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Search results for: PEIERLS TRANSITION
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Nanostructure of the laser-modified transition metal nanocomposites for water splitting
PublicationAlthough hydrogen is considered by many to be the green fuel of the future, nowadays it is primarily produced through steam reforming, which is a process far from ecological. Therefore, emphasis is being put on the development of electrodes capable of the efficient production of hydrogen and oxygen from water. To make the green alternative possible, the solution should be cost-efficient and well processable, generating less waste...
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Potential energy curves, transition and permanent dipole moments of KRb
PublicationWe present extensive calculations of 48 adiabatic potential energy curves of the KRb molecule. Efforts have been focused on preparing the appropriate basis sets. Compared to previous approaches, the set of new potential energy curves is extended to higher excitations, including the single-excited K(4s2S)+Rb(5d2D) and double-excited K(4p2P)+Rb(5p2P) atomic limits. Larger distances between nuclei are also taken into account. New...
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Lattice Dynamics and Structural Phase Transitions in Eu2O3
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Storm petrels as indicators of pelagic seabird exposure to chemical elements in the Antarctic marine ecosystem
PublicationData on trace element bioavailability in the south-polar marine ecosystem is still scarce, compared to that relating to temperate zones. Seabirds can be used as indicators of ecosystem health and sentinels of environmental pollution, constituting a link between marine and terrestrial environments. Here, we analysed the concentration of 17 elements (with special emphasis on mercury, Hg) in feathers of adults and chicks of two pelagic...
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Early vascular ageing in translation
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Pressure-induced phase transition in LiLuF4:Pr3+investigated by an optical technique
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Optical processes in YVO4:Eu3+across zircon-to-scheelite phase transition
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Calix[4]arene-Thioamides as Ionophores for Transition and Heavy Metal Cations.
PublicationPochodne kaliks[4]arenów odgrywają ważną rolę jako materiał aktywny w membranowych elektrodach jonoselektywnych. Obecnie duży nacisk kładzie się na kontrolę stężeń kationów metali ciężkich, takich jak Pb, Cd, Hg, Cu w wodach naturalnych. Naszym zadaniem było zaprojektować i zsyntezować ligandy, które wykazują zdolność do wiązania kationów metali ciężkich i przejściowych. Synteza, struktury krystaliczne, ekstrakcja i właściwości...
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First-order magnetic transition in single-crystallineCaFe2As2detected byA75snuclear magnetic resonance
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Superconducting transition in granular Bi-Sr-Ca-Cu-O superconductors
PublicationW układzie(Bi,Pb)-Sr-Ca-Cu-O poprzez krystalizację w fazie stałej można wytworzyć materiały o bardzo różnych właściwościach elektrycznych i nadprzewodzących. W zależności od warunków krystalizacji, można wytworzyć nadprzewodnik o temperaturze krytycznej między 8 a 105 st. K lub materiał nie przechodzący do stanu nadprzewodzącego. Przejście do stanu nadprzewodzacego w materiałach granulastych ma charakter dwustopniowy. Zbadano wpływ...
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Application of Coordination Compounds with Transition Metal Ions in the Chemical Industry—A Review
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Order-Disorder Transition in 2D Conserved Spin System with Cooperative Dynamics
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Studies on the separation of some transition metals using trialkylimidazole as selective extractant
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Expression of Selected Epithelial-Mesenchymal Transition Transcription Factors in Endometrial Cancer
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Global energy transition: From the main determinants to economic challenges regions
PublicationDynamic global energy transition has been accelerating for the last decade. Interestingly, the energy transition is multidimensional and concerns both the dimensions of technique/ technology and the economic, social, institu-tional, and legal spheres (Shuguang et al., 2022; Tzeremes et al., 2022; Ram-zan et al., 2022; Tzeremes et al., 2022). The literature also points to the signif-icant impact of the digitization of the global...
