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Search results for: TRANSITIONS METALS
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Molecular Dynamics to Predict Cryo-EM: Capturing Transitions and Short-Lived Conformational States of Biomolecules
PublicationSingle-particle cryogenic electron microscopy (cryo-EM) has revolutionized the field of the structural biology, providing an access to the atomic resolution structures of large biomolecular complexes in their near-native environment. Today’s cryo-EM maps can frequently reach the atomic-level resolution, while often containing a range of resolutions, with conformationally variable regions obtained at 6 Å or worse. Low resolution...
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Structural phase transitions in multicomponent La0.2Nd0.2Sm0.2Gd0.2RE50.2NbO4 (RE5 = Ho, Y, Tb, Eu, Pr) oxides
PublicationIn this work, the influence of compositional complexity on the structural and thermal properties of multicomponent rare-earth ortho-niobates from the La0.2Nd0.2Sm0.2Gd0.2RE50.2NbO4 (RE5 = Ho, Y, Tb, Eu, Pr) series have been investigated. Based on X-ray powder diffraction studies using synchrotron radiation, it was found that all tested materials were pure single-phase compositions and showed stability in the monoclinic I2/c crystal...
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Natural Environments for Nanoparticles Synthesis of Metal, Metal Oxides, Core–Shell and Bimetallic Systems
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Phosphoroorganic Metal Complexes in Therapeutics
PublicationThe present mini-review highlights recent developments on antitumor activity of metal-based therapeutics which have been a subject of researches for the last few decades. In 1965, Rosenberg found that during an electrolysis on platinum electrodes a complex of Pt is generated which inhibited to a great extent a binary fission in Escherichia coli bacteria. This discovery started a new chapter in medicinal chemistry and the interesting...
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Possible quadrupole-order-driven commensurate-incommensurate phase transition in B20 CoGe
PublicationThe B20-type cobalt germanide CoGe was investigated by measuring the specific heat, resistivity, and 59Co nuclear magnetic resonance (NMR).We observed a phase transition at TQ = 13.7 K, evidenced by a very narrow peak of the specific heat and sharp changes of the nuclear spin-spin (T −1 2 ) and spin-lattice (T −1 1 ) relaxation rates. The fact that the entropy release is extremely small and the Knight shift is almost independent...
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Assessment of the effect of vegetation on the transition of the flood wave using hydraulic 2D models
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Restructuring of the Coal Mining Industry and the Challenges of Energy Transition in Poland (1990–2020)
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How Do Intermolecular Interactions Evolve at the Nematic to Twist–Bent Phase Transition?
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Anomalous Thermal Behavior of Salicylsalicylic Acid and Evidence for a Monotropic Transition to a Nematic Phase
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Surface area investigation of materials with transition layers of continuously changing electron density
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Closing the gap – the opportunity for sustainability and smart transition in the Central and East Europe countries
PublicationFor almost half a century the countries of CEE were part of- or were remaining under the influence of- the Soviet Union what caused gaping difference in the starting line towards sustainability. Here the prefabricated concrete blocks of flats were being built at the scale unseen in the western countries. Those buildings, approximately a quarter of the residential market, are in a structurally sound condition to last another five...
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Integrating Art into Places in Transition - Rose Kennedy Greenway in Boston as a Case Study
PublicationAmong the many projects realized in public spaces, some are truly unique – and these are the ones that build the identity of a place. The aim of this paper is to examine how integrating art and cultural strategies into public space can enhance and reinforce the sense of a place. Particular attention is devoted to urban spaces that we call “places in transition”, where public art improves the city’s imaginative capacity, enlivens...
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On the fast BSS transition algorithms in the IEEE 802.11r local area wireless networks
PublicationHandover performance is critical to support multimedia services that are becoming increasingly available over the wireless devices. The high transition delay can be unaccepted for such services or can be a source of disruption on the session. On the other side, IEEE 802.11 standard is being extended with new functionalities. Security and QoS features, included in recent IEEE 802.11-2007 standard, add management frames that are...
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The time of the first transition of the semi-Markov process in the evaluation of diesel engine operation
PublicationW referacie przedstawiono rozwinięcie prezentowanej w literaturze metody ilościowej oceny działania na przykładzie okrętowego silnika głównego z zapłonem samoczynnym. Według tej interpretacji, działanie silnika może zostać przedstawione jako wielkość fizyczna. W tym aspekcie, na przykładzie okrętowego silnika napędu głównego dokonano oceny przydatności tej wielkości do opisu własności niezawodnościowych silnika. Precyzyjne określenie...
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Gel glass transition in silica and nitrided silica aerogels experiment and computer modelling.
PublicationPrzedstawiono dane eksperymentalne i symulacje komputerowe metodą dynamiki molekularnej procesu densyfikacji do szkła aerożeli krzemianowych i azotowanych aerożeli krzemianowych.
