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Search results for: LASER ABLATION IN WATER NANOCRYSTALLINE TITANIUM DIOXIDE
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Preparation of platinum modified titanium dioxide nanoparticles with the use of laser ablation in water
PublicationWe report on the preparation method of nanocrystalline titanium dioxide modified with platinum by using nanosecond laser ablation in liquid (LAL). Titania in the form of anatase crystals has been prepared in a two-stage process. Initially, irradiation by laser beam of a titanium metal plate fixed in a glass container filled with deionized water was conducted. After that, the ablation process was continued, with the use of a platinum...
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Nanoporous TiO2 electrode grown by laser ablation of titanium in air at atmospheric pressure and room temperature
PublicationRecently, fabrication of the nanoporous TiO2 photoelectrode on metal foils by means of sputtering of the Ti film on preheatedmetal substrate followed by the TiO2 deposition (doctor blade technique) and sintering represents the frequently applied technique. This is despite the relatively complicated procedure and number of parameters to be controlled in order to fabricate films of required properties. In this work an approach is...
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Review on robust laser light interaction with titania – Patterning, crystallisation and ablation processes
PublicationTitanium dioxide is regarded as a very promising semiconducting material that is widely applied in many everyday-use products, devices, and processes. In general, those applications can be divided into energy or environmental categories, where a high conversion rate, and energy and power density are of particular interest. Therefore, many efforts are being put towards the elaboration of novel production routes, and improving the...
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Investigation of the laser generated ablation plasma plume dynamics and plasma plume sound wave dynamics
PublicationWe investigated the dynamics of laser generated ablation plasma plume expanding in ambient air and dynamics of the sound wave generated by the expanding plasma. The ablation plasma plume was generated during nanosecond laser micromachining of the thin metal foil. The time-resolved images of the expanding plasma plume and sound wave were captured at several nanosecond intervals. Using captured images the expansion rate of the plasma...
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Impedance and cyclic voltammetry studies of GPLA electrodes after laser ablation
Open Research DataThe 3D printed GPLA electrodes present a brand new opportunity for electrode material for electrochemical biosensors. In order for the electrodes to be considered viable for electroanalysis studies, the pretreatment procedure must be applied in order to etch PLA matrix and reveal graphene filler. The following dataset presents an approach towards such...
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Aggregation of Rhodamine 6G in titanium dioxide nanolayers and bulk xerogels
PublicationNanolayers and bulk xerogels of Rhodamine 6G (Rh6G) in titanium dioxide (Rh6G/TiO2) were prepared using the sol–gel method. The spectroscopic and structural properties of these two types of hybrid matrices were studied as a function of dye concentration. In both cases absorption, fluorescence and time resolved emission spectra show the formation of fluorescent aggregates. The observed stronger changes in characteristics of bulk...
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Scaling Up the Process of Titanium Dioxide Nanotube Synthesis and Its Effect on Photoelectrochemical Properties
PublicationIn this work, for the first time, the influence of scaling up the process of titanium dioxide nanotube (TiO2NT) synthesis on the photoelectrochemical properties of TiO2 nanotubes is presented. Titanium dioxide nanotubes were obtained on substrates of various sizes: 2 × 2, 4 × 4, 5 × 5, 6 × 6, and 8 × 8 cm2. The electrode material was characterized using scanning electron microscopy as well as Raman and UV–vis spectroscopy in order...
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SEM-EDS images of expanded polystyrene spheres coated with silicon dioxide (SiO2) and/or titanium dioxide (TiO2)
Open Research DataData contain SEM and SEM-EDS images of expanded polystyrene spheres coated with silicon dioxide (SiO2) and/or titanium dioxide (TiO2). The detailed equipment and measurement data was described in measurement info.txt file.