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Calix[4]arene-Thioamides as Ionophores for Transition and Heavy Metal cations
PublicationCalix[4]arene derivatives play an important role as sensing materials in Ion Selective Electrodes(ISEs). Nowadays a high impact is put to control in natural waters the level of toxic heavy metals, like Pb ,Cd, Hg or Cu which may cause the great risk to human health. Our goal was to design and to synthesize ligands possessing ability to bind transition and heavy metal cations. The synthesis, crystal structures,extractive and ionophoric...
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Introduction to smart solutions for wastewater: Road-mapping the transition to circular economy
PublicationToday there is an urgent need to move from a linear to a circular economy approach with special focus to water and environment. Despite the paramount importance, this transition is hampered by barriers which concern not only technological but embrace also organizational, regulatory, social, and economic aspects. In order to overcome such barriers, innovative water-smart solutions are needed and a robust roadmap for the transition...
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A mobile loop order–disorder transition modulates the speed of chaperonin cycling
PublicationMolecular machines order and disorder polypeptides as they form and dissolve large intermolecular interfaces, but the biological significance of coupled ordering and binding has been established in few, if any, macromolecular systems. The ordering and binding of GroES co-chaperonin mobile loops accompany an ATP-dependent conformational change in the GroEL chaperonin that promotes client protein folding. Following ATP hydrolysis,...
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S-Shaped Suppression of the Superconducting Transition Temperature in Cu-Intercalated NbSe2
Publication2H-NbSe2 is the prototype and most frequently studied of the well-known transition metal dichalcogenide (TMDC) superconductors. As 2H-NbSe2 is widely acknowledged as a conventional superconductor, its transition temperature to the superconducting state (Tc) is 7.3 K, a Tc that is substantially higher than those seen for the majority of TMDCs, where Tc values between 2 and 4 K are the norm. Here we report the intercalation of Cu...
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Do Judges’ Delegations Affect Judicial Performance? A Transition Economy Evidence
PublicationThe aim of this study is to discern whether, by delegating judges from the court to the Ministry of Justice, the Minister of Justice influences the results of courts in terms of adjudication. The study used a unique set of data for the Polish judicial system over a period of five years. The research results indicate that there are three reasons for delegating judges. Firstly, the delegation system serves to fill staff shortages...
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Inferring perfect phylogenies with restrictions on character state transitions
PublicationZnana z klasycznej literatury metoda rekonstrukcji drzewa filogenetycznego zbioru gatunków na podstawie ich cech analizowanych w modelu doskonałej filogenezy często okazuje się niewystarczająca ze względu na założenia tego modelu, zmuszające do pominięcia znanych biologom informacji. W pracy definiujemy rozszerzenie umożliwiając wprowadzenie dla każdej cechy grafu skierowanego dopuszczalnych przejść ewolucyjnych pomiędzy jej stanami....
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Numerical Simulation of Open Channel Flow between Bridge Piers
PublicationPrzedstawiono dwuwymiarowy model przepływu wody płytkiej, który wykorzystano do symulacji przepływu wody w kanale otwartym w rejonie przekroju mostowego. Równania przepływu rozwiązano metodą objętości skończonych. Wyniki symulacji ruchu wody pomiędzy filarami mostowymi porównano z pomiarami laboratoryjnymi przeprowadzonymi w Laboratorium Hydrauliki i Inżynierii Środowiska politechniki Gdańskiej. Zgodność uzyskanych wyników obliczeń...
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Surface area investigation of materials with transition layers of continuously changing electron density
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Identification of multisite behavior in a broadly emitting transition-metal system using pressure
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Assessment of the effect of vegetation on the transition of the flood wave using hydraulic 2D models
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Restructuring of the Coal Mining Industry and the Challenges of Energy Transition in Poland (1990–2020)
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How Do Intermolecular Interactions Evolve at the Nematic to Twist–Bent Phase Transition?
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Anomalous Thermal Behavior of Salicylsalicylic Acid and Evidence for a Monotropic Transition to a Nematic Phase
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Apparent molar volumes of divalent transition metal bromides in dimethyl sulfoxide solutions
PublicationWyznaczono pozorne i cząstkowe molowe objętości bromków dwuwartościowych metali przejściowych szeregu Mn(II)-Zn(II)w roztworach w dimetylosulfotlenku. Przedyskutowano korelacje między objętościami molowymi a stanami koordynacyjnymi i sposobem jonizacji soli.