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A constitutive law for concrete with smooth transition from continuous into discontinuous cracks’ description
PublicationPaper presents a constitutive model for concrete that combines a continuous and discontinuous crack’s description to simulate the concrete under tensile dominated loads. In a continuum regime, two different constitutive laws were used. First, a plasticity model with the Rankine failure criterion and an associated flow rule was used. Second, a constitutive law based on isotropic damage mechanics was formulated. Both model alternatives...
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Superconductivity in a breathing kagome metals ROs2 (R = Sc, Y, Lu)
PublicationWe have successfully synthesized three osmium-based hexagonal Laves compounds ROs2 (R = Sc, Y, Lu), and discussed their physical properties. LeBail refinement of pXRD data confirms that all compounds crystallize in the hexagonal centrosymmetric MgZn2- type structure (P63/mmc, No. 194). The refined lattice parameters are a = b = 5.1791(1) Å and c = 8.4841(2) Å for ScOs2, a = b = 5.2571(3) Å and c = 8.6613(2) Å for LuOs2 and a =...
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The speciation of selected heavy metals in sewage sludge stabilized in reed basins
PublicationThe aim of the work was to determine influence of time on organic matter content, nutrients concentrations as well as speciation of selected heavy metals (Cd, Pb, Ni, Cr, Cu and Zn) in sewage sludge stabilized in reed basins during 7-15 years. The analyzed sewage sludge was collected from reed basins from four municipal WWTPs located in Denmark serving from 9 000 to 40 000 pe in Vallo, Rudkøbing, Nakskov and Helsinge. Sewage...
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Removal and speciation of heavy metals in the constructed wetland treating landfill leachate
PublicationThe results of heavy metals removal and speciation of metals at two treatment wetlands receiving landfill are discussed. The first TW is a surface flow facility consisting of 10 ponds. The next TW is a newly constructed pilot-scale facility consisting of three beds with alternately vertical and horizontal sub-surface flow. The metals concentrations were analysed in leachate(both TWs) and bottom sediments (surface flow TW). Seasonal...
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Application of bismuth film electrode for determination of heavy metals by stripping voltammetry
PublicationWhen Wang's research group introduced a new type of a working electrode: bismuth film plated electrode (BiFE), it has started attracting increasing attention in the field of electrochemical stripping analysis. These electrodes are shown to be very attractive alternative to common mercury-based electrodes, which are predominantly used in analysis of trace heavy metals.For the determination of heavy metals (Zn, Cd, Pb, Cu) used square...
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Changes of heavy metals concentrations in the profile of sewage slugde in reed beds
PublicationW Polsce pojawiły się jedynie pilotowe obiekty trzcinowe unieszkodliwiające osady ściekowe. Natomiast w Danii są one eksploatowane w pełnej skali w dużych oczyszczalniach ścieków. Materiał badawczy pobrano z czterech duńskich obiektów o długim czasie eksploatacji wynoszącym od 7 do 15 lat. Obiekty te zlokalizowane były na terenie oczyszczalni: Rudkobing, Vallo, Naskov i Helsinge koło Kopenhagi obsługujących od 9 000 do 40 000 mieszkańców....
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Biosorption of toxic metals using freely suspended Microcystis aeruginosa biomass
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Accumulation and fate of selected heavy metals in biological wastewater treatment system
PublicationBadano akumulację oraz stopień usuwania metali ciężkich (Cd, Cu, Pb, Zn) w systemie biologicznego oczyszczania ścieków. Porównano zawartość wybranych metali w ściekach surowych i oczyszczonych, a także ich stężenie w osadzie czynnym przed i po beztlenowej stabilizacji.
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Diversity of microorganisms from forest soils differently polluted with heavy metals
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NANOCRYSTALLINE CATHODES FOR SOLID OXIDE FUEL CELLS MADE OF NOBLE METALS
PublicationCathodes for solid oxide fuel cells prepared by the infiltration method at 600 °C are presented. The infiltration method allows to produce stable, nanostructured electrodes. Cathodes were prepared using gold, platinum, La2NiO4+δ (L2N) and La0.6Sr0.4Co0.2Fe0.8O3 δ (LSCF). Symmetrical cathode/electrolyte/cathode samples were prepared and examined with SEM microscopy and electrochemical impedance spectroscopy. Despite successful deposition...
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Corrosion monitoring of selected metals in artificial seawater by harmonic synthesis method
PublicationPrzedstawiono podstawy teoretyczne nowej metody elektrochemicznej nazwanej metodą syntezy harmonicznej (SH). Metoda jest oparta na pomiarach pierwszych trzech składowych harmonicznych prądu generowanego przez korodującą elektrodę po pobudzeniu sinusoidalnym sygnałem napięciowym bardzo niskiej częstotliwości. Na tej podstawie rekonstruowana jest dyskretna quasi-stacjonarna charakterystyka polaryzacyjna elektrody. Jej analiza numeryczna...