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Tin oxide nanoparticles from laser ablation encapsulated in a carbonaceous matrix – a negative electrode in lithium-ion battery applications
PublicationThis report concerns carbonaceous electrodes doped with tin(II) oxide nanoparticles. Tin nanoparticles are obtained by pulsed laser ablation in water. Crystalline nanoparticles have been encapsulated in a carbonaceous matrix formed after pyrolysis of a mixture consisting of tin/tin(IV) oxide nanoparticles and gelatine. The obtained material is characterized by means of X-ray diffraction, selected area diffraction, scanning electron...
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Application of titanium dioxide thin films in fiber optic sensors
PublicationThe advance in the nanotechnology and fabrication of micro- and nanostructures has significant impact on development of new optical sensors. Presented study focuses on the applications of the titanium dioxide (TiO2) thin films in fiber optic sensors. The concept of a sensing fiber optic interferometer integrating TiO2 thin film is presented. The cavity of this interferometer is delimited by a 80 nm film fabricated on the end-face...
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Properties of surface layers of titanium alloy Ti6Al4V after laser melting processes
PublicationThe article presents the investigation results of titanium alloy Ti6Al4V surface layer after laser melting process. The process of laser melting was performed using Nd-YAG laser. The evaluation of structure of the alloy as well as hardness and chemical composition was performed. It was shown that laser melting changes the structure and properties of titanium alloy Ti6Al4V and process parameters as scanning speed affects the thickness...
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Influence of laser melting on surface layer properties of titanium alloy Ti6Al4V
PublicationIn time of rapid technology and medicine progress, implants are becoming more widely used in the human body, ranging from dental implants, stabilizing plates, screws, orthopaedic prostheses. For example, there are many types of hip prostheses used for hip replacement as well as various types of materials used for these orthopaedic prostheses. Properties of titanium alloys used in hip prostheses combined with good strength properties,...
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Influence of Surface Laser Treatment on Mechanical Properties and Residual Stresses of Titanium and its Alloys
PublicationSurface modification of the titanium and its alloys used in implantology with a long-pulse laser can change the surface topography, but it also leads to changes in the stress sign and magnitude in the resulting subsurface layer. The presented research was aimed at evaluating the state of stress after laser remelting with the Nd:YAG laser of pre-etched titanium alloys Ti6Al4V and Ti13Nb13Zr and pure titanium. The obtained surface...
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Influence of Laser Modification on the Surface Character of Biomaterials: Titanium and Its Alloys—A Review
PublicationLaser surface modification is a widely available and simple technique that can be applied to different types of materials. It has been shown that by using a laser heat source, reproducible surfaces can be obtained, which is particularly important when developing materials for medical applications. The laser modification of titanium and its alloys is advantageous due to the possibility of controlling selected parameters and properties...
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Influence of Laser Modification on the Surface Character of Biomaterials: Titanium and Its Alloys—A Review
PublicationLaser surface modification is a widely available and simple technique that can be applied to different types of materials. It has been shown that by using a laser heat source, reproducible surfaces can be obtained, which is particularly important when developing materials for medical applications. The laser modification of titanium and its alloys is advantageous due to the possibility of controlling selected parameters and properties...
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Effect of high loading of titanium dioxide particles on the morphology and selected properties of natural rubber-based composites
PublicationThe aim of this work was to prepare and characterize the natural rubber vulcanizates contained different amounts of titanium dioxide particles. At first rubber mixture was prepared using a laboratory two-roll mill and then samples were vulcanized in a hydraulic press. The formulation of rubber mixture and rubber-processing technique is based on our earlier investigations. Materials were obtained at the different titanium dioxide...
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Electrical properties of hybrid planar diode based on palladium phthalocyanine and titanium dioxide
PublicationThis work details experimental studies of a planar diode made of indium tin oxide/titanium dioxide/palladium phthalocyanine/gold. The rectification ratio of current was 105 at 1.5 V. The analysis of the electrical properties of the system was based on small signal complex capacitance spectra measured in the frequency range of 25 Hz-1 MHz at different values of bias. No depletion region at the TiO2/PdPc interface was observed. Forward...
