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Search results for: MIXED CONDUCTOR SOFC
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Structural properties of mixed conductor Ba1−xGd1−yLax+yCo2O6−δ
PublicationBa1−xGd1−yLax+yCo2O6−δ (BGLC) compositions with large compositional ranges of Ba, Gd, and La have been characterised with respect to phase compositions, structure, and thermal and chemical expansion. The results show a system with large compositional flexibility, enabling tuning of functional properties and thermal and chemical expansion. We show anisotropic chemical expansion and detailed refinements of emerging phases as La is...
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Investigation methods of ionic conductivity measurements in polycrystalline MIEC (mixed ionic-electronic conductor) based on perovskite ceramics
PublicationPaper about the measurements of ionic conductivity in LSM and strontium titanate ceramics.
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The Influence of Iron Doping on Performance of SrTi1-XFexO3-δ Perovskite Oxygen Electrode for SOFC
PublicationSolid Oxide Fuel Cells (SOFC) are based on electrolytes and mixed ionic and electronic conductivity (MIEC) materials. The need to reduce costs causes an increase in interest of new compounds suitable for operating temperatures between 600 °C and 800 °C. The SrTi1-xFexO3 (STF) perovskite material is a perspective material that could be used for the oxygen electrodes. In this work STF materials with different content of iron (x =...
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Ionic conductivity behavior by activated hopping conductivity (AHC) of barium aluminoborosilicate glass–ceramic system designed for SOFC sealing
PublicationNon-conducting BaO-B2O3-Al2O3-SiO2 parent glasses designed for solid oxide fuel cell (SOFC) sealing applications were prepared using the melt-quenching technique. The glass formation region was determined according to phase equilibrium relations and was found to be in the composition range 70BaO-(x)Al2O3-(10−x)B2O3-20SiO2 where 3.0 < x < 6.0 wt%. The conductivity values obtained conductivity ranged from 10−5 to 10−10 S/cm at temperatures...
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Hebb–Wagner polarization method for determining the oxygen ion conductivity in barium cerate-zirconate
PublicationIn this work, the partial conductivity of oxygen ions in BaCe0.6Zr0.2Y0.2O3 was studied at different temperatures and water partial pressures. For this purpose, a modified DC Hebb–Wagner polarization method with an electrode blocking for protons and electrons was used. A new type of measuring cell as well as a suitable calculation model were proposed for the determination of partial oxygen ionic conductivity in materials with three...
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CGO as a barrier layer between LSCF electrodes and YSZ electrolyte fabricated by spray pyrolysis for solid oxide fuel cells
PublicationPerovskite La0.6Sr0.4Co0.2Fe0.8O3 − δ (LSCF) is often used as a cathode material for solid oxide fuel cells (SOFC) due to high mixed ionic and electronic conductivity and good catalytic activity. Unfortunately, sintering of the LSCF cathode together with the yttria stabilized zirconia (YSZ) electrolyte, leads to formation of the La2Zr2O7 and SrZrO3 phases in the interface. These phases increase the resistance of the cell. To avoid...
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Study of oxygen electrode reactions on symmetrical porous SrTi0.30Fe0.70O3-δ electrodes on Ce0.8Gd0.2O1.9 electrolyte at 800 °C–500 °C
PublicationIron doped strontium titanates (SrTi1-xFexO3-δ) are an interesting mixed ionic-electronic conductor model used to study basic oxygen reduction/oxidation reactions. In this work, we performed an impedance spectroscopy study on symmetrical porous SrTi0.30Fe0.70O3-δ (STF70) electrodes on a ceriabased electrolyte. The sample was measured in varying oxygen concentration: from 0.3% to 100% in 800 °C - 500 °C temperature range. Low polarisation...
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Structural and electrical transport properties of Pr-doped SrTi0.93Co0.07O3-δ a novel SOEC fuel electrode materials
PublicationSolid Oxide Electrolyzer Cells (SOECs) are very promising electrochemical devices for the production of syngas (H2/CO) by H2O and CO2 co-electrolysis. The structure, microstructure and electrical properties of the fuel electrode material play a crucial role in the performance of the whole cell and efficiency of electrocatalytic reduction of steam into hydrogen. In the present work, a novel Co and Pr co-doped SrTiO3-δ material attracted...
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Impact of configuration of earth continuity conductor on induced sheath voltages in power cables
PublicationIn high voltage power cable systems a problem of induced sheath voltages exist. Due to these voltages electric shock and damage of non-metallic outer sheath of the cables may occur. Exposure to voltage of the outer sheath may be very high in case of earth fault with high value of earth current. In order to reduce induced sheath voltages an earth continuity conductor (conductors) along power cables is applied. Configuration of this...