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Removal and retention of selected heavy metals in components of a hybrid wetland system
PublicationProwadzone badania z określeniem możliwosci retencjonowania metali ciężkichw systemie hybrydowej oczyszczalni hydrofitowej. Wykazano, że znaczna rete- ncja tych pierwiastków następowała w wyniku sorpcji. Przeprowadzona ekstra- kcyjna analiza sekwencyjna wykazała, że Pb2+ i Cu2+ zostały zakumulowane w połączeniach trwałych i nie powinny ulegać wymywaniu z oczyszczalni. Nato- miast Cd2+ wskutek sorpcji we frakcjach labilnych może...
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Reductive cleavage of the halogen-phosphorus and sulfur-phosphorus bonds with alkali metals
PublicationBadano redukcję chlorków kwasów tiofosforowych za pomocą: sodu lub potasu w ciekłym amoniaku i za pomocą antracenidku oraz naftalenidku potasu. Związki te ulegają, co wykazano, szybkiej redukcji do anionów >P-S- a te mogą być efektywnie utleniane siarką elementarną w ciekłym amoniaku.
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Metal–metal interactions in bent cyano-bridged trinuclear octacyanomolybdate(IV)–platinum(IV) complexes
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Security of export transactions in the offer of leading banks on the Polish market
PublicationThe following article presents the so-called conditioned payment methods, i.e. instruments for securing export transactions, such as letter of credit, documentary collection, bank guarantees, factoring and forfaiting. The characteristics of each particular method are presented as well as the transactions using them are described. In the following paper, the author included also the leading Polish banks, which offer the above- mentioned...
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An analysis of the current situation for Polish ferry operators in a transitional environment
PublicationArtykuł rozpoczyna analiza sytuacji polskiej żeglugi promowej na tle procesów zachadzących w otoczeniu. W dalszej części została przedstawiona analiza SWOT, która wskazała główne problemy, którym muszą stawić czoła polscy armatorzy promowi. W pracy zaproponowano strategie marketingowe i dokano oceny ich roli w dalszym rozwoju badanych przedsiębiorstw promowych.
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DEM ANALYSIS OF EFFECT OF INTERFACIAL TRANSITIONAL ZONES ON FRACTURE IN CONCRETE.
PublicationArtykuł omawia wyniki numeryczne dotyczące pękania betonu uzyskane stosując metodę elementów dyskretnych. Trójwymiarowe obliczenia wykonano dla próbek betonowych podczas zginania. Beton został opisany jako model 4-fazowy. Mikrostrukturę betonu przyjęto na podstawie 3D zdjęć mikro-tomograficznych. Zbadano wpływ stref przejściowych na wytrzymałość i proces pękania. Wyniki numeryczne zostały porównane z wynikami doświadczalnymi. Uzyskano...
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Combining the MARTINI and Structure-Based Coarse-Grained Approaches for the Molecular Dynamics Studies of Conformational Transitions in Proteins
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Attaching an alkali metal atom to an alkaline earth metal oxide (BeO, MgO, or CaO) yields a triatomic metal oxide with reduced ionization potential and redirected polarity
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Nowe konstrukcje przekładkowe metal-pianka poliuretanowa = New sandwich plate systems metal - PU foam
PublicationWyznaczono statyczne własności mechaniczne przy ściskaniu, rozciąganiu oraz ścinaniu w óżnych kierunkach względem wzrostu piany oraz przy cyklicznych naprężeniach ściskających i ścinających. Stwierdzono różnice własności mechanicznych w zależności od kierunku i formy naprężeń.
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The unstable thermoelectric effect in non-stoichiometric Cu2Se during the non-equilibrium phase transition
PublicationThe superionic α ↔ β phase transition in Cu1.96Se thermoelectric material is investigated by means of thermal analysis (DSC) and measurements of Seebeck coefficient and electrical conductivity. Results of the DSC measurements with 1–10 K/min heating and cooling rates show that the material is close to the equilibrium phase composition during the transformation. However, the kinetic limitation of the process exists, which is indicated...
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Origin of the liquid-liquid phase transition for trans-1,2-dichloroethylene observed by IR spectroscopy
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Family business as a breeding ground for nascent entrepreneurs. An insight into transition economy: the case of Poland
PublicationArtykuł przedstawia analizę zagadnienia zdolności firm rodzinnych do generowania postaw preprzedsiębiorczych na przykładzie Polski jako kraju o gospodarce transformującej się od centralnie sterowanej do rynkowej. Część empiryczna oparta jest wynikach pilotażowych badań przeprowadzonych na studentach pierwszego roku WZiE PG, które to wyniki posłużyły do stworzenia wstępnej wersji modelu opisującego determinanty procesu generowania...
