work is framed within the context of Circular Economy and proposes a multidisciplinary study for the development of more efficient, economically viable and non-polluting energy conversion systems, based on the synergetic combination of different technologies: fuel cells, biofuels,...
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New Carvone-Based Deep Eutectic Solvents for Siloxanes Capture from Biogas
PublicationDuring biogas combustion, siloxanes form deposits of SiO2 on engine components, thus shortening the lifespan of the installation. Therefore, the development of new methods for the purification of biogas is receiving increasing attention. One of the most effective methods is physical absorption with the use of appropriate solvents. According to the principles of green engineering, solvents should be biodegradable, non-toxic, and...
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Investigation of catalytic layers on anode for solid oxide fuel cells operating with synthetic biogas
PublicationIn this paper solid oxide fuel cells operating with dry synthetic biogas have been examined. In order to increase their stability the layers of CuO-CeO2, Cu1.3Mn1.7O4 and Y0.08Sr0.92Ti0.8Fe0.2O3 -δ have been deposited on the Ni-YSZ anode site. These layers should catalyze the internal biogas reforming and prevent the carbon deposition on the anode site. It has been found that CuO-CeO2 and Cu1.3Mn1.7O4 catalysts led to an increase...
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Investigation of functional layers of solid oxide fuel cell anodes for synthetic biogas reforming
PublicationSolid oxide fuel cells (SOFCs) are one of the most promising energy conversion devices due to their high efficiency, low pollution and fuel flexibility. Unfortunately, when hydrocarbons are used as a fuel, for example in the form of a biogas, solid carbon can deposit on the anode surface. This process leads to the degradation of the fuel cell performance. A possible solution to this problem is to apply an additional catalytic material,...
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Deodorization of model biogas by means of novel non-ionic deep eutectic solvent
PublicationThe paper presents new non-ionic deep eutectic solvent (DES) composed of natural and non-toxic components i.e. guaiacol, camphor and levulinic acid in 1:1:3 molar ratio as a promising absorbent for removal of selected volatile organic compounds (VOCs) including dichloromethane, toluene, hexamethyldisiloxane and propionaldehyde from model biogas. The affi nity of DES for VOCs was determined as vapour-liquid coeffi cients and the...
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Possibilities of Leachate Co-Treatment Originating from Biogas Production in the Deammonification Process
PublicationIn the methane fermentation process, sewage sludge is the single substrate or serves as a co-substrate with the addition of various waste products. After the treatment stable digestate is obtained, which consists of two phases solid and liquid. Liquid phase, called as a leachate, due to the high content of nutrients must be treated before they are discharged into the final receiver. Physical and chemical methods of leachate treatment...
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Copper and cobalt co-doped ceria as an anode catalyst for DIR-SOFCs fueled by biogas
PublicationThe nanocrystalline compounds of Co and Cu co-doped ceria (with up to 20 mol.% of dopants) were fabricated by the reverse microemulsion synthesis method. They were deposited in a form of layers on the surface of SOFC anode in an aim to act as electrochemically active materials for biogas reforming process. Fourier Transformed Infrared Spectroscopy was used to analyze a composition of outlet gases simultaneously with the tests of...
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The Impact of Technological Processes on Odorant Emissions at Municipal Waste Biogas Plants
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Biogas upgrading using supported liquid membranes based on ionic liquids
PublicationZastosowanie cieczy jonowych osadzonych w porach nośników polimerowych bądź ceramicznych jest nowoczesnym podejściem do separacji ditlenku węgla z mieszanin gazowych. Znikoma prężność par cieczy jonowych i możliwość modyfikacji budowy kationu i wyboru anionu wchodzących w skład cieczy jonowych sprawiają, że związki te mogą zastąpić obecnie stosowane w procesach separacji aminy. W publikacji przedstawiono wpływ struktury chemicznej,...
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Monitoring of absorptive model biogas purification process using sensor matrices and gas chromatography
PublicationThis study examined the process of purifying model biogas using a new type of absorbent based on a Deep Eutectic Solvent (DES) and a commercially available absorbent (Genosorb) to remove acetone, toluene, and cyclohexane. The main aim of the research was to control the purification efficiency using gas chromatography (GC) and an alternative method based on sensor matrices (SM). As a result of comparing the multidimensional SM signals...
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Investigation of praseodymium and samarium co-doped ceria as an anode catalyst for DIR-SOFC fueled by biogas
PublicationThe Pr and Sm co-doped ceria (with up to 20 mol.% of dopants) compounds were examined as catalytic layers on the surface of SOFC anode directly fed by biogas to increase a lifetime and the efficiency of commercially available DIR-SOFC without the usage of an external reformer. The XRD, SEM and EDX methods were used to investigate the structural properties and the composition of fabricated materials. Furthermore, the electrical...
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The Use of Chemical Sensors to Monitor Odour Emissions at Municipal Waste Biogas Plants
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Methods of Assessing Odour Emissions from Biogas Plants Processing Municipal Waste
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Ranking of Generation Source Locations by a Hybrid Multi-Criteria Method
PublicationThe paper presents a ranking of the locations of eight renewable energy sources (RES) made using a hybrid multi-criteria analysis method. The method is a combination of the analytical hierarchical process (AHP) method and numerical taxonomy. The considered generating sources, i.e. solar plants, biogas plants, and wind farms are sources that will significantly contribute to implementing the provisions of the energy and climate package...