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Laser-assisted modification of titanium dioxide nanotubes in a tilted mode as surface modification and patterning strategy
PublicationElectrochemical anodization is regarded as a facile and easily scalable fabrication method of titania nanotubes (TiO2NTs). However, due to the extended duration of calcination and further modifications, much faster alternatives are highly required. As a response to growing interest in laser modification of nanotube arrays, a comprehensive investigation of pulsed-laser irradiation and its effect onto TiO2NT properties has been carried out....
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Partial PLA composite surface activation by femtosecond laser ablation
Open Research DataThe dataset contains the studies on electrochemical activity of PLA composite (commercially available CB-PLA Protopasta), which was 3D printed in a form of 1x1cm electrodes. The electrodes were submitted to femtosecond laser ablation operating with different parameters. These were: gas atmosphere (He or air, data in different subfolders), the percentage...
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Mechanical Properties and Residual Stress Measurements of Grade IV Titanium and Ti-6Al-4V and Ti-13Nb-13Zr Titanium Alloys after Laser Treatment
PublicationNowadays, surface engineering focuses on research into materials for medical applications. Titanium and its alloys are prominent, especially Ti-6Al-4V and Ti-13Nb-13Zr. Samples made of pure grade IV titanium and the titanium alloys Ti-6Al-4V and Ti-13Nb-13Zr were modified via laser treatment with laser beam frequency f = 25 Hz and laser beam power P = 1000 W during a laser pulse with duration t = 1 ms. Subsequently, to analyze...
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Effect of Laser Treatment on Intrinsic Mechanical Stresses in Titanium and Some of Its Alloys
PublicationLaser surface treatment conducted at different power levels is an option to modify titanium bone implants to produce nano- and microtopography. However, such processing can lead to excess mechanical stress within the surface layer. This research aims to calculate the level of such residual stresses after the surface processing of Ti grade IV, Ti15Mo, and Ti6Al7Nb alloys with an Nd:YAG laser. Light and scanning electron microscopies...
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Partial PLA composite surface activation by femtosecond laser ablation
Open Research DataThe dataset contains the studies on electrochemical activity of PLA composite (commercially available CB-PLA Protopasta), which was 3D printed in a form of 1x1cm electrodes. The electrodes were submitted to femtosecond laser ablation, etching a certain % of the electrochemically-exposed electrode size. The % value is in the name of each file. The goal...
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The pulsed laser ablation synthesis of colloidal iron oxide nanoparticles for the enhancement of TiO2 nanotubes photo-activity
PublicationThe rapid, only a few minutes long synthesis of FeO, Fe3O4, and Fe2O3nanoparticles mixture utilizing the pulsedlaser ablation using simply pure iron target and water was demonstrated. The size and crystal phase of Fe-basedNPs were characterized using DLS and HR-TEM techniques, respectively. The metastable suspension of FeO,Fe3O4, and Fe2O3nanoparticles was used to the decoration of anodized TiO2nanotubes (TiO2-NTs) by means ofthe...
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Carbon Dioxide and Water Vapour Fluxes of a Alkaline Fen and Their Dependence on Reflectance
PublicationThis study shows results of parallel measurements of greenhouse gases fluxes (carbon dioxide and water vapour) and canopy reflectance of alkaline fen. Fluxes were measured using eddy-covariance technique on micrometeorological station located in the Upper Biebrza Basin (NE Poland) in Rogożynek Village. Study site is located in the Biebrza National Park which was established to protect one of the biggest coherent lowland wetland...
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Nanoindentation tests titanium alloy Ti-6Al-4V after interference laser treatment
PublicationThe study aimed was to assess selected mechanical properties of surface layers obtained after interference laser treatment – DLIL of titanium alloy Ti-6Al-4V used for implants. The samples were melted in still air at room temperature, for this purpose Nd:YAG laser was used, the number of laser shots was variable. Next, nanoindentation tests were performed, based on which Young’s modulus and nanohardness in the obtained surface...