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Impedance spectroscopy of single chamber SOFC.
PublicationMechanizm działania jednokomorowego ogniwa paliwowego SOFC, które pracuje w mieszaninie powietrza i paliwa, nie jest do końca zbadany. W tej pracy przedstawiono wyniki badań ogniwa paliwowego zbudowanego z tlenku cyrkonu stabilizowanego itrem jako nośnego elektrolitu, cermetu z tlenku niklu jako anody i perovskitu LSCF jako katody w temperaturach 500-700C z użyciem mieszaniny propanu i powietrza. Wykorzystując spektroskopię impedancyjną...
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Comparison of anode and electrolyte support configuration of single- chamber SOFC.
PublicationW pracy przedstawiono wyniki badań jednokomorowych ogniw paliwowych SOFC, wytworzonych na podłożu z anody i elektrolitu. Użyto typowych materiałów wykorzystywanych do budowy dwukomorowych ogniw paliwowych SOFC: elektrolit - domieszkowany tlenek cyrkonu, anoda - cermet niklowo cyrkonowy, katoda - lantanian strontowo manganowy. Ogniwa były przygotowane w technologii odlewania ceramicznego i sitodruku. Parametry syntezy katody były...
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Single chamber electrolyte supported SOFC module.
PublicationZaproponowano konstrukcję modułu składającego się z dwóch jednokomorowych ogniw paliwowych SOFC na nośnym elektrolicie. Moduł zbudowany jest z jednego substratu z tlenku ceru i domieszkowanym samarem oraz dwóch anod z cermetu na bazie tlenku niklu i dwóch katod z perovskitu LSCF. Przygotowano i zbadano moduły z różną powierzchnią elektrod, które były testowane w mieszaninach powietrza i propanu. Wielkość elektrod miała silny wpływ...
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Przegląd materiałów stosowanych w tlenkowych ogniwach paliwowych typu sofc
PublicationArtykuł przeglądowy opisujący nano i mikrokrystaliczne materiały elektrodowe i elektrolitowe stosowane obecnie do budowy ogniw paliwowych ze stałym elektrolitem tlenkowym (SOFC).
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Structural and electrical properties of STF materials for SOFC applications = Właściwości strukturalne i elektryczne materiałów STF do zastosowań w SOFC
PublicationTytaniany strontu domieszkowane elazem (STF) rozważane są jako potencjalne materiały katodowe w SOFC do pracy w temperaturach z przedziału 600-800°C. Ich synteza, właściwości elektrochemiczne i strukturalne są w tym artykule badane. Analiza wydajności elektrochemicznej przeprowadzono za pomoc elektrochemicznej spektroskopii impedancyjnej na symetrycznych komórkach spieczonych w różnych temperaturach. Wzajemne oddziaływanie chemiczne...
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Structure and electrical properties of Y, Fe-based perovskite mixed conducting composites fabricated by a modified polymer precursor method
PublicationIn this work, samples of Y0.07Sr0.93Ti1-xFexO3-d with 20, 40, 60 and 80 mol% of iron amount were prepared by a low-temperature polymer precursor method. The SEM-EDS analysis proved that analyzed Y0.07Sr0.93Ti1-xFexO3-d samples were composites of two Ti- and Fe-rich perovskite samples. This kind of composite consists of two phases in which one has a good ionic and the other electronic conductivity, which makes such a composite a...
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Modyfikowany tytanian strontu jako anoda do tlenkowych ogniw paliwowych typu sofc
PublicationPublikacja przeglądowa na temat sposobu modyfikacji materiału anodowego opartego na bazie perowskitu SrTiO3 pod względem możliwości zastosowania w ogniwach typu SOFC
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A note on mixed tree coloring
PublicationZaproponowano liniowy algorytm dla problemu kolorowania mieszanego w drzewach, uzyskując tym samym poprawę w stosunku do algorytmu o złożoności O(n^2) podanego w pracy [P. Hansen, J. Kuplinsky, D. de Werra, Mixed graph colorings, Math. Methods Oper. Res. 45 (1997) 145-160].
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Investigation of praseodymium and samarium co-doped ceria as an anode catalyst for DIR-SOFC fueled by biogas
PublicationThe Pr and Sm co-doped ceria (with up to 20 mol.% of dopants) compounds were examined as catalytic layers on the surface of SOFC anode directly fed by biogas to increase a lifetime and the efficiency of commercially available DIR-SOFC without the usage of an external reformer. The XRD, SEM and EDX methods were used to investigate the structural properties and the composition of fabricated materials. Furthermore, the electrical...