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Gel glass transition in silica and nitrided silica aerogels experiment and computer modelling.
PublicationPrzedstawiono dane eksperymentalne i symulacje komputerowe metodą dynamiki molekularnej procesu densyfikacji do szkła aerożeli krzemianowych i azotowanych aerożeli krzemianowych.
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On the fast BSS transition algorithms in the IEEE 802.11r local area wireless networks
PublicationHandover performance is critical to support multimedia services that are becoming increasingly available over the wireless devices. The high transition delay can be unaccepted for such services or can be a source of disruption on the session. On the other side, IEEE 802.11 standard is being extended with new functionalities. Security and QoS features, included in recent IEEE 802.11-2007 standard, add management frames that are...
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The time of the first transition of the semi-Markov process in the evaluation of diesel engine operation
PublicationW referacie przedstawiono rozwinięcie prezentowanej w literaturze metody ilościowej oceny działania na przykładzie okrętowego silnika głównego z zapłonem samoczynnym. Według tej interpretacji, działanie silnika może zostać przedstawione jako wielkość fizyczna. W tym aspekcie, na przykładzie okrętowego silnika napędu głównego dokonano oceny przydatności tej wielkości do opisu własności niezawodnościowych silnika. Precyzyjne określenie...
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Large magnetoresistance and first-order phase transition in antiferromagnetic single-crystalline EuAg4Sb2
Publicationpresent the results of a thorough investigation of the physical properties of single crystals using magnetization, heat capacity, and electrical resistivity measurements. High-quality single crystals, which crystallize in a trigonal structure with space group , were grown using a conventional flux method. Temperature-dependent magnetization measurements along different crystallographic orientations confirm two antiferromagnetic...
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Closing the gap – the opportunity for sustainability and smart transition in the Central and East Europe countries
PublicationFor almost half a century the countries of CEE were part of- or were remaining under the influence of- the Soviet Union what caused gaping difference in the starting line towards sustainability. Here the prefabricated concrete blocks of flats were being built at the scale unseen in the western countries. Those buildings, approximately a quarter of the residential market, are in a structurally sound condition to last another five...
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Possible quadrupole-order-driven commensurate-incommensurate phase transition in B20 CoGe
PublicationThe B20-type cobalt germanide CoGe was investigated by measuring the specific heat, resistivity, and 59Co nuclear magnetic resonance (NMR).We observed a phase transition at TQ = 13.7 K, evidenced by a very narrow peak of the specific heat and sharp changes of the nuclear spin-spin (T −1 2 ) and spin-lattice (T −1 1 ) relaxation rates. The fact that the entropy release is extremely small and the Knight shift is almost independent...
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Integrating Art into Places in Transition - Rose Kennedy Greenway in Boston as a Case Study
PublicationAmong the many projects realized in public spaces, some are truly unique – and these are the ones that build the identity of a place. The aim of this paper is to examine how integrating art and cultural strategies into public space can enhance and reinforce the sense of a place. Particular attention is devoted to urban spaces that we call “places in transition”, where public art improves the city’s imaginative capacity, enlivens...
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Transition-Metal-Promoted Oxidative Cyclization To Give 1,2,4-Trisubstituted Carbazole Scaffolds
PublicationHerein, we describe the synthesis of a 1,2,4-trisubstituted carbazole core from 5-(1H-indol-3-yl)-3-oxopentanoic acid esters or amides. For oxidative cyclization, we tested two different approaches. First, we used manganese triacetate as a conventional moderate oxidizer to ensure the radical course of the reaction. Second, we examined the use of a more complex oxidizing agent I2/Me(OTf)3. In both cases, formation of a fused-ring...
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A constitutive law for concrete with smooth transition from continuous into discontinuous cracks’ description
PublicationPaper presents a constitutive model for concrete that combines a continuous and discontinuous crack’s description to simulate the concrete under tensile dominated loads. In a continuum regime, two different constitutive laws were used. First, a plasticity model with the Rankine failure criterion and an associated flow rule was used. Second, a constitutive law based on isotropic damage mechanics was formulated. Both model alternatives...