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The topography of carbon black-polylactide composite 3D printed electrodes after femtosecond laser ablation
Open Research DataThis dataset contains a series of scanning electron microscopy images revealing the topography of 3D printed carbon black-polylactide composite electrodes after laser ablation with a femtosecond laser. Different laser powers were investigated, namely: 10%, 25%, 50%, 75% and 100%. The CB-PLA electrodes were 3D printed using an Ender printer. Femtosecond laser NKT Photonics, Origami XP parameters: power at 100%...
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Influence of plasmon resonance on the luminescence of titanium dioxide thin films doped with rare earth ions
PublicationIn this work the study of the optical properties of europium doped titanium dioxide thin films (TiO2:Eu) enhanced by gold plasmonic nanostructures are presented. Plasmonic platforms were manufactured by thermal annealing of thin film of Au, deposited on a Corning glass substrate. As a result of thermal treatment, gold spherical nanostructures with average dimensions of 50 nm were obtained. Luminescent TiO2:Eu film was deposited...
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Nanocrystalline Polymer Impregnated [Fe(pz)Pt(CN)4] Thin Films Prepared by Matrix-Assisted Pulsed Laser Evaporation
PublicationIn this work, the fabrication of [Fe(pz)Pt(CN)4] (pz = pyrazine) thin films by means of matrix-assisted pulsed laser evaporation (MAPLE) was investigated. As starting material, a cryogenically cooled suspension of anocrystalline [Fe(pz)Pt- (CN)4] (0.35wt.-%) in a mixture of 1,1-dichloroethane and polyethylene glycol (PEG) was used. Films of a thickness up to 150–200 nm were deposited on Si substrates by laser ablation at λ = 1064...
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Titanium Dioxide Nanoparticles: Prospects and Applications in Medicine
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The application of titanium dioxide for deactivation of bioparticulates: An overview
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Influence of titanium dioxide modification on the antibacterial properties
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Effect of pulse laser treatment at different process variables on mechanical behavior of carbon nanotubes electrophoretically deposited on titanium alloy
PublicationPurpose: Titanium and its alloys are widely used as biomaterials for long-term implants, but they are usually surface-modified due to their weak bioactivity and wear resistance. Laser processing was used to modify the surface layer, and elemental carbon was a component of the deposited coatings. This research aims to use a combination of both methods based on preliminary electrophoretic deposition of multi-wall carbon nanotubes...
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Solubility of carbon dioxide in water: Some useful results for hydrate nucleation
PublicationIn this paper, the solubility of carbon dioxide (CO2) in water along the isobar of 400 bar is determined by computer simulations using the well-known TIP4P/Ice force field for water and the TraPPE model for CO2. In particular, the solubility of CO2 in water when in contact with the CO2 liquid phase and the solubility of CO2 in water when in contact with the hydrate have been determined. The solubility of CO2 in a liquid–liquid...
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Carbon dioxide photoconversion. The effect of titanium dioxide immobilization conditions and photocatalyst type.
PublicationBadanie efektywności procesu fotokonwersji CO2 prowadzono w fazie gazowej w obecności promieniowania UV-Vis, pary wodnej oraz fotokatalizatorów. Zbadano wpływ wybranych parametrów tj. masa, temperatura i czas suszenia fotokatalizatora oraz rodzaj nośnika na efektywność procesu fotokonwersji. Wyznaczono optymalne parametry prowadzenia procesu oraz przedstawiono wstępne wyniki badań w obecności fotokatalizatorów modyfikowanych nanoczastkami...