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Journal of Mixed Methods Research
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Minimization of Eddy Current Losses in a Straight Rectangular Cross Section Conductor
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Antimony substituted lanthanum orthoniobate proton conductor – structure and electronic properties.
PublicationX‐ray and neutron diffraction have been utilized to analyze the crystalline and electronic structure of lanthanum orthoniobate substituted by antimony. Using X‐ray absorption spectroscopy and photoelectron spectroscopy, changes in the electronic structure of the material upon substitution have been analyzed. The structural transition temperature between fergusonite and scheelite phases for 30 mol% antimony substitution was found...
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Nanocrystalline cathode functional layer for SOFC
PublicationRecently, it was shown that thin functional layers introduced between an electrolyte and cathode might improve cathode performance. However, the mechanism of this improvement still needs analysis. In this paper, a thin (∼140 nm), spin-coated perovskite layer (La0.6Sr0.4Co0.2Fe0.8O3-δ) was placed between a cathode (La0.6Sr0.4Co0.2Fe0.8O3-δ) and an electrolyte (Ce0.8Gd0.2O2-δ) and the effects of this investigated. The microstructure...
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Carbon activity coefficients of SOFC and SOFC with LSCNT layer fueled by biogas mixture at 750 C - longterm
Open Research DataThe dataset contains the calculated carbon activity coefficient for the SOFC and SOFC with LSCNT layer (La0.27Sr0.54Ce0.09Ni0.1Ti0.9O3-s) fueled by synthetic biogas mixture (60:40 CH4:CO2). The outlet concentration of the gases from SOFC were measured using novel FTIR-based unit.
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Protective coatings for stainless steel for SOFC applications
PublicationW pracy przedstawiono badania związane z warstwami antykorozyjnymi stali nierdzewnych stosowanych w tlenkowych ogniwach paliwowych. Warstwy przygotowana z użyciem prekursorów polimerowych na bazie Y i Co. Użyta stal to Crofer 22 APU.
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Role of composite cathodes in single chamber SOFC.
PublicationZbadano wpływ składu katody na napięcie oraz wydajność ogniw paliwowych pracujących w konfiguracji jednokomorowej. W związku z tym, że takie ogniwo pracuje w mieszanienie powietrza i paliwa, napięcie jest określone przez różnice aktywności katalitycznej anody i katody. Typowy cermet na bazie niklu oraz związki perovskitów pracują dobrze odpowiednio jako anoda i katoda. Jednakże perowskity mają również właściwości katalityczne,...
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Reaction quotients of reforming reactions for SOFC and SOFC with LSCNT layer fueled by biogas mixture at 750 C - longterm
Open Research DataThe dataset contains the calculated reaction quotients of reforming reactions for the SOFC and SOFC with LSCNT layer (La0.27Sr0.54Ce0.09Ni0.1Ti0.9O3-s) fueled by synthetic biogas mixture (60:40 CH4:CO2). The outlet concentration of the gases from SOFC were measured using novel FTIR-based unit.
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Change of exhaust gases concentration for reference SOFC and SOFC with LSCNT layer fueled by biogas mixture at 750 C
Open Research DataThe dataset changes of exhaust gases concentrations (CH4,CO,CO2,H2) over working time for SOFC with La0.27Sr0.54Ce0.09Ni0.1Ti0.9O3-s layer as well as reference SOFEC (unmodified). Concentrations were calculated based on the FTIR measurements and calibration curves presented in different dataset. Longterm measurements of SOFC were performed using in-house...
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Multi-fidelity robust aerodynamic design optimization under mixed uncertainty
PublicationThe objective of this paper is to present a robust optimization algorithm for computationally efficient airfoil design under mixed (inherent and epistemic) uncertainty using a multi-fidelity approach. This algorithm exploits stochastic expansions derived from the Non-Intrusive Polynomial Chaos (NIPC) technique to create surrogate models utilized in the optimization process. A combined NIPC expansion approach is used, where both...
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The Multiplatform Environment for Simulation and Features Estimation of Mixed-Signal Devices
PublicationThe use of simulation laboratories is gaining popularity in thedomains of engineering programs. However, the experience in teaching showsthat the simulation itself is not very effective in didactic processes. Teachingprocesses in thefield of specialist subjects, designed for students of technicaluniversities, should be based on direct operations performed by the student onreal devices. At the same time, at the later stages of didactic...