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MicroscopicA75sNMR study of the effect of impurities on the first-order spin-density-wave transition inBaFe2As2
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High temperature monoclinic-to-tetragonal phase transition in magnesium doped lanthanum ortho-niobate
PublicationMagnesium doped lanthanum ortho-niobate (La0.98Mg0.02NbO4) was prepared by the molten salt synthesis method. X-ray diffraction and dilatometry methods were used to study high temperature behavior of the ceramic material. Special attention was paid to the phase transition between the monoclinic and tetragonal phases. The values of spontaneous strain on the basis of unit cell parameter, obtained by Rietveld refinement, have been...
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Management of the transition spaces - comparison of the East European, West European and North American examples
PublicationArtykul dotyczy zagadnienia zagospodarowania przestrzeni stykowych pomiędzy strukturami portowymi i miejskimi w miastach portowych. Opisano w nim szereg przygkładów oraz zarysowano możliwe strategie zarządznaia tymi obszarami..
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Experimental comparison of the transition speed of a hydrodynamic journal bearing lubricated with oil and magnetorheological fluid
PublicationA journal bearing test bench is used to find the transition speed between the hydrodynamic and mixed lubrication regimes for a modified magnetorheological (MR) fluid. It is shown that the transition speed of the bearing can be reduced by applying a local magnetic field near minimum film when it is lubricated with the MR fluid, and that this will only marginally increase friction. The lubricating performance of the MR fluid is compared...
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Mechanical properties and interfacial transition zone microstructure of concrete with waste basalt powder addition
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Rotation Triggers Nucleotide-Independent Conformational Transition of the Empty β Subunit of F1-ATPase
PublicationF1-ATPase (F1) is the catalytic portion of ATP synthase, a rotary motor protein that couples proton gradients to ATP synthesis. Driven by a proton flux, the F1 asymmetric γ subunit undergoes a stepwise rotation inside the α3β3 headpiece and causes the β subunits’ binding sites to cycle between states of different affinity for nucleotides. These concerted transitions drive the synthesis of ATP from ADP and phosphate. Here, we study...
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Low-energy electron scattering from molecular hydrogen: Excitation of the X1Σg+ to b3Σu+ transition
PublicationWe present time-of-flight differential cross-section measurements and convergent close-coupling calculations of differential cross sections for the electron-impact excitation of the X 1 g + → b 3 u + transition in molecular hydrogen. A part of this work was recently published [M. Zawadzki et al., Phys. Rev. A 97, 050702(R) (2018)]. In this work, agreement between theory and experiment is excellent overall, and marks a transition...
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Superconductivity in Metal-Rich Chalcogenide Ta2Se
PublicationThe metal–metal bond in metal-rich chalcogenide is known to exhibit various structures and interesting physical properties. Ta2Se can be obtained by both arc-melting and solid-state pellet methods. Ta2Se crystallizes a layered tetragonal structure with space group P4/nmm (No. 129; Pearson symbol tP6). Each unit cell consists of four layers of body-centered close-packing Ta atoms sandwiched between two square nets of Se atoms, forming...
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Membranes for toxic- and heavy-metal removal
PublicationSince time ago, membranes have greatly attracted the attention of researchers for different types of water-treatment applications, such as wastewater treatment, water purification, removal of microorganisms, chemical compounds, and heavy metals. Nowadays, one of the current challenges of research community definitely deals with the removal of toxic and heavy metals from water. In this regard, the current chapter provides enough...
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Monitoring of metal structures with the dynamic methods
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Metal dusting in CCR platforming unit
PublicationPrzedstawiono mechanizm pylenia metalu w stali 9Cr-1Mo w instalacji platformingu CCR, na postawie badań rury podgrzewacza wsadu po 10 latach pracy, przy temperaturze metalu koło 600C. W badaniach wykorzystano techniki elektronowej mikroskopii skaningowej, dyfrakcji rentgenowskiej i mikroanalizy rentgenowskiej. Wykazano, że dyfuzji wegla w głąb stali toarzyszy odrdzeniowa dyfuzja pierwiastków węglikotwórczych - chromu i molibdenu....
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Metal dusting in CCR platforming unit
PublicationPrzedstawiono mechanizm pylenia metalu w stali 9Cr-1Mo w instalacji platformingu CCR, na postawie badań rury podgrzewacza wsadu po 10 latach pracy, przy temperaturze metalu koło 600C. W badaniach wykorzystano techniki elektronowej mikroskopii skaningowej, dyfrakcji rentgenowskiej i mikroanalizy rentgenowskiej. Wykazano, że dyfuzji wegla w głąb stali toarzyszy odrdzeniowa dyfuzja pierwiastków węglikotwórczych - chromu i molibdenu....