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Functional phase bistability in a nanocrystalline RbMn[Fe(CN)6] thin film fabricated by matrix-assisted laser evaporation
PublicationOne of the main barriers hindering applications of Prussian blue metal assemblies is their poor processability, which makes the fabrication of intact thin films very difficult. In this work, a nanocrystalline RbMn[Fe(CN)6]·xH2O film on silicon substrate was obtained for the first time via laser-stimulated deposition and investigated. Temperature-induced phase transition and bistability within broad hysteresis loop (120 K), along...
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Nucleation and growth of CVD diamond on fused silica optical fibres with titanium dioxide interlayer
PublicationNucleation and growth processes of thin diamond films on fused silica optical fibres have been investigated. Fibres were coated with diamond film using microwave plasma enhanced chemical vapour deposition (µPE CVD) system. Since the growth of diamond on the fused silica glass requires high seeding density, two types of glass pre-treatment were applied: titanium dioxide (TiO2) interlayer deposition and sonication in nanodiamond...
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Fatigue of titanium alloy Ti6Al4V with diamond structure obtained by Laser Power Bed Fusion method
PublicationThis paper presents the results of fatigue tests conducted on Ti6Al4V titanium alloy with diamond structure obtained by the Laser Power Bed Fusion method. Samples used in tests were printed with porosities: 81%, 73%, 50%, 34% and near-zero porosity. Samples were subjected to cyclic tests with a constant stress amplitude. The number of cycles until sample failure was registered. Obtained fatigue test results made it possible to...
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Mechanical Properties and Wear Susceptibility Determined by Nanoindentation Technique of Ti13Nb13Zr Titanium Alloy after “Direct Laser Writing”
PublicationLaser treatment has often been applied to rebuild the surface layer of titanium and its alloys destined for long-term implants. Such treatment has always been associated with forming melted and re-solidified thin surface layers. The process parameters of such laser treatment can be different, including the patterning of a surface by so-called direct writing. In this research, pulse laser treatment was performed on the Ti13Nb13Zr...
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Concentration-Dependent Fluorescence Properties of Rhodamine 6G in Titanium Dioxide and Silicon Dioxide Nanolayers
PublicationWytworzono cienkie warstwy zawierające rodaminę 6G w dwutlenku tytanu (R6G/TiO2) i w dwutlenku krzemu (R6G/SiO2) stosując metodę zol-żel. Badane były dwa rodzaje matryc, w których domieszkowano barwnik rodamina 6G (R6G) o różnych koncentracjach. Został stwierdzony istotny wpływ koncentracji barwnika na widma absorpcji i emisji oraz na czasowo rozdzielone widma fluorescencji. W szczególności stwierdzono znacznie mniejszą zdolność...
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Nanostructure of the laser-modified transition metal nanocomposites for water splitting
PublicationAlthough hydrogen is considered by many to be the green fuel of the future, nowadays it is primarily produced through steam reforming, which is a process far from ecological. Therefore, emphasis is being put on the development of electrodes capable of the efficient production of hydrogen and oxygen from water. To make the green alternative possible, the solution should be cost-efficient and well processable, generating less waste...
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Caffeine detection using CB-PLA electrode after Nd:YAG laser ablation in He atmosphere
Open Research DataThe dataset contains electrochemical studies in form of cyclic voltammetry (CV) and differential pulse voltammetry (DPV) of laser-activated 3D printed CB-PLA electrodes. The ablation of the 3D-printed CB-PLA electrodes was carried out using a pulsed LaserBlast 500 Nd:YAG laser (Quantel, France) operating at 1064 nm and a 6 ns pulse duration.
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Preparation and photocatalytic activity of B-doped titanium dioxide
PublicationOtrzymano TiO2 domieszkowany borem, aktywny w reakcjach fotodegradacji pod wpływem światła widzialnego (λ>400 nm). Fotokatalizatory otrzymano poprzez hydrolizę tytanianu(IV) izopropylu w obecności związków boru lub poprzez ucieranie ST-01 z prekursorami B i następnie kalcynację w temperaturze 450stC. Jako źródło boru zastosowano kwas borowy (0,5 i 10%wag.) lub trietylo ester kwasu borowego (0,5; 1; 5 i 10%wag.). Najwyższą aktywność...