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The electrical properties mesurements of SOFC with Ce0.9Cu0.1O2-s functional layer
Open Research DataThe dataset includes the electrical properties mesurements of SOFC with Ce0.9Cu0.1O2-s layer. Samples were produced using aqueous soft chemistry methods (microemulsion method) and applied in form of a layer onto the anode of the commercial SOFC. The SOFC was working under biogas feeding at 750oC. The layers were sintered at 1100oC.
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The electrical properties mesurements of SOFC with Ce0.9Co0.1O2-s functional layer
Open Research DataThe dataset includes the electrical properties mesurements of SOFC with Ce0.9Co0.1O2-s layer. Samples were produced using aqueous soft chemistry methods (microemulsion method) and applied in form of a layer onto the anode of the commercial SOFC. The SOFC was working under biogas feeding at 750oC. The layers were sintered at 1100oC.
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The electrical properties mesurements of SOFC with Ce0.8Co0.1Cu0.1O2-s functional layer
Open Research DataThe dataset includes the electrical properties mesurements of SOFC with Ce0.8Co0.1Cu0.1O2-s layer. Samples were produced using aqueous soft chemistry methods (microemulsion method) and applied in form of a layer onto the anode of the commercial SOFC. The SOFC was working under biogas feeding at 750oC. The layers were sintered at 1100oC.
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The electrical properties mesurements of SOFC with Ce0.8Co0.15Cu0.05O2-s functional layer
Open Research DataThe dataset includes the electrical properties mesurements of SOFC with Ce0.8Co0.15Cu0.05O2-s layer. Samples were produced using aqueous soft chemistry methods (microemulsion method) and applied in form of a layer onto the anode of the commercial SOFC. The SOFC was working under biogas feeding at 750oC. The layers were sintered at 1100oC.
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The comparison of SrTi0.98Nb0.02O3–δ-CeO2 and SrTi0.98Nb0.02O3–δ-YSZ composites for use in SOFC anodes
PublicationComposites of Nb-doped strontium titanate mixed with yttria-stabilized zirconia or cerium oxide in 50:50, 70:30 and 85:15 weight ratios were evaluated as possible anode/electrolyte interface materials for solid oxide fuel cells in terms of chemical compatibility, electrical conductivity and mechanical properties. It has been shown that composite samples prepared by typical powder-mixing methods remain single-phase up to 1400°C....
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Composite (La, Sr)MnO3-YSZ cathode for SOFC
PublicationW pracy przedstawiono właściwości elektryczne kompozytów (La,Sr)MnO3-YSZ. Materiały te dzieki swoim włąściwościom mogą staniwć dobry materiał na katody ogniw paliwowych. Przedstawiono też wyniki badań ogniwa paliwowego pracującego z paliwem wodorowym zbudowanego na bazie katody z kompozytu LSM-YSZ i anody Ni-YSZ. Uzyskano gęstośc mocy 0.26 W cm−2 przy temperaturze 850°C.
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Evaluation of 316L porous stainless steel for SOFC support
PublicationW pracy przedstawiono wyniki badań stali typu 316L związanych z zastosowaniem w tlenowych ogniwach paliwowych.
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Donor-substituted SrTi1+xO3−δ anodes for SOFC
PublicationPrzebadano wpływ niestechiometrii na właściwości tytanianu strontu domieszkowanego niobem. Zaproponowano chemię defektów dla tego typu związków.
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Structural and Electrical Properties of STF Materials for SOFC Applications
PublicationW tym artykule przedstawiono badania tytanian strontu domieszkowanego żelazem. Synteza dwuetapowa była niezbędna do uzyskania czystego fazowo proszku o pożądanych właściwościach. Przewodnictwo elektryczne wykazało właściwości typu zero-TCR dla składu STF35. Poziom przewodnictwa elektrycznego różnił się o więcej niż jeden rząd wartości dla wytworzonych materiałów. Reaktywność chemiczną między YSZ i STF badano w zakresie temperatur...
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Donor-substituted SrTi1+xO3−δ anodes for SOFC
PublicationNonstoichiometric Nb-substituted SrTiO3 compounds were investigated in order to discuss the influence of nonstoichiometry at the sample properties in the light of recent results reported in the literature. Structural and electrical properties of samples were characterized. Investigated compounds were also applied as anodes for Solid Oxide Fuel Cells and their reactivity with YSZ electrolyte was examined. The defect chemistry explaining...