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Powrót na wieś? Tradycja, nowoczesność, odnowiona tradycja = Back to the village? Tradition,modernity, renewed tradition.
PublicationW krajobrazie wiejskim obserwujemy gwałtowne zmiany. W globalnej rzeczywistości miasto atakuje wieś niszcząc jej kulturowy fenomen.Zachowanie piękna krajobrazu wiejskiego zależy dziś od wyjaśnienia społecznych i kulturowych uwarunkowań tego procesu. Należy podjąć temat erozji tradycji, zmiany społecznej i relacji pomiędzy wiedzą lokalną i specjalistyczną.
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Phase Transitions in Pores: Experimental and Simulation Studies of Melting and Freezing
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Thermal Transitions in P3HT:PC60BM Films Based on Electrical Resistance Measurements
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Sharp transitions in low-number quantum dots Bayesian magnetometry
PublicationWe consider Bayesian estimate of static magnetic field, characterized by a prior Gaussian probability distribution, in systems of a few electron quantum dot spins interacting with infinite temperature spin environment via hyperfine interaction. Sudden transitions among optimal states and measurements are observed. Usefulness of measuring occupation levels is shown for all times of the evolution, together with the role of entanglement...
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Greening Higher Education in Europe. Institutional Transitions to Sustainable Development
PublicationThis book provides a comprehensive overview of the advances made in European higher education institutions (HEIs) over the last twenty years in response to the challenges of sustainable development. In recent years, there has been a visible shift toward sustainable development, and universities have been addressing their accountability to the public through corporate social responsibility. Greening Higher Education in Europe explores...
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Adiabatic Compressibilities of Divalent Transition-Metal Perchlorates and Chlorides in N,N-Dimethylacetamide and Dimethylsulfoxide
PublicationZmierzono prędkości rozchodzenia się dźwięku roztworów nadchloranów i chlorków manganu(II), kobaltu(II), niklu(II), miedzi(II) i cynku(II) w N,N-dimetyloacetamidzie i dimetylosulfotlenku w temperaturze 298.15 K. Obliczono ściśliwości adiabatyczne i pozorne ściśliwości adiabatyczne badanych roztworów. Przedyskutowano wpływ anionu i rodzaju rozpuszczalnika na uzyskane graniczne wartości pozornych ściśliwości adiabatycznych soli.
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MicroscopicA75sNMR study of the effect of impurities on the first-order spin-density-wave transition inBaFe2As2
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The K x-ray line structures of the 3d-transition metals in warm dense plasma
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Mechanical properties and interfacial transition zone microstructure of concrete with waste basalt powder addition
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Origin of the liquid-liquid phase transition for trans-1,2-dichloroethylene observed by IR spectroscopy
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Family business as a breeding ground for nascent entrepreneurs. An insight into transition economy: the case of Poland
PublicationArtykuł przedstawia analizę zagadnienia zdolności firm rodzinnych do generowania postaw preprzedsiębiorczych na przykładzie Polski jako kraju o gospodarce transformującej się od centralnie sterowanej do rynkowej. Część empiryczna oparta jest wynikach pilotażowych badań przeprowadzonych na studentach pierwszego roku WZiE PG, które to wyniki posłużyły do stworzenia wstępnej wersji modelu opisującego determinanty procesu generowania...
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Apparent molar volumes of divalent transition metal perchlorates and chlorides in N,N-dimethylacetamide.
PublicationZmierzono gęstości roztworów nadchloranów i chlorków manganu(II), kobaltu(II), niklu(II), miedzi(II) i cynku(II) w temperaturach 10, 20,25, 30, 40, 50 i 60(o)C. Obliczono pozorne objętości molowe. Wyznaczono graniczne wartości cząstkowych molowych objętości tych soli oraz odpowiednie rozszerzalności. Przeanalizowano i wyjaśniono różnice we właściwościach wolumetrycznych roztworów nadchloranów i chlorków.