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Photocatalytic degradation using nitrogen-modified titanium dioxide
PublicationPrzepływowy reaktor z wypełnieniem został zastosowany do przeprowadzenia fotodegradacji 4-chlorofenolu za pomocą światła widzialnego. Fotokatalizator w postaci tlenku tytanu(IV) modyfikowanego azotem, został naniesiony na powierzchnię kulek szklanych. Źródło światła widzialnego stanowiła 8W lampa fluorescencyjna. Powietrze było w sposób ciągły przepuszczane przez zawartość reaktora.
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Antibacterial properties of laser-encapsulated titanium oxide nanotubes decorated with nanosilver and covered with chitosan/Eudragit polymers
PublicationTo provide antibacterial properties, the titanium samples were subjected to electrochemical oxidation in the fluoride-containing diethylene glycol-based electrolyte to create a titanium oxide nanotubular surface. Afterward, the surface was covered by sputtering with silver 5 nm film, and the tops of the nanotubes were capped using laser treatment, resulting in an appearance of silver nanoparticles (AgNPs) of around 30 nm in diameter...
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Effect of hybrid modification by ceramic layer formation in MAO process and laser remelting on the structure of titanium bio-alloy Ti13Nb13Zr
PublicationTo improve the biological properties of titanium alloy Ti13Nb13Zr, hybrid modifications involving micro-arc oxidation (MAO) and Nd: YAG laser remelting were carried out in two combinations. The first consisted of laser modification before the production of the ceramic layer by the micro-arc oxidation process, and the second combination involved Nd: YAG laser modification after the MAO process. The creation of developed surface...
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Photocatalytic decomposition of acetaldehyde over TiO2 (titanium dioxide) supported on nickel foam and Ni-doped (nickel-doped) TiO2
Open Research DataThis dataset contains chromatograms recorded during the decomposition of acetaldehyde in a high-temperature reaction chamber under UV irradiation using as photocatalytic systems TiO2 (titanium dioxide) supported on nickel foam, TiO2 supported on oxidized nickel foam and TiO2 doped by metallic nickel (Ni) powder. The detailed equipment and measurement...
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Images revealing the effect of local femtosecond laser ablation of conductive poly(lactic acid) 3D printed electrodes
Open Research DataThe dataset reveals the images of the femtosecond laser (FSL) ablation at the surface of commercially available carbon black-filled poly(lactic acid) 3D printed electrode. The process is used for the increase of the charge transfer of this electrode in electrochemical studies.
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Synthesis of Titanium Dioxide via Surfactant-Assisted Microwave Method for Photocatalytic and Dye-Sensitized Solar Cells Applications
PublicationIn this study, titania nanoparticles were obtained using the microwave-assisted technique. Moreover, different surfactants (PEG (Mn = 400), Pluronic P123 and Triton X−100) were used during the synthesis in order to determine their impact on the crystallinity and morphology of the final products. Subsequently, techniques such as XRD, SEM and TEM (performed in high contrast and high-resolution mode), diffuse reflectance spectroscopy...
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Optimized photodegradation of palm oil agroindustry waste effluent using multivalent manganese–modified black titanium dioxide
PublicationThis article presents a methodological approach to use manganese (Mn3+Mn7+)-modified black titanium dioxide (Mn/BTiO2) as a photocatalyst to optimize and improve visible-light-driven photodegradation of treated agro-industrial effluent (TPOME). A modified wet chemical process was used to prepare BTiO2. The BTiO2 was then wet impregnated with Mn and calcined at 300 °C for 1 h to produce Mn/BTiO2. The activity of Mn/BTiO2 was investigated...
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Modification of titanium dioxide towards photocatalytic activity in visible light
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