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Phosphinophosphoranes: Mixed-Valent Phosphorus Compounds with Ambiphilic Properties
PublicationHerein, we present a simple synthesis of mixed-valent phosphinophosphoranes bearing three- and five-coordinate phosphorus centers. Compounds with phosphorus–phosphorus bonds were synthesized via a reaction of lithium phosphides RR′PLi with cat2PCl (cat = catecholate), whereas derivatives with methylene-linked phosphorus centers were obtained via a reaction of phosphanylmethanides RR′CH2Li with cat2PCl. The presence of accessible...
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The electrical properties mesurements of SOFC with Ce0.8Pr0.15Sm0.05O2-s layer
Open Research DataThe dataset includes The electrical properties mesurements of SOFC with Ce0.8Pr0.15Sm0.05O2-s layer. Samples were produced using aqueous soft chemistry methods (microemulsion method) and applied in form of a layer onto the anode of the commercial SOFC. The SOFC was working under biogas feeding.
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The electrical properties mesurements of SOFC with Ce0.8Pr0.2O2-s layer
Open Research DataThe dataset includes The electrical properties mesurements of SOFC with Ce0.8Pr0.2O2-s layer. Samples were produced using aqueous soft chemistry methods (microemulsion method) and applied in form of a layer onto the anode of the commercial SOFC. The SOFC was working under biogas feeding.
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The electrical properties mesurements of SOFC with Ce0.8Sm0.2O2-s layer
Open Research DataThe dataset includes The electrical properties mesurements of SOFC with Ce0.8Sm0.2O2-s layer. Samples were produced using aqueous soft chemistry methods (microemulsion method) and applied in form of a layer onto the anode of the commercial SOFC. The SOFC was working under biogas feeding.
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The electrical properties mesurements of SOFC with Ce0.8Pr0.1Sm0.1O2-s layer
Open Research DataThe dataset includes The electrical properties mesurements of SOFC with Ce0.8Pr0.1Sm0.1O2-s layer. Samples were produced using aqueous soft chemistry methods (microemulsion method) and applied in form of a layer onto the anode of the commercial SOFC. The SOFC was working under biogas feeding.
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The electrical properties mesurements of SOFC with Ce0.8Pr0.05Sm0.15O2-s layer
Open Research DataThe dataset includes The electrical properties mesurements of SOFC with Ce0.8Pr0.05Sm0.15O2-s layer. Samples were produced using aqueous soft chemistry methods (microemulsion method) and applied in form of a layer onto the anode of the commercial SOFC. The SOFC was working under biogas feeding.
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Mixed 4-node shell element with assumed strain and stress in 6-parameter theory
PublicationWe propose a mixed hybrid 4-node shell elements based on Hu-Washizu principle. Apart from displacements both strains and stress fields are treated as independent fields. The element is derived in the framework of a general nonlinear 6-field shell theory with drilling rotation which is dedicated to the analysis of multifold irregular shells with intersections. The novelty of the presented results stems from the fact that the measures...
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Mixed 4-node shell element with assumed strain and stress in 6-parameter theory
PublicationWe propose a mixed hybrid 4-node shell elements based on Hu-Washizu principle. Apart from displacements both strains and stress fields are treated as independent fields. The element is derived in the framework of a general nonlinear 6-field shell theory with drilling rotation which is dedicated to the analysis of multifold irregular shells with intersections. The novelty of the presented results stems from the fact that the measures...
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Sensing properties of a mixed-potential type NOx sensor based on YSZ ceramic
PublicationW pracy przedstawiono wyniki badań czujnika typu ''mixed-potential''. Czujnik zbudowany jest na bazie YSZ z warstwą NiO. Zbadano właściwości czujnika w rożnych stężeniach NO2. Zbadano wpływ grubości warstwy NiO na właściwości czujnika.
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A testing method of analog parts of mixed-signal electronic systems equipped with the IEEE1149.1 test bus
PublicationA new solution of the JTAG BIST for testing analog circuits in mixed-signal electronic microsystems controlled by microcontrollers and equipped with the IEEE1149.1 bus is presented. It is based on a new fault diagnosis method in which an analog circuit is stimulated by a buffered signal from the TMS line, and the time response of the circuit to this signal is sampled by the ADC equipped with the JTAG. The method can be used for...
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Effects of Sr/Ti stoichiometry in SrTiO3-based SOFC anodes
PublicationScharakteryzowano wpływ stechiometrii Sr/Ti na właściwości strukturalne, elektryczne i mechaniczne anod na bazie tytanianu strontu. Wyjaśniono genezę niektórych zjawisk w oparciu o chemię defektów związków niestechiometrycznych na bazie istniejących pozycji literaturowych.